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CN203927879U - A kind of economizer that improves SCR operational percentage under running on the lower load - Google Patents

A kind of economizer that improves SCR operational percentage under running on the lower load Download PDF

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CN203927879U
CN203927879U CN201420097259.8U CN201420097259U CN203927879U CN 203927879 U CN203927879 U CN 203927879U CN 201420097259 U CN201420097259 U CN 201420097259U CN 203927879 U CN203927879 U CN 203927879U
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economizer
scr
header
lower load
under running
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司风琪
喻聪
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Southeast University
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Abstract

本实用新型公开了一种在低负荷工况下提高SCR投运率的省煤器,省煤器入口给水管道上设置一条旁路,旁路管路和省煤器的中间联箱相连接,在旁路上沿着介质流动的方向依次装配有单向阀、节流阀和流量调节阀。本实用新型是利用在低负荷工况下调节旁路阀门开度来减少锅炉内省煤器进口联箱和中间联箱间的介质流量,从而降低省煤器烟气侧的放热量,使得省煤器出口烟温升高,有效地提高了电厂SCR在低负荷工况下的投运率,SCR系统温度的升高导致SCR催化剂活性提升,SCR系统获得更高脱硝能力,从而帮助电厂在更长时间范围内更好地达到环保指标。

The utility model discloses an economizer which improves the operation rate of the SCR under low-load working conditions. A bypass is arranged on the water supply pipe at the inlet of the economizer, and the bypass pipeline is connected with the middle header of the economizer. A check valve, a throttle valve and a flow regulating valve are sequentially installed on the bypass along the direction of medium flow. The utility model utilizes the adjustment of the opening of the bypass valve under low-load conditions to reduce the medium flow between the inlet header and the intermediate header of the economizer in the boiler, thereby reducing the heat release on the flue gas side of the economizer and saving energy. The rise of the flue gas temperature at the outlet of the coal burner has effectively improved the operation rate of the power plant's SCR under low-load conditions. Better achieve environmental protection indicators in a long-term range.

Description

一种在低负荷工况下提高SCR投运率的省煤器A Coal Economizer for Improving the Commissioning Rate of SCR in Low Load Condition

技术领域 technical field

本实用新型涉及电站锅炉烟气脱硝领域,具体指一种在低负荷工况下提高SCR投运率的省煤器。 The utility model relates to the field of flue gas denitrification of power plant boilers, in particular to an economizer which improves the operation rate of SCR under low-load working conditions.

背景技术 Background technique

选择性催化还原法(SCR)是目前工业上最成熟的脱硝技术。该技术主要应用于火力发电厂、机动车、船舶等领域,它的主要作用是脱除锅炉或发动机燃烧所产生的氮氧化物。氮氧化物中NO占到约为95%,NO2占到约为5%,另外还含有少量的N2O,这些气体排放到大气中,会产生酸雨、光化学烟雾、臭氧层耗损等危害。我国的主要能源来自煤炭燃烧,据统计,我国67%的氮氧化物排放量来自于煤炭的燃烧,而火电厂氮氧化物产生量占全国总量的50%,因此控制火电厂氮氧化物排放是控制我国氮氧化物排放总量的重中之重。 Selective catalytic reduction (SCR) is currently the most mature denitrification technology in industry. This technology is mainly used in thermal power plants, motor vehicles, ships and other fields. Its main function is to remove nitrogen oxides produced by boiler or engine combustion. In nitrogen oxides, NO accounts for about 95%, NO 2 accounts for about 5%, and also contains a small amount of N 2 O. These gases are discharged into the atmosphere, causing acid rain, photochemical smog, and ozone layer depletion. my country's main energy comes from coal combustion. According to statistics, 67% of my country's nitrogen oxide emissions come from coal combustion, and thermal power plants account for 50% of the national total. It is the top priority to control the total emission of nitrogen oxides in my country.

近年来大气污染物排放标准日愈严格,在火力发电厂方面,国内要求对未安装脱硝设备的现役机组进行加装SCR系统的改造工作。SCR工艺系统的布置方式主要包括高温高尘布置、高温低尘布置以及低温低尘布置,其中高温高尘布置采用得最为普遍,即把SCR反应器布置在省煤器和空气预热器之间,这种布置方式使进入SCR脱硝系统的烟气温度保持在280℃~420℃,满足多数催化剂的活性温度区间,在活性温度区间内,SCR系统能获得较好的效果,且脱硝性能随着烟气温度的升高而升高。但当烟气温度低于催化剂活性温度区间下限时,催化剂活性较低,使得一方面脱硝效率较低,另一方面氨逃逸率较高,逃逸的NH3会和烟气中的SO3反应生成硫酸铵(NH4)2SO4和硫酸氢铵NH4HSO4,严重时会造成催化剂反应通道和下游空气预热器的堵塞。但当烟气温度高于催化剂活性温度区间上限时,会使催化剂烧结或再结晶,减少催化剂的使用寿命。考虑到SCR系统的烟气温度对SCR系统以及下游设备的影响,SCR系统的运行温度一般设计在300℃~400℃,在该温度区间内,催化剂能保证在较高的活性下运行。由于电站的发电负荷受电网调度指挥,在用电高峰期,电站锅炉保持在BMCR或高负荷工况下运行,脱硝装置的入口温度能保证在SCR的投运温度区间内,脱硝系统正常运行。然而电站锅炉无法长期高负荷运行,在用电低峰期,电网对电站发电负荷的需求量较低,电站锅炉在低负荷下运行,此时SCR系统中烟气的反应温度较低,由于催化剂的活性随温度降低而降低,因此脱硝效率也较低。此外,当脱硝装置入口烟气温度达不到脱硝系统投运温度下限时,脱硝系统停止运行,氮氧化物的排放量增加,电站难以达到国家规定的环保指标。另一方面虽然催化剂停止工作,但仍然处于烟气的冲刷中,飞灰对催化 剂的磨损没有减少,导致催化剂的使用寿命降低。因此,在电站锅炉低负荷运行工况下,保证SCR脱硝系统效率和提高SCR脱硝系统投运时间是国内脱硝领域技术上需要解决的难题。 In recent years, the emission standards of air pollutants have become increasingly stringent. In terms of thermal power plants, domestically, it is required to retrofit SCR systems for active units without denitrification equipment. The layout of the SCR process system mainly includes high-temperature and high-dust layout, high-temperature and low-dust layout, and low-temperature and low-dust layout, among which the high-temperature and high-dust layout is the most common, that is, the SCR reactor is arranged between the economizer and the air preheater , this arrangement keeps the temperature of the flue gas entering the SCR denitrification system at 280°C to 420°C, which meets the activity temperature range of most catalysts. In the active temperature range, the SCR system can achieve better results, and the denitrification performance increases with the increase with the increase of flue gas temperature. However, when the flue gas temperature is lower than the lower limit of the catalyst activity temperature range, the catalyst activity is low, so that on the one hand, the denitrification efficiency is low, and on the other hand, the ammonia slip rate is high, and the escaped NH 3 will react with the SO 3 in the flue gas to form Ammonium sulfate (NH 4 ) 2 SO 4 and ammonium bisulfate NH 4 HSO 4 , in severe cases, will cause blockage of the catalyst reaction channel and the downstream air preheater. However, when the flue gas temperature is higher than the upper limit of the active temperature range of the catalyst, the catalyst will be sintered or recrystallized, reducing the service life of the catalyst. Considering the impact of the flue gas temperature of the SCR system on the SCR system and downstream equipment, the operating temperature of the SCR system is generally designed at 300°C to 400°C, and within this temperature range, the catalyst can operate at a relatively high activity. Since the power generation load of the power station is controlled by the dispatching command of the power grid, during the peak period of power consumption, the boiler of the power station is kept running under BMCR or high load conditions, and the inlet temperature of the denitrification device can be guaranteed to be within the operating temperature range of the SCR, and the denitrification system can operate normally. However, power plant boilers cannot operate at high load for a long time. During the off-peak period of electricity consumption, the power grid’s demand for power generation load of the power plant is low, and the power plant boiler operates under low load. At this time, the reaction temperature of the flue gas in the SCR system is low. The activity decreases with the decrease of temperature, so the denitrification efficiency is also low. In addition, when the flue gas temperature at the inlet of the denitrification device does not reach the lower limit of the operating temperature of the denitrification system, the denitrification system will stop operating, and the emission of nitrogen oxides will increase, making it difficult for the power station to meet the environmental protection indicators stipulated by the state. On the other hand, although the catalyst stops working, it is still being scoured by flue gas, and the wear of the catalyst by the fly ash does not decrease, resulting in a reduction in the service life of the catalyst. Therefore, under the low-load operating conditions of power plant boilers, ensuring the efficiency of the SCR denitrification system and improving the commissioning time of the SCR denitrification system are technical problems that need to be solved in the domestic denitrification field.

发明内容 Contents of the invention

实用新型目的:为了克服现有技术中存在的不足,实用新型提供一种在低负荷工况下提高SCR投运率的省煤器。 Purpose of the utility model: In order to overcome the deficiencies in the prior art, the utility model provides an economizer which improves the operation rate of SCR under low-load conditions.

技术方案:为解决上述技术问题,本实用新型提供的一种在低负荷工况下提高SCR投运率的省煤器,包括壳体、设在壳体内的省煤器出口联箱、与省煤器出口联箱相连的换热装置、与换热装置相连的省煤器进口联箱以及与壳体底部相连的SCR反应器;所述换热装置包括一组与省煤器出口联箱相连的省煤器悬吊管、与每个省煤器悬吊管连接的省煤器中间联箱、与省煤器中间联箱相连的一组省煤器蛇形管,所述省煤器蛇形管与省煤器进口联箱相连;所述省煤器进口联箱与省煤器中间联箱之间设有一支路管,所述支路管沿着流体流动方向上分别依次设有单通阀、截止阀和流量调节阀。 Technical solution: In order to solve the above technical problems, the utility model provides an economizer that improves the operation rate of SCR under low load conditions, including a shell, an economizer outlet header set in the shell, and a economizer The heat exchange device connected to the outlet header of the coal generator, the inlet header of the economizer connected to the heat exchange device, and the SCR reactor connected to the bottom of the shell; the heat exchange device includes a group connected to the outlet header of the economizer The economizer suspension pipe, the economizer intermediate header connected to each economizer suspension pipe, and a set of economizer serpentine pipes connected to the economizer intermediate header, the economizer snake shaped pipe is connected to the inlet header of the economizer; a branch pipe is provided between the inlet Through valves, shut-off valves and flow regulating valves.

进一步地,所述SCR反应器包括反应器壳体、依次设在反应器壳体内的催化剂预留层、催化剂首层和催化剂次层。 Further, the SCR reactor includes a reactor shell, a catalyst reserve layer, a catalyst first layer and a catalyst second layer sequentially arranged in the reactor shell.

进一步地,所述壳体底部设有一省煤器灰斗。 Further, an economizer ash hopper is provided at the bottom of the housing.

进一步地,所述支路管的两端分别设有一三通管连接器,支路管与中间联箱连接方式为焊接。 Further, the two ends of the branch pipe are respectively provided with a three-way pipe connector, and the connection method between the branch pipe and the intermediate header is welding.

进一步地,所述调节阀为电动控制调节阀门。 Further, the regulating valve is an electrically controlled regulating valve.

有益效果:本实用新型相对于现有技术而方具有以下优点: Beneficial effect: compared with the prior art, the utility model has the following advantages:

本实用新型是利用在低负荷工况下调节旁路阀门开度来减少锅炉内省煤器进口联箱和中间联箱间的介质流量,从而降低省煤器烟气侧的放热量,使得省煤器出口烟温升高,由于省煤器出口和SCR反应器入口之间没有换热设备,因此进入SCR系统的烟气温度同样获得提升,使某些原本达不到SCR投运条件的低负荷工况满足SCR投运的温度要求,有效地提高了电厂SCR在低负荷工况下的投运率。此外,SCR系统温度的升高导致SCR催化剂活性提升,SCR系统获得更高脱硝能力,从而帮助电厂在更长时间范围内更好地达到环保指标。 The utility model utilizes the adjustment of the opening of the bypass valve under low-load conditions to reduce the medium flow between the inlet header and the intermediate header of the economizer in the boiler, thereby reducing the heat release on the flue gas side of the economizer and saving energy. The temperature of the flue gas at the outlet of the coal burner rises. Since there is no heat exchange equipment between the outlet of the economizer and the inlet of the SCR reactor, the temperature of the flue gas entering the SCR system also increases, making some low The load conditions meet the temperature requirements for SCR operation, which effectively improves the operation rate of SCR in power plants under low load conditions. In addition, the increase in the temperature of the SCR system leads to an increase in the activity of the SCR catalyst, and the SCR system obtains a higher denitrification capacity, thereby helping the power plant to better meet environmental protection indicators in a longer period of time.

附图说明 Description of drawings

图1是本实用新型的结构示意图。 Fig. 1 is the structural representation of the utility model.

图2是本实用新型的支路管连接示意图。 Fig. 2 is a schematic diagram of branch pipe connection of the present invention.

具体实施方式 Detailed ways

下面结合附图对本实用新型作更进一步的说明。 Below in conjunction with accompanying drawing, the utility model is described further.

如图1和图2所示,一种在低负荷工况下提高SCR投运率的省煤器,包括壳体20、设在壳体20内的省煤器出口联箱2、与省煤器出口联箱2相连的换热装置、与换热装置相连的省煤器进口联箱10以及与壳体20底部相连的SCR反应器;所述换热装置包括一组与省煤器出口联箱2相连的省煤器悬吊管3、与每个省煤器悬吊管3连接的省煤器中间联箱4、与省煤器中间联箱4相连的一组省煤器蛇形管6,所述省煤器蛇形管6与省煤器进口联箱10相连;所述省煤器进口联箱10与省煤器中间联箱4之间设有一支路管5,所述支路管5沿着流体流动方向上分别依次设有单通阀9、截止阀8和流量调节阀7,所述SCR反应器包括反应器壳体21、依次设在反应器壳体21内的催化剂预留层14、催化剂首层15和催化剂次层16,所述壳体20底部设有一省煤器灰斗12,所述支路管5的两端分别设有一第一三通管连接器18、第二三通管连接器19,所述流量调节阀7为电动控制调节阀门。 As shown in Figures 1 and 2, an economizer that improves the SCR commissioning rate under low-load conditions includes a shell 20, an economizer outlet header 2 set in the shell 20, and a coal economizer The heat exchange device connected to the outlet header 2 of the economizer, the inlet header 10 of the economizer connected to the heat exchange device, and the SCR reactor connected to the bottom of the shell 20; Economizer suspension pipe 3 connected to box 2, economizer intermediate header 4 connected to each economizer suspension pipe 3, a group of economizer serpentine pipes connected to economizer intermediate header 4 6. The serpentine pipe 6 of the economizer is connected to the inlet header 10 of the economizer; a branch pipe 5 is provided between the inlet header 10 of the economizer and the intermediate header 4 of the economizer. The pipeline 5 is respectively provided with a one-way valve 9, a shut-off valve 8 and a flow regulating valve 7 sequentially along the direction of fluid flow. Reserved layer 14, catalyst first layer 15 and catalyst sub-layer 16, an economizer ash hopper 12 is provided at the bottom of the housing 20, and a first three-way pipe connector 18 is provided at both ends of the branch pipe 5 . The second three-way pipe connector 19, the flow regulating valve 7 is an electric control regulating valve.

SCR脱硝系统投运的条件根据SCR催化剂的活性温度区间确定,一般设计为300℃~400℃。在低负荷运行工况下,省煤器进口烟气1进入省煤器,锅炉省煤器出口烟气11温度低于300℃,而省煤器出口和SCR反应器入口之间没有换热设备,故SCR反应器入口烟气13温度和省煤器出口温度近似相等,低于SCR系统投运温度区间的下限,此时开启旁路截止阀8,并逐步增加调节阀7阀门开度来控制旁路的介质流量,由于旁路的分流作用,参加换热的介质流量会减少,导致介质和烟气的换热量减少,故烟气在省煤器受热面区域的放热量减少,使省煤器出口烟气11和SCR进口烟气13温度升高超过300℃,达到SCR系统的投运温度区间,有效地提高了SCR系统的投运率和催化剂的有效使用时间。 The operating conditions of the SCR denitrification system are determined according to the active temperature range of the SCR catalyst, which is generally designed to be 300°C to 400°C. Under low-load operating conditions, the flue gas 1 at the inlet of the economizer enters the economizer, the temperature of the flue gas 11 at the outlet of the boiler economizer is lower than 300°C, and there is no heat exchange equipment between the economizer outlet and the SCR reactor inlet , so the temperature of the flue gas 13 at the inlet of the SCR reactor is approximately equal to the temperature at the outlet of the economizer, which is lower than the lower limit of the operating temperature range of the SCR system. At this time, the bypass stop valve 8 is opened, and the opening of the regulating valve 7 is gradually increased to control The medium flow rate of the bypass, due to the shunt effect of the bypass, the flow rate of the medium participating in the heat exchange will decrease, resulting in a decrease in the heat exchange between the medium and the flue gas, so the heat release of the flue gas in the heating surface area of the economizer is reduced, so that the economizer The temperature of the flue gas 11 at the outlet of the coal burner and the flue gas 13 at the inlet of the SCR rises by more than 300°C, reaching the operating temperature range of the SCR system, which effectively improves the operating rate of the SCR system and the effective use time of the catalyst.

本实用新型的一种提高低负荷工况SCR投运率的策略在实际工作时情况如下: A kind of strategy of improving the operation rate of SCR in the low-load working condition of the utility model is as follows in actual work:

锅炉省煤器换热装置17主要由省煤器悬吊管3和省煤器蛇形管5组成,蛇形管连接在进口联箱10和中间联箱6之间,悬吊管连接在中间联箱和出口联箱2之间,蛇形管的换热面积大于悬吊管,起到主要的换热作用。在锅炉低负荷运行工况下,省煤器出口烟气11温度低于300℃,此时开启旁路截止阀8,并逐步增加调节阀7阀门开度来控制旁路的介质流量,由于旁路的分流作用,在蛇形管中参加换热的介质流量会减少,导致介质和烟气的换热量减少,故烟气在蛇形管换热区域的放热量减少,从而使省煤器出口烟气温度升高超过300℃。SCR系统的设计投运温度区间为300℃~400℃,反应器内设计三层催化剂,首层为预留层14,预留层下面为填装有蜂窝式催化剂的催化剂首层15和催化剂次层16,由于省煤器出口和SCR反应器入口之间没有换热设备,故进入SCR第一层催化剂15的烟气13温度和省煤器出口温度近似相等,达到SCR系统的投运温度区间,有效地提高了SCR系统的投运率和催化剂的有效使用时间。此外,介质侧的 热容量高于烟气侧,当减少相同的换热量时,烟气侧出口温度升高的幅度大于介质侧出口温度减少的幅度,因此对省煤器介质出口温度降低的对锅炉经济运行的影响较小,保证了本实用新型在工程中的可操作性。 Boiler economizer heat exchange device 17 is mainly composed of economizer suspension pipe 3 and economizer serpentine pipe 5, the serpentine pipe is connected between the inlet header 10 and the middle header 6, and the suspension pipe is connected in the middle Between the header box and the outlet header 2, the heat exchange area of the serpentine tube is larger than that of the suspension tube, which plays a major role in heat exchange. Under the low-load operating condition of the boiler, the temperature of the flue gas 11 at the outlet of the economizer is lower than 300°C. At this time, the bypass stop valve 8 is opened, and the valve opening of the regulating valve 7 is gradually increased to control the medium flow of the bypass. Due to the shunting effect of the road, the flow rate of the medium participating in the heat exchange in the serpentine tube will decrease, resulting in a decrease in the heat exchange between the medium and the flue gas, so the heat release of the flue gas in the heat exchange area of the serpentine tube will be reduced, thereby making the economizer The outlet flue gas temperature rises by more than 300°C. The design and operation temperature range of the SCR system is 300°C to 400°C. Three catalyst layers are designed in the reactor. Layer 16, since there is no heat exchange equipment between the economizer outlet and the SCR reactor inlet, the temperature of the flue gas 13 entering the catalyst 15 of the first layer of the SCR is approximately equal to the temperature at the economizer outlet, reaching the operating temperature range of the SCR system , effectively improving the operating rate of the SCR system and the effective use time of the catalyst. In addition, the heat capacity of the medium side is higher than that of the flue gas side. When the same amount of heat exchange is reduced, the increase in the outlet temperature of the flue gas side is greater than the decrease in the outlet temperature of the medium side. The economical operation of the boiler has less impact, which ensures the operability of the utility model in engineering.

以上所述仅是本实用新型的优选实施方式,应当指出:对于本技术领域的普通技术人员来说,在不脱离本实用新型原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本实用新型的保护范围。 The above is only a preferred embodiment of the utility model, it should be pointed out that for those of ordinary skill in the art, without departing from the principle of the utility model, some improvements and modifications can also be made. Retouching should also be regarded as the scope of protection of the present utility model.

Claims (5)

1. under running on the lower load, improve an economizer for SCR operational percentage, it is characterized in that: the SCR reactor that comprises housing, is located at the economizer exit header in housing, the heat-exchanger rig being connected with economizer exit header, the economizer inlet header being connected with heat-exchanger rig and is connected with housing bottom; Described heat-exchanger rig comprises one group of Coal Saver Hanged Pipe connected with economizer exit header, the economizer intermediate header being connected with each Coal Saver Hanged Pipe, the one group of economizer coiled pipe being connected with economizer intermediate header, and described economizer coiled pipe is connected with economizer inlet header; Between described economizer inlet header and economizer intermediate header, be provided with a bypass duct, described bypass duct is provided with successively respectively one-way valve, stop valve and flow control valve on fluid flow direction.
2. the economizer that improves SCR operational percentage under running on the lower load according to claim 1, is characterized in that: described SCR reactor comprises reactor shell, is located at the reserved layer of catalyst, the catalyst first floor and the catalyst sublevel in reactor shell successively.
3. the economizer that improves SCR operational percentage under running on the lower load according to claim 1, is characterized in that: described housing bottom is provided with an economizer hopper.
4. the economizer that improves SCR operational percentage under running on the lower load according to claim 1, is characterized in that: the two ends of described bypass duct are respectively equipped with a three-way pipe connector.
5. the economizer that improves SCR operational percentage under running on the lower load according to claim 1, is characterized in that: described control valve is electronic control and regulation valve.
CN201420097259.8U 2014-03-05 2014-03-05 A kind of economizer that improves SCR operational percentage under running on the lower load Expired - Lifetime CN203927879U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103939884A (en) * 2014-03-05 2014-07-23 东南大学 Economizer improving SCR commissioning rate under low load working condition
CN104406155A (en) * 2014-11-27 2015-03-11 哈尔滨锅炉厂有限责任公司 Connecting pipe for improving water temperature of coal economizer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103939884A (en) * 2014-03-05 2014-07-23 东南大学 Economizer improving SCR commissioning rate under low load working condition
CN104406155A (en) * 2014-11-27 2015-03-11 哈尔滨锅炉厂有限责任公司 Connecting pipe for improving water temperature of coal economizer

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