CN202415545U - Continuous flow type microbial fermentation hydrogen generation device - Google Patents
Continuous flow type microbial fermentation hydrogen generation device Download PDFInfo
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- CN202415545U CN202415545U CN 201120523923 CN201120523923U CN202415545U CN 202415545 U CN202415545 U CN 202415545U CN 201120523923 CN201120523923 CN 201120523923 CN 201120523923 U CN201120523923 U CN 201120523923U CN 202415545 U CN202415545 U CN 202415545U
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- 238000000855 fermentation Methods 0.000 title claims abstract description 54
- 230000004151 fermentation Effects 0.000 title claims abstract description 52
- 239000001257 hydrogen Substances 0.000 title claims abstract description 46
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 46
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 230000000813 microbial effect Effects 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 20
- 239000007789 gas Substances 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 239000002699 waste material Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 230000002572 peristaltic effect Effects 0.000 claims abstract 5
- 239000012528 membrane Substances 0.000 claims description 9
- 238000001471 micro-filtration Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims 1
- 230000008855 peristalsis Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 13
- 239000002921 fermentation waste Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 9
- 230000000050 nutritive effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000193403 Clostridium Species 0.000 description 2
- 241000186542 Clostridium baratii Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000001888 Peptone Substances 0.000 description 2
- 108010080698 Peptones Proteins 0.000 description 2
- PLXBWHJQWKZRKG-UHFFFAOYSA-N Resazurin Chemical compound C1=CC(=O)C=C2OC3=CC(O)=CC=C3[N+]([O-])=C21 PLXBWHJQWKZRKG-UHFFFAOYSA-N 0.000 description 2
- VLSOAXRVHARBEQ-UHFFFAOYSA-N [4-fluoro-2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(F)C=C1CO VLSOAXRVHARBEQ-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 229940041514 candida albicans extract Drugs 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000002054 inoculum Substances 0.000 description 2
- 239000002207 metabolite Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 235000019319 peptone Nutrition 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000009469 supplementation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012138 yeast extract Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
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- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/44—Means for regulation, monitoring, measurement or control, e.g. flow regulation of volume or liquid level
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
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- C12M45/00—Means for pre-treatment of biological substances
- C12M45/03—Means for pre-treatment of biological substances by control of the humidity or content of liquids; Drying
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M47/00—Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
- C12M47/10—Separation or concentration of fermentation products
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Abstract
本实用新型涉及一种连续流式微生物发酵制氢装置，由原料池、蠕动进料泵、发酵反应器、NaOH反应器、气体干燥器、气体流量计、储气装置串联组成，所述的发酵反应器内设有搅拌器，发酵反应器的废液出口通过蠕动出料泵与废液收集池连接。反应原料通过蠕动进料泵从原料池连续流入发酵反应器中进行生物发酵制氢反应，同时发酵废液通过蠕动出料泵连续排出发酵反应器，进料速度应与排料速度一致，保持反应器内液体总量恒定。本实用新型具有结构紧凑、产氢连续高效、节能的特点。
The utility model relates to a continuous flow microbial fermentation hydrogen production device, which is composed of a raw material pool, a peristaltic feed pump, a fermentation reactor, a NaOH reactor, a gas dryer, a gas flow meter and a gas storage device in series. A stirrer is arranged in the reactor, and the waste liquid outlet of the fermentation reactor is connected with the waste liquid collection pool through a peristaltic discharge pump. The reaction raw materials continuously flow into the fermentation reactor from the raw material pool through the peristaltic feed pump to carry out the bio-fermentation hydrogen production reaction. At the same time, the fermentation waste liquid is continuously discharged from the fermentation reactor through the peristaltic discharge pump. The total amount of liquid in the container is constant. The utility model has the characteristics of compact structure, continuous and efficient hydrogen production, and energy saving.
Description
Technical field
The utility model relates to the efficient ferment for hydrogen production device of a kind of mikrobe, and concrete is a kind of fermentation reaction apparatus of continuously streamed.
Background technology
The high speed development height of current world economy is according to anti-fossil energy, and its demand accounts for 80% of overall energy requirement, and limited fossil energy will be exhausted rapidly in the near future.Fossil energy is non-renewable, and the utilization of fossil energy can cause serious pollution to environment inevitably, and the renewable energy of development and utilization cleaning has just become the direction that various countries research institution endeavours to study since being derived from last century always.Hydrogen is regarded as the most potential clean energy in this century with its cleaning, efficient, safe, continuable characteristic.Hydrogen production process has a lot, but by contrast, biological hydrogen production has its special advantages.The bio-hydrogen production technology reaction conditions is gentle, low, the cleanliness without any pollution of energy consumption, and can be raw material with depleted biomass resource or organic waste water, can properly solve the contradiction of energy and environment, thereby becomes the hot research field that the various countries scientist focuses on.
Biological hydrogen production is a physiological action of utilizing mikrobe self, under certain envrionment conditions, obtains hydrogen through metabolism.Bio-hydrogen production technology mainly comprises optical drive process and two kinds of routes of fermentation and hydrogen production technology, and the former utilizes photosynthetic bacterium directly conversion of solar energy to be hydrogen, and its optical energy utilization efficiency is lower, the photoreactor difficult design, and cost is also higher; And the latter is the anaerobically fermenting that utilizes hydrogenogens, and its substrate conversion efficiency is high, and hydrogen-producing speed is fast, and reactor design is simple relatively, realizes using in short-term more easily with respect to the former.There are the characteristics of fermentation period than traditional written instructions fermentation, develop that a kind of to have efficient, as to continue hydrogen production potential microorganism continuous ferment for hydrogen production device be a kind of inexorable trend.
Summary of the invention
In order to solve the inefficient problem of batch fermentation that prior art exists, the utility model provides a kind of continuously streamed microbial fermentation device for producing hydrogen, this apparatus structure compact, product hydrogen continuous high-efficient.
The technical scheme of the utility model is: a kind of continuously streamed microbial fermentation device for producing hydrogen; Be composed in series by feed reservoir, wriggling fresh feed pump, fermentation reactor, NaOH reactor drum, gas flow dryer, gas meter, accumulator unit; Be provided with whisking appliance in the described fermentation reactor, the waste liquid outlet of fermentation reactor is connected with the waste collection pond through the wriggling discharging pump.The bottom of described fermentation reactor is provided with microfiltration membrane.
Beneficial effect:
(1) in continuous supplementation nutritive substance and matrix, successive discharging fermented liquid is effectively kept thalline activity and concentration, alleviates the accumulation of harmful meta-bolites, reaches the purpose that continues highly effective hydrogen yield.
(2) fermentation reactor bottom is provided with microfiltration membrane, is used to realize separating of thalline and fermented liquid, makes thalline effectively be trapped in inside reactor, has effectively improved cell concentration in the fermentation reactor, reaches the purpose that continues highly effective hydrogen yield.
(3) reaction raw materials continuously flows into from feed reservoir through the wriggling fresh feed pump and carries out the fermentative hydrogen production reaction the fermentation reactor; Fermented waste fluid is discharged fermentation reactor continuously through the wriggling discharging pump simultaneously; Input speed should be consistent with discharge velocity; Total amount of liquid is constant in the reactor drum, guarantees to continue in the reactor drum to produce hydrogen.The gas that fermentation reaction generates is discharged from reactor head, after through NaOH solution, realizes H
2And CO
2Separation, the speed and the total amount of producing hydrogen through gas meter on-line monitoring microbial fermentation.
Description of drawings
Fig. 1 is the structural representation of the utility model.
Among the figure: 1-feed reservoir, the 2-fresh feed pump of wriggling, 3-whisking appliance, 4-fermentation reactor, 5-microfiltration membrane, the 6-discharging pump of wriggling, 7-fermented liquid collecting tank, 8-NaOH reactor drum, 9-gas flow dryer, 10-gas meter, 11-accumulator unit.
Embodiment
A kind of continuously streamed microbial fermentation device for producing hydrogen; Be composed in series by feed reservoir 1, wriggling fresh feed pump 2, fermentation reactor 4, NaOH reactor drum 8, gas flow dryer 9, gas meter 10, accumulator unit 11; Be provided with whisking appliance 3 in the described fermentation reactor 4, the waste liquid outlet of fermentation reactor 4 is connected with waste collection pond 7 through wriggling discharging pump 6.
The bottom of described fermentation reactor 4 is provided with microfiltration membrane.
Mikrobe and nutritive substance, matrix are fed in the fermentation reactor 4, carry out fermentation and hydrogen production.When treating that its hydrogen-producing speed peaks; Fresh nutritive substance and matrix continuously flowed into from feed reservoir 1 through wriggling fresh feed pump 2 carry out the fermentative hydrogen production reaction the fermentation reactor 4; Fermented waste fluid is discharged fermentation reactor 4 continuously through wriggling discharging pump 6 simultaneously; Input speed should be consistent with discharge velocity, keeps fermentation reactor 4 interior total amount of liquid constant.Fermentation reactor 4 bottoms are provided with microfiltration membrane, are used to realize separating of thalline and fermented liquid, make thalline effectively be trapped in fermentation reactor 4 inside, and fermented waste fluid is expelled to waste collection pond 7.The gas that fermentation reaction generates is realized H through behind the NaOH solution
2And CO
2Separation.
Embodiment 1: the continuously streamed fermentation and hydrogen production
Use reactor volume to be the efficient ferment for hydrogen production device of the continuously streamed mikrobe of 10L in the laboratory, reactor bottom is provided with microfiltration membrane.With Clostridium baratii, clostridium butylicum, enteroaerogen ratio in 1: 1: 1, amount to 10% inoculum size, and the nutritive substance of 6L and matrix, throw in to fermentation reactor jointly.The component of nutritive substance and matrix and concentration are: peptone 10g/L, Carnis Bovis seu Bubali cream 2.4g/L, yeast extract 5.0g/L, Na
2HPO
44g/L, L-halfcystine 0.2g/L, L-cysteine hydrochloride one water 0.5g/L, resazurin (0.2%) 1mL/L, glucose 20g/L.Behind the speed stirring reaction 6h with 170rpm, begin to open wriggling fresh feed pump and wriggling discharging pump, the charging nutritive substance is as above consistent with substrate concn.Discharging and feeding rate are 5ml/min, and the hydrogen of miscarrying continuously continues 24h its hydrogen-producing speed of test and total amount.
Comparative Examples: batch fermentation produces hydrogen
Use reactor volume to carry out batch fermentation hydrogen manufacturing as the efficient ferment for hydrogen production device of the mikrobe of 10L in the laboratory, reactor bottom does not have microfiltration membrane.With Clostridium baratii, clostridium butylicum, enteroaerogen ratio in 1: 1: 1, amount to 10% inoculum size, and the nutritive substance of 6L and matrix, throw in to fermentation reactor jointly.The component of nutritive substance and matrix and concentration are: peptone 10g/L, Carnis Bovis seu Bubali cream 2.4g/L, yeast extract 5.0g/L, Na
2HPO
44g/L, L-halfcystine 0.2g/L, L-cysteine hydrochloride one water 0.5g/L, resazurin (0.2%) 1mL/L, glucose 20g/L.With the speed stirring reaction of 170rpm, the formula of criticizing is produced hydrogen, continues 24h its hydrogen-producing speed of test and total amount.
Adopt the device for producing hydrogen that originally continuously ferments to carry out the continuously streamed fermentation; Owing to behind 6h, start wriggling fresh feed pump and wriggling discharging pump, can continuous supplementation nutritive substance and matrix, and the continuous blow-down fermented waste fluid; Effectively keep thalline activity and concentration, alleviate the accumulation of harmful meta-bolites; In addition, fermentation reactor bottom is provided with microfiltration membrane, has realized separating of thalline and fermented liquid; Make thalline effectively be trapped in inside reactor; Effectively improved cell concentration in the fermentation reactor, behind 6h, still kept higher hydrogen-producing speed, attenuation trend has not taken place; Realized the purpose of lasting highly effective hydrogen yield, its hydrogen output is 4 times that batch fermentation produces hydrogen.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201120523923 CN202415545U (en) | 2011-12-15 | 2011-12-15 | Continuous flow type microbial fermentation hydrogen generation device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201120523923 CN202415545U (en) | 2011-12-15 | 2011-12-15 | Continuous flow type microbial fermentation hydrogen generation device |
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| Publication Number | Publication Date |
|---|---|
| CN202415545U true CN202415545U (en) | 2012-09-05 |
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ID=46740325
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| CN 201120523923 Expired - Fee Related CN202415545U (en) | 2011-12-15 | 2011-12-15 | Continuous flow type microbial fermentation hydrogen generation device |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382436A (en) * | 2013-06-24 | 2013-11-06 | 江苏元洲生物工程有限公司 | Continuous perfusion device of fermentation tank |
| CN107488584A (en) * | 2017-09-25 | 2017-12-19 | 南京律智诚专利技术开发有限公司 | One kind is based on the intelligent feeding-system that discharges |
| CN114106988A (en) * | 2012-10-26 | 2022-03-01 | 麻省理工学院 | Humidity Control in Chemical Reactors |
-
2011
- 2011-12-15 CN CN 201120523923 patent/CN202415545U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114106988A (en) * | 2012-10-26 | 2022-03-01 | 麻省理工学院 | Humidity Control in Chemical Reactors |
| CN103382436A (en) * | 2013-06-24 | 2013-11-06 | 江苏元洲生物工程有限公司 | Continuous perfusion device of fermentation tank |
| CN107488584A (en) * | 2017-09-25 | 2017-12-19 | 南京律智诚专利技术开发有限公司 | One kind is based on the intelligent feeding-system that discharges |
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|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120905 Termination date: 20121215 |