Novel low thermal resistance cast-iron cooling wall and manufacture method thereof
Technical field
Technical field under the present invention is the body of heater cooling technology of high temperature stoves such as blast furnace and other metallurgical furnaces, heating furnace, combustion furnace, relates to a kind of novel low thermal resistance cast-iron cooling wall of new construction, and the manufacture method of this cooling wall.
Background technology
The body of heater of high temperature stoves such as blast furnace and other metallurgical furnaces, heating furnace, combustion furnace all needs cooling technology, and cooling wall (device) promptly is set in the furnace wall.The material of traditional cooling wall (device) mainly contains spheroidal graphite cast-iron, casting pig, mild steel and fine copper cooling wall, all cooling-water duct will be set in the cooling wall of any material (device).Except the fine copper cooling wall, the cooling-water duct in the cooling wall of other material all uses the seamless steel pipe of low-carbon steel material.
1. cast-iron cooling wall
Cast-iron cooling wall in order to prevent the carburizing to cooling water pipe, must be coated anti-carburization coating at the outer surface of seamless steel pipe on the manufacturing process of cooling wall in manufacture process, and then carries out the cast of foundry goods; Because of the difference of two kinds of material thermal coefficient of expansions, cooling water pipe and cooling wall body must leave the air gap simultaneously.Since the air gap between the coating between cooling water pipe and the cast iron and coating and cast iron (or claiming air cleft) thus existence reduced the heat transfer and the cooling effect of cooling wall significantly, accelerated the damage process of cooling wall.
2. cast steel cooling wall
Cast steel cooling wall is because its body material is a mild steel, therefore cooling water pipe can not removed the anti-carburization coating of low heat conduction by carburizing in manufacture process, simultaneously because cooling wall body material is identical with the cooling water pipe material, need not specially leave the expansion clearance, therefore improve the overall thermal conductivity energy of cooling wall.But the material of cooling water pipe still is a mild steel, and steel pipe inwall ratio is easier to generate incrustation scale.
3. cooling water pipe
Except the fine copper cooling wall, the cooling water pipe in the cooling wall all is the mild steel seamless pipe.The cooling medium that is used for cooling wall mainly is the circulation of open circuit cooling water, the circulation of preliminary treatment cooling water, soft water inclosed recirculated cooling water, pure water sealing and circulating.Cooling water quality is good, and is just slow at the scale velocity of cooling water pipe inwall.But no matter use which type of cooling medium inevitably will produce fouling at the cooling water pipe inwall.Use open circuit recirculated water to be: A3 steel>20 steel>brass>fine copper>stainless steel>aluminium to the scale velocity of unlike material; Use the scale velocity of preliminary treatment recirculated water unlike material to be: 20 steel>A3 steel>aluminium>fine copper>brass>stainless steel.The thermal conductivity factor of incrustation scale is 1.6~1.8W/mk, only is 1/24~1/30 of original material, and the cooling water pipe interior wall construction causes cooling water heat exchange amount to reduce significantly with the cooling wall body temperature rising significantly, finally quicken the damage process of cooling wall.
Summary of the invention
At above-mentioned three deficiencies of conventional art, the novel low thermal resistance cast-iron cooling wall that the purpose of this invention is to provide a kind of new construction substitutes above cooling wall (device), and this new type cooling stave is made of spheroidal graphite cast-iron or casting pig; The cooling water pipe material is selected fine copper material seamless pipe, and therefore the cooling water pipe outer surface does not need to spray anti-carburization coating when making, and has eliminated the thermal resistance that anti-carburization coating brought; And the cooling duct material in the cooling wall is the pure copper tube of high thermal conductivity material, increased considerably the overall thermal conductivity energy of cooling wall, thereby be the efficient cooling wall of a kind of brand-new low thermal resistance, all can adopt this novel cast-iron cooling wall (device) to replace traditional cooling wall at blast-furnace shaft and other kiln all sites, prolong the life of the blast furnace and improve the blast furnace productivity effect.The present invention simultaneously will provide the manufacture method of this new construction cooling wall.
The technical scheme of finishing the foregoing invention task is: novel low thermal resistance cast-iron cooling wall is characterized in that: cooling wall body material is the spheroidal graphite cast-iron or the casting pig of high-melting-point (〉=1200 ℃), cooling-water duct in the cooling wall is made of low melting point (1080 ℃) pure copper tube, and key problem in technology will guarantee that low-melting pure copper tube is not by burn through and fusing when the cast cooling wall.
1. described cooling water pipe is the pure copper tube of impervious carbon, high thermal conductivity (340 kilocalories/meter time ℃), high-elongation (〉=30);
2. the gap between cooling wall body and the pure copper tube outer wall is less than 0.1mm;
3. described pure copper tube is selected the pure copper tube of 6~8mm wall thickness for use.
Because the molten iron temperature of spheroidal graphite cast-iron and casting pig is at 1300~1380 ℃, and 1083 ℃ of the fusing points of fine copper, if adopt traditional casting method, pure copper tube will water fashionable the thawing at molten iron, can't produce cooling wall of the present invention.The application provides following technology,
The manufacture method of novel low thermal resistance cast-iron cooling wall:
It is fixing that the pure copper tube of typing is put into the sandbox that need make according to the cooling wall external form;
When pouring into a mould, the pure copper tube of being poured into a mould is carried out the cooling of inerting steam, cast molding with the molten iron of spheroidal graphite cast-iron or casting pig.
Above-described " pure copper tube is carried out the cooling of inerting steam " can adopt following method:
1. the molten iron heat was evenly distributed when cast gate was also noted that casting as rising head except considering the feeding effect;
2. at the chill of the arranged around some that is cast into copper pipe, reduce the wash away fusing effect of high temperature liquid iron to pure copper tube;
3. in casting process, the pure copper tube that is cast into is passed to low amounts of water, make it in the copper pipe that is heated by high temperature liquid iron, produce a large amount of heats of vapor absorption and reduce the resulting heat of copper pipes, reduce the temperature of copper pipe and prevent the copper pipe fusing;
According to the copper pipe cross section water yield is controlled at 0.5~2.0kg/min; The water yield of this patent is controlled at 0.8kg/min;
4. for all parts to the even cooling copper tube of steam of water flowing generation in the copper pipe, must feed inert gas in water flowing, one can prevent that steam from accumulating in pure copper tube, and two can prevent the oxidation of casting process high temperature to copper pipe;
The inert gas that this patent is recommended to adopt is a nitrogen; The flow velocity of inert gas is controlled at 8~15m/s.
Novel low thermal resistance cast-iron cooling wall provided by the invention and manufacture method thereof have been improved the structure and the casting technique of traditional blast furnace cooling stave, and the pure copper tube that is cast into impervious carbon, high thermal conductivity (340 kilocalories/meter time ℃), high-elongation (〉=30), slow fouling in cast iron quality is as the cooling water water pipe; Eliminated the thermal resistance that anti-carburization coating brings, thereby cooling water is increased the heat exchange efficiency of cooling wall body; Use its encrustation of fine copper cooling water pipe to slow down simultaneously, further improve the overall thermal conductivity energy of cast-iron cooling wall, prolong the life-span of cast-iron cooling wall.
Description of drawings
Fig. 1, Fig. 2 are respectively the cutaway view and the vertical view of structural representation of the present invention;
Fig. 3 casts sandbox and cast gate schematic diagram for the present invention.
The specific embodiment
Embodiment 1,
Novel low thermal resistance cast-iron cooling wall, and its manufacturing process (control intensity of cooling casting technique), referring to Fig. 1~Fig. 3:
Novel low thermal resistance cast-iron cooling wall: cooling wall body 1 material is the spheroidal graphite cast-iron or the casting pig of high-melting-point (〉=1200 ℃), and the cooling-water duct 2 in the cooling wall is made of low melting point (1080 ℃) pure copper tube.Cooling water pipe is the pure copper tube of impervious carbon, high thermal conductivity (340 kilocalories/meter time ℃), high-elongation (〉=30); Gap between cooling wall body and the pure copper tube outer wall is less than 0.1mm; Pure copper tube is selected the pure copper tube of 6~8mm wall thickness for use.
Preparation method's step of above structure is as follows:
It is fixing that the pure copper tube of typing is put into the sandbox 3 that need make according to the cooling wall external form;
When pouring into a mould, the pure copper tube of being poured into a mould is carried out the cooling of inerting steam, cast molding with the molten iron of spheroidal graphite cast-iron or casting pig.
Above-described " pure copper tube is carried out the cooling of inerting steam " adopts following method:
Employing drenches with rain and casts cast gate, is dispersed in the both sides that are cast into copper pipe length.The molten iron heat was evenly distributed when cast gate was also noted that casting as rising head except considering the feeding effect.
In order to prevent that pure copper tube is melted in the casting process, so at first will reduce the wash away fusing effect of high temperature liquid iron at the chill of the arranged around some that is cast into copper pipe to pure copper tube.
In cast with the inert gas and the water flowing that feed copper pipe, water enters in the copper pipe that is heated by molten iron in the casting process back and produces steam and absorb the heat that high temperature liquid iron is transmitted to copper pipe with this and prevent that copper pipe is melted, and according to the copper pipe cross section water yield is controlled at 0.5~2.0kg/min.The present embodiment water yield is controlled at 0.8kg/min.
According to the temperature of when casting pouring molten iron, before beginning cast, pass to inert gas (as nitrogen) in to copper pipe, the flow velocity of inert gas is controlled at 8~15m/s.
Behind casting finished product excision cast gate, the rising head, to the copper pipe inner surface treatment.
The principle of novel low thermal resistance cast-iron cooling wall casting technique and points for attention:
1, the key of casting technique is must the copper pipe that be cast into be cooled off, when not taking any measure casting-cooling wall, because the liquid steel temperature of cast is much larger than the fusion temperature that is cast into copper pipe, even the thermal capacity of its molten iron also is enough to melt the fine copper cooling water pipe that is cast into behind the molten steel solidification.Therefore in casting process, must pass to low amounts of water, make it in the copper pipe that is heated by high temperature liquid iron, produce a large amount of heats of vapor absorption and reduce the resulting heat of copper pipes, that is to say the temperature that reduces copper pipe and prevent that copper pipe from melting the pure copper tube that is cast into.
2, simultaneously for all parts to the even cooling copper tube of steam of water flowing generation in the copper pipe, in water flowing, must feed inert gas, the inert gas that this patent uses is a nitrogen, and logical together inert gas also prevents the oxidation of copper pipe inwall in casting process in the time of to the copper pipe water flowing in the casting process.
At the logical simultaneously inert gas of an end and the water of copper pipe, the other end of copper pipe must guarantee the mist discharging of inert gas and water vapour without any obstruction when 3, casting, and prevents that the mixed cooling gas body from accumulating in the inner security incident that produces of copper pipe.