CN203955014U - A kind of device that removes dioxin in high-temperature flue gas - Google Patents
A kind of device that removes dioxin in high-temperature flue gas Download PDFInfo
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- CN203955014U CN203955014U CN201420284161.3U CN201420284161U CN203955014U CN 203955014 U CN203955014 U CN 203955014U CN 201420284161 U CN201420284161 U CN 201420284161U CN 203955014 U CN203955014 U CN 203955014U
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- absorbent
- dioxin
- flue gas
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000003546 flue gas Substances 0.000 title claims abstract description 45
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 title 1
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000002250 absorbent Substances 0.000 claims abstract description 59
- 230000002745 absorbent Effects 0.000 claims abstract description 59
- 238000010521 absorption reaction Methods 0.000 claims abstract description 26
- 150000002013 dioxins Chemical class 0.000 claims abstract description 26
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000428 dust Substances 0.000 claims abstract description 17
- 238000011084 recovery Methods 0.000 claims abstract 10
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000012717 electrostatic precipitator Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 238000003421 catalytic decomposition reaction Methods 0.000 description 7
- 238000007599 discharging Methods 0.000 description 6
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- 150000004706 metal oxides Chemical class 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 231100000770 Toxic Equivalency Factor Toxicity 0.000 description 5
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- 239000000203 mixture Substances 0.000 description 5
- 238000004056 waste incineration Methods 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
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- 238000000926 separation method Methods 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- -1 aromatic organic compounds Chemical class 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
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- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
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- 241001465754 Metazoa Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
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- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
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- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 231100000244 chromosomal damage Toxicity 0.000 description 1
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- 238000002485 combustion reaction Methods 0.000 description 1
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- 239000000039 congener Substances 0.000 description 1
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- 230000000593 degrading effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
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- 239000002920 hazardous waste Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
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- 230000002427 irreversible effect Effects 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
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- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100001239 persistent pollutant Toxicity 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
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- 229910052697 platinum Inorganic materials 0.000 description 1
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- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
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- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
本实用新型公开的脱除高温烟气中二恶英的装置包括两个除尘设备，含吸收剂的二恶英吸收塔，吸收剂回收反应器和臭氧发生器，第一除尘设备的烟气出口与含吸收剂的二恶英吸收塔的烟气进口相连，含吸收剂的二恶英吸收塔的烟气出口与第二除尘设备的烟气进口相连，第二除尘设备的烟气出口与烟囱相连，含吸收剂的二恶英吸收塔的出料口与吸收剂回收反应器的进料口相连，第二除尘器的出料口和吸收剂回收反应器的进料口相连，吸收剂回收反应器的出料口与含吸收剂的二恶英吸收塔的进料口相连，吸收剂回收反应器和臭氧发生器相连。该装置结构简单，把吸收剂吸收二恶英和臭氧促进催化分解二恶英的优点结合在一起，可实现高效廉价地脱除高温烟气中的二恶英。
The device for removing dioxin in high-temperature flue gas disclosed by the utility model includes two dust removal equipment, a dioxin absorption tower containing absorbent, an absorbent recovery reactor and an ozone generator, and the flue gas outlet of the first dust removal equipment It is connected with the flue gas inlet of the dioxin absorption tower containing absorbent, and the flue gas outlet of the dioxin absorption tower containing absorbent is connected with the flue gas inlet of the second dust removal equipment, and the flue gas outlet of the second dust removal equipment is connected with the chimney The outlet of the dioxin absorption tower containing absorbent is connected to the inlet of the absorbent recovery reactor, the outlet of the second dust collector is connected to the inlet of the absorbent recovery reactor, and the absorbent recovery The discharge port of the reactor is connected with the feed port of the dioxin absorption tower containing the absorbent, and the absorbent recovery reactor is connected with the ozone generator. The device has a simple structure and combines the advantages of absorbing dioxins by an absorbent and catalytically decomposing dioxins by ozone, and can efficiently and cheaply remove dioxins in high-temperature flue gas.
Description
Technical field
The utility model relates to the treating apparatus of high-temperature flue gas, particularly relates to a kind of device that removes dioxin in high-temperature flue gas.
Background technology
To be a class connect 2 tricyclic aromatic organic compounds that the phenyl ring being replaced by chlorine forms by 2 or 1 oxygen atom to dioxin, comprises polychlorinated dibenzo-2 evil English and polychlorinated dibenzo, has 210 kinds of isomers/congeners.Dioxin is the highly stable lipophilicity solid chemical compound of a class, and its fusing point is higher, and decomposition temperature is greater than 700 ℃, and the utmost point is insoluble in water, dissolves in majority of organic solvent.Natural microbial degradation, hydrolysis and photolysis are less on the molecular structure impact of dioxin, are difficult to natural degradation.Some isomers in dioxin are extremely toxic substances, and its acute toxicity is equivalent to 1000 times of potassium cyanide.A large amount of zooperies show, the dioxin of very low concentrations just shows lethal effect to animal.The diseases such as dioxin also causes skin acne, has a headache, becomes deaf, melancholy, insomnia, and may cause chromosome damage, heart failure, cancer etc.Its greatest danger is to have irreversible teratogenesis, carcinogenic, mutagenic three intoxicatings.In addition, dioxin also affects reproductive function, and therefore disturbance endocrine system is known as " poison in century ".As height persistent pollutant, dioxin has strong compatibility to soil and bed mud, be easy to accumulate in biological tissue, and finally by food chain a large amount of enrichments in human body, and accumulate with more stable form.Once dioxin concentration of (especially women and children) in human body reaches certain value, the genotoxicity himself having, immunotoxicity and Endocrine toxicity will cause disease of skin, viscera disease, cancer and deformed child, affect the mankind's survival and development.
Dioxin is mainly not intended to produce in various pyroprocesses, for example, in the flue gas of waste incineration, metal smelt, cinerator etc., often contains the dioxin of higher concentration.In view of the toxicity of dioxin, each state has all made strict restriction to the discharge of dioxin.In China, industrial waste incinerator is lower than 1.0 ng I-TEQ/Nm
3, to the dioxin standard of medical waste incineration furnace, be lower than 0.5 ng I-TEQ/Nm
3.From 2008, the dioxin standard of Beijing was brought up to 0.1 ng I-TEQ/Nm comprehensively
3.The dioxin standard of developed country is normally lower than 0.1 ng I-TEQ/Nm
3.Soon, the dioxin standard of the domestic waste incineration of China will become lower than 0.1 ng I-TEQ/Nm
3.The formulation of stricter discharge standard, the fast lifting of the common people to the attention rate of environmental protection, to high temperature facilities such as operating and waste incineration facilities that be about to build up, has proposed stern challenge.How cheap and effectively control the discharge of dioxin, become a difficult problem in the urgent need to address.
The emission control of dioxin in pyroprocess, at the well-known control incineration temperature that passes through, on the basis of turbulivity and gas residence time, can also by inhibitor, suppress three approach of decomposition elimination of dioxin generation, absorption and separation dioxin and dioxin, further reduce the discharge of dioxin.
Article one, approach is in pyroprocess, to add to suppress the inhibitor that dioxin generates.For example, it is inhibitor that CN101725989A discloses a kind of sulphur, sulphur coal, calcium oxide, calcium hydroxide or calcium carbonate of being adopted as, and suppresses the method that in Refuse Incineration Process, dioxin generates.CN101485955 discloses and a kind of troilite and rubbish has been put in incinerator in the lump, by controlling the addition of troilite, suppresses the method that in Refuse Incineration Process, dioxin generates.CN201419076 discloses the method that realizes dioxin emission reducing by the control of the sulphur composition in coal.
Second approach is to adopt active carbon to absorb, and dioxin is separated from flue gas.CN201537442U discloses a kind of by spraying active carbon and calcium oxide and contact the device of the dioxin in absorption flue gas with flue gas is powerful in flue gas in venturi reactor.CN201949799U discloses a kind of device that adopts two cloth bags control dioxin, by venturi reactor, in first cloth bag, sprays into lime, in second cloth bag, sprays into active carbon.Improve active carbon and contact with flue gas, reach the object of effective absorption dioxin, and active carbon can reuse until dioxin saturated adsorption has reduced system operation cost.CN1246597 discloses by spray into active carbon in flue gas, then the Activated carbon separation that absorption is had to a dioxin out, delivers to combustion chambers burn and processes the method for eliminating dioxin.CN201997249U discloses and has adopted the discharge that reduces dioxin to the method that sprays into alkaline cooling fluid in flue gas.
Article three, approach is to decompose, and conventionally under the effect of catalyst, allows dioxin oxidation Decomposition at lower temperature.For example, CN1626277 discloses a kind of based on V
2o
5(WO
3, MoO
3) and TiO
2catalyst, can, at the temperature of 240-320 ℃, effectively remove the dioxin in flue gas.CN101559362 discloses first by TiO
2load on volcanic rock, and then supported V
2o
5, can at the temperature of 200-450 ℃, effectively remove dioxin.European patent (the patent No.: 634206) the disclosed catalyst that removes dioxin is also with TiO
2load barium oxide.United States Patent (USP) (the patent No.: 5227356) disclosed catalyst activity composition is transition metal oxide and noble metal.Japan Patent (the patent No.: 200024460 peace-11047592) disclosed catalyst activity component comprises metal oxide and the noble metals such as V, W, Cu, Mn, Cr, Pd, Ru, Pt, and catalyst carrier can be TiO
2, SiO
2, Al
2o
3, ZrO
2.The disclosed catalyst of Japan Patent (patent No.: flat-11226397) is the oxide that loads on the transition metal such as V, W on active carbon, Mo, Cu, Mn, Fe, Co, Cr, Ni.Also catalyst activity composition and polytetrafluoroethylene fibre can be prepared into the filter bag with catalytic activity, as CN101580973, CN101255615 and the United States Patent (USP) (patent No.: 5620669).In addition, CN201921634U discloses and has utilized ultraviolet emission device activation photocatalyst coating, reaches the object of catalytic decomposition of dioxins.CN101485958 discloses a kind of photo catalysis reactor and method for activating photocatalyst for the flue gas dioxin of degrading.Recently find, ozone can effectively promote the catalytic decomposition of dioxin, and for example, CN102814108A discloses ozone effect and promoted the low-temperature decomposition of dioxin on metal oxide catalyst.
But above patent, all exists some obvious shortcomings, for example, add inhibitor and conventionally can cause other pollution.The simple active carbon that uses absorbs dioxin technology, and not only active carbon is expensive, and has absorbed the active carbon after dioxin and must process as hazardous waste, or directly burns as fuel, and operating cost is high.Adopt catalysis filter bag technology, because pressure drop is too large, the flow velocity of flue gas is partially slow, and has the problem of catalyst loss, has increased equally operating cost.And catalytic decomposition technology faces equally that facility scale is huge, catalyst poisoning and need periodic replacement, flue gas to heat again, etc. problem.Even if adopt ozone to promote dioxin catalytic decomposition, face equally the still problem such as a large amount of uses of huge, ozone and catalyst periodic replacement of facility scale.
Summary of the invention
The purpose of this utility model is to provide a kind of device that removes dioxin in high-temperature flue gas of efficient cheapness.
Of the present utility modelly remove the device of dioxin in high-temperature flue gas and comprise the first cleaner, dioxins adsorption tower containing absorbent, the second cleaner, absorbent reclaims reactor and ozone generator, the exhanst gas outlet of the first cleaner is connected with the gas approach that contains the dioxins adsorption tower of absorbent, the exhanst gas outlet that contains the dioxins adsorption tower of absorbent is connected with the gas approach of the second cleaner, the exhanst gas outlet of the second cleaner is connected with chimney, the discharging opening that contains the dioxins adsorption tower of absorbent is connected with the charging aperture that absorbent reclaims reactor, the discharging opening of the second deduster is connected with the charging aperture that absorbent reclaims reactor, the discharging opening that absorbent reclaims reactor is connected with the charging aperture that contains the dioxins adsorption tower of absorbent, absorbent reclaims reactor and is connected with ozone generator.
The first above-mentioned cleaner can be sack cleaner, electric cleaner, cyclone dust collectors or their combination.The second described cleaner can be also sack cleaner, electric cleaner, cyclone dust collectors or their combination.
In the utility model, the described dioxins adsorption tower containing absorbent can be fixed bed absorption tower, fluid bed absorption tower or thermopnore absorption tower.
During work, first the flue gas after UTILIZATION OF VESIDUAL HEAT IN and chilling passes into the first cleaner, filters the particles such as flying dust of removing in flue gas in the first cleaner; Then enter the dioxins adsorption tower that contains absorbent, allow absorbent fully contact with flue gas, effectively the dioxin in absorption and separation flue gas.Utilize the absorbent dust containing dioxin that the second cleaner trap filter escapes from dioxins adsorption tower, after purification, reach the flue gas of national discharge standard from air flue emission.The absorbent dust of collecting from the second cleaner is sent into absorbent and is reclaimed reactor.In dioxins adsorption tower, having adsorbed dioxin reaches the saturated absorbent of absorption and is also fed to absorbent and reclaims in reactor.The ozone input absorbent that ozone generator is produced reclaims reactor, and at 25 ℃ ~ 350 ℃, reaction, utilizes the super oxidability of ozone and the catalytic activity of absorbent, and the dioxin being adsorbed on absorbent is thoroughly decomposed.Absorbent after processing is sent into dioxins adsorption tower, recycles.
Above-mentioned absorbent can be the active carbon of active carbon, CNT, process metal oxide modified or the CNT of process metal oxide modified, wherein metal oxide accounts for 0～50% of absorbent gross mass, and described metal oxide is one or more in the oxide of manganese, cerium, copper, vanadium, iron, molybdenum, tungsten, chromium or nickel.
Usefulness of the present utility model is: the device that removes the dioxin in high-temperature flue gas that the utility model is carried, simple in structure, absorbent is absorbed together with the advantages that dioxin and ozone promotes catalytic decomposition of dioxins, and not only absorbent can recycle but also the temperature of dioxin catalytic decomposition is low, facility scale is little, operating cost is low.And when utilizing catalytic decomposition of ozone dioxin, can not be subject to the impact of other compositions in flue gas, thereby reach the effect that efficiently removes at an easy rate the dioxin in high-temperature flue gas.Be applicable to comprise efficiently removing of dioxin in the high-temperature flue gas of waste incineration, smelting iron and steel, cement kiln, cinerator etc. and other volatile organic matter.
Accompanying drawing explanation
Fig. 1 is the device schematic diagram that removes dioxin in high-temperature flue gas.
In figure: 1, the first cleaner, 2, containing the dioxins adsorption tower of absorbent, the 3, second cleaner, 4, absorbent reclaims reactor, 5, ozone generator.
The specific embodiment
Below in conjunction with accompanying drawing, further illustrate the utility model
With reference to Fig. 1, the device that removes dioxin method in high-temperature flue gas of the present utility model comprises the first cleaner 1, dioxins adsorption tower 2 containing absorbent, the second cleaner 3, absorbent reclaims reactor 4 and ozone generator 5, the exhanst gas outlet of the first cleaner 1 is connected with the gas approach that contains the dioxins adsorption tower 2 of absorbent, the exhanst gas outlet that contains the dioxins adsorption tower 2 of absorbent is connected with the gas approach of the second cleaner 3, the exhanst gas outlet of the second cleaner 3 is connected with chimney, the discharging opening that contains the dioxins adsorption tower 2 of absorbent is connected with the charging aperture that absorbent reclaims reactor 4, the discharging opening of the second deduster is connected with the charging aperture that absorbent reclaims reactor 4, the discharging opening that absorbent reclaims reactor 4 is connected with the charging aperture that contains the dioxins adsorption tower 2 of absorbent, absorbent reclaims reactor 4 and is connected with ozone generator 5.First cleaner 1 here and the second cleaner 3 can be all sack cleaner, electric cleaner, cyclone dust collectors or their combination.Dioxins adsorption tower 2 containing active carbon can be fixed bed absorption tower, fluid bed absorption tower or thermopnore absorption tower.
Claims (4)
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| CN201420284161.3U CN203955014U (en) | 2014-05-30 | 2014-05-30 | A kind of device that removes dioxin in high-temperature flue gas |
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| CN201420284161.3U CN203955014U (en) | 2014-05-30 | 2014-05-30 | A kind of device that removes dioxin in high-temperature flue gas |
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| CN203955014U true CN203955014U (en) | 2014-11-26 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107261830A (en) * | 2017-08-01 | 2017-10-20 | 中国科学院过程工程研究所 | A kind of system and method for ira situ degradation dioxin in flue gas class material |
| CN111229026A (en) * | 2020-02-11 | 2020-06-05 | 清华大学 | A device and method for efficiently converting volatile organic compounds |
-
2014
- 2014-05-30 CN CN201420284161.3U patent/CN203955014U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107261830A (en) * | 2017-08-01 | 2017-10-20 | 中国科学院过程工程研究所 | A kind of system and method for ira situ degradation dioxin in flue gas class material |
| CN107261830B (en) * | 2017-08-01 | 2020-11-10 | 中国科学院过程工程研究所 | System and method for in-situ degradation of dioxin-like substances in flue gas |
| CN111229026A (en) * | 2020-02-11 | 2020-06-05 | 清华大学 | A device and method for efficiently converting volatile organic compounds |
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| C14 | Grant of patent or utility model | ||
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Granted publication date: 20141126 Termination date: 20170530 |