CN201686572U - Device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water - Google Patents
Device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water Download PDFInfo
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- CN201686572U CN201686572U CN201020182435XU CN201020182435U CN201686572U CN 201686572 U CN201686572 U CN 201686572U CN 201020182435X U CN201020182435X U CN 201020182435XU CN 201020182435 U CN201020182435 U CN 201020182435U CN 201686572 U CN201686572 U CN 201686572U
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 230000001112 coagulating effect Effects 0.000 title claims abstract description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 230000003647 oxidation Effects 0.000 title claims abstract description 28
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 28
- 238000004062 sedimentation Methods 0.000 title claims abstract description 23
- 238000005406 washing Methods 0.000 title claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract description 6
- 239000003546 flue gas Substances 0.000 title abstract description 6
- 229910052799 carbon Inorganic materials 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- 239000002253 acid Substances 0.000 claims abstract description 23
- 239000003814 drug Substances 0.000 claims abstract description 9
- 239000010865 sewage Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims description 38
- 230000000630 rising effect Effects 0.000 claims description 20
- 239000011790 ferrous sulphate Substances 0.000 claims description 18
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 18
- 239000004519 grease Substances 0.000 claims description 18
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 18
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 18
- 229920002401 polyacrylamide Polymers 0.000 claims description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 16
- 239000003610 charcoal Substances 0.000 claims description 15
- 239000003517 fume Substances 0.000 claims description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 11
- 239000001110 calcium chloride Substances 0.000 claims description 11
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 11
- 239000002699 waste material Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 6
- 238000012544 monitoring process Methods 0.000 claims description 6
- 229940079593 drug Drugs 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 abstract description 3
- 239000002351 wastewater Substances 0.000 abstract description 3
- 230000015271 coagulation Effects 0.000 abstract 2
- 238000005345 coagulation Methods 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 230000010354 integration Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
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- Water Treatment By Sorption (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The utility model relates to a device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water, which is characterized in that flue gas washing water is connected with a water inlet pipe (1) of a ripple bevel board oil-removal sedimentation tank, a water outlet pipe (3) of the ripple bevel board oil-removal sedimentation tank (2) is connected with a water collecting tank (4), a water outlet pipe (6) of a first-level sewage lift pump (5) in the sedimentation tank is connected with a first-level mixing and reaction chamber (7), the first-level mixing and reaction chamber (7), a bevel pipe sedimentation chamber (8), a second-level mixing and reaction chamber (9), a sedimentation chamber (10), an acid adjustment chamber (11), an oxidizing chamber (12), a neutralization coagulation chamber (13), a bevel pipe sedimentation chamber (14) are integrated, a water outlet pipe (42) of the bevel pipe sedimentation chamber is connected with an activated carbon filter (15), a water outlet pipe (45) of the activated carbon filter is connected to a clean water tank (16), and each medicine feed box is respectively connected with the first-level mixing and reaction chamber (7), the second-level mixing and reaction chamber (9), the acid adjustment chamber (11), the advanced oxidizing chamber (12), a third-level neutralization coagulation chamber (13). The utility model is the combination of the integral equipment with high integrity, is used for treating carbon flue gas washing waste water, can enable reaction to be fully reacted, has high sedimentation efficiency, and has good outlet water quality and high degree of automation.
Description
Technical field: the utility model is a kind of novel process and the integration apparatus that the method for utilizing materialization is handled the plain fume washing water of charcoal, and particularly a kind of three grades of coagulating sedimentation+advanced oxidation is handled the plain fume washing water device of charcoal.
Background technology: at present, at also perfect without comparison technology and the integration apparatus of the plain flue gas washing water treatment of charcoal.Traditional technology mainly concentrates on removes partially fluorinated thing and suspended substance, but water outlet also is difficult to reach the emission standard of country.Traditional lime defluorinating process amount of consumption of drugs that adds separately is big, reacts not thorough, normally reacts with several common neutralization tanks and precipitates, and floor space is big, and sludge output is bigger, and treatment effect is bad.
Summary of the invention: the purpose of this utility model is to provide a kind of three grades of coagulating sedimentation+advanced oxidation to handle the plain fume washing water device of charcoal, this integrated apparatus carries out materialization to fluorine content and the high waste water of organic composition that is difficult to biochemistry to be handled, and makes effluent quality reach reuse or discharging standards.The reaction efficiency height of integration apparatus, sludge volume is little, and floor space is little, and reduced investment can be moved automatically, can be by adjusting the variation that added amount of chemical adapts to influent quality better, effluent quality is good.
Formation of the present utility model: by ripple inclined plate grease settling tank, the medicament dosing system, three grades of coagulating sedimentation+advanced oxidation systems, the charcoal absorption filtering system, the water collecting basin structures, the clean water basin structures, automatically control and on-line monitoring instrument are formed, each system is coupled together in order by pipeline, realization automatization control, the fume washing water of collecting links to each other with ripple inclined plate grease settling tank water inlet pipe, the rising pipe of ripple inclined plate grease settling tank links to each other with water collecting basin, the rising pipe that the one-level sewage pump is housed in the pond links to each other with the one-level mixing and reaction chamber, one-level mixing and reaction chamber wherein, one-level tube settling chamber, the secondary mixing and reaction chamber, secondary tube settling chamber, the acid adjustment chamber, the advanced oxidation chamber, in three grades and coagulating chamber, three grades of tube settling chambers are integrated, three grades of tube settling chamber rising pipes link to each other with activated charcoal filter, and the activated charcoal filter rising pipe is connected to clean water basin;
The calcium chloride dispensing kit is by the calcium chloride chemical feed pipe, the liquor calcis dispensing kit links to each other with the one-level mixing and reaction chamber by liquor calcis chemical feed pipe I, the polyacrylamide dispensing kit is by polyacrylamide chemical feed pipe I, the ferrous sulfate dispensing kit links to each other with the secondary mixing and reaction chamber by ferrous sulfate chemical feed pipe I, the spent acid dispensing kit links to each other with the acid adjustment chamber by the spent acid chemical feed pipe, the ferrous sulfate dispensing kit is by ferrous sulfate chemical feed pipe II, hydrogen peroxide drug storage dispensing kit links to each other with the advanced oxidation chamber by the hydrogen peroxide chemical feed pipe, and the polyacrylamide dispensing kit is by polyacrylamide chemical feed pipe II, the liquor calcis dispensing kit by liquor calcis chemical feed pipe II with three grades in link to each other with coagulating chamber;
At the calcium chloride dispensing kit, the liquor calcis dispensing kit, the polyacrylamide dispensing kit, the ferrous sulfate dispensing kit is installed water-supply pipe on the spent acid dispensing kit.
PH on-line monitoring instrument is installed in one-level mixing and reaction chamber, secondary mixing and reaction chamber, acid adjustment chamber, three grades and on the coagulating chamber.
Below ripple inclined plate grease settling tank, one-level tube settling chamber, secondary tube settling chamber, three grades of tube settling chambers, automatically controlled mud valve is installed, is linked to each other with total spoil disposal pipeline.
High pressure blower is connected with the one-level mixing and reaction chamber by one-level mixing and reaction chamber air feed pipe, links to each other with the advanced oxidation chamber by advanced oxidation chamber air feed pipe, by linking to each other with coagulating chamber in three grades with in the coagulating chamber air feed Guan Yusan level.
The backwash water pump links to each other with activated charcoal filter by the backwash water inlet pipe, and the backwash rising pipe is connected to plant area's waste pipe, and the waste oil collection tube is connected to plant area's waste oil and collects ditch.
In water collecting basin and clean water basin, be separately installed with ultrasonic liquid level sensor, the Floating Ball Liquid Level transmitter is installed respectively in each dispensing kit.
Compared with the prior art, the utility model is the combination of highly integrated integration apparatus, handles the plain flue gas washing waste water of charcoal, and sufficient reacting is arranged, and the residence time is short, the deposition efficiency height, and effluent quality is good, and floor space is little, less investment, level of automation advantages of higher.
Description of drawings: accompanying drawing is the utility model structural representation.
Among the figure: 1. ripple inclined plate grease settling tank water inlet pipe, 2. ripple inclined plate grease settling tank, 3. ripple inclined plate grease settling tank rising pipe, 4. water collecting basin, 5. one-level sewage pump, 6. one-level lift pump rising pipe, 7. one-level mixing and reaction chamber, 8. one-level tube settling chamber, 9. secondary mixing and reaction chamber, 10. secondary tube settling chamber, 11. the acid adjustment chamber, advanced oxidation chambers 12. are in 13. 3 grades and coagulating chamber, 14. three grades of tube settling chambers, 15. activated charcoal filter, 16. clean water basin, 17. backwash water pumps, 18. high pressure blower, 19. the calcium chloride dispensing kit, 20. liquor calcis dispensing kits, 21. polyacrylamide dispensing kits, 22. ferrous sulfate dispensing kit, 23. the spent acid dispensing kit, 24. hydrogen peroxide drug storage dispensing kits, 25. calcium chloride chemical feed pipes, 26. liquor calcis chemical feed pipe I, 27. liquor calcis chemical feed pipe II, 28. polyacrylamide chemical feed pipe I, 29. polyacrylamide chemical feed pipe II, 30. ferrous sulfate chemical feed pipe I, 31. ferrous sulfate chemical feed pipe II, 32. spent acid chemical feed pipes, 33. hydrogen peroxide chemical feed pipes, 34. ripple inclined plate grease sludge from sedimentation tank pipe, 35. one-level tube settling chamber shore pipe, 36. secondary tube settling chamber shore pipes, 37. 3 grades of tube settling chamber shore pipes, 38. total spoil disposal pipeline, 39. one-level mixing and reaction chamber air feed pipe, 40. advanced oxidation chamber air feed pipes are in 41. 3 grades and coagulating chamber air feed pipe, 42. three grades of tube settling chamber rising pipes, 43. water-supply pipe, 44. backwash water inlet pipes, 45. activated charcoal filter rising pipes, 46. the backwash rising pipe, 47. waste oil collection tubes.
Embodiment: as shown in the figure, by ripple inclined plate grease settling tank, the medicament dosing system, three grades of coagulating sedimentation+advanced oxidation systems, the charcoal absorption filtering system, the water collecting basin structures, the clean water basin structures, automatically control and on-line monitoring instrument are formed, each system is coupled together in order by pipeline, realization automatization control, the fume washing water of collecting links to each other with ripple inclined plate grease settling tank water inlet pipe 1, the ripple inclined plate grease settling tank rising pipe 3 of ripple inclined plate grease settling tank 2 links to each other with water collecting basin 4, the one-level lift pump rising pipe 6 that one-level sewage pump 5 is housed in the pond links to each other with one-level mixing and reaction chamber 7, one-level mixing and reaction chamber 7 wherein, one-level tube settling chamber 8, secondary mixing and reaction chamber 9, secondary tube settling chamber 10, acid adjustment chamber 11, advanced oxidation chamber 12, in three grades and coagulating chamber 13, three grades of tube settling chambers 14 are integrated, three grades of tube settling chamber rising pipes 42 link to each other with activated charcoal filter 15, and activated charcoal filter rising pipe 45 is connected to clean water basin 16;
Calcium chloride dispensing kit 19 is by calcium chloride chemical feed pipe 25, liquor calcis dispensing kit 20 links to each other with one-level mixing and reaction chamber 7 by liquor calcis chemical feed pipe I 26, polyacrylamide dispensing kit 21 is by polyacrylamide chemical feed pipe I 28, ferrous sulfate dispensing kit 22 links to each other with secondary mixing and reaction chamber 9 by ferrous sulfate chemical feed pipe I 30, spent acid dispensing kit 23 links to each other with acid adjustment chamber 11 by spent acid chemical feed pipe 32, ferrous sulfate dispensing kit 22 is by ferrous sulfate chemical feed pipe II 31, hydrogen peroxide drug storage dispensing kit 24 links to each other with advanced oxidation chamber 12 by hydrogen peroxide chemical feed pipe 33, and polyacrylamide dispensing kit 21 is by polyacrylamide chemical feed pipe II 29, liquor calcis dispensing kit 20 by liquor calcis chemical feed pipe II 27 with three grades in link to each other with coagulating chamber 13;
At calcium chloride dispensing kit 19, liquor calcis dispensing kit 20, polyacrylamide dispensing kit 21, ferrous sulfate dispensing kit 22 is installed water-supply pipe 43 on the spent acid dispensing kit 23.
In one-level mixing and reaction chamber 7, secondary mixing and reaction chamber 9, acid adjustment chamber 11, in three grades with PH on-line monitoring instrument is installed on the coagulating chamber 13.
Below ripple inclined plate grease settling tank 2, one-level tube settling chamber 8, secondary tube settling chamber 10, three grades of tube settling chambers 14, automatically controlled mud valve is installed, with total spoil disposal pipeline; 38 link to each other.
High pressure blower 18 is connected with one-level mixing and reaction chamber 7 by one-level mixing and reaction chamber air feed pipe 39, link to each other with advanced oxidation chamber 12 by advanced oxidation chamber air feed pipe 40, by in three grades with coagulating chamber air feed pipe 41 with three grades in link to each other with coagulating chamber 13.
Backwash water pump 17 links to each other with activated charcoal filter 15 by backwash water inlet pipe 44, and backwash rising pipe 46 is connected to plant area's waste pipe, and waste oil collection tube 47 is connected to plant area's waste oil and collects ditch.
In water collecting basin 4 and clean water basin 16, be separately installed with ultrasonic liquid level sensor, the Floating Ball Liquid Level transmitter is installed respectively in each dispensing kit.
Claims (6)
1. three grades of coagulating sedimentation+advanced oxidation is handled the plain fume washing water device of charcoal, by ripple inclined plate grease settling tank, the medicament dosing system, three grades of coagulating sedimentation+advanced oxidation systems, the charcoal absorption filtering system, the water collecting basin structures, the clean water basin structures, automatically control and on-line monitoring instrument are formed, it is characterized in that: each system is coupled together in order by pipeline, realization automatization control, the fume washing water of collecting links to each other with ripple inclined plate grease settling tank water inlet pipe (1), the ripple inclined plate grease settling tank rising pipe (3) of ripple inclined plate grease settling tank (2) links to each other with water collecting basin (4), the one-level lift pump rising pipe (6) that one-level sewage pump (5) is housed in the pond links to each other with one-level mixing and reaction chamber (7), wherein one-level mixing and reaction chamber (7), one-level tube settling chamber (8), secondary mixing and reaction chamber (9), secondary tube settling chamber (10), acid adjustment chamber (11), advanced oxidation chamber (12), in three grades and coagulating chamber (13), three grades of tube settling chambers (14) are integrated, three grades of tube settling chamber rising pipes (42) link to each other with activated charcoal filter (15), and activated charcoal filter rising pipe (45) is connected to clean water basin (16);
Calcium chloride dispensing kit (19) is by calcium chloride chemical feed pipe (25), liquor calcis dispensing kit (20) links to each other with one-level mixing and reaction chamber (7) by liquor calcis chemical feed pipe I (26), polyacrylamide dispensing kit (21) is by polyacrylamide chemical feed pipe I (28), ferrous sulfate dispensing kit (22) links to each other with secondary mixing and reaction chamber (9) by ferrous sulfate chemical feed pipe I (30), spent acid dispensing kit (23) links to each other with acid adjustment chamber (11) by spent acid chemical feed pipe (32), ferrous sulfate dispensing kit (22) is by ferrous sulfate chemical feed pipe II (31), hydrogen peroxide drug storage dispensing kit (24) links to each other with advanced oxidation chamber (12) by hydrogen peroxide chemical feed pipe (33), and polyacrylamide dispensing kit (21) is by polyacrylamide chemical feed pipe II (29), liquor calcis dispensing kit (20) by liquor calcis chemical feed pipe II (27) with three grades in link to each other with coagulating chamber (13);
In calcium chloride dispensing kit (19), liquor calcis dispensing kit (20), polyacrylamide dispensing kit (21), ferrous sulfate dispensing kit (22), spent acid dispensing kit (23) are gone up water-supply pipe (43) are installed.
2. three grades of coagulating sedimentation according to claim 1+advanced oxidation are handled the plain fume washing water device of charcoal, it is characterized in that: in one-level mixing and reaction chamber (7), secondary mixing and reaction chamber (9), acid adjustment chamber (11), in three grades and coagulating chamber (13) go up PH on-line monitoring instrument be installed.
3. three grades of coagulating sedimentation according to claim 1+advanced oxidation is handled the plain fume washing water device of charcoal, it is characterized in that: in ripple inclined plate grease settling tank (2), one-level tube settling chamber (8), secondary tube settling chamber (10), below, three grades of tube settling chambers (14) automatically controlled mud valve is installed, is linked to each other with total spoil disposal pipeline (38).
4. three grades of coagulating sedimentation according to claim 1+advanced oxidation is handled the plain fume washing water device of charcoal, it is characterized in that: high pressure blower (18) is connected with one-level mixing and reaction chamber (7) by one-level mixing and reaction chamber air feed pipe (39), link to each other with advanced oxidation chamber (12) by advanced oxidation chamber air feed pipe (40), by in three grades with coagulating chamber air feed pipe (41) with three grades in link to each other with coagulating chamber (13).
5. three grades of coagulating sedimentation according to claim 1+advanced oxidation is handled the plain fume washing water device of charcoal, it is characterized in that: backwash water pump (17) links to each other with activated charcoal filter (15) by backwash water inlet pipe (44), backwash rising pipe (46) is connected to plant area's waste pipe, and waste oil collection tube (47) is connected to plant area's waste oil and collects ditch.
6. three grades of coagulating sedimentation according to claim 1+advanced oxidation is handled the plain fume washing water device of charcoal, it is characterized in that: in water collecting basin (4) and clean water basin (16), be separately installed with ultrasonic liquid level sensor, the Floating Ball Liquid Level transmitter is installed respectively in each dispensing kit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201020182435XU CN201686572U (en) | 2010-05-07 | 2010-05-07 | Device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201020182435XU CN201686572U (en) | 2010-05-07 | 2010-05-07 | Device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201686572U true CN201686572U (en) | 2010-12-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201020182435XU Expired - Lifetime CN201686572U (en) | 2010-05-07 | 2010-05-07 | Device for three-level coagulating sedimentation and advanced oxidation treatment of carbon flue gas washing water |
Country Status (1)
| Country | Link |
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| CN (1) | CN201686572U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101898842A (en) * | 2010-05-07 | 2010-12-01 | 贵州绿色环保设备工程有限责任公司 | Device for treating carbon fume washing water by three-level coagulating sedimentation method and advanced oxidation method |
| CN102730890A (en) * | 2012-07-27 | 2012-10-17 | 贵州绿色环保设备工程有限责任公司 | High-concentration phosphorus-containing and fluorine-containing sewage treatment device |
-
2010
- 2010-05-07 CN CN201020182435XU patent/CN201686572U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101898842A (en) * | 2010-05-07 | 2010-12-01 | 贵州绿色环保设备工程有限责任公司 | Device for treating carbon fume washing water by three-level coagulating sedimentation method and advanced oxidation method |
| CN102730890A (en) * | 2012-07-27 | 2012-10-17 | 贵州绿色环保设备工程有限责任公司 | High-concentration phosphorus-containing and fluorine-containing sewage treatment device |
| CN102730890B (en) * | 2012-07-27 | 2013-07-24 | 贵州绿色环保设备工程有限责任公司 | High-concentration phosphorus-containing and fluorine-containing sewage treatment device |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20101229 Effective date of abandoning: 20120704 |