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CN200957340Y - Mist-absorbing spraying integrated desulfurizer of composite cooling - Google Patents

Mist-absorbing spraying integrated desulfurizer of composite cooling Download PDF

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Publication number
CN200957340Y
CN200957340Y CN 200620023173 CN200620023173U CN200957340Y CN 200957340 Y CN200957340 Y CN 200957340Y CN 200620023173 CN200620023173 CN 200620023173 CN 200620023173 U CN200620023173 U CN 200620023173U CN 200957340 Y CN200957340 Y CN 200957340Y
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CN
China
Prior art keywords
tower
section
cooling
desulfurization
venturi
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Expired - Fee Related
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CN 200620023173
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Chinese (zh)
Inventor
钟振成
赵晓辉
唐启明
陶权林
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ZIGUANG ENVIRONMENTAL PROTECTION CO Ltd
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ZIGUANG ENVIRONMENTAL PROTECTION CO Ltd
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Priority to CN 200620023173 priority Critical patent/CN200957340Y/en
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Abstract

The utility model discloses a composite cooling spray mist suction integrated desulfurization equipment, belonging to boiler and furnace flue gas desulfurization technology field is provided, which is composed of a cooling unit connected with each other, a desulfurization demisting unit, a pipeline unit and an electronic control unit, which is characterized in that as follows: the cooling unit adopts a venturi tower whose main action is cooling and the assistant action is desulfurization; the desulfurization demisting unit adopts a desulfurizing tower; an outlet tilted downwards of the venturi tower is communicated with an inlet tilted upwards of the desulfurizing tower. The utility model has the advantages of such as a perfect mass transfer effect; simple technology; low investment cost; small size; small resistance; flexible operation; a high efficiency; reliable running and so on.

Description

Combined type cooling mist is inhaled spray integrated desulfurization device
Technical field
The utility model belongs to boiler, stove flue gas desulfurization technique field, is specifically related to a kind of efficient cooling desulfurizer structural design that is combined into one with vertical venturi cooling, the suction of impulse mist and the desulfurization of spray turbulent flow.
Background technology
Current, the material that the medium small boiler of China, kiln gas desulfurizer adopt has two kinds usually: numb stone or carbon steel add corrosion-proof lining.
The desulfurizer of fiber crops work made of stones, though it is low to have a cost, resistant to elevated temperatures advantage, single its shortcoming is also clearly, not only desulfuration efficiency is low, and floor space is big, and outward appearance is coarse, and the vulnerability because of binding material causes sealing poor between the numb barnacle piece, and this body drain cigarette leaks, and causes secondary pollution.The use of present numb stone is little by little replaced by light material.
Carbon steel adds the desulphurization plant of corrosion-proof lining, lightweight and portable in volume, floor space are little, but because inner lining material (no matter being rubber or glass flake) non-refractory, (temperature is usually about 140 ℃ can not to bear the high-temperature flue gas of boiler emission, have up to 190 ℃), need before desulphurization plant, install heat sink additional usually.Traditional drum type brake spraying cooling device, the cooling volumetric ratio (is meant the heat exchange amount of cooling tower and the ratio of its volume, J/m 3) very low, the volume of the required equipment of lowering the temperature is very big.And the material of this heat sink can only be selected very high special stainless steel of Unit Weight price (as 316L, 317L) or special nickel-base steel alloy (as C276) for use.In this case, the manufacturing cost of this device will be very high.
Mechanism designs such as the internal structure great majority utilization inertial collision of medium small boiler, kiln gas desulfurizer, centrifugal moisture film, hollow-spraying-tower, eddy flow plate, sieve tray, filler.With hollow-spraying-tower the most commonly used is example, facts have proved, its desulfurized effect wants to reach the requirement (SO of the DB11/139 emission standard of air pollutants for boilers of implementing Beijing 2Concentration of emission is lower than 150mg/Nm 3), the spray number of plies need design the 4-6 layer, has not only increased equipment resistance, and has caused the ratio of height to diameter of tower also very inharmonious.
Therefore, exploitation can be satisfied the requirement of high-efficiency desulfurization, can reduce cost again and the incorporate efficient cooling desulfurizer of more efficiently combined type of floor space is that the environment-friendly engineering technical staff is badly in need of the problem that will study and solve.
Summary of the invention
The purpose of this utility model is to overcome above-mentioned the deficiencies in the prior art, design a kind of combined type cooling mist and inhale spray integrated desulfurization device, multiple characteristics such as this device has that mass transfer effect is good, technology is simple, cost of investment is cheap, volume is little, lower resistance, operating flexibility are big, high efficient and reliable operation.
The technical solution adopted in the utility model is: be made up of the unit that cools, desulfurization and the demisting unit that fuse, pipe-line cell, ECU four parts, it is characterized in that, cool the unit employing to cool, desulfurization is secondary venturi tower, and desulfurization and demisting unit adopt desulfurizing tower; The outlet under being tilted to of described venturi tower and the inlet that is tilted to of desulfurizing tower are docked and connected.
Characteristics of the present utility model and effect:
The utility model utilizes venturi principle to lower the temperature, and utilizes the speed difference between the cooling water droplet of flue gas and low mobility, makes flue gas collision and entrained drip, realizes the heat transmission of gas-liquid two-phase, and the cooling volumetric ratio of venturi cooling tower increases greatly.Reach same cooling-down effect, its volume reduces investment and occupation of land only less than 1/10 of common drum type brake cooling tower.
Further, described desulfurizing tower shock at entry section is downward-sloping, flue gas is at first held the liquid level of liquid bath in the impulse tower, evoke desulfurization slurry and scatter form vaporific, flue gas wraps up and carries desulfurization slurry secretly, and gas-liquid two-phase is mass transfer reaction under mist suction state, the enhanced primary desulfurized effect, can reduce the desulfurizing tower overall height, and guarantee desulfurized effect.
The upset of flue gas behind the impulse liquid level upwards forms than the more uniform Flow Field Distribution of direct horizontal air inlet on the cross section of whole desulfurizing tower, help flue gas and spray and under desulfurization slurry absorption of mist film and hybrid reaction take place equably.
In sum, the utility model is to inhale and the desulfurization of spray turbulent flow is the incorporate efficient cooling desulfurizer of combined type of key core technology, compound multiple flue gas desulfurization mechanism with the cooling of vertical venturi, impulse mist.Can make that flue gas cools, flue gas desulfurization, flue gas demist finishes in an equipment, pH value and serum density according to the systemic circulation slurries, automatically the outer discharge capacity of control desulfurizing agent-magnesian addition and desulfurization product has that mass transfer effect is good, technology is simple, cost of investment is cheap, volume is little, lower resistance, operating flexibility are big, the multiple characteristics of high efficient and reliable operation.
Description of drawings
Fig. 1 is the assembling embodiment schematic diagram of cooling unit of the present utility model and desulfurization and demisting unit.
Fig. 2 a is the cooling unit one venturi tower body structure schematic diagram of present embodiment.
Fig. 2 b is that the A-A of Fig. 2 a is to schematic cross-section.
Fig. 3 is the desulfurization of present embodiment and the structural representation of demisting unit-desulfurizing tower;
Fig. 4 is a general structure embodiment schematic diagram of the present utility model.
The specific embodiment
Below in conjunction with the description of drawings a kind of specific embodiment of the present utility model and the course of work.
Combined type cooling mist of the present utility model is inhaled spray integrated desulfurization device embodiment, is made up of the unit that cools, desulfurization and demisting unit, pipe-line cell, ECU four parts.
Nucleus equipment of the present utility model is the unit that cools, desulfurization and demisting unit, and as shown in Figure 1, wherein, the enforcement of the unit that cools is adopted to cool, and desulfurization is that secondary venturi tower 1 is realized, desulfurization and demisting unit adopt desulfurizing tower 2 to realize.The outlet under being tilted to of venturi tower 1 and the inlet that is tilted to of desulfurizing tower 2 are docked and connected.
The structure of the cooling unit of present embodiment-venturi cooling tower is shown in Fig. 2 a, and this tower connects into smoke inlet 11, converging transition 12, trunnion section 13, diffuser 14, the outlet section 15 of an integral cavity from top to bottom and exports 17 to be formed; The upper end heavy caliber of converging transition 12 is as the inlet of venturi cooling tower, the lower end is small-bore to be docked and connected with upper port trunnion section 13, the upper end of diffuser 14 is small-bore, be docked and connected with the lower port of trunnion section 13, the lower end heavy caliber of diffuser 14 and the upper port of outlet section 15 are docked and connected, outlet section 15 has outlet 17, and the axial and level of this outlet 17 is the 25-30 degree to angle α; At converging transition 12 cooling nozzle sets 16 is installed; On the tower wall of converging transition 12, diffuser 14 and outlet section 15, have manhole door 18.
Cooling nozzle sets 16 structures of present embodiment shown in Fig. 2 b, the main burner 161 that links into an integrated entity by the diminishing three sections pipes of internal diameter and be communicated with main burner 161 both sides respectively and arrange that in same cross section contrary spraying nozzle 162, the suitable spraying nozzle 163 of spray constitute up and down.
The venturi cooling tower of present embodiment can adopt corrosion-and high-temp-resistant material manufacturings such as 316L stainless steel or numb stone to form.
Desulfurization of the present utility model and demisting unit embodiment adopt desulfurizing tower 2, its structure as shown in Figure 3, this tower connects into the hold liquid bath 21, smoke inlet impact section 22, two film mist of an integral cavity from down to up and inhales section 23, turbulent flow spray washing section 25 and desulfurization exhanst gas outlet 26 and form; Wherein, smoke inlet impact section 22 acclivitous angle [alpha] are provided with overflow pipe 20 between 25-30 ° (identical with the outlet section tilt angle alpha of venturi cooling tower) on the top of holding liquid bath 21, and the bottom is equipped with aerator 29; In two film mists are inhaled section 23, one-level circulated sprinkling turbulator 241 and secondary circulated sprinkling turbulator 242 are installed; One-level demister 271 and backwash nozzle sets up and down 281 thereof, secondary demister 272 and backwash nozzle sets up and down 282 thereof are set in turbulent flow spray washing section 25.
The demister 271,272 of present embodiment can adopt the horizontal band to collude deflection plate.The desulfurizing tower of present embodiment can adopt ordinary carbon steel inside lining anti-corrosive (rubber or glass flake) or fiberglass manufacturing to form.
The pipe-line cell of present embodiment and ECU are as shown in Figure 4; Pipe-line cell is made up of the desulfurizing agent slaking jar 3 that links to each other with desulfurizing tower 2 by pipeline and venturi cooling tower 1, desulfurizing agent supply pump 41, slurry circulating pump 42, cooling water pump 43, overflow launder 5, oxidation fan 6 etc.; Wherein, agitator 31, ECU are installed in the desulfurizing agent slaking jar 3, and form the PLC control system with power distribution cabinet, switch board (not shown) by electrical equipment such as the electric control valve 7 that connects by electric wire, pH meter 8, densitometers 9.The annexation of pipe-line cell and each device of ECU is: desulfurizing agent slaking jar 3 is connected to turbulent flow spray washing section 25 lower ends of desulfurizing tower by desulfurizing agent supply pump 41, and the inlet of one-level circulated sprinkling turbulator 241 and secondary circulated sprinkling turbulator 242 links to each other with the outlet of desulfurizing tower bottom by slurry circulating pump 42 respectively and constitutes the slurries closed circuit; PH meter 8 and densitometer 9 also are installed in the slurries closed circuit; The two-stage water inlet of backwash nozzle sets 281 up and down links to each other with the recirculated water drainage pipeline; Oxidation fan 6 links to each other with aerator in holding liquid bath 22 by pipeline; The desulfurization exhanst gas outlet links to each other with chimney by pipeline; The cooling nozzle sets that cooling water pump 43 is connected in the converging transition of venturi cooling tower links to each other; The bottom nozzle of venturi cooling tower is installed overflow launder 5, and the drainpipe of overflow launder is communicated with the mole drain.
The venturi cooling tower of present embodiment and desulfurizing tower all can adopt existing device to carry out local flow improvement and form, and the equipment of pipe-line cell and ECU and components and parts all can adopt conventional products to assemble.
The course of work and characteristics that the combined type cooling mist of present embodiment is inhaled spray integrated desulfurization device:
The former flue gas of the high temperature of boiler or stove at first in the smoke inlet section of venturi cooling tower and the cooling water droplet even contact of contrary spraying nozzle group 162 and contrary spraying nozzle group 163 ejections, plays the purpose of preliminary cooling by vaporization heat absorption and different transfer of heat.Two groups of nozzles of present embodiment are arranged spray up and down in same cross section, make cooling water, forward transmission of heat by contact reverse with the high-temperature flue gas while, and cooling-down effect is better.The time and the space of the heat exchange of gas-liquid physics have been extended.Enter converging transition, flue gas flow rate progressively improves, and flue gas flow rate rises to (between 40-50 m/s) about 45 m/s rapidly when arriving the trunnion section.Formed huge current difference between the water droplet of the cooling of this moment flue gas and free-falling, thereby made that flue gas catches up with, collision and entrained drip, realized the instantaneous efficient transmission of heat between gas-liquid two-phase, the cooling volumetric ratio of venturi cooling tower increases greatly.In this cools the unit, reach same cooling-down effect, its volume has been saved the device fabrication cost greatly and has been taken up an area of the space only less than 1/10 of common drum type brake cooling device.Flue-gas temperature is reduced to below 100 ℃, and its effect has three aspects: first low temperature environment helps improving the desulfurization absorption reaction of follow-up desulfurization unit; Its two effect of playing first grade desulfurizing; The 3rd is to help follow-up desulfurization unit to make Material Selection (can adopt non-refractory, but the cheap material of anticorrosion antiwear).
The shock at entry section 22 of flue gas under being tilted to after the cooling enters desulfurizing tower, the inclined angle alpha of the impact section that present embodiment links to each other with the outlet of venturi cooling tower is about 30 °, flue gas is at first held the liquid level of liquid bath in the impact tower, evoke desulfurization slurry and scatter, form vaporificly, flue gas parcel and carry desulfurization slurry secretly forms water-bath and impacts, gas-liquid two-phase is mass transfer reaction under mist suction state, the enhanced primary desulfurized effect.Subsequently, the flue gas behind the impact liquid level then upwards, flue gas distribute on the lateral cross section of desulfurizing tower, and also to tap into cigarette with respect to straight horizontal more even.Following slurries droplet reverse-impact contact the flue gas that rises with spray, simultaneously droplet is played the effect of shearing and tearing, and brings in constant renewal in the contact interface of gas-liquid two-phase mass transfer reaction, the secondary desulfurization of formation pair film mists suction.Flue gas after this effect only needs to spray through two-layer turbulent flow again, can reach the desulfuration efficiency more than 95%.And general spray desulphurization plant does not have the inlet impulse of front and the two-step desulfurization that two film mist is inhaled, and reach the desulfuration efficiency more than 95%, needs configuration 4-6 layer spray, and the height of equipment and resistance all can increase greatly.Discharge behind the flue gas process two-stage demister dehydrating demisting after the desulfurization, avoided the band water of blower fan and back-end ductwork.The sulfur dioxide concentration content of fume emission is lower than 150mg/Nm 3, can reach the requirement of Beijing DB11/139 standard fully.
The PLC control system of present embodiment can be implemented in automatically, the operation down of three kinds of states of control room push-botton operation, on-site manual operation, pH meter can be realized the automatic control and adjustment slurry pH value, densitometer is controlled the flow that effluxes slurries by electric control valve, satisfies the requirement of desulfuration efficiency.

Claims (7)

1, a kind of combined type cooling mist is inhaled spray integrated desulfurization device, form by the unit that cools, desulfurization and the demisting unit that fuse, pipe-line cell, ECU four parts, it is characterized in that, cool the unit employing to cool, desulfurization is secondary venturi tower, and desulfurization and demisting unit adopt desulfurizing tower; The outlet under being tilted to of described venturi tower and the inlet that is tilted to of desulfurizing tower are docked and connected.
2, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that, this tower connects into smoke inlet, converging transition, trunnion section, diffuser, the outlet section of an integral cavity from top to bottom and forms; Its annexation is: the upper end heavy caliber of described converging transition is as the inlet of venturi cooling tower, the upper port of the small-bore and described trunnion section in the lower end of converging transition is docked and connected, the upper end of described diffuser is small-bore to be docked and connected with the lower port trunnion section, the lower end heavy caliber of this diffuser and the upper port of outlet section are docked and connected, outlet section, the axial and level of this outlet section is the 25-30 degree to angle α; At described converging transition the cooling nozzle sets is installed.
3, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that, has manhole door on the tower wall of described converging transition, diffuser and outlet section.
4, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that the main burner that described cooling nozzle sets is linked into an integrated entity by the diminishing multistage pipe of internal diameter and be communicated with the main burner both sides respectively and the contrary spraying nozzle and the suitable spraying nozzle of the spray up and down arranged in same cross section constitute.
5, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that, described desulfurizing tower connects into the hold liquid bath, smoke inlet impact section, two film mist of an integral cavity from down to up and inhales section, turbulent flow spray washing section and desulfurization exhanst gas outlet and form, the smoke inlet impact section axially and level be the 25-30 degree to angle α; Be provided with overflow pipe on this top of holding liquid bath; In two film mists are inhaled section, one-level circulated sprinkling turbulator and secondary circulated sprinkling turbulator are installed; One-level demister and backwash nozzle sets up and down thereof, secondary demister and backwash nozzle sets up and down thereof are set in turbulent flow spray washing section.
6, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that described demister adopts the horizontal band to collude deflection plate.
7, combined type cooling mist as claimed in claim 1 is inhaled spray integrated desulfurization device, it is characterized in that, described pipe-line cell is made up of the desulfurizing agent slaking jar, desulfurizing agent supply pump, slurry circulating pump, cooling water pump, overflow launder, the oxidation fan that link to each other with desulfurizing tower by pipeline and venturi cooling tower, in the described desulfurizing agent slaking jar agitator is installed; The PLC control system that described ECU is made up of the power distribution cabinet, switch board, electric control valve, pH meter, the densitometer that connect by electric wire; Its annexation is: desulfurizing agent slaking jar is connected to the turbulent flow spray washing section lower end of desulfurizing tower by the desulfurizing agent supply pump, and the inlet of one-level circulated sprinkling turbulator and secondary circulated sprinkling turbulator links to each other with the outlet of desulfurizing tower bottom by slurry circulating pump respectively and constitutes the slurries closed circuit; PH meter also is installed in the slurries closed circuit and holds liquid bath and be communicated with; The two-stage water inlet of backwash nozzle sets up and down links to each other with the recirculated water drainage pipeline; Oxidation fan links to each other with aerator in holding liquid bath by pipeline; The desulfurization exhanst gas outlet links to each other with chimney by pipeline; Cooling water pump is connected to the converging transition of venturi cooling tower; The bottom nozzle of venturi cooling tower is installed overflow launder, and the drainpipe of overflow launder is communicated with the mole drain.
CN 200620023173 2006-06-30 2006-06-30 Mist-absorbing spraying integrated desulfurizer of composite cooling Expired - Fee Related CN200957340Y (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101659756A (en) * 2009-03-04 2010-03-03 索红卫 Quick cooling technology and equipment of high-temperature regeneration rubber powder by water cooling shock method
CN101890286A (en) * 2010-08-04 2010-11-24 姜辉 Method and device for removing hydrogen sulfide from gas by using suspension of ferric oxide powder
CN102743965A (en) * 2012-06-15 2012-10-24 无锡翱翔环保机械有限公司 Direction-changing Venturi tube used for desulfurization system
CN107510993A (en) * 2017-08-14 2017-12-26 绵阳行之智汇知识产权服务有限公司 A kind of desulfurizing tower of electric power plant
CN108344309A (en) * 2017-01-22 2018-07-31 同方环境股份有限公司 A kind of cooling device for handling water cooling tower in sludge incineration tail gas
CN108686492A (en) * 2017-04-12 2018-10-23 中国石油化工股份有限公司 Flue-gas dust-removing and desulfurization tower and dust-collecting sulfur-removing method
CN108686491A (en) * 2017-04-12 2018-10-23 中国石油化工股份有限公司 A kind of flue-gas dust-removing and desulfurization tower and dust-collecting sulfur-removing method
CN112044245A (en) * 2020-09-24 2020-12-08 浙江大学 Staged temperature self-adaptive precise regulation and enhancement of SO2 absorption-oxidation ship exhaust gas purification device and process

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101659756A (en) * 2009-03-04 2010-03-03 索红卫 Quick cooling technology and equipment of high-temperature regeneration rubber powder by water cooling shock method
CN101890286A (en) * 2010-08-04 2010-11-24 姜辉 Method and device for removing hydrogen sulfide from gas by using suspension of ferric oxide powder
CN101890286B (en) * 2010-08-04 2012-11-14 姜辉 Method and device for removing hydrogen sulfide from gas by using suspension of ferric oxide powder
CN102743965A (en) * 2012-06-15 2012-10-24 无锡翱翔环保机械有限公司 Direction-changing Venturi tube used for desulfurization system
CN108344309A (en) * 2017-01-22 2018-07-31 同方环境股份有限公司 A kind of cooling device for handling water cooling tower in sludge incineration tail gas
CN108686492A (en) * 2017-04-12 2018-10-23 中国石油化工股份有限公司 Flue-gas dust-removing and desulfurization tower and dust-collecting sulfur-removing method
CN108686491A (en) * 2017-04-12 2018-10-23 中国石油化工股份有限公司 A kind of flue-gas dust-removing and desulfurization tower and dust-collecting sulfur-removing method
CN107510993A (en) * 2017-08-14 2017-12-26 绵阳行之智汇知识产权服务有限公司 A kind of desulfurizing tower of electric power plant
CN112044245A (en) * 2020-09-24 2020-12-08 浙江大学 Staged temperature self-adaptive precise regulation and enhancement of SO2 absorption-oxidation ship exhaust gas purification device and process

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