CN204073840U - Granule activated coke multistage suspension formula flue gas desulfur device - Google Patents
Granule activated coke multistage suspension formula flue gas desulfur device Download PDFInfo
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- CN204073840U CN204073840U CN201420525660.7U CN201420525660U CN204073840U CN 204073840 U CN204073840 U CN 204073840U CN 201420525660 U CN201420525660 U CN 201420525660U CN 204073840 U CN204073840 U CN 204073840U
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- Prior art keywords
- activated coke
- flue gas
- bed
- granule
- overflow pipe
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- 239000000571 coke Substances 0.000 title claims abstract description 93
- 239000008187 granular material Substances 0.000 title claims abstract description 50
- 239000003546 flue gas Substances 0.000 title claims abstract description 46
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000000725 suspension Substances 0.000 title claims abstract description 45
- 238000009826 distribution Methods 0.000 claims abstract description 25
- 239000000779 smoke Substances 0.000 claims abstract description 15
- 239000007789 gas Substances 0.000 claims abstract description 12
- 238000005303 weighing Methods 0.000 claims abstract description 11
- 239000011148 porous material Substances 0.000 claims description 5
- 238000006477 desulfuration reaction Methods 0.000 abstract description 17
- 230000023556 desulfurization Effects 0.000 abstract description 15
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003245 coal Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 abstract description 3
- 239000011593 sulfur Substances 0.000 abstract description 3
- 108090000623 proteins and genes Proteins 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000001172 regenerating effect Effects 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 230000003009 desulfurizing effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
The utility model provides a kind of granule activated coke multistage suspension formula flue gas desulfur device, belongs to energy environment protection technical field.This device comprises former smoke inlet, circumference joint, deflector, suspension bed, air distribution plate, overflow pipe, exhanst gas outlet and activated coke weighing feeding system; Suspension bed arranges 3 ~ 8 grades as required, containing SO
2former flue gas from bottom to top through multistage suspension bed bioreactor, contact with the activated coke in bed at different levels in multistage suspension bed bioreactor, removed the SO in former flue gas by the physical absorption of activated coke and chemisorption
2.Flue gas after desulfurization by deduster except deentrainment particle after by smoke stack emission.Granule activated coke is added by reactor head, moves from top to bottom.This device has that Sulfur capacity utilization rate is high, Pollutant-degrading gene is high, SR is little, activated coke wearing and tearing are little, initial cost and the feature such as operating cost is low, is applicable to very much the flue gas desulfurization in the few water area of rich coal.
Description
Technical field
The utility model relates to energy environment protection technical field, refers to a kind of granule activated coke multistage suspension formula flue gas desulfur device especially.
Background technology
Activated coke desulfurization technology is the flue gases purification that a kind of physical absorption-chemisorbed combines.Activated coke after absorption, through regeneration, can obtain sulfuric acid, liquid SO
2or the byproduct such as elemental sulfur, realize the recovery of Sulphur ressource.
Activated coke desulfurization technology because of efficient, water saving, can the advantages such as Sulphur ressource be reclaimed, become a kind of flue gas pollutant control technology being particularly suitable for the few water area of the rich coal of China.Activated coke desulfurization system mainly comprises flue gas desulfur device, regenerating unit, device for transporting objects and by-product production device.Flue gas desulfur device is the important component part of activated coke desulfurization system, determines desulfuration efficiency and the availability of desulphurization system.
At present, the principal mode that activated coke desulfurization device adopts has fixed bed, moving bed and fluid bed three kinds of forms, wherein, applies most often moving bed desulfurizer at present.
In fixed bed desulfurizer, active carbon is fixed in device, and the flue gas entered adsorbs in fixed bed, and after charcoal absorption is saturated, beginning switching device carries out the regeneration of adsorbent; Moving bed desulfurizer can realize continuous operation, and active carbon generally moves from top to bottom by gravity, and flue gas is horizontal or flow from bottom to top, with active carbon cross-flow or counter current contacting; Adsorption zone in fluidized bed desulfurizing device, flue gas and active carbon layer counter current contacting, reach the upper end storage tank that the saturated active carbon of absorption delivers to fluid bed, and be conveyed to renewing zone, the active carbon after regeneration enters adsorption zone downwards again.Fixed bed desulfurizer can run into the large and regeneration of air flow method inequality, pressure drop and switch the problems such as frequent when the exhaust gas volumn processed is large, and usually can only accomplish semicontinuous operation; Moving bed desulfurizer continuously-running, but there is the problems such as activated coke loss is larger; Then there is bad adaptability in fluidized bed desulfurizing device, to problems such as operation control overflow are high.
The activated coke that usual active coke desulphurizing device adopts is that Constitutive active is burnt, and conventional diameter is about 5 ~ 9mm, and length is about 10 ~ 20mm.Constitutive active Jiao obtains by being carried out by feed coal bonding, after shaping, carbonization and activation process, and price is relatively high.Meanwhile, Constitutive active is burnt also exists the larger problem of wearing and tearing in running.Therefore, this inevitably causes the problems such as the operating cost of desulfurizer is higher.Granule activated coke, can by the feed coal direct carbonization of certain particle size activation preparation activated coke in the fabrication process without the need to adopting bonding, moulding process, and manufacturing cost is compared can reduce by more than 80% with Constitutive active Jiao.Therefore, if active coke desulphurizing device adopts granule activated coke to substitute shaping activated coke as absorbent, greatly operating cost can be reduced.
At present, although granule activated coke has larger price advantage, when active coke desulphurizing adopts moving-burden bed reactor, reactor resistance will greatly increase for activated coke, and also may cause moving-burden bed reactor cannot continuous and steady operation.
Adopt moving-burden bed reactor to adopt granule activated coke resistance large and may continuous and steady operation to solve, and adopt the problem that the burnt price of Constitutive active is higher, need to research and develop novel granule activated coke desulfurization device.
Utility model content
The technical problems to be solved in the utility model is to provide a kind of granule activated coke multistage suspension formula flue gas desulfur device.
This flue gas desulfur device comprises desulfurizer straight section, also comprises former smoke inlet, deflector, circumference joint, air distribution plate, overflow pipe, exhanst gas outlet and activated coke weighing feeding system;
Wherein, former smoke inlet is saved by elbow be connected with circumference, and arrange deflector in elbow, after making flue gas enter reactor straight section, VELOCITY DISTRIBUTION is more even; Circumference joint is connected with desulfurizer straight section, and desulfurizer straight section is circular, and wherein arrange multistage suspension bed, suspension bed arranges 3 ~ 8 grades according to Practical Project parameter and required desulfuration efficiency; It is air distribution plate bottom suspension bed, granule activated coke holds up to suspended state formation granule activated coke bed by air distribution plate by flue gas, on air distribution plate perforate be convenient to granule activated coke by and formed suspended state, the percent opening of air distribution plate and opening diameter are determined according to parameters such as Practical Project parameter and activated coke particle diameters, pore size scope is 2 ~ 10mm, percent opening scope is 3% ~ 20%, and the arrangement in hole adopts equilateral triangle or arranged in squares; Overflow pipe top is on air distribution plate, bottom is goed deep in the granule activated coke bed of next stage suspension bed, ensure the downward conveying of granule activated coke in overflow pipe, the diameter of overflow pipe is determined according to absorbent granules size, be 30 ~ 80mm, the height of overflow pipe regulated according to the time of staying of granule activated coke, thus make between former flue gas and activated coke, to form contact fully and enough time of staying, and then ensure that the Sulfur capacity of activated coke maximizes the use, overflow pipe or outer overflow pipe in overflow pipe adopts; Connect exhanst gas outlet above desulfurizer straight section, activated coke weighing feeding system is positioned at the top of desulfurizer straight section.
This device application diameter is the granule activated coke of 1-8mm.
The beneficial effect of technique scheme of the present utility model is as follows:
In such scheme; granule activated coke can be made full use of; and granule activated coke multistage suspension formula flue gas desulfur device has that Sulfur capacity utilization rate is high, Pollutant-degrading gene is high, SR is little, activated coke wearing and tearing are little, initial cost and the advantage such as operating cost is low, can run continuously, is applicable to very much the flue gas desulfurization in the few water area of rich coal.
Accompanying drawing explanation
Fig. 1 is granule activated coke multistage suspension formula flue gas desulfur device schematic diagram of the present utility model;
Fig. 2 is air distribution plate schematic diagram in granule activated coke multistage suspension formula flue gas desulfur device of the present utility model;
Fig. 3 is overflow pipe schematic diagram in granule activated coke multistage suspension formula flue gas desulfur device of the present utility model.
[main element symbol description]
The former smoke inlet of 1-, 2-deflector, 3-has an area of joint, 4-air distribution plate, 5-granule activated coke bed, 6-overflow pipe, 7-exhanst gas outlet, 8-activated coke weighing feeding system.
Detailed description of the invention
For making the technical problems to be solved in the utility model, technical scheme and advantage clearly, be described in detail below in conjunction with the accompanying drawings and the specific embodiments.
As shown in Figure 1, for granule activated coke multistage suspension formula flue gas desulfur device schematic diagram of the present utility model, this device comprises desulfurizer straight section, also comprises former smoke inlet 1, deflector 2, circumference joint 3, air distribution plate 4, overflow pipe 6, exhanst gas outlet 7 and activated coke weighing feeding system 8; Wherein, former smoke inlet 1 is connected with circumference joint 3 by elbow; deflector 2 is set in elbow; circumference joint 3 is connected with desulfurizer straight section; in desulfurizer straight section, suspension bed is set; it is air distribution plate 4 bottom suspension bed; granule activated coke holds up to suspended state formation granule activated coke bed 5 by air distribution plate 4 by flue gas; overflow pipe 6 top is on air distribution plate 4; bottom is goed deep in the granule activated coke bed 5 of next stage suspension bed; connect exhanst gas outlet 7 above desulfurizer straight section, activated coke weighing feeding system 8 is positioned at the top of desulfurizer straight section.
As shown in Figure 2, be the schematic diagram of this device air distribution plate, the hole on air distribution plate can adopt triangular arrangement, also can adopt arranged in squares.As shown in Figure 3, be the overflow pipe schematic diagram of this device, overflow pipe or outer overflow pipe in overflow pipe adopts.
Embodiment 1
In actual applications, diameter is adopted to be that the granule activated coke of 1-6mm carries out flue gas desulfurization.Arrange 5 grades of suspension beds at desulfurizer straight section, air distribution plate used adopts equilateral triangle to arrange, its pore size is 6mm, and percent opening is 12%, and overflow pipe in overflow pipe adopts, its diameter is 50mm.
Containing SO
2former flue gas enter desulfurizer by former smoke inlet 1; and from bottom to top through 5 grades of suspension beds; contact with the activated coke in granule activated coke bed 5 at different levels in these 5 grades of suspension beds, removed the SO in former flue gas by the physical absorption of activated coke and chemisorption
2; Flue gas after desulfurization is delivered to after deduster dedusting by smoke stack emission by exhanst gas outlet 7; Granule activated coke is added by the activated coke weighing feeding system 8 of reactor head, granule activated coke by overflow pipe 6 from top to bottom step by step to the motion of lower floor suspension bed, adsorb saturated after activated coke deliver to activated coke regenerator and carry out regenerating rear recycling.
Embodiment 2
Employing diameter is that the granule activated coke of 1-2mm carries out flue gas desulfurization.Arrange 3 grades of suspension beds at desulfurizer straight section, air distribution plate used adopts equilateral triangle to arrange, its pore size is 2mm, and percent opening is 20%, and overflow pipe adopts outer overflow pipe, and its diameter is 30mm.
Containing SO
2former flue gas enter desulfurizer by former smoke inlet 1; and from bottom to top through 3 grades of suspension beds; contact with the activated coke in granule activated coke bed 5 at different levels in these 3 grades of suspension beds, removed the SO in former flue gas by the physical absorption of activated coke and chemisorption
2; Flue gas after desulfurization is delivered to after deduster dedusting by smoke stack emission by exhanst gas outlet 7; Granule activated coke is added by the activated coke weighing feeding system 8 of reactor head, granule activated coke by overflow pipe 6 from top to bottom step by step to the motion of lower floor suspension bed, adsorb saturated after activated coke deliver to activated coke regenerator and carry out regenerating rear recycling.
Embodiment 3
Employing diameter is that the granule activated coke of 1-8mm carries out flue gas desulfurization.Arrange 8 grades of suspension beds at desulfurizer straight section, air distribution plate used adopts arranged in squares, and its pore size is 10mm, and percent opening is 3%, and overflow pipe in overflow pipe adopts, its diameter is 80mm.
Containing SO
2former flue gas enter desulfurizer by former smoke inlet 1; and from bottom to top through 8 grades of suspension beds; contact with the activated coke in granule activated coke bed 5 at different levels in these 8 grades of suspension beds, removed the SO in former flue gas by the physical absorption of activated coke and chemisorption
2; Flue gas after desulfurization is delivered to after deduster dedusting by smoke stack emission by exhanst gas outlet 7; Granule activated coke is added by the activated coke weighing feeding system 8 of reactor head, granule activated coke by overflow pipe 6 from top to bottom step by step to the motion of lower floor suspension bed, adsorb saturated after activated coke deliver to activated coke regenerator and carry out regenerating rear recycling.
The above is preferred embodiment of the present utility model; should be understood that; for those skilled in the art; under the prerequisite not departing from principle described in the utility model; can also make some improvements and modifications, these improvements and modifications also should be considered as protection domain of the present utility model.
Claims (7)
1. a granule activated coke multistage suspension formula flue gas desulfur device; comprise desulfurizer straight section; it is characterized in that: also comprise former smoke inlet (1), deflector (2), circumference joint (3), air distribution plate (4), overflow pipe (6), exhanst gas outlet (7) and activated coke weighing feeding system (8); wherein
Multistage suspension bed is set in desulfurizer straight section;
Former smoke inlet (1) saves (3) by elbow with circumference and is connected; deflector (2) is set in elbow; circumference joint (3) is connected with desulfurizer straight section; it is air distribution plate (4) bottom every grade of suspension bed; granule activated coke bed (5) is positioned at bottom suspension bed at different levels; overflow pipe (6) top is on air distribution plate (4); bottom is goed deep in the granule activated coke bed (5) of next stage suspension bed; connect exhanst gas outlet (7) above desulfurizer straight section, activated coke weighing feeding system (8) is positioned at the top of desulfurizer straight section.
2. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: described desulfurizer straight section is for circular, and suspension bed arranges 3 ~ 8 grades as required.
3. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: the percent opening of described air distribution plate (4) is 3% ~ 20%.
4. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: the pore size of described air distribution plate (4) is 2 ~ 10mm.
5. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: the arrangement in the upper hole of described air distribution plate (4) adopts equilateral triangle or arranged in squares.
6. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: the diameter of described overflow pipe (6) is 30 ~ 80mm.
7. granule activated coke multistage suspension formula flue gas desulfur device according to claim 1, is characterized in that: overflow pipe or outer overflow pipe in described overflow pipe (6) adopts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420525660.7U CN204073840U (en) | 2014-09-12 | 2014-09-12 | Granule activated coke multistage suspension formula flue gas desulfur device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420525660.7U CN204073840U (en) | 2014-09-12 | 2014-09-12 | Granule activated coke multistage suspension formula flue gas desulfur device |
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| Publication Number | Publication Date |
|---|---|
| CN204073840U true CN204073840U (en) | 2015-01-07 |
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|---|---|---|---|
| CN201420525660.7U Withdrawn - After Issue CN204073840U (en) | 2014-09-12 | 2014-09-12 | Granule activated coke multistage suspension formula flue gas desulfur device |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104190244A (en) * | 2014-09-12 | 2014-12-10 | 北京国电清新环保技术股份有限公司 | Multi-stage suspension type flue gas desulfurization device for granular active coke and flue gas desulfurization method thereof |
| CN105709710A (en) * | 2016-03-03 | 2016-06-29 | 北京清新环境技术股份有限公司 | Multilayer fluidized bed parsing device for conducting pneumatic material return through row tube type heat exchange and coupling of molten salt |
| CN108686489A (en) * | 2017-04-12 | 2018-10-23 | 北京华石联合能源科技发展有限公司 | A kind of suspension bed wet desulfurizing process |
-
2014
- 2014-09-12 CN CN201420525660.7U patent/CN204073840U/en not_active Withdrawn - After Issue
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104190244A (en) * | 2014-09-12 | 2014-12-10 | 北京国电清新环保技术股份有限公司 | Multi-stage suspension type flue gas desulfurization device for granular active coke and flue gas desulfurization method thereof |
| CN105709710A (en) * | 2016-03-03 | 2016-06-29 | 北京清新环境技术股份有限公司 | Multilayer fluidized bed parsing device for conducting pneumatic material return through row tube type heat exchange and coupling of molten salt |
| CN108686489A (en) * | 2017-04-12 | 2018-10-23 | 北京华石联合能源科技发展有限公司 | A kind of suspension bed wet desulfurizing process |
| CN108686489B (en) * | 2017-04-12 | 2021-01-01 | 北京华石联合能源科技发展有限公司 | Suspension bed wet desulphurization process |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 100036 Beijing, Haidian District, west of the eight mile road, No. 69, people's Political Consultative Conference building, floor 9 Patentee after: BEIJING SPC ENVIRONMENT PROTECTION TECH CO., LTD. Address before: 100036 Beijing, Haidian District, west of the eight mile road, No. 69, people's Political Consultative Conference building, floor 9 Patentee before: Beijing SPC Environment Protection Tech Co., Ltd. |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20150107 Effective date of abandoning: 20160706 |
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| C25 | Abandonment of patent right or utility model to avoid double patenting |