CN203247158U - High-efficient adsorption columella for detecting bromate in drinking water - Google Patents
High-efficient adsorption columella for detecting bromate in drinking water Download PDFInfo
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- CN203247158U CN203247158U CN 201320281942 CN201320281942U CN203247158U CN 203247158 U CN203247158 U CN 203247158U CN 201320281942 CN201320281942 CN 201320281942 CN 201320281942 U CN201320281942 U CN 201320281942U CN 203247158 U CN203247158 U CN 203247158U
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- sieve plate
- bromate
- drinking water
- adsorption
- sieve
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- 238000001179 sorption measurement Methods 0.000 title claims abstract description 36
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 title claims abstract description 26
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003651 drinking water Substances 0.000 title claims abstract description 26
- 235000020188 drinking water Nutrition 0.000 title claims abstract description 26
- 241000083547 Columella Species 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 238000005342 ion exchange Methods 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 3
- 238000001514 detection method Methods 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 11
- RJZNFXWQRHAVBP-UHFFFAOYSA-I aluminum;magnesium;pentahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Al+3] RJZNFXWQRHAVBP-UHFFFAOYSA-I 0.000 abstract 2
- 238000004659 sterilization and disinfection Methods 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000006385 ozonation reaction Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 bromo compound Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 229910052811 halogen oxide Inorganic materials 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000011012 sanitization Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Water Treatment By Sorption (AREA)
Abstract
本实用新型涉及一种用于饮用水中溴酸盐检测的高效吸附小柱，包括填充柱，所述填充柱内从下往上依次设置有第一筛板、层状氢氧化镁铝吸附层、强碱性离子交换纤维层以及第二筛板；所述填充柱的材质为PE，所述填充柱的内径为10-30mm，体积为50-100mL；所述第一筛板和第二筛板的材质均为玻璃砂芯，所述第一筛板的筛孔直径小于第二筛板的筛孔直径，所述第一筛板和第二筛板的筛孔直径取值范围为20-120μm。该用于饮用水中溴酸盐检测的高效吸附小柱通过层状氢氧化镁铝吸附层和强碱性离子交换纤维层可以吸附大体积水样并完成吸附浓缩过程，吸附浓缩时间短、效率高且无需能耗，适用于现场快速浓缩饮用水中溴酸盐。
The utility model relates to a high-efficiency adsorption small column for bromate detection in drinking water, which includes a packed column, and the filled column is sequentially provided with a first sieve plate and a layered magnesium-aluminum hydroxide adsorption layer from bottom to top , a strong basic ion exchange fiber layer and a second sieve plate; the material of the packed column is PE, the inner diameter of the packed column is 10-30mm, and the volume is 50-100mL; the first sieve plate and the second sieve plate The material of the plate is glass sand core, the sieve hole diameter of the first sieve plate is smaller than the sieve hole diameter of the second sieve plate, and the value range of the sieve hole diameter of the first sieve plate and the second sieve plate is 20- 120 μm. The high-efficiency adsorption column for bromate detection in drinking water can absorb large-volume water samples and complete the adsorption and concentration process through the layered magnesium aluminum hydroxide adsorption layer and strong alkaline ion exchange fiber layer, with short adsorption and concentration time and high efficiency. High and energy-free, suitable for on-site rapid concentration of bromate in drinking water.
Description
Technical field
The utility model relates to a kind of efficient adsorption pillar for the bromate in drinking water detection.
Background technology
Drinking water disinfection is to control pathogenic bacterium in the water, guarantee human life safely and the important technical of using, and the sterilization method that present tap water is commonly used mainly contains 4 kinds, i.e. chlorine disinfectant method, chloramine disinfection, ozone disinfection and disinfection by chlorine dioxide method.Use ozone to carry out the aroma and flavor that drinking water disinfection can improve tap water effectively, have simultaneously decolouring, kill microorganisms, Oxidation of Fe
2+, Mn
2+Isoionic effect, therefore be counted as a kind of very promising Drinking Water Sanitization Technology, but in using the ozonization process, can produce disinfection byproduct (DBP) (DBPs) and affect HUMAN HEALTH, disinfection byproduct (DBP) is mainly some oxygen containing compounds, such as hydrogen peroxide, aldehydes, ketone, carboxylic acid, ketone acid, bromo compound and inorganic halogen oxide etc.
Because bromide anion (Br in the nature water source
-) be extensively to exist, the way of production mainly contains seawater intrusion surface water and groundwater waterbearing stratum mineral dissolution, and the production of exploitation potassium ore deposit, colliery and soda etc. all may cause bromide anion (Br in the water in the mankind's activity
-) increase of content, when therefore using ozonization, just have a certain amount of disinfection byproduct (DBP) bromate and produce.Bromate is defined as the human suspect carcinogen of a kind of 2B level (having higher carcinogenic possibility) by international tumor tissues, developed country and China have all formulated the strict requirement of limiting the quantity of (10 micrograms per litre), the detection method of stipulating in the GB is ion chromatography, but chromatography of ions is expensive, and can not be used for field quick detection.Be adapted to on-the-spot method for quick, brought difficulty because its content is very low to detection, therefore to concentrate bromate, by domestic and international main academics search engine as: the results such as Baidu, Google show, the concentrated method of bromate in drinking water is mainly microwave-oven-heating concentrated, but the time that microwave heating concentrates is oversize, energy consumption is large, and concentration process can not be finished at the scene.
Therefore research and development are applicable to the device of on-the-spot fast concentrated bromate in drinking water, and are significant.
The utility model content
The utility model is made improvement for the problem that above-mentioned prior art exists, and it is short and need not the efficient adsorption pillar that bromate in drinking water detects that is used for of energy consumption that namely technical problem to be solved in the utility model provides a kind of adsorption time.
In order to solve the problems of the technologies described above, the technical solution of the utility model is: a kind of efficient adsorption pillar for the bromate in drinking water detection, comprise packed column, be disposed with from the bottom up the first sieve plate, stratiform Ripon adsorption layer, strong basicity ion-exchange fiber layer and the second sieve plate in the described packed column.
Further, the internal diameter of described packed column is 10-30mm, and volume is 50-100 mL.
Further, the material of described packed column is PE.
Further, the sieve diameter of described the first sieve plate is less than the sieve diameter of the second sieve plate, and the sieve diameter span of described the first sieve plate and the second sieve plate is 20-120 μ m.
Further, the material of described the first sieve plate and the second sieve plate is the glass core.
Further, the bottom of described packed column is provided with water out adapter, and described water out adapter is connected with small cap with holes.
Further, the material of layered Ripon adsorption layer is the stratiform Ripon, and its particle diameter is the 80-200 order, and its weight is 0.5-2g.
Further, the material of described strong basicity ion-exchange fiber layer is the strong basicity ion-exchange fiber, and its weight is 0.1g-1.0g.
Further, the weight ratio of layered Ripon adsorption layer and strong basicity ion-exchange fiber layer is 5:1-5:5.
Compared with prior art, the utlity model has following beneficial effect: the efficient adsorption pillar that should be used for the bromate in drinking water detection can adsorb water sample with bulk mass and finish the Adsorption Concentration process by arranging of the first sieve plate, stratiform Ripon adsorption layer, strong basicity ion-exchange fiber layer and the second sieve plate, the Adsorption Concentration time is short, efficient is high and need not energy consumption, is applicable to on-the-spot fast concentrated bromate in drinking water.
The utility model is described in more detail below in conjunction with the drawings and specific embodiments.
Description of drawings
Fig. 1 is the organigram of the utility model embodiment.
Among the figure: 1-packed column, 2-the first sieve plate, 3-stratiform Ripon adsorption layer, 4-strong basicity ion-exchange fiber layer, 5-the second sieve plate, 6-water out adapter, the small cap that 7-is with holes.
Embodiment
As shown in Figure 1, a kind of efficient adsorption pillar for the bromate in drinking water detection, comprise packed column 1, be disposed with from the bottom up the first sieve plate 2, stratiform Ripon adsorption layer 3, strong basicity ion-exchange fiber layer 4 and the second sieve plate 5 in the described packed column 1.
In the present embodiment, the material of described packed column 1 is PE, and the internal diameter of described packed column 1 is 10-30mm, and volume is 50-100mL; The material of described the first sieve plate 2 and the second sieve plate 5 is the glass core, and the sieve diameter of described the first sieve plate 2 is less than the sieve diameter of the second sieve plate 5, and the sieve diameter span of described the first sieve plate 2 and the second sieve plate 5 is 20-120 μ m.The detection volume of water sample that should adsorb for the efficient adsorption pillar that bromate in drinking water detects is 200-1000mL.
In the present embodiment, the bottom of described packed column 1 is provided with water out adapter 6, and described water out adapter 6 is connected with small cap with holes 7 with the flow velocity of control elutriant.The material of layered Ripon adsorption layer 3 is the stratiform Ripon, and its weight is 0.5-2g, and its particle diameter is the 80-200 order; The material of described strong basicity ion-exchange fiber layer 4 is the strong basicity ion-exchange fiber, and its weight is 0.1g-1.0g, and the weight ratio of this stratiform Ripon and this strong basicity ion-exchange fiber is 5:1-5:5.
Wherein, the making method of this stratiform Ripon is as follows: (1) takes by weighing the Mg (NO of certain molar ratio
3)
26H
2O, Al (NO
3)
39H
2O, NaOH and Na
2CO
3(2) with deionized water ultrasonic dissolution Mg (NO
3)
2.6H
2O and Al (NO
3)
3.9H
2O is to make mixing salt solution, with deionized water ultrasonic dissolution NaOH and Na
2CO
3To make mixed ammonium/alkali solutions; (3) mixing salt solution and mixed ammonium/alkali solutions are added in the beaker simultaneously, and violent stirring; (4) mix beaker to be placed on after complete and continue to stir certain hour on the magnetic stirring apparatus; (5) after stirring is finished beaker is inserted in the thermostat water bath, the constant temperature certain hour discards the supernatant liquor in the beaker at a certain temperature; (6) use the deionized water washing and precipitating, every the 2h repetitive operation once, until the pH=7 of supernatant liquor in the beaker, and guarantee that the time dimension of whole constant temperature water bath process is held in 24h; (7) after ageing and washing are finished, the oyster white mashed prod is transferred to the centrifugal moisture that discards in the 50mL centrifuge tube, the centrifugal throw out that obtains dry for some time under the certain temperature in baking oven, oven dry is till can grind; (8) grinding is sieved after the oven dry, namely makes hydrotalcite-based compound (LDHs); (9) LDHs that makes is placed muffle furnace, at a certain temperature roasting for some time, make Mg/Al composite oxides (CLDH), prepared product is positioned in the moisture eliminator saves backup.
The above only is preferred embodiment of the present utility model, and all equalizations of doing according to the utility model claim change and modify, and all should belong to covering scope of the present utility model.
Claims (9)
1. one kind is used for the efficient adsorption pillar that bromate in drinking water detects, comprise packed column, it is characterized in that: be disposed with from the bottom up the first sieve plate, stratiform Ripon adsorption layer, strong basicity ion-exchange fiber layer and the second sieve plate in the described packed column.
2. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1, it is characterized in that: the internal diameter of described packed column is 10-30mm, volume is 50-100 mL.
3. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1 and 2, it is characterized in that: the material of described packed column is PE.
4. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1, it is characterized in that: the sieve diameter of described the first sieve plate is less than the sieve diameter of the second sieve plate, and the sieve diameter span of described the first sieve plate and the second sieve plate is 20-120 μ m.
5. according to claim 1 or 4 described a kind of efficient adsorption pillars that detect for bromate in drinking water, it is characterized in that: the material of described the first sieve plate and the second sieve plate is the glass core.
6. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1, it is characterized in that: the bottom of described packed column is provided with water out adapter, and described water out adapter is connected with small cap with holes.
7. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1, it is characterized in that: the material of layered Ripon adsorption layer is the stratiform Ripon, and its particle diameter is the 80-200 order, and its weight is 0.5-2g.
8. a kind of efficient adsorption pillar that detects for bromate in drinking water according to claim 1, it is characterized in that: the material of described strong basicity ion-exchange fiber layer is the strong basicity ion-exchange fiber, its weight is 0.1g-1.0g.
9. according to claim 1,7 or 8 described a kind of efficient adsorption pillars that detect for bromate in drinking water, it is characterized in that: the weight ratio of layered Ripon adsorption layer and strong basicity ion-exchange fiber layer is 5:1-5:5.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201320281942 CN203247158U (en) | 2013-05-22 | 2013-05-22 | High-efficient adsorption columella for detecting bromate in drinking water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201320281942 CN203247158U (en) | 2013-05-22 | 2013-05-22 | High-efficient adsorption columella for detecting bromate in drinking water |
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| CN203247158U true CN203247158U (en) | 2013-10-23 |
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ID=49373609
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103920453A (en) * | 2014-04-22 | 2014-07-16 | 福建出入境检验检疫局检验检疫技术中心 | Preparation method of laminated magaldrate |
-
2013
- 2013-05-22 CN CN 201320281942 patent/CN203247158U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103920453A (en) * | 2014-04-22 | 2014-07-16 | 福建出入境检验检疫局检验检疫技术中心 | Preparation method of laminated magaldrate |
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|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131023 Termination date: 20210522 |
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| CF01 | Termination of patent right due to non-payment of annual fee |