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CN203238227U - System for pressurized fluidized bed - Google Patents

System for pressurized fluidized bed Download PDF

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CN203238227U
CN203238227U CN2013201868224U CN201320186822U CN203238227U CN 203238227 U CN203238227 U CN 203238227U CN 2013201868224 U CN2013201868224 U CN 2013201868224U CN 201320186822 U CN201320186822 U CN 201320186822U CN 203238227 U CN203238227 U CN 203238227U
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fluidized bed
pressurized fluidized
decompression
pipe
slag
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张宗飞
汤连英
王光友
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China Wuhuan Engineering Co Ltd
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Abstract

本实用新型涉及煤炭气化的加压流化床其系统,解决了现有系统存在的系统不稳定、除杂除尘排渣不佳的问题。技术方案包括加压流化床,所述加压流化床气化炉的反应气出口依次连接有机物分解装置、旋风除尘器、废热锅炉、高温过滤器及洗涤塔。本实用新型系统简单、操作简便、可靠性高、运行成本低、产品煤气品质优秀、系统运行稳定。

Figure 201320186822

The utility model relates to a pressurized fluidized bed system for coal gasification, which solves the problems of unstable system and poor removal of impurities, dust and slag in the existing system. The technical solution includes a pressurized fluidized bed, and the reaction gas outlet of the pressurized fluidized bed gasifier is sequentially connected to an organic matter decomposition device, a cyclone dust collector, a waste heat boiler, a high temperature filter and a washing tower. The utility model has the advantages of simple system, convenient operation, high reliability, low operation cost, excellent product gas quality and stable system operation.

Figure 201320186822

Description

加压流化床系统Pressurized fluidized bed system

技术领域 technical field

本实用新型涉及一种煤炭气化系统,具体的说是一种煤炭气化的加压流化床系统。The utility model relates to a coal gasification system, in particular to a pressurized fluidized bed system for coal gasification.

背景技术 Background technique

我国是一个少油、缺气,煤炭相对丰富的国家。高水份、高灰分低质煤占很大比重。近十几年,我国煤炭气化生产工艺技术取得了长足发展,各种煤炭工艺技术也不断提高和改善,随着国家对节能减排力度的增加,煤炭气化技术越来越受到各方面的重视。my country is a country with little oil, gas shortage and relatively rich coal. High-moisture, high-ash low-quality coal accounts for a large proportion. In the past ten years, my country's coal gasification production technology has made great progress, and various coal technology has been continuously improved and improved. With the country's increasing efforts in energy conservation and emission reduction, coal gasification technology has become more and more popular in all aspects. Pay attention to.

将煤炭气化简单分为三类,包括有:固定床气化,流化床气化和气流床气化。固定床气化中常压间歇气化由于污染等问题已被国家叫停,加压固定床气化以鲁奇炉为代表也存在废水处理困难等问题;气流床气化中有湿法GE-德士古气化炉,华东理工大学四喷嘴气化炉为代表,干法为代表的有Shell、GSP、航天炉、两段炉等,前者对煤种质量要求较高,后者投资相对较高,以Shell气化为例,单台投煤量2000吨/天的气化炉投资约8亿,且建设周期较长;目前的流化床气化中目前具有代表性的有:恩德炉、U-GAS、KBR、灰熔聚等,除恩德炉为常压气化外,其他加压流化床暂未有大型工业化示范运行装置,均处于建设阶段,未被得到成功示范。而目前我国煤炭的主要产地新疆、内蒙等地的大量劣质煤中在煤种适应性方面均需要采用投资较少、处理能力较大的加压流化床气化炉对其进行气化以生产化工产品。Coal gasification is simply divided into three categories, including: fixed bed gasification, fluidized bed gasification and entrained bed gasification. Atmospheric pressure intermittent gasification in fixed bed gasification has been stopped by the state due to pollution and other problems. Pressurized fixed bed gasification, represented by Lurgi furnace, also has problems such as wastewater treatment difficulties; entrained bed gasification has wet GE- Texaco gasifier is represented by the four-nozzle gasifier of East China University of Science and Technology, and the dry process is represented by Shell, GSP, aerospace furnace, two-stage furnace, etc. The former has higher requirements on coal quality, while the latter has relatively low investment High, taking Shell gasification as an example, the investment of a single gasifier with a coal input of 2,000 tons/day is about 800 million, and the construction period is long; the current representative fluidized bed gasification is: Ende furnace , U-GAS, KBR, ash fusion, etc., except for the Ende furnace for atmospheric pressure gasification, other pressurized fluidized beds have not yet had large-scale industrial demonstration operation devices, and they are all in the construction stage and have not been successfully demonstrated. At present, the large amount of low-quality coal in Xinjiang, Inner Mongolia, etc., which are the main producing areas of coal in my country, needs to be gasified by pressurized fluidized bed gasifiers with less investment and larger processing capacity in terms of coal type adaptability to produce Chemical Products.

目前流化床装置在常压气化基本成熟,但在加压方面一直未得到成功,主要在于以下方面:1为进料系统的不稳定和不安全性,传统的流化床采用螺旋加煤机对气化炉进行进料,此进料方式在加压气化时存在给料不均匀、容易堵塞故障和泄露的风险,如煤粉一旦泄露会导致煤粉的燃烧极不安全;2为由于流化床操作温度在900-1000℃,生产的粗煤气中具有较多的焦油、酚、萘、苯等有机物,此类物质会使得后续的净化装置处理困难,特别是经过水洗涤后,含焦油、酚的废水处理极为困难,且投资和消耗均较高;3为气化排渣方面,目前传统的常压流化床均采用冷渣机排渣,如采用加压气化会使得冷渣机密封泄露及卡死,排渣温度无法降低而导致停车;4为粗煤气化除尘方面,目前传统的流化床通过旋风分离器除尘、废热回收后直接进入洗涤塔进行水洗,然后再用文丘里进行水膜除尘达到粗煤气中含尘≤35mg/Nm3,此类工艺除尘效果较差,且产生的较多含尘废水处理成本较高。At present, the fluidized bed device is basically mature in atmospheric gasification, but it has not been successful in pressurization, mainly in the following aspects: 1. The feed system is unstable and unsafe. The traditional fluidized bed adopts spiral coal feeding The machine feeds the gasifier. This feeding method has the risk of uneven feeding, easy blockage and leakage during pressurized gasification. For example, once the pulverized coal leaks, the combustion of pulverized coal will be extremely unsafe; 2 is Since the operating temperature of the fluidized bed is 900-1000°C, the raw gas produced contains more tar, phenol, naphthalene, benzene and other organic substances, which will make it difficult to deal with the subsequent purification equipment, especially after washing with water. Wastewater containing tar and phenol is extremely difficult to treat, and the investment and consumption are high; 3. In terms of gasification and slag removal, the current traditional atmospheric fluidized bed uses a slag cooler to remove slag. If pressurized gasification is used, it will make The seal of the slag cooler is leaked and stuck, and the slag discharge temperature cannot be lowered, resulting in shutdown; 4. In terms of coarse coal gasification and dedusting, the current traditional fluidized bed is dedusted by a cyclone separator, and the waste heat is recovered and directly enters the washing tower for washing, and then Water film dedusting with Venturi is used to achieve a dust content of ≤35mg/Nm 3 in the crude gas. This type of process has a poor dedusting effect and produces a lot of dusty wastewater with high treatment costs.

发明内容 Contents of the invention

本实用新型的目的是为了解决上述技术问题,提供一种结构简单、操作简便、可靠性高、运行成本低、产品煤气品质优秀、设备投资低、系统运行稳定的煤炭气化的加压流化床系统。The purpose of this utility model is to solve the above technical problems and provide a pressure fluidized coal gasification system with simple structure, easy operation, high reliability, low operating cost, excellent product gas quality, low equipment investment and stable system operation. bed system.

本实用新型加压流化床系统,包括加压流化床,所述加压流化床气化炉的反应气出口依次连接有机物分解装置、旋风除尘器、废热锅炉、高温过滤器及洗涤塔。The pressurized fluidized bed system of the utility model includes a pressurized fluidized bed, and the reaction gas outlet of the pressurized fluidized bed gasification furnace is sequentially connected with an organic matter decomposition device, a cyclone dust collector, a waste heat boiler, a high temperature filter and a washing tower .

所述有机物分解装置包括涂覆有耐火涂料层的筒体,所述筒体两端设进口和出口,所述筒体内间隔设有至少一个填料区。The organic matter decomposition device includes a cylinder coated with a refractory paint layer, an inlet and an outlet are arranged at both ends of the cylinder, and at least one packing area is arranged at intervals in the cylinder.

所述筒体的直径是煤气输送管道直径的6~10倍。The diameter of the cylinder body is 6-10 times that of the gas delivery pipeline.

所述填料区包括多层安装在固定板网中的规整填料层,所述多层规整填料层上交错开有通孔,所述通孔孔径为50-100mm,每层规整填料层之间的间距为600-1000mm。The packing area includes a multi-layer structured packing layer installed in a fixed plate net, and through holes are staggered on the multi-layer structured packing layer, and the diameter of the through hole is 50-100mm. The spacing is 600-1000mm.

所述固定板网为可通入冷却水的水冷夹套固定板网。The fixed plate net is a water-cooled jacket fixed plate net that can be fed with cooling water.

所述加压流化床气化炉的灰渣出口依次与激冷室、封料仓、排渣减压装置、减压罐及冷渣机连接。The ash and slag outlet of the pressurized fluidized bed gasifier is sequentially connected with a chilling chamber, a material sealing bin, a slag discharge decompression device, a decompression tank and a slag cooler.

所述排渣减压装置包括减压管以及位于减压管下方的放空管,所述减压管具有缩径段,所述放空管的管壁由内至外包括过滤层、环形空腔和外管,所述环形空腔与放空阀连通。The slag discharge decompression device includes a decompression pipe and a vent pipe located below the decompression pipe. The decompression pipe has a diameter-reducing section, and the pipe wall of the vent pipe includes a filter layer, an annular space from the inside to the outside. cavity and an outer tube, and the annular cavity communicates with the vent valve.

所述环形空腔还与反吹管连通。The annular cavity is also communicated with the blowback pipe.

所述排渣减压装置有依次串联的至少2个。There are at least two slag discharge decompression devices connected in series.

所述旋风除尘器的灰粉出口经非机械阀与加压流化床气化炉的下段连接。The ash outlet of the cyclone dust collector is connected with the lower section of the pressurized fluidized bed gasifier through a non-mechanical valve.

使用上述系统的工艺包括以下步骤:将煤粉加压输送至加压流化床气化炉内,与气化剂直接接触反应在炉内上部形成密相段,下部形成稀相段,反应后的粗煤气先经有机物分解装置分解煤气中含有的有机物,然后再经旋风除尘后送入废热锅炉降温至300-350℃,再经高温过滤器进一步除尘,除尘后的粗煤气进入洗涤塔中洗涤得到含尘量≤1mg/Nm3粗煤气送如下游装置。优选密相段的反应温度为950-1000℃,气化压力为3.0-4.0MpaG。The process of using the above system includes the following steps: the pulverized coal is transported into the pressurized fluidized bed gasification furnace under pressure, and directly contacts and reacts with the gasification agent to form a dense phase section in the upper part of the furnace, and a dilute phase section in the lower part. After the reaction The crude gas is firstly decomposed by the organic matter decomposition device to decompose the organic matter contained in the gas, and then sent to the waste heat boiler to cool down to 300-350°C after being dedusted by the cyclone, and then further dedusted by the high-temperature filter, and the dedusted crude gas enters the washing tower for washing The crude gas with dust content ≤ 1mg/ Nm3 is sent to the downstream device. Preferably, the reaction temperature of the dense phase section is 950-1000° C., and the gasification pressure is 3.0-4.0 MpaG.

所述反应后的粗煤气在有机物分解装置中的停留时间为3~15s,以充分分解煤气中含有的有机物,然后再经旋风除尘后送入废热锅炉。The residence time of the reacted crude gas in the organic matter decomposition device is 3-15s to fully decompose the organic matter contained in the gas, and then sent to the waste heat boiler after cyclone dust removal.

所述煤粉经煤锁斗加压后,通过气力输送的方式在煤粉发送罐的发送下将煤粉送入加压流化床气化炉内。After the pulverized coal is pressurized by the coal lock hopper, the pulverized coal is sent into the pressurized fluidized bed gasifier by means of pneumatic conveying under the delivery of the pulverized coal sending tank.

所述加压流化床气化炉内反应后的炉渣降至炉底,经激冷室激冷到300-450℃,再经料封仓、排渣减压装置送入减压罐降压到0.2MPa(G)以下,最终通过冷渣机进行再次冷却后排出系统。The reacted slag in the pressurized fluidized bed gasification furnace is lowered to the bottom of the furnace, chilled to 300-450°C in the quenching chamber, and then sent to the decompression tank for decompression through the material sealing bin and slag discharge decompression device To below 0.2MPa (G), finally through the slag cooler to cool again and then discharged from the system.

经所述旋风除尘后收集的灰尘经非机械阀在松动气的作用下返回至加压流化床气化炉的下段,再次参加气化反应。The dust collected after the cyclone dust removal is returned to the lower section of the pressurized fluidized bed gasifier through the non-mechanical valve under the action of loose gas, and participates in the gasification reaction again.

当所述有机物分解装置内附着的焦油过多时,则短时间内提高加压流化床气化炉的出炉气体温度,使有机物分解装置内的焦油迅速分解后再回到正常操作温度,所述提高出炉气体温度的幅度为50-100℃。When there is too much tar attached in the organic matter decomposing device, the outlet gas temperature of the pressurized fluidized bed gasifier is increased in a short period of time, so that the tar in the organic matter decomposing device is quickly decomposed and then returned to the normal operating temperature. The range of increasing the temperature of the furnace gas is 50-100°C.

发明人对现有的加压流化床工艺中出反应炉的粗煤气进行分析发现为了得到高品质的煤气,并且利于后续装置的正常运行,将粗煤气中含有的焦油、酚、萘、苯等有机物有效去除是非常必要的,而这类有机物在高温下、一定时间内可迅速分解。而由于加压流化床工艺为高温高压工况,管道内粗煤气的流速快、压力大,在降温前难以满足有机物高温分解的条件,理论上讲,若需要实现有机物分解,煤气输送管道需达到80m以上甚至更长,难以在工业上实现,因此考虑增设一个有机物分解装置,从而满足粗煤气在高温下的停留时间,气化反应后的粗煤气先在有机物分解装置内停留一段时间后将焦油、酚、萘、苯等有机物在高温下分解后,再进行旋风除尘除去大颗粒的灰尘,由于粗煤气中的有机物基本已被除去,不存在焦油等有机物降温后堵塞管道的问题,因此可以通过废热锅炉换热降温后再用高温过滤器滤除细小的灰尘,从而降低设备的投资成本(耐高温材料的性能要求较低),提高了系统可靠性和安全性能,也提高了副产细灰的品质。The inventor analyzed the crude gas from the reaction furnace in the existing pressurized fluidized bed process and found that in order to obtain high-quality gas and facilitate the normal operation of subsequent devices, the tar, phenol, naphthalene, and benzene contained in the crude gas It is very necessary to wait for the effective removal of organic matter, and this type of organic matter can be rapidly decomposed under high temperature and within a certain period of time. However, since the pressurized fluidized bed process is a high-temperature and high-pressure working condition, the flow rate of crude gas in the pipeline is fast and the pressure is high, so it is difficult to meet the conditions for pyrolysis of organic matter before cooling down. It is difficult to achieve 80m or even longer in industry. Therefore, it is considered to add an organic matter decomposition device to meet the residence time of the crude gas at high temperature. The crude gas after the gasification reaction first stays in the organic matter decomposition device for a period of time. Tar, phenol, naphthalene, benzene and other organic matter are decomposed at high temperature, and then the cyclone dust removal is carried out to remove large particles of dust. Since the organic matter in the crude gas has basically been removed, there is no problem of tar and other organic matter blocking the pipeline after cooling down, so it can be After the heat exchange and cooling of the waste heat boiler, the high temperature filter is used to filter out the fine dust, thereby reducing the investment cost of the equipment (the performance requirements of the high temperature resistant material are low), improving the reliability and safety performance of the system, and also improving the fineness of by-products. gray quality.

所述机物分解装置可以为一个直径较粗的空筒,空筒内设置填料区,以保证粗煤气在该装置内的停留时间即可,但考虑到粗煤气流速高、温度高、压力高的特点,为保证粗煤气中的有机物充分分解,填料区优选采和多层安装在固定板网中的规整填料,所述多层的规整填料上交错开有通孔,所述通孔孔径为50-100mm,孔径过大会起不到停留作用,过小会使得煤气中的飞灰在此处堵塞;每层规整填料之间的间距为600-1000mm,间距过大会使得本设备长度加长,间距过小会使得煤气无法分布均匀,所述通孔采用交错布置可进一步降低粗煤气的流速,提高分解效率,使少量未来得及分解而凝出的焦油也能以附着的形式留在填料层间的表面,最终保证粗煤气中的有机物在此得到充分分解和附着。The organic matter decomposition device can be an empty cylinder with a relatively large diameter, and a packing area is set in the empty cylinder to ensure the residence time of the crude gas in the device, but considering the high gas flow rate, high temperature and high pressure of the crude gas In order to ensure that the organic matter in the crude gas is fully decomposed, the packing area is preferably made of multi-layer structured packing installed in a fixed plate net. The multi-layer structured packing is staggered with through holes, and the diameter of the through holes is 50-100mm, if the hole diameter is too large, the stop effect will not be achieved, if it is too small, the fly ash in the gas will be blocked here; the distance between each layer of structured packing is 600-1000mm, if the distance is too large, the length of the equipment will be lengthened, and the distance between If it is too small, the gas will not be evenly distributed. The staggered arrangement of the through holes can further reduce the flow rate of the crude gas and improve the decomposition efficiency, so that a small amount of tar that will be decomposed and condensed in the future can also stay in the form of adhesion between the packing layers. Finally, ensure that the organic matter in the crude gas is fully decomposed and attached here.

对于长时间运行后附着于填料层上的焦油等有机物而言,附着厚度过大,则会堵塞填料层影响分解效果,因此当所述有机物分解装置内附着的焦油过多时,则短时间内提高加压流化床气化炉的出炉气体温度,使有机物分解装置内的焦油迅速分解后再回到正常操作温度,所述提出炉气体温度的幅度为50-100℃。通过短时提高出炉气体的温度可以加速焦油等有机物的分解,使附着在填料层上的焦油等有机物迅速分解,并且由于提高炉温的时间较短(通常不超过15分钟),因而也不会影响加压流化床气化炉内正常的反应操作。所述水冷夹套固定板网可通入冷却水,利用冷却水移去在固定板网在高温气体辐射下的热量,提高固定板网的使用寿命。For organic matter such as tar attached to the packing layer after long-term operation, if the adhesion thickness is too large, the packing layer will be blocked and the decomposition effect will be affected. The outlet gas temperature of the pressurized fluidized bed gasifier is to make the tar in the organic decomposition device decompose rapidly and then return to the normal operating temperature, and the range of the outlet gas temperature is 50-100°C. By raising the temperature of the furnace gas for a short time, the decomposition of organic matter such as tar can be accelerated, so that the organic matter such as tar attached to the filler layer can be quickly decomposed, and because the time for raising the furnace temperature is short (usually no more than 15 minutes), it will not Affect the normal reaction operation in the pressurized fluidized bed gasifier. The water-cooled jacket fixed plate net can be fed with cooling water, and the cooling water is used to remove the heat of the fixed plate net under the radiation of high-temperature gas, so as to improve the service life of the fixed plate net.

进一步的,炉渣属于不可压缩物质,本身不具有压力,具有压力的是含在渣与渣间缝隙的气体,若直接排放,炉渣的高温及气体高压会使冷渣机密封泄露及卡死、排渣温度无法降低而导致停车的问题。本实用新型中通过激冷室使炉渣降温的同时,还同时降低了夹杂的气体温度,具有减压的作用,从而满足了后续排渣减压装置的进料要求,经过激冷的炉渣温度达300-450℃,仍含有少量气体,此时可利用减压管通过管径缩小方式对含少量气体的温度在300~350℃的固态的炉渣进行第一次减压(优选缩径段的管径为10-50mm),减压后气体速度加快,对设备材料磨损严重。因此含气的高速固态的炉渣不适合再用减压管进行继续减压,而是在减压管下方设放空管,经过第一次减压后的物料(固态的炉渣)通过放空管时,随着管壁中过滤层的过滤作用下,固态物料在管内继续运动,所夹带的气体则可通过过滤层、环形空腔经放气阀被排出管外,从而起到再次降压的作用。包括减压管和放气管的排渣减压装置可根据需要设置一组或串联的多组,以保证减压效果。Furthermore, the slag is an incompressible substance and does not have pressure itself. What has pressure is the gas contained in the gap between the slag and the slag. If it is discharged directly, the high temperature of the slag and the high pressure of the gas will cause the seal of the slag cooler to leak and get stuck. The slag temperature cannot be lowered, which leads to the problem of shutdown. In the utility model, while the temperature of the slag is lowered through the quenching chamber, the temperature of the mixed gas is also reduced at the same time, which has the function of decompression, thereby meeting the feeding requirements of the subsequent slag discharge and decompression device, and the temperature of the slag after quenching reaches 300-450°C, still contains a small amount of gas. At this time, the decompression tube can be used to decompress the solid slag containing a small amount of gas at a temperature of 300-350°C by reducing the diameter of the tube for the first time (preferably the tube in the reduced diameter section) The diameter is 10-50mm), the speed of the gas increases after decompression, and the equipment material is seriously worn. Therefore, the gas-containing high-speed solid slag is not suitable for further decompression with a decompression pipe, but a vent pipe is set under the decompression pipe, and the material (solid slag) after the first decompression passes through the vent pipe At this time, with the filtering effect of the filter layer in the pipe wall, the solid material continues to move in the pipe, and the entrained gas can pass through the filter layer and the annular cavity and be discharged out of the pipe through the air release valve, so as to reduce the pressure again. effect. The slagging decompression device including the decompression pipe and the air release pipe can be arranged in one group or in series as required to ensure the decompression effect.

进一步的,加压流化床气化炉内反应后的炉渣经激冷室激冷后再进入料封仓有以下目的,(1)由于炉渣温度高,采用激冷的方式可以产生大量蒸汽,激冷产生的蒸汽直接上升至炉内,可减少流化床气化炉内蒸汽的加入量,有利于系统节能降耗;(2)对高温炉渣进行降温,从而降低后续排渣减压装置的耐温耐压要求,降低后续设备和装置的材料成本。Furthermore, the slag after reaction in the pressurized fluidized bed gasifier is chilled in the chilling chamber and then enters the material sealing bin for the following purposes: (1) Due to the high temperature of the slag, a large amount of steam can be generated by chilling, The steam generated by chilling rises directly into the furnace, which can reduce the amount of steam added in the fluidized bed gasifier, which is beneficial to energy saving and consumption reduction of the system; Requirements for temperature and pressure resistance, reducing the material cost of subsequent equipment and devices.

本实用新型中,采用通过气力输送的方式在煤粉发送罐的发送下将煤粉送入加压流化床气化炉内,通过气力输送煤粉的方式使得原料煤进入更为稳定,加压流化床气化炉内温度更易于控制。In the utility model, the pulverized coal is sent into the pressurized fluidized bed gasification furnace under the transmission of the pulverized coal sending tank by means of pneumatic conveying, and the way of conveying the pulverized coal by pneumatic force makes the entry of raw coal more stable and increases The temperature in the pressurized fluidized bed gasifier is easier to control.

进一步的干法除灰方面,发明人特别选用了旋风分离器和高温过滤器(优选高温飞灰过滤器)配合除尘的方法,利用旋风分离器针对性主要除去粗煤气中大颗粒灰尘(占粗煤气中灰尘总含量的质量百分数65-80%),而高温过滤器则具有除去各种粒径范围的灰尘,特别是针对粒径小于5μm的灰尘颗粒除尘效果好的特点,能将经旋风分离器除尘后的粗煤气中的余量灰尘(极少量大颗粒灰尘及大量细小灰尘)高效去除,因此最终得到的产品煤气(洁净煤气)中含尘量极少(≤ 20mg/Nm3),以提高煤气品质并回收了飞灰。这种两级除尘的配合不仅除尘效率高,而且从投备制造体积、制造成本、使用寿命考虑,是最为优化的选择。旋风分离器可以为串联的一台、两台或多台,分离出的干灰可通过非机械阀在松动气的作用下回送至加压流化床气化炉的下段,再次参加炉内的气化反应。In terms of further dry ash removal, the inventor specially selected a cyclone separator and a high-temperature filter (preferably a high-temperature fly ash filter) to cooperate with the dust removal method, and used the cyclone separator to remove large particles of dust in the crude gas (accounting for coarse The mass percentage of the total dust content in the gas is 65-80%), while the high-temperature filter has the characteristics of removing dust in various particle sizes, especially for dust particles with a particle size of less than 5 μm. The residual dust (very small amount of large particle dust and large amount of fine dust) in the crude gas after dedusting by the deduster is efficiently removed, so the final product gas (clean gas) contains very little dust (≤ 20mg/Nm 3 ), with Improved gas quality and recovered fly ash. This combination of two-stage dust removal not only has high dust removal efficiency, but also is the most optimized choice in terms of production volume, manufacturing cost and service life. Cyclone separators can be one, two or more in series, and the separated dry ash can be sent back to the lower section of the pressurized fluidized bed gasification furnace through a non-mechanical valve under the action of loose gas, and then participates in the gasification process in the furnace again. gasification reaction.

有益效果:Beneficial effect:

(1)通过气力输送煤粉的方式可改善气化炉进行时料时给料不均匀、容易堵塞故障和泄露的问题。(1) Pneumatically transporting pulverized coal can improve the problems of uneven feeding, easy blockage and leakage when the gasifier is running.

(2)通过采用有机物分解装置可以通过增加停留时间的方式将加压流化床气化炉在生产粗煤气过程中副产的焦油、酚、萘、苯等有机物进行分解,以减少对此类物质的净化装置投资,并减少后续洗涤水处理的投资和消耗;(2) By using the organic matter decomposition device, the organic matter such as tar, phenol, naphthalene, benzene and other by-products produced by the pressurized fluidized bed gasifier in the process of producing crude gas can be decomposed by increasing the residence time, so as to reduce the impact on such Reduce investment in material purification equipment, and reduce investment and consumption in subsequent washing water treatment;

(3)通过采用激冷水对炉渣进行初步降温、减压排渣装置进一步减压以及冷渣机的组合方式对高温炉渣进行处理,尽管投资较单用冷渣机要高,但根本性解决了直接采用冷渣机密封泄露及卡死,排渣温度无法降低而导致停车的问题,保证了系统的安全稳定运行。(3) The high-temperature slag is processed through the combination of quenching water for preliminary cooling of the slag, further decompression of the decompression slag discharge device, and a slag cooler. Although the investment is higher than that of a slag cooler alone, it fundamentally solves the problem. The slag cooling machine is directly used to seal leakage and jamming, and the slag discharge temperature cannot be lowered to cause shutdown problems, ensuring the safe and stable operation of the system.

(4)将废热锅炉置于高温飞灰过滤器之前,可以降低高温飞灰过滤器的设备材料投资,在提高了对粗煤气中飞灰净化效果(含尘量≤ 20mg/Nm3),且采用高温飞灰过滤器可以得到干的飞灰,有利于环境的同时提高了整个系统的经济效益。以煤处理量为50万吨/年流化床装置为例, 一般传统常压流化床工艺废水约45万吨;若采用本方明的新工艺,废水量仅为8万吨。按1吨含焦油、酚等有机物废水的处理成本为25~33元计算,每年仅废水处理即可节省925~1220万元,节约装置费用5000万,获得干灰10000 吨,产生附加效益200万元。(4) Putting the waste heat boiler before the high-temperature fly ash filter can reduce the equipment and material investment of the high-temperature fly ash filter, and improve the purification effect of fly ash in the crude gas (dust content ≤ 20mg/Nm 3 ), and Dry fly ash can be obtained by using high temperature fly ash filter, which is beneficial to the environment and improves the economic benefit of the whole system at the same time. Taking a fluidized bed device with a coal processing capacity of 500,000 tons/year as an example, the waste water of the traditional normal pressure fluidized bed process is about 450,000 tons; if the new process of our invention is adopted, the waste water volume is only 80,000 tons. Calculated on the basis that the treatment cost of 1 ton of waste water containing tar, phenol and other organic substances is 25-33 yuan, the waste water treatment alone can save 9.25-12.2 million yuan per year, save 50 million yuan in equipment costs, obtain 10,000 tons of dry ash, and generate additional benefits of 2 million yuan Yuan.

(5)本实用新型系统简单,净化效果好,从洗涤塔顶部排出的的洁净粗煤气可直接用于下游工序,而无需作进一步处理,简化了工艺步骤、进一步降低了生产成本,缩短了生产周期。(5) The system of the utility model is simple and the purification effect is good. The clean crude gas discharged from the top of the washing tower can be directly used in the downstream process without further treatment, which simplifies the process steps, further reduces the production cost, and shortens the production process. cycle.

附图说明 Description of drawings

图1本实用新型工艺流程图暨系统图。Fig. 1 process flow diagram and system diagram of the utility model.

图2为本实用新型有机物分解装置的结构示意图。Fig. 2 is a structural schematic diagram of the organic matter decomposition device of the present invention.

图3为填料区的结构示意图。Figure 3 is a schematic structural view of the packing area.

图4为水冷夹套固定板网的示意图。Fig. 4 is a schematic diagram of a water-cooled jacket fixing an expanded metal.

图5为排渣减压装置的结构示意图。Fig. 5 is a schematic structural view of the slag discharge decompression device.

其中,1-常压煤仓、2-煤锁斗、3-煤粉发送罐、4-有机物分解装置、4.1-进口、4.2-出口、4.3-填料区、4.4-规整填料层、4.5-通孔、4.6-水冷夹套固定板网、4.7-冷却水进口、4.8-冷却水出口、4.9-筒体、5-激冷室、6-料封仓、7-排渣减压装置、7.1-减压管、7.2-缩径段、7.3-放空管、7.4-过滤层、7.5-环形空腔、7.6-外管、7.7-反吹管、7.8-放空阀、8-减压罐、9-冷渣机、10-一级旋风除尘器、11-二级旋风除尘器、12-废热锅炉、13-灰收集罐、14-灰锁斗、15-常压灰仓、16-文丘里、17-洗涤塔、18-加压流化床气化炉、19-高温过滤器。Among them, 1-atmospheric coal bunker, 2-coal lock hopper, 3-coal powder sending tank, 4-organic matter decomposition device, 4.1-inlet, 4.2-exit, 4.3-filling area, 4.4-structured packing layer, 4.5-pass Hole, 4.6-Water-cooling jacket fixed plate net, 4.7-Cooling water inlet, 4.8-Cooling water outlet, 4.9-Cylinder, 5-Quenching chamber, 6-Material sealing bin, 7-Slagging pressure reducing device, 7.1- Pressure reducing pipe, 7.2-diameter reducing section, 7.3-venting pipe, 7.4-filter layer, 7.5-annular cavity, 7.6-outer pipe, 7.7-back blowing pipe, 7.8-venting valve, 8-decompression tank, 9- Slag cooler, 10-first-level cyclone dust collector, 11-second-level cyclone dust collector, 12-waste heat boiler, 13-ash collection tank, 14-ash lock bucket, 15-atmospheric pressure ash bin, 16-venturi, 17 - scrubber, 18 - pressurized fluidized bed gasifier, 19 - high temperature filter.

具体实施方式 Detailed ways

下面结合附图对本实用新型作进一步解释说明:Below in conjunction with accompanying drawing, the utility model is further explained:

参照图1,常压煤仓1依次与煤锁斗2、煤粉发送罐3、加压流化床气化炉18的煤粉进口连接,所述加压流化床气化炉18的反应气出口依次与有机物分解装置4、一级旋风除尘器10、二级旋风除尘器11、废热锅炉12、高温过滤器19的进气口连接,所述高温过滤器12的出气口依次与文丘里16、洗涤塔17连接;所述加压流化床气化炉18的炉渣出口依次与激冷室5、料封仓6、排渣减压装置7、减压罐8、冷渣机9连接;所述一级旋风除尘器10和二级旋风除尘器11的灰粉出口经非机械阀20与加压流化床气化炉18的下段连接;所述高温过滤器19的灰出口依次与灰收集罐13、灰锁斗14、常压灰仓15连接。Referring to Fig. 1, the normal pressure coal bunker 1 is connected with the coal powder inlet of the coal lock hopper 2, the pulverized coal delivery tank 3, and the pressurized fluidized bed gasifier 18 successively, and the reaction of the pressurized fluidized bed gasifier 18 is The gas outlet is connected with the air inlet of the organic matter decomposition device 4, the primary cyclone dust collector 10, the secondary cyclone dust collector 11, the waste heat boiler 12, and the high-temperature filter 19 in sequence, and the gas outlet of the high-temperature filter 12 is connected with the venturi in turn. 16. The washing tower 17 is connected; the slag outlet of the pressurized fluidized bed gasifier 18 is sequentially connected with the quenching chamber 5, the material sealing bin 6, the slag discharge decompression device 7, the decompression tank 8, and the slag cooler 9 The ash outlet of the first-stage cyclone dust collector 10 and the second-stage cyclone dust collector 11 is connected with the lower section of the pressurized fluidized bed gasifier 18 through a non-mechanical valve 20; the ash outlet of the high-temperature filter 19 is connected with the Ash collection tank 13, ash lock bucket 14, and normal pressure ash bin 15 are connected.

参照图2-图4,其中,所述有机物分解装置4包括涂覆有耐火涂料层的筒体4.9,所述筒体4.9的直径是粗煤气输送管道直径的6~10倍,所述筒体4.9两端设进口4.1和出口4.2,所述筒体4.9内间隔设有至少一个填料区4.3(本实施例中设有两个填料区4.3),所述填料区4.3包括多层安装在固定板网中的规整填料层4.4,所述多层规整填料层4.4上交错开有通孔4.5,所述通孔4.5孔径为50-100mm,每层规整填料层4.4之间的间距L为600-1000mm。所述固定板网为可通入冷却水的水冷夹套固定板网4.6,冷却水可经水冷夹套固定板网4.6上的冷却水进口4.7流入,换热后由冷却水出口4.8流出。Referring to Fig. 2-Fig. 4, wherein, the organic matter decomposition device 4 comprises a cylinder 4.9 coated with a refractory paint layer, the diameter of the cylinder 4.9 is 6 to 10 times the diameter of the crude gas delivery pipeline, the cylinder 4.9 Both ends are provided with an inlet 4.1 and an outlet 4.2, and at least one packing area 4.3 (two packing areas 4.3 are provided in this embodiment) at intervals inside the cylinder 4.9, the packing area 4.3 includes multiple layers installed on a fixed plate The structured packing layer 4.4 in the net, the multi-layer structured packing layer 4.4 is staggered with through holes 4.5, the diameter of the through holes 4.5 is 50-100mm, and the distance L between each structured packing layer 4.4 is 600-1000mm . The fixed plate net is a water-cooled jacket fixed plate net 4.6 that can be fed into cooling water. The cooling water can flow in through the cooling water inlet 4.7 on the water-cooled jacket fixed plate net 4.6, and flow out through the cooling water outlet 4.8 after heat exchange.

参照图5,其中,所述排渣减压装置7包括减压管7.1以及位于减压管下方的放空管7.3,所述减压管7.1具有缩径段7.2,所述放空管7.3的管壁由内至外包括过滤层7.4、环形空腔7.5和外管7.6,所述环形空腔7.5与放空阀7.8及反吹管7.7连通,所述排渣减压装置7设置可根据减压要求设计串联的多组,如依次串联的至少2组。Referring to Fig. 5, wherein, the slag discharge decompression device 7 includes a decompression pipe 7.1 and a vent pipe 7.3 located below the decompression pipe, the decompression pipe 7.1 has a diameter-reducing section 7.2, and the vent pipe 7.3 The pipe wall includes a filter layer 7.4, an annular cavity 7.5 and an outer pipe 7.6 from the inside to the outside. The annular cavity 7.5 communicates with the vent valve 7.8 and the blowback pipe 7.7. Design multiple groups in series, such as at least 2 groups in series in sequence.

工艺过程:crafting process:

将存储于常压煤仓1中粒径≤8mm的煤粉在通过煤锁斗2加压至3.5-5.0MPa(G)后,通过气力输送的方式,在输送气的作用下通过煤粉发送罐3将煤粉送入加压流化床气化炉18内,粉煤和炉内的气化剂直接接触反应,在炉内上部形成密相段,下部形成稀相段,密相段温度分布均匀,气化炉内反应温度950-1000℃,气化压力为3.0-4.0MPa(G)。反应后的炉渣落到炉底,被激冷室5通入的降温水激冷到300-450℃,再经料封仓6送入排渣减压装置7,利用减压管7.1通过管径缩小方式对含少量气体的降温后的固态炉渣进行第一次减压(优选缩径段7.2的管径为10-50mm),减压后气体速度加快,进入管径较粗的放空管7.3,由于放空管7.3的管壁具有过滤层7.4、环形空腔7.5和外管7.6,且放空阀7.8与环形空腔7.5连通,开启放空阀7.8时,固态炉渣中夹渣的气体可经过滤层7.4过滤掉细灰后经环形空腔7.5、放空阀7.8排出,从而达到降低管内压力和固态炉渣流速的目的;当长时间工作,细灰过多附着于过滤层7.4表面会堵塞过滤层7.4时,则通过反吹管短时加压向环形空腔7.5内通入反吹气,使细灰在反吹气的作用下受震动及反吹压力由过滤层7.4表面脱开,避免过滤层7.5堵塞影响放空效果。固态炉渣经排渣减压装置7一次减压后,再送入减压罐8继续降压到0.2MPa(G)以下,最终通过冷渣机9进行再次冷却后排出系统。The pulverized coal with a particle size of ≤8mm stored in the atmospheric coal bunker 1 is pressurized to 3.5-5.0MPa(G) through the coal lock hopper 2, and then sent through the pulverized coal under the action of the conveying gas by means of pneumatic conveyance The tank 3 sends the pulverized coal into the pressurized fluidized bed gasifier 18. The pulverized coal and the gasification agent in the furnace directly contact and react, forming a dense phase section in the upper part of the furnace, and a dilute phase section in the lower part. The temperature of the dense phase section is Evenly distributed, the reaction temperature in the gasifier is 950-1000°C, and the gasification pressure is 3.0-4.0MPa(G). The reacted slag falls to the bottom of the furnace and is quenched to 300-450°C by the cooling water fed into the quenching chamber 5, and then sent to the slag discharge decompression device 7 through the material sealing chamber 6, and the decompression pipe 7.1 is used to pass through the pipe diameter The reduction mode decompresses the cooled solid slag containing a small amount of gas for the first time (preferably the pipe diameter of the reduced diameter section 7.2 is 10-50mm), after decompression, the gas speed is accelerated, and it enters the vent pipe 7.3 with a larger pipe diameter , since the pipe wall of the vent pipe 7.3 has a filter layer 7.4, an annular cavity 7.5 and an outer pipe 7.6, and the vent valve 7.8 communicates with the annular cavity 7.5, when the vent valve 7.8 is opened, the gas containing slag in the solid slag can be filtered Layer 7.4 filters out the fine ash and discharges it through the annular cavity 7.5 and the vent valve 7.8, so as to achieve the purpose of reducing the pressure in the pipe and the flow rate of solid slag; when working for a long time, too much fine ash adheres to the surface of the filter layer 7.4, which will block the filter layer 7.4 In this case, the blowback gas is introduced into the annular cavity 7.5 through the short-term pressurization of the blowback pipe, so that the fine ash is shaken under the action of the blowback gas and the blowback pressure is released from the surface of the filter layer 7.4, preventing the filter layer 7.5 from Blockage affects the venting effect. The solid slag is decompressed once by the slag discharge decompression device 7, and then sent to the decompression tank 8 to continue decompression to below 0.2MPa(G), and finally cooled again by the slag cooler 9 and then discharged out of the system.

反应后的粗煤气(含有灰尘)先送入机物分解装置4分解煤气中含有的有机物,粗煤气由进口4.1进入筒体4.9内,在填料区4.3经交错布置的通孔4.5依次通过多层的规整填料层4.4,由于筒体4.9的直径粗,且填料区4.3的特别设计,可使粗煤气的流速在筒体4.9内被减缓,满足了粗煤气在高温下的要求的停留时间(停留时间为3~15s),焦油等有机物在此被高温分解,从而达到为粗煤气除杂降焦的目的,规整填料层4.4表面附着的未来得及分解的焦油等有机物过多时,则短时间内提高加压流化床气化炉18的出炉气体温度,使有机物分解装置4内的焦油等有机物迅速分解后再回到正常操作温度,所述提高出炉气体温度的幅度为50-100℃。经机物分解装置4对含有的焦油等有机物高温分解后粗煤气中的焦油含量可降至100ppm以下,然后再经两级旋风除尘器10、11除尘后送入废热锅炉降温至300-350℃,再经高温过滤器19进一步除尘,除尘后的粗煤气经文丘里16使得煤气中的飞灰团聚,再进入洗涤塔17中洗涤后粗煤气中含尘量≤1mg/Nm3送入下游装置。The reacted crude gas (containing dust) is first sent to the organic matter decomposition device 4 to decompose the organic matter contained in the gas. The crude gas enters the cylinder body 4.9 from the inlet 4.1, and passes through the multi-layered through holes 4.5 arranged in a staggered manner in the packing area 4.3. The structured packing layer 4.4, due to the thick diameter of the cylinder 4.9 and the special design of the packing area 4.3, can slow down the flow velocity of the crude gas in the cylinder 4.9, meeting the residence time required by the crude gas at high temperature (residence time is 3~15s), tar and other organic substances are decomposed by high temperature here, so as to achieve the purpose of removing impurities and reducing coke in the crude gas. The outlet gas temperature of the pressurized fluidized bed gasifier 18 is to quickly decompose the organic matter such as tar in the organic matter decomposition device 4 and then return to the normal operating temperature, and the range of increasing the outlet gas temperature is 50-100°C. The tar content in the crude gas can be reduced to less than 100ppm after the pyrolysis of tar and other organic matter contained in the organic matter decomposition device 4, and then sent to the waste heat boiler to cool down to 300-350°C after being dedusted by the two-stage cyclone dust collectors 10 and 11 , and then further dedusted by the high-temperature filter 19, the dust-removed crude gas passes through the Venturi 16 to agglomerate the fly ash in the gas, and then enters the scrubber 17 for washing. .

由串联的所述一级旋风除尘器10和二级旋风除尘器11收集的灰尘经非机械阀20在松动气的作用下依靠重力返回至加压流化床气化炉18的下段,再次参加气化反应,以提高总碳转化率,降低飞灰中含碳量。The dust collected by the first-stage cyclone dust collector 10 and the second-stage cyclone dust collector 11 in series returns to the lower section of the pressurized fluidized bed gasifier 18 by gravity through the non-mechanical valve 20 under the action of the loose gas, and then participates in the process again. Gasification reaction to increase the total carbon conversion rate and reduce the carbon content in fly ash.

经所述高温过滤器19过滤得到的飞灰通过灰收集罐13、灰锁斗14及常压灰仓15进行降压回收。The fly ash filtered by the high-temperature filter 19 is recovered through the ash collection tank 13 , the ash lock hopper 14 and the normal-pressure ash bin 15 .

经本实用新型工艺处理后的粗煤气中含尘量≤1mg/Nm3,有机物含量小于100ppm,焦油含量小于100ppm,总碳转化率为95%以上。系统稳定运行20年。The crude gas treated by the process of the utility model has a dust content of ≤1mg/Nm 3 , an organic matter content of less than 100ppm, a tar content of less than 100ppm, and a total carbon conversion rate of over 95%. The system has been in stable operation for 20 years.

Claims (10)

1.一种加压流化床系统,包括加压流化床,其特征在于,所述加压流化床气化炉的反应气出口依次连接有机物分解装置、旋风除尘器、废热锅炉、高温过滤器及洗涤塔。1. A pressurized fluidized bed system, comprising a pressurized fluidized bed, characterized in that, the reaction gas outlet of the pressurized fluidized bed gasifier is connected successively with an organic matter decomposition device, a cyclone dust collector, a waste heat boiler, a high temperature Filters and scrubbers. 2.如权利要求1所述的加压流化床系统,其特征在于,所述有机物分解装置包括涂覆有耐火涂料层的筒体,所述筒体两端设进口和出口,所述筒体内间隔设有至少一个填料区。2. The pressurized fluidized bed system as claimed in claim 1, wherein the organic matter decomposition device comprises a cylinder coated with a refractory paint layer, the two ends of the cylinder are provided with an inlet and an outlet, and the cylinder The interbody compartment is provided with at least one padding area. 3.如权利要求2所述的加压流化床系统,其特征在于,所述筒体的直径是煤气输送管道直径的6~10倍。3. The pressurized fluidized bed system according to claim 2, characterized in that the diameter of the cylinder is 6-10 times the diameter of the gas delivery pipeline. 4.如权利要求2所述的加压流化床系统,其特征在于,所述填料区包括多层安装在固定板网中的规整填料层,所述多层规整填料层上交错开有通孔,所述通孔孔径为50-100mm,每层规整填料层之间的间距为600-1000mm。4. The pressurized fluidized bed system as claimed in claim 2, characterized in that, the packing area comprises multi-layer structured packing layers installed in the fixed plate net, and the multi-layer structured packing layers are staggered with through holes. holes, the diameter of the through holes is 50-100mm, and the distance between each structured packing layer is 600-1000mm. 5.如权利要求2所述的加压流化床系统,其特征在于,所述固定板网为可通入冷却水的水冷夹套固定板网。5 . The pressurized fluidized bed system according to claim 2 , wherein the fixed expanded metal is a water-cooled jacket fixed expanded metal that can be fed with cooling water. 6 . 6.如权利要求1-5任一项所述的加压流化床系统,其特征在于,所述加压流化床气化炉的灰渣出口依次与激冷室、封料仓、排渣减压装置、减压罐及冷渣机连接。6. The pressurized fluidized bed system according to any one of claims 1-5, characterized in that, the ash outlet of the pressurized fluidized bed gasifier is successively connected with the quenching chamber, the sealing bin, and the discharge chamber. Slag decompression device, decompression tank and slag cooling machine connection. 7.如权利要6所述的加压流化床系统,其特征在于,所述排渣减压装置包括减压管以及位于减压管下方的放空管,所述减压管具有缩径段,所述放空管的管壁由内至外包括过滤层、环形空腔和外管,所述环形空腔与放空阀连通。7. The pressurized fluidized bed system as claimed in claim 6, wherein the slag discharge decompression device comprises a decompression pipe and a vent pipe positioned below the decompression pipe, and the decompression pipe has a reduced diameter section, the pipe wall of the vent pipe includes a filter layer, an annular cavity and an outer pipe from the inside to the outside, and the annular cavity communicates with the vent valve. 8.如权利要求7所述的加压流化床系统,其特征在于,所述环形空腔还与反吹管连通。8. The pressurized fluidized bed system according to claim 7, characterized in that, the annular cavity is also communicated with a blowback pipe. 9.如权利要求7或8所述的加压流化床系统,其特征在于,所述排渣减压装置有依次串联的至少2个。9. The pressurized fluidized bed system according to claim 7 or 8, characterized in that there are at least two slag discharge decompression devices connected in series in sequence. 10.如权利要求1-5任一项所述的加压流化床系统,其特征在于,所述旋风除尘器的灰粉出口经非机械阀与加压流化床气化炉的下段连接。10. The pressurized fluidized bed system according to any one of claims 1-5, characterized in that the ash outlet of the cyclone dust collector is connected to the lower section of the pressurized fluidized bed gasifier through a non-mechanical valve .
CN2013201868224U 2013-04-15 2013-04-15 System for pressurized fluidized bed Expired - Lifetime CN203238227U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103224813A (en) * 2013-04-15 2013-07-31 中国五环工程有限公司 Pressurized fluidized bed technology for coal gasification and pressurized fluidized bed system
CN104263410A (en) * 2014-09-28 2015-01-07 中国东方电气集团有限公司 Coal gasification waste heat recovery system
CN104650990A (en) * 2015-03-16 2015-05-27 上海锅炉厂有限公司 Slag discharging device for pressurized circulating fluidized bed

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103224813A (en) * 2013-04-15 2013-07-31 中国五环工程有限公司 Pressurized fluidized bed technology for coal gasification and pressurized fluidized bed system
CN104263410A (en) * 2014-09-28 2015-01-07 中国东方电气集团有限公司 Coal gasification waste heat recovery system
CN104650990A (en) * 2015-03-16 2015-05-27 上海锅炉厂有限公司 Slag discharging device for pressurized circulating fluidized bed

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