CN203986075U - A kind of nitrogen-doped carbon nanometer pipe composite cigarette filter tip - Google Patents
A kind of nitrogen-doped carbon nanometer pipe composite cigarette filter tip Download PDFInfo
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- CN203986075U CN203986075U CN201420378662.8U CN201420378662U CN203986075U CN 203986075 U CN203986075 U CN 203986075U CN 201420378662 U CN201420378662 U CN 201420378662U CN 203986075 U CN203986075 U CN 203986075U
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- nitrogen
- nanometer carbon
- doped nanometer
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- cigarette filter
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 35
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 title claims abstract 18
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract 6
- 238000012946 outsourcing Methods 0.000 claims abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 241000208125 Nicotiana Species 0.000 claims description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000003546 flue gas Substances 0.000 abstract 2
- 238000012856 packing Methods 0.000 abstract 1
- 239000002041 carbon nanotube Substances 0.000 description 29
- 229910021393 carbon nanotube Inorganic materials 0.000 description 29
- 239000000779 smoke Substances 0.000 description 15
- 238000001179 sorption measurement Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
技术领域technical field
本实用新型涉及一种氮掺杂碳纳米管复合香烟滤嘴,用于降低烟气中的有害成份。The utility model relates to a nitrogen-doped carbon nanotube composite cigarette filter tip, which is used for reducing harmful components in smoke.
背景技术Background technique
卷烟燃烧过程中产生的主流烟气中含有大量化学物质,包括焦油、烟碱、氨(NH3)、氢氰酸(HCN)、低分子醛类物质(乙醛、丙醛、巴豆醛等)和易挥发的气体(VOC)等,这些化学物质相互混溶后以气溶胶的形式通过香烟滤嘴后部分进入吸烟者体内。香烟滤嘴的作用主要是通过增加烟雾微粒的相互碰撞凝集频率和吸附作用减少进入人体的有害成分。The mainstream smoke produced during the burning of cigarettes contains a large number of chemical substances, including tar, nicotine, ammonia (NH3), hydrocyanic acid (HCN), low molecular aldehydes (acetaldehyde, propionaldehyde, crotonaldehyde, etc.) and Volatile gas (VOC), etc., these chemical substances are mixed with each other and partly enter the smoker's body after passing through the cigarette filter in the form of aerosol. The role of the cigarette filter is mainly to reduce the harmful components entering the human body by increasing the frequency of mutual collision and agglutination of smoke particles and adsorption.
目前,市售卷烟通常采用醋酸纤维丝束作为滤嘴,为进一步降低挥发性、半挥发性有机毒物,一些卷烟滤嘴中添加了部分活性组分,如多孔活性炭,实践证明多孔活性炭在去除卷烟烟气中部分有害物质的同时,也一并去除了烟气中的一些芳香族化合物而造成香气不足,影响卷烟风味;甲壳素(专利授权公告号CN200941810Y)、茶仔粉(专利申请号201210540305.2)用作卷烟滤嘴,其活性组分自身的味道较易改变香烟风味,因此添加合适的活性组分在有效吸附烟气中有害物质的同时,较小影响卷烟口感和品质的卷烟滤嘴成为本领域迫切需要解决的技术问题。At present, commercially available cigarettes usually use cellulose acetate tow as the filter. In order to further reduce volatile and semi-volatile organic poisons, some active components are added to some cigarette filters, such as porous activated carbon. It has been proved that porous activated carbon is effective in removing At the same time as some harmful substances in the smoke, some aromatic compounds in the smoke are also removed, resulting in insufficient aroma and affecting the flavor of the cigarette; When used as a cigarette filter, the taste of its active components can easily change the flavor of cigarettes. Therefore, adding suitable active components can effectively absorb harmful substances in the smoke, and at the same time, a cigarette filter that has less impact on the taste and quality of cigarettes has become the basic Technical problems that urgently need to be solved in the field.
实用新型内容Utility model content
本实用新型公开了一种氮掺杂碳纳米管复合香烟滤嘴,旨在克服现有技术中香烟滤嘴存在的影响卷烟口感,同时不能有效地吸附烟气中的有害物质的弊端,本实用新型设计的氮掺杂碳纳米管复合香烟滤嘴,不仅对烟气中有害物质的吸附量大大提高,有效降低对人体健康的危害,而且可以保持卷烟原有的品质和香气。The utility model discloses a nitrogen-doped carbon nanotube composite cigarette filter tip, which aims at overcoming the drawbacks of existing cigarette filter tips affecting the taste of cigarettes and being unable to effectively absorb harmful substances in smoke in the prior art. The newly designed nitrogen-doped carbon nanotube composite cigarette filter not only greatly improves the adsorption capacity of harmful substances in smoke, effectively reduces the harm to human health, but also maintains the original quality and aroma of cigarettes.
本实用新型技术方案是这样实现的:The technical scheme of the utility model is achieved in that:
一种氮掺杂碳纳米管复合香烟滤嘴,由过滤体、外包纸筒组成,其特征在于:所述过滤体为两段结构,包括近烟丝段的氮掺杂纳米碳管段和近嘴段的醋酸纤维素段,所述近烟段的氮掺杂纳米碳管段由氮掺杂纳米碳管和醋酸纤维丝束构成,氮掺杂纳米碳管均匀地分布在所述醋酸纤维丝束上,外包纸筒包覆在过滤体外构成所述香烟滤嘴。A nitrogen-doped carbon nanotube composite cigarette filter, which is composed of a filter body and an outer wrapping paper tube, and is characterized in that: the filter body has a two-section structure, including a nitrogen-doped carbon nanotube section near the shredded tobacco section and a section near the mouth The cellulose acetate section, the nitrogen-doped carbon nanotube section of the near-smoke section is composed of nitrogen-doped carbon nanotubes and cellulose acetate tow, and the nitrogen-doped carbon nanotubes are evenly distributed on the cellulose acetate tow, The outer wrapping paper tube wraps the filter body to form the cigarette filter tip.
所述氮掺杂纳米碳管段的长度为1.0-2.2厘米。The nitrogen-doped carbon nanotube segment has a length of 1.0-2.2 centimeters.
所述氮掺杂纳米管段,氮掺杂纳米碳管的添加量为0.5-2mg/mm。For the nitrogen-doped nanotube segments, the nitrogen-doped carbon nanotubes are added in an amount of 0.5-2 mg/mm.
所述氮掺杂纳米碳管段,氮与纳米碳管的质量比为:0.1-1。In the nitrogen-doped carbon nanotube segment, the mass ratio of nitrogen to carbon nanotube is 0.1-1.
本实用新型具有如下优点和积极效果:The utility model has the following advantages and positive effects:
1.氮掺杂纳米碳管稳定性好,比表面积大,表面孔隙结构规整完整,同时由于掺氮后在表面引入更多的活性位点,具有对卷烟中香气物质的吸附少,对烟雾中的颗粒焦油物质及酚类物质等的选择吸附性高的特点。在较小影响香烟风味的同时,有效降低烟雾中焦油物质及有害物质含量,从而更好地保护吸烟者的健康。1. Nitrogen-doped carbon nanotubes have good stability, large specific surface area, and regular and complete surface pore structure. At the same time, since more active sites are introduced on the surface after nitrogen doping, it has less adsorption of aroma substances in cigarettes and less impact on smoke. It has the characteristics of high selective adsorption of particulate tar substances and phenolic substances. While slightly affecting the flavor of cigarettes, it can effectively reduce the content of tar substances and harmful substances in smoke, so as to better protect the health of smokers.
2.氮掺杂纳米碳管对生物无毒害,以化学键键合在醋酸纤维丝束表面,不易脱落,可以制成理想的滤嘴复合材料。2. Nitrogen-doped carbon nanotubes are non-toxic to organisms. They are chemically bonded to the surface of cellulose acetate tow and are not easy to fall off. They can be made into ideal filter composite materials.
附图说明Description of drawings
图1为本实用新型的氮掺杂碳纳米管复合滤嘴的结构示意图;Fig. 1 is the structural representation of the nitrogen-doped carbon nanotube composite filter of the present utility model;
图2为滤嘴中近烟段氮掺杂碳纳米管段结构示意图。Fig. 2 is a schematic diagram of the structure of the nitrogen-doped carbon nanotube segment near the smoke in the filter.
1、纸筒,2、过滤体,21、氮掺杂纳米碳管段,22、醋酸纤维素段,211、氮掺杂纳米碳管,212、醋酸纤维丝束。1. Paper tube, 2. Filter body, 21. Nitrogen-doped carbon nanotube segment, 22. Cellulose acetate segment, 211. Nitrogen-doped carbon nanotube, 212. Acetate cellulose tow.
具体实施方式Detailed ways
以下结合附图和实施例对本实用新型进行详细说明。The utility model is described in detail below in conjunction with accompanying drawings and embodiments.
一种氮掺杂碳纳米管复合香烟滤嘴,结构如图1所示,由过滤体2、外包纸筒1组成。所述过滤体2为两段结构,包括近烟丝段的氮掺杂纳米碳管段21和近嘴段的醋酸纤维素段22,所述近烟段的氮掺杂纳米碳管段21,由氮掺杂纳米碳管211和醋酸纤维丝束212构成。A nitrogen-doped carbon nanotube composite cigarette filter, the structure of which is shown in FIG. The filter body 2 is a two-section structure, including a nitrogen-doped carbon nanotube section 21 near the cut tobacco section and a cellulose acetate section 22 near the mouth section, and the nitrogen-doped carbon nanotube section 21 near the tobacco section is made of nitrogen-doped Heterogeneous carbon nanotubes 211 and cellulose acetate tows 212.
如图2所示,氮掺杂纳米碳管211均匀地分布在所述醋酸纤维丝束212上。As shown in FIG. 2 , nitrogen-doped carbon nanotubes 211 are evenly distributed on the acetate tow 212 .
外包纸筒1包覆在过滤体2外,构成所述香烟滤嘴。The outer wrapping paper tube 1 wraps the outside of the filter body 2 to form the cigarette filter.
其中:氮掺杂纳米碳管段的长度为1.0-2.2厘米;氮掺杂纳米碳管的添加量为0.5-2mg/mm;氮掺杂碳纳米管段的氮与纳米碳管的质量比为:0.1-1。Among them: the length of the nitrogen-doped carbon nanotube segment is 1.0-2.2 cm; the addition amount of the nitrogen-doped carbon nanotube is 0.5-2 mg/mm; the mass ratio of nitrogen to the carbon nanotube in the nitrogen-doped carbon nanotube segment is: 0.1 -1.
吸烟时,点燃烟卷,烟气经氮掺杂纳米碳管段21后,由于氮掺杂碳纳米管稳定性好,比表面积大,表面孔隙结构规整完整,同时由于掺氮后在表面引入更多的活性位点,对烟雾中的颗粒焦油物质及醛类物质的吸附量大大提高,能够在较小影响香烟风味的同时,有效降低烟气中有害物质含量;再经近嘴段的醋酸纤维素段22,进一步过滤有害物质,从而更好地保护吸烟者的健康。When smoking, ignite the cigarette, and after the smoke passes through the nitrogen-doped carbon nanotube segment 21, the nitrogen-doped carbon nanotube has good stability, large specific surface area, and the surface pore structure is regular and complete. The active site can greatly increase the adsorption capacity of tar particles and aldehydes in the smoke, which can effectively reduce the content of harmful substances in the smoke while slightly affecting the flavor of the cigarette; and then pass through the cellulose acetate section near the mouth 22. Further filter harmful substances, so as to better protect the health of smokers.
Claims (4)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106509985A (en) * | 2016-12-14 | 2017-03-22 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Cigarette filter tip and preparation method thereof |
CN106723343A (en) * | 2017-04-06 | 2017-05-31 | 上海烟草集团有限责任公司 | A kind of composite cigarette filter stick for reducing releasing content of coke tar in cigarette and preparation method thereof |
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2014
- 2014-07-09 CN CN201420378662.8U patent/CN203986075U/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106509985A (en) * | 2016-12-14 | 2017-03-22 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Cigarette filter tip and preparation method thereof |
CN106723343A (en) * | 2017-04-06 | 2017-05-31 | 上海烟草集团有限责任公司 | A kind of composite cigarette filter stick for reducing releasing content of coke tar in cigarette and preparation method thereof |
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