CN1948607A - High polymer coated multi functional coating fabric and its production method - Google Patents
High polymer coated multi functional coating fabric and its production method Download PDFInfo
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- CN1948607A CN1948607A CN200610154437.6A CN200610154437A CN1948607A CN 1948607 A CN1948607 A CN 1948607A CN 200610154437 A CN200610154437 A CN 200610154437A CN 1948607 A CN1948607 A CN 1948607A
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- 229920000642 polymer Polymers 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 238000000576 coating method Methods 0.000 title claims description 79
- 239000011248 coating agent Substances 0.000 title claims description 61
- 239000004744 fabric Substances 0.000 title claims description 46
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 126
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 99
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 11
- UXGNZZKBCMGWAZ-UHFFFAOYSA-N dimethylformamide dmf Chemical compound CN(C)C=O.CN(C)C=O UXGNZZKBCMGWAZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 11
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 11
- 239000008188 pellet Substances 0.000 claims description 33
- 239000000654 additive Substances 0.000 claims description 30
- 230000000996 additive effect Effects 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 30
- 239000002344 surface layer Substances 0.000 claims description 16
- 239000010410 layer Substances 0.000 claims description 13
- 239000003085 diluting agent Substances 0.000 claims description 10
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 10
- 239000003242 anti bacterial agent Substances 0.000 claims description 9
- 230000002421 anti-septic effect Effects 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 claims description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000002759 woven fabric Substances 0.000 claims description 4
- 229920002101 Chitin Polymers 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000000194 fatty acid Chemical group 0.000 claims description 3
- 229930195729 fatty acid Chemical group 0.000 claims description 3
- 150000004665 fatty acids Chemical group 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 238000000643 oven drying Methods 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 150000003016 phosphoric acids Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 150000003608 titanium Chemical class 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229930007845 β-thujaplicin Natural products 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 3
- 238000002144 chemical decomposition reaction Methods 0.000 abstract 2
- 208000008454 Hyperhidrosis Diseases 0.000 abstract 1
- 238000005273 aeration Methods 0.000 abstract 1
- 208000013219 diaphoresis Diseases 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a production method of multifunctional high polymer covering woven. The weight proportion of coated cover is 100 portions chemical decomposition granules, 10-30 portions toluene, 5-30 portions dimethyl formamide, 0.05-0.5 portions Hydroxypolyether modified poly-dimethyl-siloxane 1-10 portions toner and 0.01-0.5 portions function assistant. The weight proportion of chemical decomposition granules is 100 portions thermoplastic polyurethane granules, 10-60 portions solvent dimethyl formamide, 20-50 portions liquefier toluene. The weight proportion of coated adhesion layer is 100 portions dineric polyurethane resin ,100 portions toluene, 5-30 portions solvent dimethyl formamide DMF, 5-30 portions butanone, 1-10 portions toner, 0.01-0.5 portions function assistant. The method is characterized in that the products has versatility including waterproof, rainproof, aeration, moisture, diaphoresis, dry, electrostatic prevention, flame retarded and uvioresistant etc. Especially, watertighting can reach over 5000mmH2O, and moisture can reach over 5000g/m2.24h.
Description
Technical field
The invention belongs to the fabric coating field, especially a kind of multi-functional coatings fabric and production method of polymer coating.
Background technology
Fabric coating is the new industry that China develops rapidly in recent ten years.Coated fabric then is to be base cloth with all kinds of textiless, the special material with function of shielding that forms coated with immersion coating materials processing.Development is very fast on this series products both at home and abroad, because its special function of shielding makes it be widely used in civilian (life is used), industrial or agricultural (especially transportation building), health care and military various aspects.
The top finish of fabric is an important branch of after-finishing of textile products technology, and the main application of coating product can be divided into three major types: clothes, shoes and hats class, industrial dry goods, decorating cloth class, wherein clothes, shoes and hats class consumption maximum.
Coating is given the function of fabric and is not only shielding, also has other, promptly when a certain function of shielding is provided, also will take into account other one or more functions.With the closely-related raincoat of the people's livelihood or other protective clothings, in shielding rainwater or other invaders, must take into account and wet in the market, make the wearer feel comfortable.Yet owing to technical elements or otherwise reason, when requiring water pressure resistance very high and when being strictly on guard against invader, this take into account just very difficult.The related coatings product mainly makes with direct coating macromolecular material or MULTILAYER COMPOSITE forms, and protection efficiency and water vapour permeability can not be taken into account; In addition, feel hard partially, wear the time slightly length will feel sultry.Thereby " Waterproof Breathable " fabric, " ventilative " fabric be still very important part in the coated fabric at present, and it also is the direction and goal of our enterprise technology development, Product Renewal.For remedying many deficiencies that this series products in use exists and better adapting to market demand, through sufficient market watch and investigation, I take charge of conscientious research and analysis, decision is with the existing advanced coating apparatus of company, in conjunction with advanced factory formula and technology, carry out a kind of exploitation and production application of high polymer multi-functional coatings fabric.
Summary of the invention
The objective of the invention is to overcome the deficiency of said structure, and a kind of multi-functional coatings fabric and production method of polymer coating are provided.
The technical solution adopted for the present invention to solve the technical problems.The multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part.
The multi-functional coatings manufacturing method of fabrics of this polymer coating mainly comprises the steps:
1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts, viscosity control: 8000~50000cps;
2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part; Viscosity control: 5000~10000cps;
3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m
2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
4), the surface layer after the oven dry is proceeded adhesion layer coating, coating weight 50~250g/m
2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm
2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
1), this product is to be base cloth with the Woven Fabrics effect that the present invention is useful is:, soft, snugness of fit is good, has overcome old product Boardy Feeling, the narrow defective of the scope of application.2), adopt good high-performance coating agent and special addition agent, through optimizing preparation, played the remarkable environmental effect, azo class material, content of beary metal meet European EN14362-2003 environmental protection standard.3), the best adjustment of adopting the transfer heat posted technology of novelty and carrying out technological parameter produces this product, changed old technology and directly be coated with the various drawbacks (even as became uneven, appearance style is poor, and functional parameter is low etc.) of scraping band rice.4), outstanding behaviours is multifunctionality and good surface appearance style because the innovation of above aspect improves, product can reach waterproof, rainproof, ventilative, wet thoroughly, multifunctionalities such as perspire, dry and comfortable, antistatic, fire-retardant and uvioresistant; Especially water pressure resistance can reach 5000mmH
2More than the O, vapor transfer rate can reach 5000g/m
2.24h more than.5), the multifunctionality of product has been widened its Application Areas, develop into feather dress fabric, sportswear lining, hunting dress lining, medical protective clothing and woollen sweater etc. from raincoat, clothes lining, this product has been filled up domestic blank, has good economic and social benefit.
Description of drawings
Fig. 1 is a process flow diagram of the present invention;
The specific embodiment:
Below in conjunction with drawings and Examples the present invention is further described.
Embodiment 1: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10 parts, dimethyl formamide (DMF): 5 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05 part, toner: 1 part and function additive: 0.01 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10 parts, diluent toluene: 20 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10 parts, solvent dimethyl formamide DMF:5 part, butanone (MEK): 5 parts, toner: 1 part, function additive: 0.02 part.
Described function additive is antiseptic or antistatic additive or ultra-violet absorber, and described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO
2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.Described antistatic additive adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.Described ultra-violet absorber adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
The multi-functional coatings manufacturing method of fabrics of this polymer coating mainly comprises the steps:
1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10 parts, diluent toluene: 20 parts, viscosity control: 8000~50000cps;
2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10 parts, dimethyl formamide (DMF): 5 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05 part, toner: 1 part and function additive: 0.02 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10 parts, solvent dimethyl formamide DMF:5 part, butanone (MEK): 5 parts, toner: 1 part, function additive: 0.02 part; Viscosity control: 5000~10000cps;
3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m
2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
4), the surface layer after the oven dry is proceeded adhesion layer coating, coating weight 50~250g/m
2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm
2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
Technical indicator:
1) hydraulic pressure 5000~10000mmH
2O (ISO811-1981)
2) wet thoroughly 5000~6000g/m
2.24h (ASTM E96-2000BW)
3) dry-cleaning 4~5 grades of COLOR FASTNESS (ISO105D01-1993)
4) LIGHT COLOR FASTNESS is more than 4 grades (ISO105D02-1994)
5) TENSILE STRENGTH: through 600N, latitude 680N (ISO13934-1-1999)
6) azo, content of beary metal are by the test of EN14362-2003 European standard
Embodiment 2: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 30 parts, dimethyl formamide (DMF): 30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.5 part, toner: 10 parts and function additive: 0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 60 parts, diluent toluene: 50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 50 parts, solvent dimethyl formamide DMF:30 part, butanone (MEK): 30 parts, toner: 10 parts, function additive: 0.5 part.Function additive is an antiseptic, and described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO
2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.
Embodiment 3: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 20 parts, dimethyl formamide (DMF): 20 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.2 part, toner: 5 parts and function additive: 0.2 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 30 parts, diluent toluene: 35 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 30 parts, solvent dimethyl formamide DMF:15 part, butanone (MEK): 15 parts, toner: 5 parts, function additive: 0.2 part.Described function additive is an antistatic additive, adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.
Embodiment 4: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 15 parts, dimethyl formamide (DMF): 10 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.1 part, toner: 3 parts and function additive: 0.2 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 20 parts, diluent toluene: 30 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 20 parts, solvent dimethyl formamide DMF:10 part, butanone (MEK): 10 parts, toner: 3 parts, function additive: 0.1 part.Described function additive is a ultra-violet absorber, adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
Embodiment 5: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 25 parts, dimethyl formamide (DMF): 20 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.3 part, toner: 7 parts and function additive: 0.3 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 40 parts, diluent toluene: 40 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 30 parts, solvent dimethyl formamide DMF:20 part, butanone (MEK): 20 parts, toner: 7 parts, function additive: 0.4 part.
Claims (6)
1, a kind of multi-functional coatings fabric of polymer coating, it is characterized in that: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part.
2, the multi-functional coatings fabric of polymer coating according to claim 1 is characterized in that: described function additive is antiseptic or antistatic additive or ultra-violet absorber.
3, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO
2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.
4, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described antistatic additive adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.
5, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described ultra-violet absorber adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
6, a kind of multi-functional coatings manufacturing method of fabrics of polymer coating is characterized in that: mainly comprise the steps:
6.1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts, viscosity control: 8000~50000cps;
6.2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part; Viscosity control: 5000~10000cps;
6.3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m
2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
6.4), the surface layer after the oven dry proceeds adhesion layer coating, coating weight 50~250g/m
2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm
2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
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CN101311398B (en) * | 2007-05-25 | 2011-09-14 | 东丽纤维研究所(中国)有限公司 | Nanometer durable ultraviolet ray resistant textiles |
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CN101586312B (en) * | 2009-06-12 | 2012-05-09 | 石狮龙祥制革有限公司 | Production method of non-yellowing synthetic leather |
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CN103790026A (en) * | 2014-01-24 | 2014-05-14 | 南通惠通纺织器材有限公司 | Neatening method of ultraviolet-proof antistatic fabric |
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