CN202400930U - Low-sludge-yield printing and dyeing wastewater treatment system - Google Patents
Low-sludge-yield printing and dyeing wastewater treatment system Download PDFInfo
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Abstract
本实用新型公开了一种低污泥产率的印染废水处理系统。进水泵、阀门、流量计、厌氧水解区、生物选择区、生物强化捕食好氧污泥减量区顺次相连,厌氧水解区内设有潜水搅拌机、生物填料载体,生物选择区内设有潜水搅拌机,生物选择区、生物强化捕食好氧污泥减量区底部设有曝气装置,后生动物培养投加槽与生物强化捕食好氧污泥减量区相连,生物强化捕食好氧污泥减量区上部与二沉池底部相连,二沉池上部设有出水管,二沉池底部经沉淀区污泥回流泵、污泥管与厌氧水解区底部、生物选择区底部相连。本实用新型的印染废水低污泥产率的工艺,适用于一切活性污泥法及其变形工艺,既可用于新建工程,也可用于已建工程的改造。
The utility model discloses a printing and dyeing wastewater treatment system with low sludge yield. Inlet pumps, valves, flow meters, anaerobic hydrolysis zone, biological selection zone, bio-enhanced predation and aerobic sludge reduction zone are connected in sequence. Submersible mixers and biological filler carriers are installed in the anaerobic hydrolysis zone. There is a submersible mixer, and an aeration device is installed at the bottom of the biological selection area and the bio-enhanced predation aerobic sludge reduction area. The upper part of the sludge reduction area is connected to the bottom of the secondary settling tank. The upper part of the secondary settling tank is provided with an outlet pipe. The bottom of the secondary settling tank is connected to the bottom of the anaerobic hydrolysis area and the bottom of the biological selection area through the sludge return pump and sludge pipe in the sedimentation area. The low-yield process of printing and dyeing wastewater of the utility model is applicable to all activated sludge processes and deformation processes thereof, and can be used in new constructions and renovations of existing projects.
Description
技术领域 technical field
本实用新型涉及生物工程与环境工程技术领域,尤其涉及一种低污泥产率的印染废水处理系统。 The utility model relates to the technical field of biological engineering and environmental engineering, in particular to a printing and dyeing wastewater treatment system with low sludge yield. the
背景技术 Background technique
我国日排放印染废水量为(3~4)×106t,是各行业中的排污大户之一,占总工业废水排放量的35%左右。印染废水主要由退浆废水、煮炼废水、漂白废水、丝光废水、染色废水和印花废水组成,印染加工的四个工序都要排出废水,预处理阶段(包括退浆、煮炼、漂白、丝光等工序)要排出退浆废水、煮炼废水、漂白废水和丝光废水,染色工序排出染色废水,印花工序排出印花废水和皂液废水,整理工序则排出整理废水。通常所说的印染废水是以上各类废水的混合废水,或除漂白废水以外的综合废水。印染废水的水质随采用的纤维种类和加工工艺的不同而异,污染物组分差异很大。印染废水一般具有污染物浓度高、种类多、含有毒有害成分及色度高等特点。一般印染废水pH值为6-10,CODCr为400-1000mg/L,BOD5为100-400mg/L,SS为100-200mg/L,色度为100-400倍。但当印染工艺、采用的纤维种类和加工工艺变化后,废水水质将有较大变化。近年来由于化学纤维织物的发展,仿真丝的兴起和印染后整理技术的进步,使PVA浆料、人造丝碱解物(主要是邻苯二甲酸类物质)、新型助剂等难生化降解有机物大量进入印染废水,其CODCr浓度也由原来的数百mg/L上升到2000-3000mg/L以上,BOD5增大到800mg/L以上,pH值达11.5-12,从而使原有的生物处理系统CODCr去除率降低。 The daily discharge of printing and dyeing wastewater in China is (3~4)×10 6 t, and it is one of the major pollutant dischargers in various industries, accounting for about 35% of the total industrial wastewater discharge. Printing and dyeing wastewater is mainly composed of desizing wastewater, boiling wastewater, bleaching wastewater, mercerizing wastewater, dyeing wastewater and printing wastewater. The four processes of printing and dyeing processing must discharge wastewater. The pretreatment stage (including desizing, scouring, bleaching, mercerizing and other processes) to discharge desizing wastewater, boiling wastewater, bleaching wastewater and mercerizing wastewater, dyeing wastewater is discharged from the dyeing process, printing wastewater and soap wastewater are discharged from the printing process, and finishing wastewater is discharged from the finishing process. Usually, printing and dyeing wastewater is mixed wastewater of the above types of wastewater, or comprehensive wastewater other than bleaching wastewater. The water quality of printing and dyeing wastewater varies with the fiber types and processing techniques used, and the pollutant components vary greatly. Printing and dyeing wastewater generally has the characteristics of high pollutant concentration, many types, toxic and harmful components, and high chroma. Generally, the pH value of printing and dyeing wastewater is 6-10, CODCr is 400-1000mg/L, BOD 5 is 100-400mg/L, SS is 100-200mg/L, and the chroma is 100-400 times. However, when the printing and dyeing process, the type of fiber used and the processing technology change, the quality of wastewater will change greatly. In recent years, due to the development of chemical fiber fabrics, the rise of imitation silk and the progress of printing and dyeing finishing technology, PVA pulp, rayon alkali hydrolyzate (mainly phthalic acid substances), new additives and other difficult biodegradable organic substances A large amount of printing and dyeing wastewater enters, and its COD Cr concentration rises from hundreds of mg/L to over 2000-3000mg/L, BOD 5 increases to over 800mg/L, and pH reaches 11.5-12, so that the original biological The COD Cr removal rate of the treatment system is reduced.
印染废水处理常用的方法有物理、化学及生化法,通常是几种方法的组合才能达到要求。无论哪种方法处理印染废水都将产生二次污染物--污泥,因此追求污泥的最小化也是工程设计需考虑的问题。在污水处理过程中原位减少剩余污泥产率,从源头上降低剩余污泥产量的各种污泥减量技术已成为废水生物处理研究的热点和发展方向。后生动物捕食微生物的污泥减量技术因具有经济高效、无二次污染等优点,已经引起国内外学者的广泛关注。后生动物原位消解污泥技术是根据生态学理论,基于物质与能量在食物链传递过程中逐级递减的原理,通过强化食物链中后生动物的捕食作用以减少剩余污泥的产生量,在保证出水水质达标的前提下,一定程度上使污泥的处理与处置从“末端治理”转移到“源头控制”。后生动物以有机残渣和死的生物体为食。随着水中有机物的减少,出现了轮虫、寡毛类、线虫,轮虫能够吞噬散落的污泥, Commonly used methods for printing and dyeing wastewater treatment include physical, chemical and biochemical methods, and usually a combination of several methods can meet the requirements. No matter which method is used to treat printing and dyeing wastewater, it will produce secondary pollutants—sludge, so the pursuit of minimizing sludge is also an issue that needs to be considered in engineering design. In the sewage treatment process, various sludge reduction technologies that reduce the excess sludge production rate in situ and reduce the excess sludge production from the source have become the focus and development direction of wastewater biological treatment research. The sludge reduction technology of metazoans preying on microorganisms has attracted widespread attention from scholars at home and abroad because of its advantages of cost-effectiveness and no secondary pollution. The metazoan in situ sludge digestion technology is based on the ecological theory, based on the principle of gradual decrease of matter and energy in the food chain transfer process, by strengthening the predation of metazoans in the food chain to reduce the amount of excess sludge, in order to ensure the effluent Under the premise of meeting the water quality standards, the treatment and disposal of sludge will be transferred from "end treatment" to "source control" to a certain extent. Metazoans feed on organic debris and dead organisms. With the reduction of organic matter in the water, rotifers, oligochaetes, and nematodes appeared, and the rotifers could swallow the scattered sludge,
利用微型后生动物进行污泥减量,不但能达到较高的污泥减量效果,而且具有能耗少、运行费用低、没有副产物以及对环境不产生二次污染等优点。 The use of micro-metazoans for sludge reduction not only achieves a high sludge reduction effect, but also has the advantages of less energy consumption, low operating costs, no by-products, and no secondary pollution to the environment.
发明内容 Contents of the invention
本实用新型的目的是克服现有印染废水处理过程中污泥产生量大的不足,提供一种低污泥产率的印染废水处理系统。 The purpose of the utility model is to overcome the problem of large amount of sludge produced in the existing printing and dyeing wastewater treatment process, and provide a printing and dyeing wastewater treatment system with low sludge yield. the
低污泥产率的印染废水处理系统包括进水泵、阀门、流量计、潜水搅拌机、鼓风机、厌氧水解区、生物选择区、生物强化捕食好氧污泥减量区、二沉池、曝气装置、沉淀区污泥回流泵、后生动物培养投加槽、刮泥机、生物填料载体、污泥管和出水管;进水泵、阀门、流量计、厌氧水解区、生物选择区、生物强化捕食好氧污泥减量区顺次相连,厌氧水解区内设有潜水搅拌机、生物填料载体,生物选择区内设有潜水搅拌机,生物选择区、生物强化捕食好氧污泥减量区底部设有曝气装置,鼓风机与曝气装置相连,后生动物培养投加槽与生物强化捕食好氧污泥减量区相连,生物强化捕食好氧污泥减量区上部与二沉池底部相连,二沉池内部设有刮泥机,二沉池上部设有出水管,二沉池底部经沉淀区污泥回流泵、污泥管与厌氧水解区底部、生物选择区底部相连。 The printing and dyeing wastewater treatment system with low sludge yield includes water inlet pump, valve, flow meter, submersible mixer, blower, anaerobic hydrolysis zone, biological selection zone, bio-enhanced predation aerobic sludge reduction zone, secondary settling tank, aeration Equipment, sludge return pump in sedimentation area, metazoan cultivation dosing tank, sludge scraper, biological filler carrier, sludge pipe and outlet pipe; water inlet pump, valve, flow meter, anaerobic hydrolysis area, biological selection area, bioaugmentation The predation aerobic sludge reduction area is connected in sequence, the anaerobic hydrolysis area is equipped with a submersible mixer and biological filler carrier, the biological selection area is equipped with a submersible mixer, the biological selection area, and the bottom of the bio-enhanced predation aerobic sludge reduction area An aeration device is provided, the blower is connected with the aeration device, the metazoan cultivation dosing tank is connected with the bio-enhanced predation aerobic sludge reduction area, and the upper part of the bio-enhanced predation aerobic sludge reduction area is connected with the bottom of the secondary sedimentation tank. There is a sludge scraper inside the secondary settling tank, and an outlet pipe is installed on the upper part of the secondary settling tank. The bottom of the secondary settling tank is connected to the bottom of the anaerobic hydrolysis zone and the bottom of the biological selection zone through the sludge return pump and sludge pipe in the sedimentation zone. the
本实用新型与现有技术相比具有的有益效果: The utility model has the beneficial effects compared with the prior art:
1)本工艺流程简洁、操作运行管理方便。 1) The technological process is simple and easy to operate and manage.
2)利用食物链作用强化微型动物对细菌捕食的技术,最终达到污泥自身产量的减少,致使污泥处置从“末端治理”转移到“源头控制”。 2) Using the food chain to strengthen the technology of micro-animals to prey on bacteria, and finally reduce the output of sludge itself, resulting in the transfer of sludge disposal from "end treatment" to "source control". the
3)将微生物强化消化与微型后生动物强化捕食相组合,易于形成食物链,可实现对剩余污泥40%-85%的污泥减量效果,且不影响原生化系统污水处理效果。 3) Combining the enhanced digestion of microorganisms and the enhanced predation of micrometazoans can easily form a food chain, and can achieve a sludge reduction effect of 40%-85% on the remaining sludge without affecting the sewage treatment effect of the primary chemical system. the
4)本工艺适用于一切活性污泥法废水生物处理及其变形工艺对剩余污泥的减量化,可以在不影响污水厂正常运行的情况下实施污泥减量化改造,投资省、运行费用低、见效快,推广应用价值高。 4) This process is suitable for the reduction of excess sludge by all activated sludge wastewater biological treatment and its deformation process. It can implement sludge reduction transformation without affecting the normal operation of the sewage plant, saving investment and operation The cost is low, the effect is quick, and the value of promotion and application is high. the
附图说明 Description of drawings
图1是低污泥产率的印染废水处理系统结构示意图; Fig. 1 is a schematic diagram of the structure of the printing and dyeing wastewater treatment system with low sludge yield;
图中,进水泵1、阀门2、流量计3、潜水搅拌机4、鼓风机5、厌氧水解区6、生物选择区7、生物强化捕食好氧污泥减量区8、二沉池9、曝气装置10、沉淀区污泥回流泵11、后生动物培养投加槽12、刮泥机13、生物填料载体14、污泥管15、出水管16。
In the figure, water inlet pump 1, valve 2, flow meter 3, submersible mixer 4, blower 5, anaerobic hydrolysis zone 6, biological selection zone 7, bioenhanced predation aerobic
具体实施方式 Detailed ways
如图1所示,低污泥产率的印染废水处理系统包括进水泵1、阀门2、流量计3、潜水搅拌机4、鼓风机5、厌氧水解区6、生物选择区7、生物强化捕食好氧污泥减量区8、二沉 池9、曝气装置10、沉淀区污泥回流泵11、后生动物培养投加槽12、刮泥机13、生物填料载体14、污泥管15和出水管16;所述处理工艺,根据功能分为生物厌氧水解区6、生物选择区7、生物强化捕食好氧污泥减量区8和沉淀区9;进水泵1、阀门2、流量计3、厌氧水解区6、生物选择区7、生物强化捕食好氧污泥减量区8顺次相连,厌氧水解区6内设有潜水搅拌机4、生物填料载体14,生物选择区7内设有潜水搅拌机4,生物选择区7、生物强化捕食好氧污泥减量区8底部设有曝气装置10,鼓风机5与曝气装置10相连,后生动物培养投加槽12与生物强化捕食好氧污泥减量区8相连,生物强化捕食好氧污泥减量区8上部与二沉池9底部相连,二沉池9内部设有刮泥机13,二沉池9上部设有出水管16,二沉池9底部经沉淀区污泥回流泵11、污泥管15与厌氧水解区6底部、生物选择区7底部相连。
As shown in Figure 1, the printing and dyeing wastewater treatment system with low sludge yield includes water inlet pump 1, valve 2, flow meter 3, submersible mixer 4, blower 5, anaerobic hydrolysis zone 6, biological selection zone 7, and bio-enhanced predation well Oxygen
低污泥产率的印染废水处理工艺是:印染废水通过进水泵1、阀门2和流量计3进入厌氧水解区6,厌氧水解区6内设有搅拌机4和生物载体填料14,搅拌机4保证泥水的充分接触,生物载体填料14设上下两层支架,支架之间生物载体装填料,生物载体填料可以增加生物量和拦截污泥以减少污泥流失,印染废水经过厌氧水解区6进入生物选择区7,生物选择区7主要预防污泥膨胀,生物选择区7内设有搅拌机4和曝气系统10,搅拌机4是为了保证泥水的充分接触,曝气系统是在水温较低时可以开启,用于补充氧气,印染废水经过生物选择区7进入生物强化捕食好氧污泥减量区8,曝气系统10通过管路与鼓风机5相连保证持续高效供氧,使好氧区DO在2mg/l以上;后生动物培养投加槽12定期向生物强化捕食好氧污泥减量区8补加高活性的后生动物,生物强化捕食好氧污泥减量区8的上部出水进入二沉区9的底部,经过刮泥机13后由出水管16出水外排,同时二沉区9底部的污泥通过污泥泵11主要回流到生物选择区7,少量回流到厌氧水解区6,剩余污泥去污泥处理系统处理。
The printing and dyeing wastewater treatment process with low sludge yield is: the printing and dyeing wastewater enters the anaerobic hydrolysis zone 6 through the inlet pump 1, the valve 2 and the flow meter 3, and the anaerobic hydrolysis zone 6 is equipped with a mixer 4 and a biological carrier filler 14, and the mixer 4 To ensure full contact with mud and water, the biological carrier filler 14 is provided with upper and lower layers of brackets, and the biological carrier is filled with fillers between the brackets. The biological carrier filler can increase biomass and intercept sludge to reduce sludge loss. Printing and dyeing wastewater enters through the anaerobic hydrolysis zone 6 The biological selection area 7, the biological selection area 7 mainly prevents sludge bulking, the biological selection area 7 is equipped with a mixer 4 and an
所述生物载体填料14为塑料填料、陶瓷填料、纤维填料及聚氨酯类填料。 The biological carrier filler 14 is plastic filler, ceramic filler, fiber filler and polyurethane filler. the
下面将结合附图详细说明本实用新型的具体实施方式: The specific embodiment of the utility model will be described in detail below in conjunction with accompanying drawing:
实施例1 Example 1
某印染污水水质为pH:10~13,CODcr:800~1200mg/l,NH3-N:15~30mg/l,TP:2~6mg/l,水温为35-40℃,水量为4000m3/d,污水处处理工艺为调节中和厌氧水解-生物选择池-好氧池-SBR池-出水,要求处理后出水达到CODcr<500mg/l的CJ3082-1999纳管标准。厌氧水解区停留时间为7h,区内设潜水搅拌机搅拌使泥水充分混合,设组合填料以增加生物量。生物选择池停留时间为2h,好氧池停留时间为12h,SBR池停留时间为6h。采用活性污泥法,鼓风曝气,可提升曝气管充氧,好氧区投加后生动物强化捕食,在此条件下,出水CODcr<200mg/l,污泥减量效果达80%以上,已经稳定运行四年。 The water quality of a printing and dyeing wastewater is pH: 10~13, CODcr: 800~1200mg/l, NH 3 -N: 15~30mg/l, TP: 2~6mg/l, water temperature is 35-40℃, water volume is 4000m 3 / d. The sewage treatment process is to adjust neutralization anaerobic hydrolysis-biological selection tank-aerobic tank-SBR tank-effluent, and the effluent after treatment is required to meet the CJ3082-1999 standard of CODcr<500mg/l. The residence time in the anaerobic hydrolysis zone is 7 hours. A submersible mixer is set in the zone to mix the mud and water fully, and a combined filler is set to increase the biomass. The residence time of biological selection pond is 2h, the residence time of aerobic pond is 12h, and the residence time of SBR pond is 6h. Activated sludge method, blast aeration, can improve the oxygenation of the aeration tube, add metazoans in the aerobic zone to strengthen predation, under this condition, the effluent CODcr<200mg/l, the sludge reduction effect can reach more than 80% , has been running stably for four years.
实施例2 Example 2
某园区废水以喷水织机为主,废水水质为pH5-7,CODcr:100-400mg/l,NH3-N:10-15mg/l,TP1-3mg/l,水温为常温,水量为5000m3/d,污水处处理工艺为调节—气浮--厌氧水解—生物选择池—好氧池—二沉池—砂滤--出水,要求出水达到GB18918一级B标准。厌氧水解区停留时间为8h,区内设潜水搅拌机搅拌使泥水充分混合,设组合填料以增加生物量。生物选择池停留时间为0.5h,好氧池停留时间为12.5h。采用活性污泥法,鼓风曝气,可提升曝气管充氧,好氧区投加后生动物强化捕食,在此条件下,出水优于GB18918一级B标准,污泥减量效果达70%以上,大大减少了污泥处理成本。 The wastewater in a park is mainly water-jet looms, the wastewater quality is pH5-7, CODcr: 100-400mg/l, NH 3 -N: 10-15mg/l, TP1-3mg/l, the water temperature is normal temperature, and the water volume is 5000m 3 /d, the sewage treatment process is adjustment-air flotation-anaerobic hydrolysis-biological selection tank-aerobic tank-secondary settling tank-sand filter-water outlet, and the outlet water is required to meet the GB18918 Class B standard. The residence time in the anaerobic hydrolysis zone is 8 hours. A submersible mixer is set in the zone to mix the mud and water fully, and a combined filler is set to increase the biomass. The residence time of biological selection pond is 0.5h, and the residence time of aerobic pond is 12.5h. Activated sludge method, blowing aeration, can improve the oxygenation of the aeration tube, and add metazoans to the aerobic zone to strengthen predation. Under this condition, the effluent is better than the GB18918 Class B standard, and the sludge reduction effect reaches 70% % above, greatly reducing the cost of sludge treatment.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102515427A (en) * | 2011-12-07 | 2012-06-27 | 浙江省环境保护科学设计研究院 | Printing and dyeing waste water treatment system and process with low yield of sludge |
CN103011521A (en) * | 2012-12-25 | 2013-04-03 | 绍兴县江滨水处理有限公司 | Biological treatment method and biological treatment apparatus for strongly alkaline printing and dyeing wastewater |
CN104909515A (en) * | 2015-06-03 | 2015-09-16 | 宜兴市荣盛达环保有限公司 | Industrial wastewater treatment system and method based on sludge internal consumption |
CN109179861A (en) * | 2018-08-28 | 2019-01-11 | 广州市市政工程设计研究总院有限公司 | A kind of pulling flow type coupling sewage-treatment plant and technique |
-
2011
- 2011-12-07 CN CN201120503722.0U patent/CN202400930U/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102515427A (en) * | 2011-12-07 | 2012-06-27 | 浙江省环境保护科学设计研究院 | Printing and dyeing waste water treatment system and process with low yield of sludge |
CN103011521A (en) * | 2012-12-25 | 2013-04-03 | 绍兴县江滨水处理有限公司 | Biological treatment method and biological treatment apparatus for strongly alkaline printing and dyeing wastewater |
CN104909515A (en) * | 2015-06-03 | 2015-09-16 | 宜兴市荣盛达环保有限公司 | Industrial wastewater treatment system and method based on sludge internal consumption |
CN109179861A (en) * | 2018-08-28 | 2019-01-11 | 广州市市政工程设计研究总院有限公司 | A kind of pulling flow type coupling sewage-treatment plant and technique |
CN109179861B (en) * | 2018-08-28 | 2024-01-23 | 广州市市政工程设计研究总院有限公司 | Plug-flow type coupling sewage treatment device and process |
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