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CN202214239U - Ultrasonic strengthened floating device for removing algae and algal toxin - Google Patents

Ultrasonic strengthened floating device for removing algae and algal toxin Download PDF

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Publication number
CN202214239U
CN202214239U CN2011203094110U CN201120309411U CN202214239U CN 202214239 U CN202214239 U CN 202214239U CN 2011203094110 U CN2011203094110 U CN 2011203094110U CN 201120309411 U CN201120309411 U CN 201120309411U CN 202214239 U CN202214239 U CN 202214239U
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China
Prior art keywords
algae
ultrasonic
air flotation
pool
toxins
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Expired - Fee Related
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CN2011203094110U
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Chinese (zh)
Inventor
邓慧萍
史俊
徐立克
赵纯
韩旭
陈鑫
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Tongji University
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Tongji University
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Abstract

本实用新型涉及一种除藻及藻毒素的超声波强化气浮装置,本装置将超声波和电气浮池结合在一起,主要包括混凝反应池、电气浮池、超声波反应池三个构筑相连,水体经过加药设备,在混凝反应器内形成絮体,絮体经过电气浮池,电气浮池内的电极板通过自控装置通电产生气泡,气浮除去藻体,水体中的藻类形成絮凝体,不破坏藻体,有很好的除藻效果和去浊效果。而超声波反应器中发生的超声作用则通过超声波的空化作用和自由基的强氧化作用可一并降解溶液中及气浮工艺释放出的少量藻毒素,到达明显的去除藻和藻毒素的效果。因此,将超声波和电气浮联合的工艺可以同时实现高效去除藻和藻毒素,且操作方便,藻毒素及其它有机物去除速度快,效率高,设备一次性投资少,运行费低,使用较广泛。

Figure 201120309411

The utility model relates to an ultrasonic intensified air flotation device for removing algae and algae toxins. The device combines ultrasonic waves and electric floating pools, and mainly includes a coagulation reaction pool, an electric floating pool, and an ultrasonic reaction pool. Pharmaceutical equipment, flocs are formed in the coagulation reactor, and the flocs pass through the electric floating pool, and the electrode plates in the electric floating pool are energized by the automatic control device to generate air bubbles, and the air flotation removes the algae, and the algae in the water body form flocs without destroying the algae , has a good effect of removing algae and removing turbidity. The ultrasonic effect in the ultrasonic reactor can degrade a small amount of algae toxins in the solution and released by the air flotation process through the cavitation of ultrasonic waves and the strong oxidation of free radicals, achieving the obvious effect of removing algae and algae toxins . Therefore, the process of combining ultrasonic wave and electric floatation can achieve high-efficiency removal of algae and algal toxins at the same time, and is easy to operate. The removal speed of algae toxins and other organic matter is high, the efficiency is high, the equipment has less investment at one time, low operating costs, and is widely used.

Figure 201120309411

Description

A kind of intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin
Technical field
The utility model belongs to field of water treatment technology application, is specifically related to a kind of intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin.
Background technology
Along with the quickening of social process of industrialization, the mankind enter pollutent nitrogenous in a large number, phosphorus in water body in industrial and agricultural production and daily life, quickened the eutrophication process of river, lake and reservoir.Body eutrophication has become the main illness of global water body, and algal bloom forms " wawter bloom ", consumes oxygen in water, distributes stench, destroys the eubiosis of water surrounding, and wawter bloom is the main environment disaster of body eutrophication.In the water body of eutrophication, in the production of tap water, high algae source water can stop up the filter tank; Also influence the coagulating sedimentation effect, its coagulation complex compound can penetrate the filter tank, influences delivery turbidity, causes the corrosion and the secondary pollution of pipe network.At present to the treatment process of algae comprise mainly that manual work is fished for, flocculation, chemical method, air supporting and chemical oxidization method etc.
The lake of China more than 70% receives algae pollution; China considerable part city all is to be main water source with reservoir, lake; Frond discharges a large amount of algae toxin humans and animals is produced very big toxic action, causes severe contamination for living water, influences water treatment procedure.Each big lake and reservoir of China detected in succession Microcystin (Microcystins, MC).People more and more is paid close attention to the harm of the Microcystin of wawter bloom release to environment and HUMAN HEALTH.Treatment process to the algae toxin mainly comprises filtration and absorption, chemical method, photochemical catalytic oxidation, membrane technique, biological degradation and ultrasonic technology etc.
Air supporting is used widely aspect algae removal, adopts air-float technology to handle high algae water, and its advantage is reached common understanding in field of water treatment, obtains promotion and application gradually at water supply plant.But discover that air-float technology has certain limitation to ultra's processing, when raw water turbidity surpassed 100 NTU, the water outlet effect worsened.Test shows, air flotation pool remove algae efficient up to 90%, but exist algae-residue to be difficult to shortcomings such as processing, stink weight, operating environment difference.Air-float technology can effectively be removed algae in the water, but can't remove dissolved algae toxin in the water.
Utilize UW that the degrade research of aspect of algae has also been obtained progress.Ultrasonic radiation can suppress the division of blue-green algae cell.Ultrasonic while ripple can make that pseudo-ghost breaks in the blue-green algae cell, and breaking of pseudo-ghost can make cell sink in the blue-green algae cell, so reduce frustule photosynthesis, strengthen the predation of zoobenthos, thereby reach the effect of control algae.Simultaneously, the UW algae toxin of can also degrading effectively, the ultrasonic generator of 640 kHz to MC-LR 3min after concentration reduce to original half the.But discover that the healthy of drinking person in serious threat if directly irradiation can cause frustule to break on the contrary and discharge certain algae toxin.
air supporting and ultrasonic technology can both be removed certain algae or algae toxin separately, but simple air floatation alga removing can't be removed dissolved algae toxin in the water, and simple UW removal algae can make frustule break and discharge the algae toxin.Therefore, await further raising, seek the method that is fit to remove simultaneously algae and algae toxin and seem particularly important for the removal efficient of algae and algae toxin.
Summary of the invention
The purpose of the utility model is to provide a kind of has the ability of removing more by force, efficiently remove the intensified by ultrasonic wave air-floating apparatus of algae and algae toxin.
The intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin that the utility model proposes; Connected to form through pipeline and valve by tank 1, coagulation reaction tank 7, electric air flotation pool 8 and ultrasonic response pond 15, tank 1 bottom one side is through valve 2, intake pump 3 and valve 4 and pipe connection coagulation reaction tank 7 tops; Coagulation reaction tank 7 tops are equipped with medicine machine 5, and whisking appliance 6 inserts in the coagulation reaction tank 7; In the electricity air flotation pool 8 battery lead plate 9 is installed; Electricity air flotation pool 8 tops are equipped with track type dreg scraper 10; Track type dreg scraper 10 1 sides link to each other with scum silica frost receiving tank 11; Mass-energy transmodulator 16 and ultrasonic generator 17 are housed in the ultrasonic response pond 15, and mass-energy transmodulator 16 connects ultrasonic generator 17, and whisking appliance 6, battery lead plate 9, track type dreg scraper 10, mass-energy transmodulator 16 and ultrasonic generator 17 are connected self-con-tained unit 14 respectively.
In the utility model, the quantity of said battery lead plate 9 is determined on a case-by-case basis, and the positive and negative electrode battery lead plate is alternately arranged.
In the utility model, 15 tops, said ultrasonic response pond, one side is provided with overflow weir 18, and overflow weir 18 belows are provided with rising pipe 19.
In the utility model, said electric air flotation pool 8 bottoms are provided with blow-down pipe 12, and said blow-down pipe 12 connects valve 13.
In the utility model, said self-con-tained unit 14 adopts rly..
The advantage of the utility model is: investigate removal effect from the aspects such as starting point concentration of ultrasonic frequency, power, ultrasonic time, coagulating agent kind, air supporting required voltage and algae (algae toxin); Overcome and remove the deficiency of algae and algae toxin technology now separately, thereby set up a kind of new process integration.Utilize air supporting to remove in the water it is thus clear that behind the algae, through remaining algae toxin in the cavitation effect of ultrasonic waves removal water, this method can effectively be removed algae and algae toxin simultaneously.
The utility model is dosing in coagulation reactor, stirs certain hour, makes frond form flco; Through the electric floating frond come-up that makes, the frond of come-up is removed under the effect of track type dreg scraper then, and frond forms flocs unit in the water; Do not destroy frond, have well and go turbid effect except that algae.UW is then removed a small amount of algae toxin that deliquescent algae toxin and electric floating technology discharge, and reaches rapidly and efficiently removal frond and the effect of algae toxin.
In the utility model, used ultrasonic time is 15 ~ 30min.
The used coagulating agent of the utility model is PAC, electric floating required voltage 20V, and pH remains on 7.0, and PAC is 30mg/L ~ 40mg/L, and electric current is 0.4 ~ 0.8A, stirs (pool time) 1min soon and stirs (flocculation time) 3min slowly.
The device materials that the utility model relates to is the PVC material.
The utility model application example; Concrete parameter is following: PAC is 50mg/L; Electric current is 1A, and when stirring (pool time) 1min soon and stirring (flocculation time) 3min slowly, the ultrasonic echography time is 15 ~ 30min in the ultrasonic response pond; The clearance of green capsule algae toxin is 96%, and the clearance of algae toxin is 90%.
This installs integrated packaged type device, and is rationally distributed, and compact construction is simple to operate, can remove algae and algae toxin effectively.Electric floating technology can be removed most algae, avoids effect of ultrasound that frustule is broken and discharges the algae toxin; Ultrasonication then destroys the cellularstructure of algae through cavitation effect of ultrasonic waves and strong oxidation of free radical, makes the aggregation of frond and settleability improve, and reaches a small amount of algae toxin that air-float technology discharges in the degraded solutions in the lump.Act on algae and algae toxin to ultrasonic this characteristics combined echocardiography and air supporting process integration.
Description of drawings
Fig. 1 is the structural representation of the utility model.
Label among the figure: 1. tank, 2. valve, 3. intake pump, 4. valve, 5. medicine machine; 6. whisking appliance, 7. coagulation reaction tank, 8. electric air flotation pool, 9. battery lead plate, 10. track type dreg scraper; 11. the scum silica frost receiving tank, 12. blow-down pipes, 13. valves, 14. self-con-tained units, 15. ultrasonic response ponds; 16. the mass-energy transmodulator, 17. ultrasonic generators, 18. overflow weirs, 19. rising pipes.
Embodiment
Combine accompanying drawing to further specify the utility model through embodiment below.
Embodiment 1: referring to Fig. 1, tank 1 links to each other with coagulation reaction tank 7 through valve 2, intake pump 3, valve 4, and coagulation reaction tank 7 tops are equipped with medicine machine 5 and whisking appliance 6; Coagulation reaction tank 7 back connect electric air flotation pool 8; Battery lead plate 9 has been installed in electricity air flotation pool 8 inside, and track type dreg scraper 10 has been installed in the top, and there is scum silica frost receiving tank 11 in electric air flotation pool 8 upper right side; Blow-down pipe 12 is equipped with in the bottom of electricity air flotation pool 8, and blow-down pipe 12 is connected by valve 13; Mass-energy transmodulator 16 is equipped with in 15 inside, ultrasonic response pond, and mass-energy transmodulator 16 is connected on the self-con-tained unit 14 with ultrasonic generator 17; There are overflow weir 18 and rising pipe 19 in 15 tops, ultrasonic response pond; Whisking appliance 6, battery lead plate 9, track type dreg scraper 10, ultrasonic generator 17 all are connected with self-con-tained unit 14.Wherein, self-con-tained unit 14 belongs to a kind of of rly..
The working process of the utility model is following:
Water in the tank 1 at first passes through valve 2, intake pump 3, valve 4 in medicine machine 5, and the water of process dosing has arrived in the coagulation reaction tank 7, by self-con-tained unit 14 control cohesion and flocculation times.1min is condensed in stirring fast under the effect of whisking appliance 6, stirs flocculation 3min then at a slow speed, and water body gets in the electric air flotation pool 8 through coagulation formation flco after a while; Thereafter self-con-tained unit 14 is connected battery lead plate 9, under the voltage of 20V, produces electric floating; Let the frond come-up of flocculating in the water, remove the most fronds in the water body, simultaneously; 10 motions of track type dreg scraper scrape the frond that floats in the scum silica frost receiving tank 11, regularly the frond in the emptying scum silica frost receiving tank 11.Water body is at last through ultrasonic response pond 15, and self-con-tained unit 14 starts ultrasonic generator 17, and ultra-sonic generator 17 begins response, and mass-energy transmodulator 16 sends UW, and cavitation effect of ultrasonic waves is removed remaining algae toxin in the water, and hyperacoustic time is 30min; Water body through ultrasound-enhanced processing gets into overflow weir 18, from rising pipe 19, flows out.

Claims (4)

1. intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin; Connect to form through pipeline and valve by tank (1), coagulation reaction tank (7), electric air flotation pool (8) and ultrasonic response pond (15), it is characterized in that tank (1) bottom one side is through valve (2), intake pump (3) and valve (4) and pipe connection coagulation reaction tank (7) top; Coagulation reaction tank (7) top is equipped with medicine machine (5), and whisking appliance (6) inserts in the coagulation reaction tank (7); In the electricity air flotation pool (8) battery lead plate (9) is installed; Electricity air flotation pool (8) top is equipped with track type dreg scraper (10); Track type dreg scraper (10) one sides link to each other with scum silica frost receiving tank (11); Mass-energy transmodulator (16) and ultrasonic generator (17) are housed in the ultrasonic response pond (15), and mass-energy transmodulator (16) connects ultrasonic generator (17), and whisking appliance (6), battery lead plate (9), track type dreg scraper (10), mass-energy transmodulator (16) and ultrasonic generator (17) are connected self-con-tained unit (14) respectively.
2. the intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin according to claim 1 is characterized in that top, said ultrasonic response pond (15) one side is provided with overflow weir (18), and overflow weir (18) below is provided with rising pipe (19).
3. the intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin according to claim 1 is characterized in that said electric air flotation pool (8) bottom is provided with blow-down pipe (12), and said blow-down pipe (12) connects valve (13).
4. the intensified by ultrasonic wave air-floating apparatus that removes algae and algae toxin according to claim 1 is characterized in that said self-con-tained unit (14) adopts rly..
CN2011203094110U 2011-08-24 2011-08-24 Ultrasonic strengthened floating device for removing algae and algal toxin Expired - Fee Related CN202214239U (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103387305A (en) * 2013-08-01 2013-11-13 广东沃杰森环保科技有限公司 Wastewater Treatment Sonic Electro-Oxidation Process
CN103787526A (en) * 2014-01-16 2014-05-14 同济大学 Method for removing blue-green algae by using microbubble hydrodynamic cavitation enhanced coagulation
CN104370431A (en) * 2014-11-25 2015-02-25 湖南大学 Blue algae dehydrating method
CN104768877A (en) * 2012-04-17 2015-07-08 源油公司 Harvesting and dewatering algae using a two-stage process
CN105189728A (en) * 2013-04-17 2015-12-23 奥瑞金可利尔公司 Producing algae biomass having reduced concentration of contaminants
CN107364926A (en) * 2017-07-21 2017-11-21 河海大学 A kind of ultrasonic wave depth algae-removing device and method
CN108467079A (en) * 2018-03-08 2018-08-31 深圳市安思科电子科技有限公司 A kind of air floatation machine convenient for maintenance with electrode clean function

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104768877A (en) * 2012-04-17 2015-07-08 源油公司 Harvesting and dewatering algae using a two-stage process
CN105189728A (en) * 2013-04-17 2015-12-23 奥瑞金可利尔公司 Producing algae biomass having reduced concentration of contaminants
CN103387305A (en) * 2013-08-01 2013-11-13 广东沃杰森环保科技有限公司 Wastewater Treatment Sonic Electro-Oxidation Process
CN103787526A (en) * 2014-01-16 2014-05-14 同济大学 Method for removing blue-green algae by using microbubble hydrodynamic cavitation enhanced coagulation
CN104370431A (en) * 2014-11-25 2015-02-25 湖南大学 Blue algae dehydrating method
CN104370431B (en) * 2014-11-25 2017-02-22 湖南大学 Blue algae dehydrating method
CN107364926A (en) * 2017-07-21 2017-11-21 河海大学 A kind of ultrasonic wave depth algae-removing device and method
CN108467079A (en) * 2018-03-08 2018-08-31 深圳市安思科电子科技有限公司 A kind of air floatation machine convenient for maintenance with electrode clean function

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Granted publication date: 20120509

Termination date: 20160824