[go: up one dir, main page]

CN203519540U - Single-chip micro-gas sensor - Google Patents

Single-chip micro-gas sensor Download PDF

Info

Publication number
CN203519540U
CN203519540U CN201320599081.2U CN201320599081U CN203519540U CN 203519540 U CN203519540 U CN 203519540U CN 201320599081 U CN201320599081 U CN 201320599081U CN 203519540 U CN203519540 U CN 203519540U
Authority
CN
China
Prior art keywords
silicon
heating element
stiff end
temperature measuring
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN201320599081.2U
Other languages
Chinese (zh)
Inventor
马洪宇
王文娟
丁恩杰
赵小虎
程婷婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China University of Mining and Technology CUMT
Original Assignee
China University of Mining and Technology CUMT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China University of Mining and Technology CUMT filed Critical China University of Mining and Technology CUMT
Priority to CN201320599081.2U priority Critical patent/CN203519540U/en
Application granted granted Critical
Publication of CN203519540U publication Critical patent/CN203519540U/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Landscapes

  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

一种单片微瓦斯传感器,传感器的加热元件和测温元件通过固定端固定在硅框架支座上,在加热元件上设有催化剂载体,加热元件和测温元件是相互独立的,加热元件、测温元件不存在电气连接;采用加热元件单独加热催化剂载体,测温元件单独检测因瓦斯催化燃烧形成的温升;采用MEMS技术加工的用于煤矿井下检测瓦斯浓度的一种瓦斯传感器,其制备工艺与CMOS工艺兼容。优点:该传感器配置简单,操作容易,功耗低、灵敏度高。加热元件整体嵌入催化剂载体中,提高电致发热效率,高效利用加热器的热量,还可独立调控加热元件、检测测温元件。

Figure 201320599081

A monolithic micro-gas sensor, the heating element and the temperature measuring element of the sensor are fixed on the silicon frame support through the fixed end, a catalyst carrier is arranged on the heating element, the heating element and the temperature measuring element are independent of each other, and there is no electrical connection between the heating element and the temperature measuring element; the heating element is used to heat the catalyst carrier alone, and the temperature measuring element is used to detect the temperature rise caused by the catalytic combustion of gas alone; a gas sensor processed by MEMS technology for detecting gas concentration in coal mines, and its preparation process is compatible with CMOS process. Advantages: The sensor has simple configuration, easy operation, low power consumption and high sensitivity. The heating element is embedded in the catalyst carrier as a whole, which improves the efficiency of electrothermal heating, efficiently utilizes the heat of the heater, and can also independently control the heating element and detect the temperature measuring element.

Figure 201320599081

Description

一种单片微瓦斯传感器A single-chip microgas sensor

技术领域 technical field

    本实用新型涉及一种瓦斯传感器,特别是一种单片微瓦斯传感器。 The utility model relates to a gas sensor, in particular to a single-chip micro gas sensor.

背景技术 Background technique

目前基于传统铂丝加热的催化燃烧式瓦斯传感器仍在煤矿井下广泛应用,但其功耗较大,不能很好的满足物联网对低功耗瓦斯传感器的应用需求。而其它的瓦斯传感器则较难适应煤矿井下高湿度的环境。以往报道的微瓦斯传感器,多采用金属铂电阻作为加热元件,该铂电阻同时也作为测温元件。由于加热元件、测温元件是同一个铂电阻,这使得对温度测量的诸多先进技术受同时施加在铂电阻上的加热电压或电流的制约而无法应用,限制了瓦斯检测技术的发展。 At present, the catalytic combustion gas sensor based on traditional platinum wire heating is still widely used in coal mines, but its power consumption is relatively large, which cannot well meet the application requirements of the Internet of Things for low-power gas sensors. Other gas sensors are more difficult to adapt to the environment of high humidity in coal mines. Most of the microgas sensors reported in the past use metal platinum resistors as heating elements, and the platinum resistors are also used as temperature measuring elements. Since the heating element and the temperature measuring element are the same platinum resistor, many advanced technologies for temperature measurement are restricted by the heating voltage or current applied to the platinum resistor at the same time, which limits the development of gas detection technology.

实用新型内容 Utility model content

技术问题:本实用新型的目的是提供一种单片微瓦斯传感器,解决现有催化燃烧式瓦斯传感器的铂丝电阻元件复用所带来的问题,即同一个铂丝电阻同时作为加热元件及测温元件在控制温度与测量温度时无法分别调控的问题。 Technical problem: The purpose of this utility model is to provide a single-chip micro-gas sensor to solve the problem caused by the reuse of platinum wire resistance elements of existing catalytic combustion gas sensors, that is, the same platinum wire resistance can be used as a heating element and a heating element at the same time. The problem that the temperature measuring element cannot be adjusted separately when controlling the temperature and measuring the temperature.

技术方案:本实用新型的目的是这样实现的:该单片微瓦斯传感器包括催化剂载体、加热元件、测温元件、固定端与硅框架支座;所述硅框架支座包括硅衬底与设在硅衬底上的埋层氧化硅;所述固定端包括支撑硅层、设在支撑硅层外的氧化硅层,设在氧化硅层上的用作电引出焊盘Pad的金属层;所述固定端的支撑硅层内设有掺杂硅层;所述电引出焊盘Pad的金属层通过氧化硅层的窗口与固定端的掺杂硅层相接触构成欧姆接触;所述固定端设在硅框架支座上的埋层氧化硅上;所述加热元件、测温元件均包括支撑硅层、设在支撑硅层外的氧化硅层;加热元件设有硅加热器、两个对称设置的硅悬臂;所述硅加热器较佳为圆环形,圆环形硅加热器中间较佳设有两个对称内伸的散热-支撑硅块;所述硅悬臂的一端与硅加热器相连,另一端与硅框架支座上的固定端相连;所述加热元件的硅加热器上设有催化剂载体,加热元件的硅加热器完全嵌入在催化剂载体中,并且催化剂载体贯穿于硅加热器中,尤其是催化剂载体是一个整体结构;所述测温元件设有硅测温环、两个对称设置的硅连接臂,两个对称设置的硅支撑臂;所述硅测温环、硅连接臂、硅支撑臂、固定端依次相连;加热元件、测温元件分别与其各自的固定端构成独立的二端器件通路,并通过固定端固定在硅框架支座上的埋层氧化硅上;  Technical solution: the purpose of this utility model is achieved in this way: the single-chip micro gas sensor includes a catalyst carrier, a heating element, a temperature measuring element, a fixed end and a silicon frame support; the silicon frame support includes a silicon substrate and a device Buried layer of silicon oxide on the silicon substrate; the fixed end includes a supporting silicon layer, a silicon oxide layer disposed outside the supporting silicon layer, and a metal layer disposed on the silicon oxide layer as an electrical lead-out pad Pad; The supporting silicon layer of the fixed end is provided with a doped silicon layer; the metal layer of the electrical lead-out pad Pad is in contact with the doped silicon layer of the fixed end through the window of the silicon oxide layer to form an ohmic contact; the fixed end is arranged on the silicon On the buried layer of silicon oxide on the frame support; the heating element and the temperature measuring element all include a supporting silicon layer and a silicon oxide layer arranged outside the supporting silicon layer; the heating element is provided with a silicon heater, two symmetrically arranged silicon Cantilever; the silicon heater is preferably circular, and two symmetrical heat dissipation-supporting silicon blocks are preferably provided in the middle of the circular silicon heater; one end of the silicon cantilever is connected with the silicon heater, and the other One end is connected with the fixed end on the silicon frame support; the silicon heater of the heating element is provided with a catalyst carrier, the silicon heater of the heating element is completely embedded in the catalyst carrier, and the catalyst carrier runs through the silicon heater, especially The catalyst carrier is an integral structure; the temperature measuring element is provided with a silicon temperature measuring ring, two symmetrically arranged silicon connecting arms, and two symmetrically arranged silicon supporting arms; the silicon temperature measuring ring, the silicon connecting arm, the silicon The support arm and the fixed end are connected in sequence; the heating element and the temperature measuring element form independent two-terminal device paths with their respective fixed ends, and are fixed on the buried silicon oxide on the silicon frame support through the fixed ends;

所述测温元件的硅测温环与加热元件的硅加热器的边缘距离为3um至100um;与测温元件相连的固定端以及与加热元件相连的固定端较佳设置在硅框架支座的相同一侧的位置; The edge distance between the silicon temperature measuring ring of the temperature measuring element and the silicon heater of the heating element is 3um to 100um; the fixed end connected with the temperature measuring element and the fixed end connected with the heating element are preferably arranged on the silicon frame support position on the same side;

加热元件独立加热催化剂载体,测温元件独立检测因瓦斯催化燃烧造成的温升,测温元件测量时不受加热元件所施加的电压或电流的影响。 The heating element independently heats the catalyst carrier, and the temperature measuring element independently detects the temperature rise caused by the catalytic combustion of gas. The temperature measuring element is not affected by the voltage or current applied by the heating element during measurement.

有益效果,由于采用了上述方案,本实用新型的单片硅微瓦斯传感器采用MEMS工艺加工,加热元件与测温元件从SOI硅片中释放出来、悬在空气中,很大程度上降低了通过SOI硅片的热量损失,因此可有效的降低加热元件的功耗;加热元件与测温元件没有直接接触,加热元件及其在在瓦斯催化燃烧时所释放的热量主要通过空气的热传导及热辐射的方式被其一侧的测温元件检测。其制备方法可与CMOS工艺兼容,批量制作可降低成本、并提高一致性。传感器功耗低、灵敏度高,能够满足煤矿井下环境物联网对瓦斯传感器的需求。 Beneficial effects, due to the adoption of the above scheme, the single-chip silicon micro-gas sensor of the present invention is processed by MEMS technology, and the heating element and the temperature measuring element are released from the SOI silicon chip and suspended in the air, which greatly reduces the temperature passing through. The heat loss of the SOI silicon chip can effectively reduce the power consumption of the heating element; the heating element and the temperature measuring element are not in direct contact, and the heat released by the heating element and its catalytic combustion of gas is mainly through the heat conduction and heat radiation of the air The way is detected by the temperature measuring element on one side. The preparation method is compatible with the CMOS process, and the batch production can reduce the cost and improve the consistency. The sensor has low power consumption and high sensitivity, which can meet the needs of the coal mine environment Internet of Things for gas sensors.

优点:本实用新型提供的单片微瓦斯传感器,其加热元件与测温元件都通过固定端固定在同一个器件上,实现瓦斯的单片检测;加热元件与测温元件相互独立,不再受传统的单一元件加热与测温功能复用的限制,可单独调控加热元件、单独对测温元件进行检测。分别对加热元件与测温元件进行调控,可为传感器提供多样性的工作模式,且配置简单、工作灵活、因此提高了传感器的综合性能。 Advantages: The single-chip micro-gas sensor provided by the utility model has both the heating element and the temperature measuring element fixed on the same device through the fixed end, so as to realize single-chip detection of gas; the heating element and the temperature measuring element are independent of each other and are no longer affected Due to the limitations of the multiplexing of the traditional single element heating and temperature measurement functions, the heating element can be controlled separately and the temperature measurement element can be tested separately. Regulating the heating element and the temperature measuring element separately can provide a variety of working modes for the sensor, and the configuration is simple and the work is flexible, thus improving the overall performance of the sensor.

所述加热元件、测温元件等构件的图形根据MEMS加工实际情况可能不同于本实用新型的描述,仍属本实用新型所主张的权利要求。 The graphics of the heating element, temperature measuring element and other components may be different from the description of the utility model according to the actual situation of MEMS processing, and still belong to the claims of the utility model.

附图说明 Description of drawings

图1为本实用新型的分立的硅器件的俯视示意图。 FIG. 1 is a schematic top view of a discrete silicon device of the present invention.

图2为本实用新型的分立的硅器件负载催化剂载体后的俯视示意图。 Fig. 2 is a schematic top view of a discrete silicon device of the present invention loaded with a catalyst carrier.

图3为本实用新型的分立的硅器件或负载有催化剂载体及催化剂的分立的硅器件的固定端的剖视图,即图2中的A-A截面剖视图。 Fig. 3 is a cross-sectional view of the fixed end of the discrete silicon device of the present invention or the discrete silicon device loaded with catalyst carrier and catalyst, that is, the cross-sectional view of A-A in Fig. 2 .

图4为本实用新型的分立的硅器件负载催化剂载体后的剖视图,即图2中的B-B截面剖视图。  Fig. 4 is a cross-sectional view of a discrete silicon device of the present invention loaded with a catalyst carrier, that is, a cross-sectional view along B-B in Fig. 2 . the

具体实施方式 Detailed ways

下面结合附图对本实用新型的一个实施例作进一步的描述: An embodiment of the present utility model is further described below in conjunction with accompanying drawing:

如图1、图2所示,本实用新型的单片微瓦斯传感器包括催化剂载体105、加热元件103、测温元件104、固定端102与硅框架支座101;所述硅框架支座101包括硅衬底11与设在硅衬底11上的埋层氧化硅12;所述固定端102如图3所示,包括支撑硅层21、设在支撑硅层21外的氧化硅层23,设在氧化硅层23上的用作电引出焊盘Pad的金属层22;所述固定端102的支撑硅层21内设有掺杂硅层24;所述电引出焊盘Pad的金属层22通过氧化硅层23的窗口与固定端102的掺杂硅层24相接触构成欧姆接触;所述固定端102设在硅框架支座101上的埋层氧化硅12上;所述加热元件103、测温元件104均包括支撑硅层21、设在支撑硅层21外的氧化硅层23;加热元件103设有硅加热器1031、两个对称设置的硅悬臂1032;所述硅加热器1031较佳为圆环形,圆环形硅加热器1031中间较佳设有两个对称内伸的散热-支撑硅块1033;所述硅悬臂1032的一端与硅加热器1031相连,另一端与硅框架支座101上的固定端102相连;所述加热元件103的硅加热器1031上设有催化剂载体105,加热元件103的硅加热器1031完全嵌入在催化剂载体105中,并且催化剂载体105贯穿于硅加热器1031中,尤其是催化剂载体105是一个整体结构,如图4所示;所述测温元件104设有硅测温环1041、两个对称设置的硅连接臂1042,两个对称设置的硅支撑臂1043;所述硅测温环1041、硅连接臂1042、硅支撑臂1043、固定端102依次相连;加热元件103、测温元件104分别与其各自的固定端102构成独立的二端器件通路,并通过固定端102固定在硅框架支座101上的埋层氧化硅12上;  As shown in Fig. 1 and Fig. 2, the monolithic microgas sensor of the present utility model includes a catalyst carrier 105, a heating element 103, a temperature measuring element 104, a fixed end 102 and a silicon frame support 101; the silicon frame support 101 includes Silicon substrate 11 and the buried silicon oxide layer 12 disposed on the silicon substrate 11; the fixed end 102, as shown in Figure 3, includes a supporting silicon layer 21, a silicon oxide layer 23 arranged outside the supporting silicon layer 21, and The metal layer 22 used as the electrical lead-out pad Pad on the silicon oxide layer 23; the supporting silicon layer 21 of the fixed end 102 is provided with a doped silicon layer 24; the metal layer 22 of the electric lead-out pad Pad passes through The window of the silicon oxide layer 23 is in contact with the doped silicon layer 24 of the fixed end 102 to form an ohmic contact; the fixed end 102 is arranged on the buried silicon oxide 12 on the silicon frame support 101; the heating element 103, measuring The temperature elements 104 all include a supporting silicon layer 21 and a silicon oxide layer 23 outside the supporting silicon layer 21; the heating element 103 is provided with a silicon heater 1031 and two symmetrically arranged silicon cantilevers 1032; the silicon heater 1031 is preferably It is circular, and two symmetrical heat dissipation-supporting silicon blocks 1033 are preferably provided in the middle of the circular silicon heater 1031; one end of the silicon cantilever 1032 is connected with the silicon heater 1031, and the other end is connected with the silicon frame support. The fixed ends 102 on the seat 101 are connected; the silicon heater 1031 of the heating element 103 is provided with a catalyst carrier 105, and the silicon heater 1031 of the heating element 103 is completely embedded in the catalyst carrier 105, and the catalyst carrier 105 runs through the silicon heater. In the device 1031, especially the catalyst carrier 105 is an integral structure, as shown in Figure 4; the temperature measuring element 104 is provided with a silicon temperature measuring ring 1041, two symmetrically arranged silicon connecting arms 1042, and two symmetrically arranged silicon connecting arms 1042. The supporting arm 1043; the silicon temperature measuring ring 1041, the silicon connecting arm 1042, the silicon supporting arm 1043, and the fixed end 102 are sequentially connected; the heating element 103, the temperature measuring element 104 and their respective fixed ends 102 form independent two-terminal device paths , and fixed on the buried silicon oxide 12 on the silicon frame support 101 through the fixed end 102;

所述测温元件104的硅测温环1041与加热元件103的硅加热器1031的边缘距离为3um至100um;与测温元件104相连的固定端102以及与加热元件103相连的固定端102较佳设置在硅框架支座101的相同一侧的位置; The edge distance between the silicon temperature measuring ring 1041 of the temperature measuring element 104 and the silicon heater 1031 of the heating element 103 is 3um to 100um; Preferably set on the same side of the silicon frame support 101;

加热元件103独立加热催化剂载体105,测温元件104独立检测因瓦斯催化燃烧造成的温升,测温元件104测量时不受加热元件103所施加的电压或电流的影响。 The heating element 103 independently heats the catalyst carrier 105, and the temperature measuring element 104 independently detects the temperature rise caused by the gas catalytic combustion, and the temperature measuring element 104 is not affected by the voltage or current applied by the heating element 103 during measurement.

Claims (1)

1. the micro-firedamp sensor of monolithic, is characterized in that: the micro-firedamp sensor of this monolithic comprises catalyst support (105), heating element (103), temperature element (104), stiff end (102) and silicon frame bearing (101); Described silicon frame bearing (101) comprises silicon substrate (11) and is located at the buried regions monox (12) on silicon substrate (11); Described stiff end (102) comprises support silicon layer (21), is located at and supports the outer silicon oxide layer (23) of silicon layer (21), is located at the metal level (22) of drawing pad Pad as electricity on silicon oxide layer (23); In the support silicon layer (21) of described stiff end (102), be provided with doped silicon layer (24); The metal level (22) that described electricity is drawn pad Pad is by the window of silicon oxide layer (23) and the doped silicon layer (24) of stiff end (102) the formation Ohmic contact that contacts; Described stiff end (102) is located on the buried regions monox (12) on silicon frame bearing (101); Described heating element (103), temperature element (104) include and support silicon layer (21), are located at and support the outer silicon oxide layer (23) of silicon layer (21); Heating element (103) is provided with silicon well heater (1031), two symmetrically arranged silicon cantilevers (1032); Described silicon well heater (1031) is preferably annular, the better heat radiation-support silico briquette (1033) stretched in two symmetries that is provided with in the middle of annular silicon well heater (1031); One end of described silicon cantilever (1032) is connected with silicon well heater (1031), and the other end is connected with the stiff end (102) on silicon frame bearing (101); The silicon well heater (1031) of described heating element (103) is provided with catalyst support (105), the silicon well heater (1031) of heating element (103) is embedded in catalyst support (105) completely, and catalyst support (105) is in silicon well heater (1031), and especially catalyst support (105) is an one-piece construction; Described temperature element (104) is provided with silicon firing ring (1041), two symmetrically arranged silicon linking arms (1042), two symmetrically arranged silicon sway braces (1043); Described silicon firing ring (1041), silicon linking arm (1042), silicon sway brace (1043), stiff end (102) are connected successively; Heating element (103), temperature element (104) form independently two-terminal device path with its stiff end (102) separately respectively, and are fixed on the buried regions monox (12) on silicon frame bearing (101) by stiff end (102);
The silicon firing ring (1041) of described temperature element (104) is 3um to 100um with the Edge Distance of the silicon well heater (1031) of heating element (103); The stiff end (102) being connected with temperature element (104) and the better position that is arranged on phase the same side of silicon frame bearing (101) of the stiff end (102) being connected with heating element (103);
Heating element (103) independent heating catalyst support (105), the temperature rise that temperature element (104) independent detection Yin Wasi catalytic combustion causes, is not subject to voltage that heating element (103) applies or the impact of electric current when temperature element (104) is measured.
CN201320599081.2U 2013-09-26 2013-09-26 Single-chip micro-gas sensor Expired - Lifetime CN203519540U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201320599081.2U CN203519540U (en) 2013-09-26 2013-09-26 Single-chip micro-gas sensor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201320599081.2U CN203519540U (en) 2013-09-26 2013-09-26 Single-chip micro-gas sensor

Publications (1)

Publication Number Publication Date
CN203519540U true CN203519540U (en) 2014-04-02

Family

ID=50378458

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201320599081.2U Expired - Lifetime CN203519540U (en) 2013-09-26 2013-09-26 Single-chip micro-gas sensor

Country Status (1)

Country Link
CN (1) CN203519540U (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103499617A (en) * 2013-09-26 2014-01-08 中国矿业大学 Monolithic micro-gas sensor and manufacturing method thereof
WO2016066089A1 (en) * 2014-10-31 2016-05-06 中国矿业大学 Methane sensor based on single heating component, manufacturing method, and applications
WO2016066106A1 (en) * 2014-10-31 2016-05-06 中国矿业大学 All-silicon mems methane sensor, fuel gas detection application, and manufacturing method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103499617A (en) * 2013-09-26 2014-01-08 中国矿业大学 Monolithic micro-gas sensor and manufacturing method thereof
WO2016066089A1 (en) * 2014-10-31 2016-05-06 中国矿业大学 Methane sensor based on single heating component, manufacturing method, and applications
WO2016066106A1 (en) * 2014-10-31 2016-05-06 中国矿业大学 All-silicon mems methane sensor, fuel gas detection application, and manufacturing method

Similar Documents

Publication Publication Date Title
CN203519540U (en) Single-chip micro-gas sensor
CN104541161A (en) Micro-hotplate device and sensor comprising such micro-hotplate device
CN103017943A (en) Double-range pressure sensing mechanism
CN104316574B (en) A kind of methane transducer and preparation method and application based on single heating element heater
CN108120747B (en) Preparation method of tin dioxide-based gas sensor and carbon monoxide gas sensor system
Xu et al. A high heating efficiency two-beam microhotplate for catalytic gas sensors
Lu et al. Micro catalytic methane sensors based on 3D quartz structures with cone-shaped cavities etched by high-resolution abrasive sand blasting
CN103499617B (en) A kind of monolithic micro gas sensor and its preparation method
CN102590289B (en) Catalytic combustion type gas sensor
CN202814906U (en) Catalytic combustion type gas sensor
CN106662548B (en) Gas sensor
CN207571069U (en) A kind of gas sensor
CN104458828A (en) Acetone gas sensory semiconductor sensor
CN103482562B (en) Micro-gas sensor with laminated structure and preparation method thereof
CN204154677U (en) Based on the MEMS methane transducer of silicon well heater
CN204154680U (en) A kind of MEMS methane transducer
CN203513269U (en) Micro-gas sensor with laminated structure
CN104316575A (en) Full-silicon MEMS (micro-electromechanical system) methane sensor, gas detection application and preparation method of full-silicon MEMS methane sensor
CN203519541U (en) Recoverable repeatedly prepared gas micro-sensor
CN104316576B (en) MEMS methane transducers based on silicon heater and preparation method and application
CN204154679U (en) A kind of methane transducer based on single heating element
CN204154676U (en) A kind of methane transducer based on flip chip bonding encapsulation
JP5927647B2 (en) Gas detector
CN104316577A (en) Methane sensor based on flip-chip packaging, as well as preparation method and application thereof
CN109239137B (en) A kind of miniature methane sensor and methane detection method

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
AV01 Patent right actively abandoned

Granted publication date: 20140402

Effective date of abandoning: 20150708

AV01 Patent right actively abandoned

Granted publication date: 20140402

Effective date of abandoning: 20150708

RGAV Abandon patent right to avoid regrant