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CN202849189U - Device for removing lead in industrial waste water by utilizing tea leaves - Google Patents

Device for removing lead in industrial waste water by utilizing tea leaves Download PDF

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Publication number
CN202849189U
CN202849189U CN 201220202026 CN201220202026U CN202849189U CN 202849189 U CN202849189 U CN 202849189U CN 201220202026 CN201220202026 CN 201220202026 CN 201220202026 U CN201220202026 U CN 201220202026U CN 202849189 U CN202849189 U CN 202849189U
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China
Prior art keywords
tea dregs
tea
screen
waste water
lead
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Expired - Fee Related
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CN 201220202026
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Chinese (zh)
Inventor
张玲
朱颖
左丹
吴彪
裴君辉
冯雪
李文杞
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Changsha University of Science and Technology
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Changsha University of Science and Technology
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  • Water Treatment By Sorption (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

本实用新型提供一种工业废水利用茶渣除铅的装置,就是在废水处理程序的第一步通过粗细栏栅格后,在其后加入装有茶渣的旋转过滤细筛网装置,旋转过滤细筛网为圆形框架和转动装置组成,筛网孔眼直径为0.2~0.5mm,筛网是一个密封装置,有个可以开的口,用于换洗里面的茶渣。本装置有效的利用了低成本生物去吸附酸性工业废水中的重金属,结构简单,并且这些茶渣环保,易回收利用。

Figure 201220202026

The utility model provides a device for removing lead from industrial waste water by using tea dregs, that is, after passing through the thick and thin grids in the first step of the waste water treatment procedure, a rotary filter fine screen device equipped with tea dregs is added thereafter, and the filter is rotated and filtered. The fine screen is composed of a circular frame and a rotating device. The diameter of the screen mesh is 0.2~0.5mm. The screen is a sealing device with an opening that can be opened for changing and washing the tea dregs inside. The device effectively utilizes low-cost organisms to adsorb heavy metals in acidic industrial wastewater, has a simple structure, and these tea dregs are environmentally friendly and easy to recycle.

Figure 201220202026

Description

一种工业废水利用茶渣除铅的装置A device for removing lead from industrial wastewater using tea dregs

技术领域 technical field

对酸性工业废水中的的铅离子重金属有很好的吸附效果,适用于含有大量铅离子,并且呈酸性的工业废水吸收。  It has a good adsorption effect on lead ions and heavy metals in acidic industrial wastewater, and is suitable for the absorption of acidic industrial wastewater containing a large amount of lead ions. the

技术背景 technical background

电镀,金属加工,矿石处理,电池制造,石油精炼等行业都需要用到金属铅,铅在广泛应用的同时也不同成度的对环境造成了污染。铅及其化合物进入人体并可在肝脏和肾脏中积累,导致血红蛋白合成受阻而出现贫血,从而对人的身体健康产生不良影响。传统的含铅废水处理技术有,化学沉淀法,电解法,吸附法,离子交换法等。化学沉淀法对化学试剂很能量的消耗较大,而且存在二次污染的可能;电解法消耗电量大,处理废水量小,要是把生物吸附用于废水处理的前期,可以大大的减少金属铅的含量,在后面的化学沉淀或电解法中可以减少化学药剂的投机量,也可以不用消耗大量的电能。  Metal lead is used in electroplating, metal processing, ore processing, battery manufacturing, petroleum refining and other industries. While lead is widely used, it also pollutes the environment to varying degrees. Lead and its compounds enter the human body and can accumulate in the liver and kidneys, resulting in hemoglobin synthesis being blocked and anemia occurring, thus having adverse effects on human health. Traditional lead-containing wastewater treatment technologies include chemical precipitation, electrolysis, adsorption, and ion exchange. The chemical precipitation method consumes a lot of energy for chemical reagents, and there is a possibility of secondary pollution; the electrolysis method consumes a lot of electricity and treats a small amount of wastewater. If biosorption is used in the early stage of wastewater treatment, it can greatly reduce the amount of metal lead. Content, in the following chemical precipitation or electrolysis method can reduce the speculation of chemical agents, and also can not consume a lot of electric energy. the

生物吸附材料化学结构中所含的羧基,氨基可以成为重金属的吸附位。利用茶渣吸附铅离子是因为茶渣对铅离子除了有离子交换的化学吸附作用外,还由于茶叶具有网状多孔的结构,铅离子与茶叶表面的细胞壁发生了物理吸附作用。但茶渣的投加量,pH值,温度都会影响茶渣对水中铅离子的吸附效果,并且茶中的茶多酚也可在后面添加絮凝剂PAC出去,但是茶多酚与金属离子反应有可逆性,预处理产生的沉淀物可通过加酸处理而使茶多酚游离出来,且茶多酚的经济价值又很高,故建议在实际工程中考虑对茶多酚的回收利用,这样可减少污水处理的费用。  The carboxyl groups and amino groups contained in the chemical structure of bioabsorbent materials can become the adsorption sites of heavy metals. The use of tea dregs to adsorb lead ions is because tea dregs has not only ion exchange chemical adsorption for lead ions, but also because tea has a reticular porous structure, lead ions have physical adsorption with the cell wall on the surface of tea leaves. However, the dosage of tea dregs, pH value and temperature will all affect the adsorption effect of tea dregs on lead ions in water, and the tea polyphenols in tea can also be removed by adding flocculant PAC later, but the reaction between tea polyphenols and metal ions is limited. Reversibility, the precipitate produced by pretreatment can free tea polyphenols through acid treatment, and the economic value of tea polyphenols is very high, so it is recommended to consider the recycling of tea polyphenols in actual projects, which can Reduce the cost of sewage treatment. the

实用新型内容 Utility model content

本实用新型为工业废水利用茶渣除铅的装置,就是在废水处理程序的第一步通过粗细栏栅格后,在其后加入装有茶渣的旋转细筛网过滤装置,旋转细筛网圆形框架和转动装置组成,筛网孔眼直径为0.2~0.5mm,筛网是一个密封装置,有个可以开的口,用于换洗里面的茶渣。  The utility model is a device for removing lead from industrial waste water by using tea dregs. After passing through the thick and thin grids in the first step of the wastewater treatment procedure, a rotating fine screen filtering device equipped with tea dregs is added thereafter, and the rotating fine screen It is composed of a circular frame and a rotating device. The mesh diameter of the screen is 0.2~0.5mm. The screen is a sealing device with an opening that can be opened for changing and washing the tea dregs inside. the

对原本有的旋转筛网进行改造,原本的空壳内经改进可以成为密封的可以将茶渣放在其中,这样当水流经入口缓缓流入转桶内,工业废水中的大部分铅会被茶渣吸附,过滤后的水可以通过转筒下部筛网排除,进入下一个程序。水中的纤维,纸浆等细小悬浮物会被拦截,而水中的重金属铅,也可以被茶渣吸收,当一定时间后更换茶渣,使用过的茶渣可以经过清洗,干燥等继续重复使用。要是把生物吸附用于废水处理的前期,可以大大的减少金属铅的含量,在后面的化学沉淀或电解法中可以减少化学药剂的投机量,也可以不用消耗大量的电能。  The original rotating screen is modified, and the original empty shell can be improved to be airtight, and tea residue can be placed in it, so that when the water flows through the inlet and slowly flows into the rotating bucket, most of the lead in the industrial wastewater will be absorbed by the tea. The slag is adsorbed, and the filtered water can be discharged through the lower screen of the drum and enter the next procedure. Fine suspended matter such as fibers and pulp in the water will be intercepted, and the heavy metal lead in the water can also be absorbed by the tea residue. When the tea residue is replaced after a certain period of time, the used tea residue can be washed and dried for reuse. If biosorption is used in the early stage of wastewater treatment, the content of metal lead can be greatly reduced, and in the subsequent chemical precipitation or electrolysis method, it can reduce the speculation of chemical agents, and it can also avoid consuming a lot of electricity. the

附图说明 Description of drawings

图1为工业废水处理的流程图;  Fig. 1 is the flowchart of industrial wastewater treatment;

图中:1-原废水;2-粗细格栅; 3-茶渣筛网过滤器;4-沉砂池;5-初沉池;6-曝气池;7-空气;8-二沉池;9- Cl2或其它消毒剂;10-接触池;11-出水;12-污泥回流;13-污泥回流泵房;14-集泥井; 15-絮凝剂; 16-污泥浓缩池;17-一级消化池;18-二级消化池;19-污泥脱水机房;20-泥饼外运;21-上清液回流  In the figure: 1-raw wastewater; 2-coarse and fine grille; 3-tea dregs screen filter; 4-grit chamber; 5-primary sedimentation tank; 6-aeration tank; 7-air; 8-secondary sedimentation tank ;9- Cl 2 or other disinfectants; 10-contact pool; 11-outlet water; 12-sludge return; 13-sludge return pump room; 14-silt collection well; 15-flocculant; ;17-first-level digester; 18-secondary digester; 19-sludge dewatering machine room; 20-mud cake transport; 21-supernatant backflow

图2离心筛网一体式过滤系统结构示意图  Figure 2 Schematic diagram of centrifugal screen integrated filtration system

图中:22-支架;23-冲洗阀;24-离心过滤器罐体;25-进水口;26-顶盖;27-排气阀;28-旋流加速隔离筒;29-筛网过滤器;30-排污室;31-排污口  In the figure: 22-bracket; 23-flush valve; 24-centrifugal filter tank; 25-water inlet; 26-top cover; 27-exhaust valve; ; 30-sewage chamber; 31-sewage outlet

具体实施方式 Detailed ways

首先要回收茶渣,对茶渣进行预处理;  Firstly, the tea dregs should be recovered and pretreated;

接着要根据废水中的铅含量来确定茶渣的投加量;  Then the amount of tea dregs to be added should be determined according to the lead content in the waste water;

要适当的调节废水温度,pH,来使茶渣对铅的吸收达到最大值;  It is necessary to properly adjust the temperature and pH of the wastewater to maximize the absorption of lead by the tea residue;

装入一定量的茶渣,让废水过滤后的水可以通过转筒下部筛网排除,进入下一个程序。水中的纤维,纸浆等细小悬浮物会被拦截,而水中的重金属铅,也可以被茶渣吸收。  A certain amount of tea dregs is loaded, so that the filtered water of the waste water can be discharged through the screen at the lower part of the drum and enter the next procedure. Fine suspended matter such as fiber and pulp in the water will be intercepted, and the heavy metal lead in the water can also be absorbed by the tea dregs. the

要定期的更换废茶渣,将其中的重金属及茶多酚进行回收,茶渣在清洗晾干后可以二次使用。  The waste tea dregs should be replaced regularly to recover the heavy metals and tea polyphenols, and the tea dregs can be reused after being washed and dried. the

这种装置只能出去一部分的铅离子,但是减少了后面操作的工作量,并且茶渣无毒无害,环保易得。  This device can only remove part of the lead ions, but reduces the workload of subsequent operations, and the tea residue is non-toxic and harmless, environmentally friendly and easy to obtain. the

Claims (1)

1.一种工业废水利用茶渣除铅的装置,就是在废水处理程序的第一步通过粗细栏栅格后,在其后加入装有茶渣的旋转过滤细筛网装置,旋转过滤细筛网为圆形框架和转动装置组成,筛网孔眼直径为0.2~0.5mm,筛网是一个密封装置,有个可以开的口,用于换洗里面的茶渣。  1. A device for removing lead from industrial wastewater using tea dregs, which is to pass through the thick and thin grids in the first step of the wastewater treatment process, and then add a rotating and filtering fine screen device equipped with tea dregs, and then rotate and filter the fine sieve The net is composed of a circular frame and a rotating device. The diameter of the screen mesh is 0.2~0.5mm. The screen mesh is a sealing device with an opening that can be opened for changing and washing the tea dregs inside. the
CN 201220202026 2012-05-08 2012-05-08 Device for removing lead in industrial waste water by utilizing tea leaves Expired - Fee Related CN202849189U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601315A (en) * 2013-11-12 2014-02-26 西南科技大学 Method for treating heavy metal wastewater in mining and metallurgy by use of waste tea dust
CN104944617A (en) * 2015-06-15 2015-09-30 威洁(石狮)中水回用技术有限公司 Heavy metal wastewater treatment equipment and treatment method
CN104959131A (en) * 2015-06-15 2015-10-07 威洁(石狮)中水回用技术有限公司 Nano material application equipment and nano material recycling method
CN107129001A (en) * 2017-07-17 2017-09-05 安徽建筑大学 A kind of method that utilization tealeaves removes Pb In Exhausted Water ion
CN107285422A (en) * 2017-07-17 2017-10-24 安徽建筑大学 A kind of method that utilization tea grounds removes Pb In Exhausted Water ion

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601315A (en) * 2013-11-12 2014-02-26 西南科技大学 Method for treating heavy metal wastewater in mining and metallurgy by use of waste tea dust
CN103601315B (en) * 2013-11-12 2016-04-20 西南科技大学 A kind of method utilizing useless tea to consider process mining and metallurgy heavy metal wastewater thereby to be worth doing
CN104944617A (en) * 2015-06-15 2015-09-30 威洁(石狮)中水回用技术有限公司 Heavy metal wastewater treatment equipment and treatment method
CN104959131A (en) * 2015-06-15 2015-10-07 威洁(石狮)中水回用技术有限公司 Nano material application equipment and nano material recycling method
CN104959131B (en) * 2015-06-15 2017-06-30 威洁(石狮)中水回用技术有限公司 Application of micron equipment and its resource utilization method
CN107129001A (en) * 2017-07-17 2017-09-05 安徽建筑大学 A kind of method that utilization tealeaves removes Pb In Exhausted Water ion
CN107285422A (en) * 2017-07-17 2017-10-24 安徽建筑大学 A kind of method that utilization tea grounds removes Pb In Exhausted Water ion

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Granted publication date: 20130403

Termination date: 20140508