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CN204054831U - High-resistant diaphragm can be printed - Google Patents

High-resistant diaphragm can be printed Download PDF

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Publication number
CN204054831U
CN204054831U CN201420396264.9U CN201420396264U CN204054831U CN 204054831 U CN204054831 U CN 204054831U CN 201420396264 U CN201420396264 U CN 201420396264U CN 204054831 U CN204054831 U CN 204054831U
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CN
China
Prior art keywords
layer
polyethylene
barrier layer
barrier
resistant diaphragm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN201420396264.9U
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Chinese (zh)
Inventor
张蔚萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Tangke New Material Technology Co ltd
Original Assignee
SHANGHAI TANGKE NEW PACKAGE MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Priority to CN201420396264.9U priority Critical patent/CN204054831U/en
Application granted granted Critical
Publication of CN204054831U publication Critical patent/CN204054831U/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

The utility model provides one can print high-resistant diaphragm, it comprises the PETG 1,4-CHDM ester layer of compound successively, the first adhesive layer, the first polyethylene layer, the second polyethylene layer, the second adhesive layer, the first barrier layer, the second barrier layer, the 3rd barrier layer, the 3rd adhesive layer, the 3rd polyethylene layer and the 4th polyethylene layer.Compared with prior art, PETG 1,4-CHDM ester layer is outermost layer, and it has higher adhesive force, smooth, without the need to printing through sided corona treatment; First adhesive layer can play cementation, increases the compatibility between PETG 1,4-CHDM ester layer and the first polyethylene layer; First barrier layer, the second barrier layer and the 3rd barrier layer have good barrier property, the materials such as steam, oxygen, carbon dioxide can be intercepted, play the effect extended the shelf life.

Description

High-resistant diaphragm can be printed
Technical field
The utility model belongs to functional membrane technical field, and particularly relating to one can print high-resistant diaphragm.
Background technology
Along with the development of Chemical Engineering Technology, the functionalization development trend of plastic film is day by day obvious, and wherein, high-barrier plastic film is one of function film with fastest developing speed at present.High-resistant diaphragm refers to that protection package is content-filled, avoids the small-molecule substance such as pollutant and oxygen, steam, liquid and smell to infiltrate, the packing film that simultaneously also can prevent pack content from oozing out.The high barrier of high-resistant diaphragm refer to 23 DEG C, under the standard state of 65% relative humidity, the transit dose < 5ml/m of oxygen 2below day, the transit dose < 2g/m of steam 2d.
For reducing costs and practical function variation, Obstruct membrane many employings composite construction.Outer employing PE film, PP film, PFT film etc., can improve printing effect while reducing costs, intermediate layer adopts the film that barrier is high, realizes the specific functions such as obstruct.
The technological difficulties of high-resistant diaphragm except the synthesis of high-barrier resin raw material, mainly multi-layer co-extruded combination process.Complex method mainly contains 4 kinds: dry type compound, solvent-free compound, individual layer extrude compound, multi-layer co-extruded compound.Multi-layer co-extruded compound has that cost is low, raw material mix is flexible, and the advantage that composite performance is high is the main flow direction of future development.Multi-layer co-extruded compound is exactly the extruder of employing more than 3, by the resin raw material of difference in functionality, as PA, PE, PP etc., melt extrudes respectively, converges shaping through inflation, cooling combined process by respective runner at a die head again.
Along with film is in the extensive use of packaging field, also more and more higher to the requirement of outward appearance.In order to attract the eyeball of consumer, almost often kind of film all drops into packaging production again after color printing, and this has certain requirement to the superficial attractive forces of film, and therefore most of high-resistant diaphragm is in order to meet printable requirement, all adopts and need adopt sided corona treatment.
Utility model content
In view of this, the technical problems to be solved in the utility model is to provide one to print high-resistant diaphragm, and this can print high-resistant diaphragm and can directly print.
The utility model provides one can print high-resistant diaphragm, comprising:
PETG 1,4-CHDM ester layer;
Be compounded in the first adhesive layer in described PETG 1,4-CHDM ester layer;
Be compounded in the first polyethylene layer on described first adhesive layer;
Be compounded in the second polyethylene layer on described first polyethylene layer;
Be compounded in the second adhesive layer on described second polyethylene layer;
Be compounded in the first barrier layer on described second adhesive layer;
Be compounded in the second barrier layer on described first barrier layer;
Be compounded in the 3rd barrier layer on described second barrier layer;
Be compounded in the 3rd adhesive layer on the 3rd barrier layer;
Be compounded in the 3rd polyethylene layer on described 3rd adhesive layer;
Be compounded in the 4th polyethylene layer on described 3rd polyethylene layer.
Preferably, described first barrier layer is the first polyamide barrier layer.
Preferably, described second barrier layer is the second polyamide barrier layer.
Preferably, described 3rd barrier layer is melamine barrier layer.
Preferably, the thickness of described PETG 1,4-CHDM ester layer is can print high-resistant diaphragm thickness 5% ~ 20%.
Preferably, the thickness of described first adhesive layer, the second adhesive layer and the 3rd adhesive layer is independently of one another for can print 2% ~ 15% of high-resistant diaphragm thickness.
Preferably, the thickness of described first polyethylene layer and the second polyethylene layer is independently of one another for can print 6% ~ 20% of high-resistant diaphragm thickness.
Preferably, the thickness of described first barrier layer and the 3rd barrier layer is independently of one another for can print 2% ~ 9% of high-resistant diaphragm thickness.
Preferably, the thickness of described second barrier layer is can print high-resistant diaphragm thickness 4% ~ 14%.
Preferably, the thickness of described 3rd polyethylene layer and the 4th polyethylene layer is independently of one another for can print 6% ~ 24% of high-resistant diaphragm thickness.
The utility model provides one can print high-resistant diaphragm, and it comprises: PETG 1,4-CHDM ester layer; Be compounded in the first adhesive layer in described PETG 1,4-CHDM ester layer; Be compounded in the first polyethylene layer on described first adhesive layer; Be compounded in the second polyethylene layer on described first polyethylene layer; Be compounded in the second adhesive layer on described second polyethylene layer; Be compounded in the first barrier layer on described second adhesive layer; Be compounded in the second barrier layer on described first barrier layer; Be compounded in the 3rd barrier layer on described second barrier layer; Be compounded in the 3rd adhesive layer on the 3rd barrier layer; Be compounded in the 3rd polyethylene layer on described 3rd adhesive layer; Be compounded in the 4th polyethylene layer on described 3rd polyethylene layer.Compared with prior art, PETG 1,4-CHDM ester layer is outermost layer, it not only has high plastic uptake power, high transparency, high glaze, low haze, and there is higher adhesive force, surfacing, without the need to printing through sided corona treatment; First adhesive layer can play cementation, increases the compatibility between PETG 1,4-CHDM ester layer and the first polyethylene layer; First barrier layer, the second barrier layer and the 3rd barrier layer have good barrier property, the materials such as steam, oxygen, carbon dioxide can be intercepted, play the effect extended the shelf life.
Accompanying drawing explanation
The structural representation of the printed high-resistant diaphragm that Fig. 1 provides for the utility model;
Fig. 2 is multi-layer co-extruded process flow diagram.
Detailed description of the invention
The utility model provides one can print high-resistant diaphragm, comprising:
PETG 1,4-CHDM ester layer;
Be compounded in the first adhesive layer in described PETG 1,4-CHDM ester layer;
Be compounded in the first polyethylene layer on described first adhesive layer;
Be compounded in the second polyethylene layer on described first polyethylene layer;
Be compounded in the second adhesive layer on described second polyethylene layer;
Be compounded in the first barrier layer on described second adhesive layer;
Be compounded in the second barrier layer on described first barrier layer;
Be compounded in the 3rd barrier layer on described second barrier layer;
Be compounded in the 3rd adhesive layer on the 3rd barrier layer;
Be compounded in the 3rd polyethylene layer on described 3rd adhesive layer;
Be compounded in the 4th polyethylene layer on described 3rd polyethylene layer.
The printed high-resistant diaphragm that the utility model provides is by the PETG 1 of phase compound successively, 4-cyclohexanedimethanoester ester layer, first adhesive layer, first polyethylene layer, second polyethylene layer, second adhesive layer, first barrier layer, second barrier layer, 3rd barrier layer, 3rd adhesive layer, 3rd polyethylene layer and the 4th polyethylene layer form, PETG 1, 4-cyclohexanedimethanoester ester layer is outermost layer, it not only has high plastic uptake power, high transparency, high glaze, low haze, and there is higher adhesive force, surfacing, without the need to printing through sided corona treatment, first adhesive layer can play cementation, increases the compatibility between PETG 1,4-CHDM ester layer and the first polyethylene layer, first barrier layer, the second barrier layer and the 3rd barrier layer have good barrier property, the materials such as steam, oxygen, carbon dioxide can be intercepted, play the effect extended the shelf life.
See the structural representation that Fig. 1, Fig. 1 are the printed high-resistant diaphragm that the utility model provides, wherein, A is PETG 1,4-CHDM ester (PETG) layer, and B is the first adhesive layer, C is the first polyethylene layer, and D is the second polyethylene layer, and E is the second adhesive layer, F is the first barrier layer, G is the second barrier layer, and H is the 3rd barrier layer, and I is the 3rd adhesive layer, J is the 3rd polyethylene layer, and K is the 4th polyethylene layer.
PETG 1,4-cyclohexanedimethanoester ester layer A is the described outermost layer that can print high-resistant diaphragm, and it not only has high plastic uptake power, high transparency, high glaze, low haze, and has higher adhesive force, surfacing, without the need to printing through sided corona treatment.The thickness of described PETG 1,4-CHDM ester layer preferably can print 5% ~ 20% of high-resistant diaphragm thickness, is more preferably 8% ~ 15%, then is preferably 8% ~ 12%, most preferably is 10%.
First adhesive layer B is compound on PETG 1,4-CHDM ester layer A, can play cementation, increases the compatibility between PETG 1,4-CHDM ester layer A and the first polyethylene layer C; First adhesive layer B by binding resin, as formation such as TIE; In the utility model, the thickness of the first adhesive layer B preferably can print 2% ~ 15% of high-resistant diaphragm thickness, is more preferably 6% ~ 12%, then is preferably 6% ~ 10%, most preferably is 8%.
First polyethylene layer C is compound on the first adhesive layer B, has the effect improving Film Optics performance.In the utility model, the first polyethylene layer C is formed primarily of polyethylene (PE) resin, not only can improve the optical property of film, and can the mechanical property of enhanced film.The thickness of described first polyethylene layer C is preferably as can print 6% ~ 20% of high-resistant diaphragm thickness, is more preferably 10% ~ 15%, then is preferably 11% ~ 14%, most preferably is 13%.
Second polyethylene layer D is compound on the first polyethylene layer C, and have the effect improving thin film mechanical performance, it is formed primarily of polyethylene (PE) resin; The thickness of described second polyethylene layer D is preferably as can print 6% ~ 20% of high-resistant diaphragm thickness, is more preferably 10% ~ 15%, then is preferably 11% ~ 14%, most preferably is 13%.
Second adhesive layer E is compound on the second polyethylene layer D, in order to increase the compatibility between the second polyethylene layer D and the first barrier layer F, the second adhesive layer E by binding resin, as formation such as TIE; In the utility model, the thickness of the second adhesive layer D preferably can print 2% ~ 15% of high-resistant diaphragm thickness, is more preferably 6% ~ 12%, then is preferably 6% ~ 10%, most preferably is 8%.
First barrier layer F is compounded on the second adhesive layer E, plays iris actions such as hindering oxygen, block water, can print the barrier property of high-resistant diaphragm described in improving.In the present embodiment, the first barrier layer F is formed primarily of polyamide (PA) resin; In other embodiments, the first barrier layer F also can by other resins as ethylene-vinyl alcohol copolymer (EVOH) etc. be formed, as long as have good barrier property.In the utility model, the thickness of described first barrier layer F preferably can print 2% ~ 9% of high-resistant diaphragm thickness, is more preferably 3% ~ 6%, then is preferably 4% ~ 5%, most preferably is 4.5%.
Second barrier layer G is compounded on the first barrier layer F, plays iris actions such as hindering oxygen, block water, can print the barrier property of high-resistant diaphragm described in improving.In the present embodiment, the second barrier layer G is formed primarily of polyamide (PA) resin; In other embodiments, the second barrier layer G also can by other resins as ethylene-vinyl alcohol copolymer (EVOH) etc. be formed, as long as have good barrier property.In the utility model, the thickness of described second barrier layer G preferably can print 4% ~ 14% of high-resistant diaphragm thickness, is more preferably 5% ~ 10%, then is preferably 6% ~ 8%, most preferably is 7%.
3rd barrier layer H is compounded on the second barrier layer G, plays iris actions such as hindering oxygen, block water, can print the barrier property of high-resistant diaphragm described in improving.In the present embodiment, the 3rd barrier layer H is formed primarily of polyamide (PA) resin; In other embodiments, the 3rd barrier layer H also can by other resins as ethylene-vinyl alcohol copolymer (EVOH) etc. be formed, as long as have good barrier property.In the utility model, the thickness of described 3rd barrier layer H preferably can print 2% ~ 9% of high-resistant diaphragm thickness, is more preferably 3% ~ 6%, then is preferably 4% ~ 5%, most preferably is 4.5%.
3rd adhesive layer I is compounded on the 3rd barrier layer H, in order to increase the compatibility between the 3rd barrier layer H and the 3rd polyethylene layer J; 3rd adhesive layer I by binding resin, as formation such as TIE; In the utility model, the thickness of the 3rd adhesive layer I preferably can print 2% ~ 15% of high-resistant diaphragm thickness, is more preferably 6% ~ 12%, then is preferably 6% ~ 10%, most preferably is 8%.
3rd polyethylene layer J is compounded on the 3rd adhesive layer I, can increase the mechanical property of film, and it is formed primarily of polyethylene (PE) resin; In the utility model, the thickness of the 3rd polyethylene layer J preferably can print 6% ~ 24% of high-resistant diaphragm thickness, is more preferably 8% ~ 16%, then is preferably 10% ~ 14%, most preferably is 12%.
4th polyethylene layer K is compounded on the 3rd polyethylene layer J, and it is the innermost layer that can print high-resistant diaphragm, can increase the mechanical property of film, and it is formed primarily of polyethylene (PE) resin; In the utility model, the thickness of the 4th polyethylene layer K preferably can print 6% ~ 24% of high-resistant diaphragm thickness, is more preferably 8% ~ 16%, then is preferably 10% ~ 14%, most preferably is 12%; In order to strengthen the heat sealability can printing high-resistant diaphragm, preferably also comprising metallocene in described 4th polyethylene layer, playing heat-sealing effect; The content of described metallocene is preferably 30% ~ 50% of the 4th polyethylene layer quality, is more preferably 40%.
The printed high-resistant diaphragm that the utility model provides has the structure of eleventh floor, has good barrier property and impressionability energy.
The gross thickness of the printed high-resistant diaphragm that the utility model provides can be 25 ~ 250 μm, and to this, the utility model does not have special restriction, and those skilled in the art can carry out the adjustment of thickness according to actual barriering effect.
The utility model adopts and can print high-resistant diaphragm (described multi-layer co-extruded process flow diagram as shown in Figure 2) described in the preparation of multi-layer co-extruded method and not only have good compound peel strength, superior environmental resistance, chemical-resistance, good mechanical property, and there is good barrier property and printing performance, make can print high-resistant diaphragm without the need to can directly print through sided corona treatment, eliminate a procedure, both having saved time again reduces cost.
The above is only preferred embodiment of the present utility model; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the utility model principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection domain of the present utility model.

Claims (10)

1. can print a high-resistant diaphragm, it is characterized in that, comprise:
PETG 1,4-CHDM ester layer;
Be compounded in the first adhesive layer in described PETG 1,4-CHDM ester layer;
Be compounded in the first polyethylene layer on described first adhesive layer;
Be compounded in the second polyethylene layer on described first polyethylene layer;
Be compounded in the second adhesive layer on described second polyethylene layer;
Be compounded in the first barrier layer on described second adhesive layer;
Be compounded in the second barrier layer on described first barrier layer;
Be compounded in the 3rd barrier layer on described second barrier layer;
Be compounded in the 3rd adhesive layer on described 3rd barrier layer;
Be compounded in the 3rd polyethylene layer on described 3rd adhesive layer;
Be compounded in the 4th polyethylene layer on described 3rd polyethylene layer.
2. according to claim 1ly print high-resistant diaphragm, it is characterized in that, described first barrier layer is the first polyamide barrier layer.
3. according to claim 1ly print high-resistant diaphragm, it is characterized in that, described second barrier layer is the second polyamide barrier layer.
4. according to claim 1ly print high-resistant diaphragm, it is characterized in that, described 3rd barrier layer is melamine barrier layer.
5. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described PETG 1,4-CHDM ester layer is can print high-resistant diaphragm thickness 5% ~ 20%.
6. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described first adhesive layer, the second adhesive layer and the 3rd adhesive layer is independently of one another for can print 2% ~ 15% of high-resistant diaphragm thickness.
7. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described first polyethylene layer and the second polyethylene layer is independently of one another for can print 6% ~ 20% of high-resistant diaphragm thickness.
8. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described first barrier layer and the 3rd barrier layer is independently of one another for can print 2% ~ 9% of high-resistant diaphragm thickness.
9. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described second barrier layer is can print high-resistant diaphragm thickness 4% ~ 14%.
10. according to claim 1ly print high-resistant diaphragm, it is characterized in that, the thickness of described 3rd polyethylene layer and the 4th polyethylene layer is independently of one another for can print 6% ~ 24% of high-resistant diaphragm thickness.
CN201420396264.9U 2014-07-17 2014-07-17 High-resistant diaphragm can be printed Expired - Lifetime CN204054831U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201420396264.9U CN204054831U (en) 2014-07-17 2014-07-17 High-resistant diaphragm can be printed

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201420396264.9U CN204054831U (en) 2014-07-17 2014-07-17 High-resistant diaphragm can be printed

Publications (1)

Publication Number Publication Date
CN204054831U true CN204054831U (en) 2014-12-31

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104608451A (en) * 2015-02-15 2015-05-13 轩福君 Multilayer improved thermal shrinkage preservative film/bag and base material composition thereof
CN107502221A (en) * 2017-10-09 2017-12-22 深圳市美信电子有限公司 A kind of compound mould release membrance of high barrier and adhesive tape
CN118772605A (en) * 2024-09-09 2024-10-15 淄博中南医药包装材料股份有限公司 A solid medicinal hard tablet and its preparation process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104608451A (en) * 2015-02-15 2015-05-13 轩福君 Multilayer improved thermal shrinkage preservative film/bag and base material composition thereof
CN104608451B (en) * 2015-02-15 2017-01-04 轩福君 A kind of multilamellar improvement thermal contraction preservative film/bag
CN107502221A (en) * 2017-10-09 2017-12-22 深圳市美信电子有限公司 A kind of compound mould release membrance of high barrier and adhesive tape
CN118772605A (en) * 2024-09-09 2024-10-15 淄博中南医药包装材料股份有限公司 A solid medicinal hard tablet and its preparation process

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Legal Events

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C14 Grant of patent or utility model
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 201508 No. 611, Shantong Road, Shanyang Town, Jinshan District, Shanghai

Patentee after: Shanghai Tangke New Material Technology Co.,Ltd.

Address before: 201508 No. 611, Shantong Road, Shanyang Town, Jinshan District, Shanghai

Patentee before: SHANGHAI TANGKE NEW PACKAGE MATERIAL Co.,Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20141231