CN1834056A - Decorative material and prepn. thereof - Google Patents
Decorative material and prepn. thereof Download PDFInfo
- Publication number
- CN1834056A CN1834056A CN 200510082981 CN200510082981A CN1834056A CN 1834056 A CN1834056 A CN 1834056A CN 200510082981 CN200510082981 CN 200510082981 CN 200510082981 A CN200510082981 A CN 200510082981A CN 1834056 A CN1834056 A CN 1834056A
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- ornament materials
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Links
- 239000000463 material Substances 0.000 title claims abstract description 517
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 89
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 70
- 238000002360 preparation method Methods 0.000 claims abstract description 66
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 35
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 35
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 35
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 35
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 35
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 29
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 29
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 217
- 239000002994 raw material Substances 0.000 claims description 112
- 239000000047 product Substances 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 238000005259 measurement Methods 0.000 claims description 29
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 27
- 238000010304 firing Methods 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 229910052788 barium Inorganic materials 0.000 claims description 10
- 229910052733 gallium Inorganic materials 0.000 claims description 9
- 229910052712 strontium Inorganic materials 0.000 claims description 9
- 235000012054 meals Nutrition 0.000 claims description 7
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 229910052790 beryllium Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 76
- 239000004579 marble Substances 0.000 abstract description 18
- 239000010438 granite Substances 0.000 abstract description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 92
- 238000010521 absorption reaction Methods 0.000 description 86
- 239000011734 sodium Substances 0.000 description 72
- 238000000034 method Methods 0.000 description 51
- 239000000126 substance Substances 0.000 description 41
- 238000002844 melting Methods 0.000 description 35
- 230000008018 melting Effects 0.000 description 35
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 22
- 239000011737 fluorine Substances 0.000 description 22
- 229910052731 fluorine Inorganic materials 0.000 description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 18
- 239000011265 semifinished product Substances 0.000 description 18
- 239000000919 ceramic Substances 0.000 description 16
- 239000011449 brick Substances 0.000 description 15
- 238000000465 moulding Methods 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- 238000002425 crystallisation Methods 0.000 description 14
- 230000008025 crystallization Effects 0.000 description 14
- 230000006911 nucleation Effects 0.000 description 14
- 238000010899 nucleation Methods 0.000 description 14
- 238000001816 cooling Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- 229910004261 CaF 2 Inorganic materials 0.000 description 12
- 238000005352 clarification Methods 0.000 description 12
- 239000011575 calcium Substances 0.000 description 11
- 238000001514 detection method Methods 0.000 description 11
- 239000011521 glass Substances 0.000 description 11
- 238000005498 polishing Methods 0.000 description 11
- 230000035939 shock Effects 0.000 description 11
- 208000037656 Respiratory Sounds Diseases 0.000 description 10
- 238000012856 packing Methods 0.000 description 10
- 239000011236 particulate material Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 238000005245 sintering Methods 0.000 description 10
- 229910016569 AlF 3 Inorganic materials 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 9
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 229910005269 GaF 3 Inorganic materials 0.000 description 5
- 238000006124 Pilkington process Methods 0.000 description 5
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 5
- 150000002222 fluorine compounds Chemical class 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- VEMKTZHHVJILDY-UHFFFAOYSA-N resmethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UHFFFAOYSA-N 0.000 description 5
- 235000010339 sodium tetraborate Nutrition 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- 239000002969 artificial stone Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000010436 fluorite Substances 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 229910016036 BaF 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000003670 easy-to-clean Effects 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 235000014380 magnesium carbonate Nutrition 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000002928 artificial marble Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 235000015193 tomato juice Nutrition 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021537 Kernite Inorganic materials 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- CMVOJSWILFNLFI-UHFFFAOYSA-L magnesium;dibromate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-]Br(=O)=O.[O-]Br(=O)=O CMVOJSWILFNLFI-UHFFFAOYSA-L 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
This invention relates to a kind of decoration material and its preparation method, which is attributed to the field of inorganic nonmetallic materials. Counting in terms of oxide net content, the terminal product comprises: 45~72% SiO2, 2~20% R2O, 5~40% RO and 0~10% Al2O3, where R2 represents alkali metals and R represents alkaline metals. It can also contains 0.0001~7% Fe2O3, 0~7% ZnO, 0~7% BaO, 0~7% TiO2, 0~8% ZrO2, 0~2% HfO2, 0~7% B2O3 and some fluoride. Thanks to reasonable composition and compact texture, properties such as modulus of rupture, compression strength after drying and Mohs' hardness of the decoration materials are better than those of granite and marble.
Description
Technical field
The present invention relates to a kind of ornament materials and preparation method thereof, belong to field of inorganic nonmetallic material.
Background technology
Popular building decorative plates mainly contains granite, marble, pottery, porose devitrified glass, aluminium-plastic panel, artificial marble etc. on the domestic and international market at present. The granite entire body has pore, and crackle is arranged, easily soil pick-up, not easy to clean, case hardness is inhomogeneous, and is easy to wear, lustrous surface is not lasting, easy-weathering is rotten, and aberration is large, and majority has higher radioactivity, harm to human body is large, and a large amount of exploitation meeting heavy damage ecological environments cause soil erosion, the harm nature; Marble is loosely organized, and intensity is low, and crackle and a large amount of pore are arranged, easy soil pick-up, not easy to clean, case hardness is low, easy to wear, be unsuitable for floor file, only be suitable for decorated wall surface, acid-proof alkaline is poor, generally need the back side to paste resin and silk screen during Marble processing, hole, hole are replenished with resin in the front, fugitive color after polishing is used, gloss duration can be poor, a large amount of exploitation harm natures; Architectural pottery is divided into the glazed tile polishing vitrified tile consistent with entire body that glaze is arranged. Glazed tile is comprised of two layers of base substrate and glazes, when coefficient of expansion difference is large, easily chaps, and glaze peels off, and the glaze layer is generally thinner, and hardness is low, so anti-wear performance is poor, is only suitable for decorated wall surface, and its specification is little, and there is pin hole on the surface. There are many pores polishing vitrified tile surface and side, easily inhale dirtyly, and stain resistance is poor, the at present domestic pollution that does not almost have a polishing vitrified tile can really resist tea or ink, and the polishing vitrified tile of specification generally all has evil mind or interlayer defect greatly; Porose devitrified glass is as a kind of finishing material that just rose in recent years, and its fatal shortcoming is exactly that pore is many, and is yielding, the impurity blurring, and there is graininess on the surface, and easily soil pick-up can not renovate processing, has a strong impact on its purposes; Aluminium-plastic panel is that aluminium sheet and plastics are composited, and one deck decorative fabric is plated or sprays on the surface again, and its weather resistance is poor, yielding fading; Artificial marble be by resin and filler through stirring, mix, low temperature drying is composited, color and luster is abundant, but case hardness is poor, and is easy to wear, is out of shape and fades.
Summary of the invention
The object of the present invention is to provide a kind of ornament materials and preparation method thereof, belong to field of inorganic nonmetallic material.
This ornament materials adopts reasonably prescription, and can adopt multiple conventional artificial stone's processing method compacting to obtain the fine and close hard ornament materials of quality, fine and close because of quality, the performance indications such as the modulus of rupture of this ornament materials, dry rear compressive strength, Mohs' hardness are better than granite, marble. Rationally adopt low temperature to flux because filling a prescription and melt well behaved alkali metal; the alkali earth metal oxide; and quality is fine and close; the cohesive of this ornament materials all raw materials in forming process is good; entire body is not easy to produce pore; the defectives such as crackle, pore, impurity and aberration that produce in granite, marble or polishing vitrified tile, the devitrified glass brick forming process have been overcome; be in particular in that water absorption rate is low; acid resistance, alkali resistance, thermal shock resistance are good; this means this ornament materials long service life; it is easy to clean to bear dirty, best in quality.
Technical scheme of the present invention is:
A kind of ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-80％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal.
Ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：
45-78％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal.
Ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：
45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal.
Ornament materials, wherein: R2For among the Li in the alkali metal, Na, the K any one or more than one.
Ornament materials, wherein: R be among Be, Mg, the Ca in the alkali earth metal any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with oxide net content percetage by weight: Fe2O
3：0.0001-7％；ZnO：0-7％；BaO：0-7％；TiO
2：0-7％；ZrO
2：0-8％；HfO
2：0-2％；
B
2O
3：0-7％。
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.0001-7%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.05-6%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.1-5%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.2-4%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.4-3.5%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.0001-5%, wherein M be among Ga, Al, the In any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.05-5%, wherein M be among Ga, Al, the In any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.1-5%, wherein M be among Ga, Al, the In any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.2-4%, wherein M be among Ga, Al, the In any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.4-3.5%, wherein M be among Ga, Al, the In any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.0001-5%, wherein N be among Zr, the Hf any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.05-5%, wherein N be among Zr, the Hf any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.1-5%, wherein N be among Zr, the Hf any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.2-4%, wherein N be among Zr, the Hf any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.4-3.5%, wherein N be among Zr, the Hf any one or more than one.
Ornament materials, wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.0001-7%.
Ornament materials, wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.05-6%.
Ornament materials, wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.1-5%.
Ornament materials, wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.2-4%.
Ornament materials, wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.4-3.5%.
Ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：50-65％；R
2O：4-15％；RO：12-30％；Al
2O
3：0-8％。
Ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：55-65％；K
2O：3-8％；Na
2O：2-7％；CaO：5-15％；MgO：9-25％；Al
2O
3：0-5％。
Ornament materials, wherein: the density 2.52-3.2 of this ornament materials g/cc.
Ornament materials, wherein: 6 grades-8 grades of the Mohs' hardness of this ornament materials.
Ornament materials, wherein: the modulus of rupture of this ornament materials: 60--180MPa.
Ornament materials, wherein: dry rear compressive strength: the 280-800Mpa of this ornament materials.
Ornament materials, wherein: the density 2.71-3.0 of this ornament materials g/cc.
Ornament materials, wherein: 6 grades-7 grades of the Mohs' hardness of this ornament materials.
Ornament materials, wherein: the modulus of rupture of this ornament materials: 80--150MPa.
Ornament materials, wherein: dry rear compressive strength: the 300-500Mpa of this ornament materials.
Ornament materials, wherein: the water absorption rate 0-0.4% of this ornament materials.
Ornament materials, wherein: the water absorption rate 0.001-0.3% of this ornament materials.
Ornament materials, wherein: the water absorption rate 0.01-0.2% of this ornament materials.
Ornament materials, wherein: the water absorption rate 0.03-0.1% of this ornament materials.
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.6-3.2 g/cc blank for pressurization compacting under 1100-1400 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature firing time 2-100 hour, must burn till material at 1250 ℃-1600 ℃; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; The raw material that mixes is put into stove, and temperature is controlled at 1300-1600 ℃, until melting, again clarification; Under 600-1200 ℃ of temperature, use roll-forming, progressively be cooled to room temperature from 600 ℃ again, obtain transparent semi-finished product end-product; Cut into again all lengths specification, advance kiln, under 400-550 ℃ of condition, carry out nucleation and processed 2-10 hour, make crystallization at 1120-1400 ℃ again and processed 2-10 hour, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material squeezes, presses, draws moulding through 1300-1600 ℃ temperature melting 2-5 hour, cooling in 800-1200 ℃ interval, at 600 ℃ interval heat treatment 1-8 hour progressively is cooled to room temperature from 600 ℃ again; Cut into all lengths specification again, advance kiln, make nucleation and processed 2-10 hour under 400-550 ℃ of condition, make crystallization at 1120-1400 ℃ again and processed 2-10 hour, then cooling is polished, cuts, is packed.
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; It is liquation that raw material is put into the melting under 1500-1650 ℃ of temperature of high temperature kiln, then this liquation is emitted from the stove mouth, cool off rapidly with high-pressure pump input cooling water, make liquid become the shrend particulate material, the shrend particulate material mould of packing into is put into stove carry out sintering, sintering temperature under nitrogen atmosphere, programming rate is 20 ℃/minute, be warming up to 1300-1600 ℃, be incubated 2-4 hour, then be cooled to below 600 ℃ and come out of the stove; 600 ℃ of lower insulations 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, send in the large-size ball mill mixedly through Belt Conveying, grind evenly, put into stirring pool and stir, send in the spray tower about 600 ℃ material dry with plunger displacement pump, it is old that material is put into feed bin, compressing with large-scale brick machine, sends in the roller way drying kiln below 200 ℃ dry 40 minutes, send in the roller kilns again and burn till, firing temperature 900--1200 ℃, firing time polished, cuts, packs about 8 hours.
The preparation method of ornament materials measures the content of oxide in the raw material and fluoride, and more in proportion conversion is by the ratio selection raw material proportioning of end-product with oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, even in airtight stirrer for mixing, join gradually in the two string kilns of 1200--1600 ℃ high-temperature melting furnace or glass or horseshoe flame furnace or the cross fire furnace etc. fusing evenly, last more than 2 days, through the moulding of float glass process moulding process, cut into the semi-finished product end-product at the kiln tail again. The semi-finished product end-product is put into roller kilns or tunnel cave or shuttle kiln heat treatment again, and nucleation temperature 400--1000 ℃, crystallization temperature 600--1200 ℃, last 8 hours, be cooled to again normal temperature, polishing, cutting, packing.
The invention has the advantages that: ornament materials quality of the present invention is sparkling and crystal-clear, bright and clean, beautiful, the soft nature of color and luster, no color differnece, the entire body pore-free, free from admixture, spot, not soil pick-up, environmental protection, hardness is high, anti-folding, resistance to compression, shock resistance, weathering resistance, colour-fast, high temperature resistant, wear-resistant, corrosion-resistant, and can arbitrarily renovate processing. The production technology of ornament materials of the present invention is fairly simple; overcome lithotome and artificial stone's defective; be a kind of desirable ornament materials, reduced demand and the exploitation of people to lithotome, conservation of nature, protection of the environment, beautify life have been played good effect.
During ornament materials prescription design of the present invention, confirm that by a certain scope proportioning end-product is with the SiO of oxide net content percetage by weight2、R
2O, RO. When the ore of selecting differing texture is raw material, such as: feldspar (feldspar is the aluminium silicate mineral of the alkali metal such as potassium, sodium, calcium, barium or alkaline-earth metal), diopside, wollastonite, magnesite, talcum, calcite, kaolin, fluorite, clay, quartz, dolomite etc. SiO in can its sample ore of first test analysis2、R
2The grade of O, RO is adjusted the consumption of each component of raw material again by the proportioning of end-product, so after the proportioning of end-product confirmed, although raw material sources are different, grade was different, and raw material is ever-changing, when pressing certain SiO2、R
2After O, RO proportioning are confirmed component, can both obtain the ornament materials of function admirable.
Owing to all contain SiO in a lot of natural crystals2、R
2O, RO, so SiO2With R2The proportioning of O, RO has consisted of the Main Ingredients and Appearance of raw material, and selects R2If O is because if contain an amount of K in the raw material2O、Na
2O, etc. alkali metal oxide fluxing action can be arranged, can be than preparing ornament materials under the low melting glass, but energy savings. The RO of the forms such as MgO, CaO simultaneously; K2O、Na
2The R of the forms such as O2O also is the part that end-product structure of the present invention forms.
Al
2O
3It also is a kind of common composition in the ore; Al2O
3Normal and SiO2Exist in the ore in conjunction with the form with aluminosilicate, in prescription of the present invention; Al2O
3Dispensable composition even its content is O, does not affect the performance of finished product of the present invention yet, but because Al2O
3Be present in a lot of natural crystals, so the present invention is difficult to avoid Al when selecting raw material sometimes2O
3Existence, but end-product of the present invention is with Al2O
3Content to be controlled at below 10% be the distinctive marks of difference the present invention and other artificial stones, ceramic, for example, Al among the artificial stone2O
3Content 〉=15%, Al in the ceramic2O
3Content 〉=17%.
The fluoride of the elements such as Ba, Mg, Ca, Sr, Zn, Ga, Al, In, Zr, Hf also has good hydrotropy effect, particularly CaF2The flux of (claiming again fluorite) form, cheap, wide material sources can reduce the fusion temperature of raw material. When lacking CaF2During in fluoride, ornament materials of the present invention will consume the energy in process of production, but not affect the performance of the finished product of ornament materials, but the fluorides such as fluorite can also reduce the viscosity of melting ore deposit liquid as preferred version, be conducive to improve homogenizing and the clarification of ore deposit liquid, reduce pore.
The introduction of fluorine compounds also helps the raising of the thermal shock resistance of finished product.
At ore and Material Field: with the formal representation of metal fluoride, this becomes the expression way of this field approval to fluorine compounds usually in the finished product. Such as forming with the fluoride form of the elements such as Ba, Mg, Ca, Sr, Zn, Ga, Al, In, Zr, Hf and the product that oxide form is explained a kind of glass in the granted patent 02111140 of denomination of invention " the thoroughly fluoride germanate glass of infrared light ".
Because the introduction of fluorine compounds mainly is in order to reduce production costs, reduce energy resource consumption, the fluoride of the elements such as Ba, Mg, Ca, Sr, Zn, Ga, Al, In, Zr, Hf all helps to reduce energy resource consumption as raw material, and the variation of concrete metal pentafluoride compound kind does not affect the good action of energy savings.
Since the combining form of fluorine compounds and metal does not affect the good action of energy savings, the present invention attempts describing ornament materials of the present invention with a kind of succinct mode, and wherein: the end-product of this material also comprises with fluorine element net content percetage by weight: F 0.0001-7%; Or F 0.05-6%; Or F 0.1-5%; Or F0.2-4%; Or F 0.4-3.5%.
Same Fe2O
3Extensively be present in the multiple natural crystal, although therefore can not select Fe2O
3, existence is difficult to avoid but it is as the impurity form, when its content is controlled at below 7%, does not affect ornament materials finished product performance.
Same ZnO, BaO, TiO2Can be artificial the interpolation, also can be because raw material itself bring, but that they are not the present invention is necessary, when its content is controlled at below 7%, does not affect the performance of ornament materials.
Although the B element in the raw material occurs mainly with boratory form, for example, borax, kernite, Boratex calcium, line borate, antifungin. But in ore field B unit usually with oxide B2O
3Formal representation. This becomes the universal expression mode in the ore field.
ZrO
2、HfO
2Introduction can be to bring in the ore, also can artificially add afterwards ZrO2、
HfO
2As additive, help to improve the high temperature resistant of product, corrosion resistance, its thermal shock resistance is good.
After end-product proportioning of the present invention was determined, multinomial embodiment showed that different material sets out and can both obtain well behaved ornament materials. This proof limits the present invention with the form of oxide in the end-product and preferred oxide, content of fluoride foundation, and the performance of finished product and the proportioning components of finished product are closely related, and little with the variation relevance of raw material.
After end-product proportioning of the present invention is determined. Use distinct methods, can obtain well behaved ornament materials, the proportioning components of this proof end-product has determined the performance of end-product. The difference of distinct methods is production cost, and energy consumption and production equipment have different, but this does not affect the performance of end-product.
End-product of the present invention is most important technical indicator except proportioning, an other most important technical indicator is its fine and close density, traditional stone material: granite, marble, Ceramic Tiles, the density of crystallite brick seldom has above 2.7 g/ccs, and ornament materials of the present invention can reach 2.52 g/ccs, 2.71 g/ccs of preferred density reachables, 3.0 g/ccs, 3.2 g/ccs.
The density of ornament materials of the present invention and the prescription of end-product have determined other premium properties:
(1), density 2.52-3.2 g/cc; Preferred density 2.71-2.9 g/cc; Pressing GB/T3810.3-1999 detects.
(2), the modulus of rupture:＞60Mpa; Pressing GB/T3810.4-1999 detects.
(3), dry rear compressive strength:＞280Mpa; Pressing GB/T9966.1-2001 detects.
(4), water absorption rate 0-0.4%; Water absorption rate 0.001-0.3%; Water absorption rate 0.01-0.2%; Water absorption rate 0.03-0.1% presses GB/T9966.3-2001 and detects.
(5), radioactivity: meet the GB6566-2001 standard.
(6), Mohs' hardness: greater than 6 grades, reach 7 grades, 8 grades.
(7), acid resistance: 1.0% sulfuric acid solution soaking at room temperature 650 hours, outward appearance is unchanged. Pressing GB/T3810.13-1999 detects.
(8), alkali resistance: 1.0% sodium hydroxide solution soaking at room temperature 650 hours, outward appearance is unchanged. Pressing GB/T3810.13-1999 detects.
(9), thermal shock resistance: the product of 100mm * 100mm * 18mm is placed on than in the high 100 ℃ constant temperature oven of indoor water temperature 30 minutes, taking-up is put into and is equivalent to 20 times of water with upper volume of product, take out phenomenons such as observing surperficial flawless, avalanche after the cooling, and it is unchanged to strike its sound. By this fixed standard detection of the present invention.
Ornament materials of the present invention and traditional granite, marble, the ceramic polished brick contrast is as follows:
| The present invention | Granite | Marble | Ceramic polished brick | |
| Density: g/cc | 2.52-3.2 | Usually be no more than 2.7 less than 2.5 | Usually be no more than 2.7 less than 2.5 | Usually be no more than 2.5 less than 2.3 |
| Modulus of rupture MPa | Greater than 60 | 30 | 15 | 40 |
| Compressive strength: Mpa after dry | Greater than 280 | 150 | 50 | 200 |
| Water absorption rate % | 0--0.4 | 0.35-1.0 | 0.3-1.4 | 0.45-0.7 |
| Radioactivity | Meet GB6566-2001 standards | / | / | / |
| Mohs' hardness | 6-8 | 5.5 | 3.0--5.0 | 6.5 |
| Acid resistance | Superior, outward appearance is unchanged | Local corrosion is arranged | Local corrosion is arranged | Local corrosion is slightly arranged |
| Alkali resistance | Superior, outward appearance is unchanged | Local corrosion is arranged | Local corrosion is arranged | Local corrosion is slightly arranged |
| Thermal shock resistance | Superior, flawless, without avalanche, it is unchanged to strike its sound | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Generally, crackle and avalanche are arranged slightly, strike its sound and change |
Different densities is on the impact of ornament materials performance of the present invention: (A)
| The present invention | Contrast 1 | Contrast 2 | Contrast 3 | |
| Density: g/cc | 2.52-3.2 | 2.3 | 2.2 | 2.1 |
| Modulus of rupture MPa | Greater than 60 | 40 | 30 | 15 |
| Compressive strength: Mpa after dry | Greater than 280 | 200 | 120 | 90 |
| Water absorption rate % | 0-0.4 | 0.8 | 0.9 | 2 |
| Mohs' hardness | 6-8 | 5-7 | 5-7 | 5-7 |
Different densities is on the impact of ornament materials performance of the present invention: (B)
| The present invention 1 | The present invention 2 | The present invention 3 | The present invention 4 | |
| Density: gram/cube | 2.52 | 2.86 | 3.12 | 3.2 |
| Centimetre | ||||
| Modulus of rupture MPa | 60 | 67-98 | 129-176 | 180 |
| Compressive strength: Mpa after dry | 280 | 321-388 | 663-695 | 448-800 |
| Water absorption rate % | 0-0.18 | 0-0.09 | 0-0.009 | 0 |
| Mohs' hardness | 6-7 | 6-7 | 7-8 | 7-8 |
This group experimental data is dispersed among each embodiment.
Make the sample of density 2.52-3.2 by production method of the present invention, and to make density by the same terms be 2.3,2.2,2.1 g/ccs contrast 1,2,3 sample.
This experiment comparing result shows: in the situation in finished product end-product formula range of the present invention, contrast the density of 2.3,2.2,2.1 g/ccs comparative sample, although only increase by 0.10,0.20 g/cc, when reaching more than 2.52 g/ccs, the aspect of performances such as the modulus of rupture of product, dry rear compressive strength, water absorption rate, Mohs' hardness have qualitative leap, the performance that bears dirty that causes the finished product end-product to have goodish mechanical strength to become reconciled, it is inner that the dirty material of the low meaning of water absorption rate is difficult to invade ornament materials of the present invention, means the good performance that bears dirty.
Fluorine-containing and the not fluorine-containing impact on thermal shock resistance of the present invention:
| Thermal shock resistance | Sample 1 of the present invention | Sample 2 of the present invention | Sample 3 of the present invention | Sample 4 of the present invention |
| Detection method 1 room temperature (12 ℃) | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound |
| Detection method 1 room temperature (25 ℃) | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound |
| Detection method 2 room temperatures (15 ℃) | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound |
| Detection method 2 room temperatures (28 ℃) | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Generally, crackle and avalanche are arranged slightly, strike its sound and change | Superior, flawless, without avalanche, it is unchanged to strike its sound | Superior, flawless, without avalanche, it is unchanged to strike its sound |
Thermal shock resistance has reflected homogeneous property and the rapid heat cycle stability of sample of the present invention. It is better that the fluorine-containing ornament materials thermal shock resistance of the present invention compares not fluorine-containing ornament materials thermal shock resistance.
Detection method 1: the product of 100mm * 100mm * 18mm is placed on than in the high 100 ℃ constant temperature oven of indoor water temperature 30 minutes, taking-up is put into and is equivalent to 20 times of water with upper volume of product, take out phenomenons such as observing surperficial flawless, avalanche after the cooling, and it is unchanged to strike its sound. By this fixed standard detection of the present invention.
This detection method is to investigate the rapid heat cycle stability of product when 100 ℃ of temperature contrasts.
Detection method 2: the product of 100mm * 100mm * 18mm is placed on than in the high 150 ℃ constant temperature oven of indoor water temperature 30 minutes, taking-up is put into and is equivalent to 20 times of water with upper volume of product, take out phenomenons such as observing surperficial flawless, avalanche after the cooling, and it is unchanged to strike its sound. By this fixed standard detection of the present invention.
This detection method is to investigate the rapid heat cycle stability of product when 150 ℃ of temperature contrasts.
Sample 1 of the present invention: ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：58％；K
2O：5％；Na
2O：4％；CaO：6％；MgO：25％；Al
2O
3：2％。
Sample 2 of the present invention: ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：58％；K
2O：7％；Na
2O：2％；CaO：12％；MgO：19％；Al
2O
3：2％。
Sample 3 of the present invention: ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：55％；K
2O：5％；Na
2O：4％；CaO：6％；MgO：25％；Al
2O
3：2％；CaF
2
3％。
Sample 4 of the present invention: ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：51％；K
2O：5％；Na
2O：4％；CaO：6％；MgO：25％；Al
2O
3：2％；CaF
2
7％。
End-product of the present invention is two important technical indicators except proportioning, density, also having an important technical indicator is its water absorption rate, traditional stone material: granite, marble, Ceramic Tiles, the water absorption rate of crystallite brick seldom has and to be lower than 0.3%, and ornament materials water absorption rate of the present invention approaches basically 0%. Water absorption rate is higher, expression granite, marble, Ceramic Tiles, crystallite brick is polluted by chemicals such as lemon, tomato juice, bleaching agent, coffee, fruit syrup wine, urine and corrosivity ceramic tile cleaners easily, for example absorbing several band look fluid drips smoothens in local surfaces, dry with wet cloth after several seconds, observe whether residual color dot of surface, the color dot bright pin hole of speaking more is many, easy to hang dirty, stone surface is of low quality; Can't be washed off if wipe, illustrate that the large stain resistance of water absorption rate of ornament materials is poor.
Ornament materials water absorption rate of the present invention approaches 0% basically. This shows that contamination resistance of the present invention is superpower.
Although in inferior good scheme, ornament materials water absorption rate of the present invention has up to 0.01%; 0.2%; 2%; 4% situation, but in that " (1) end-product comprises with oxide net content percetage by weight: SiO2：45-80％；
R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. (2) end-product comprises with oxide net content percetage by weight: SiO2：45-78％；R
2O：2-20％；
RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. (3) end-product comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；
Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. " in the scope, also there is not " water absorption rate 0-0.4%; Water absorption rate 0.001-0.3%; Water absorption rate 0.01-0.2%; Water absorption rate 0.03-0.1%. " report. (pressing GB/T9966.3-2001 detects. )
Even therefore a small amount of the partially overlapping of low existence of the water absorption rate of the high limit of the water absorption rate of invention and granite, marble, Ceramic Tiles, crystallite brick. Do not affect the premium properties of product of the present invention aspect the modulus of rupture, dry rear compressive strength yet.
Contamination resistance is the important indicator of difference the present invention and common granite, marble, Ceramic Tiles, crystallite brick.
Get 10 milliliters of blue inks at every turn and drop on product of the present invention and common marble, granite, Ceramic Tiles, the crystallite brick respectively 10 minutes kinds, 2 hours, 24 hours, observe the pollution color dot that whether can clean the surface after 1 month. Water absorption rate is pressed GB/T9966.3-2001 and is detected.
| Project | Can clean the pollution color dot after 10 minutes kinds. | Can clean the pollution color dot after 2 hours. | Can clean the pollution color dot after 24 hours. | Can clean the pollution color dot after 1 month. | Can clean the pollution color dot after 3 months. | |
| Water absorption rate % | ||||||
| Marble | 0.3 | Can | Cannot | Cannot | Cannot | Cannot |
| Granite | 0.35 | Can | Can | Cannot | Cannot | Cannot |
| Ceramic Tiles | 6 | Cannot | Cannot | Cannot | Cannot | Cannot |
| Crystallite brick | 0.12 | Can | Can | Can | Cannot | Cannot |
| 1# of the present invention | 0.4 | Can | Can | Can | Cannot | Cannot |
| 2# of the present invention | 0.3 | Can | Can | Can | Can | Can |
| 3# of the present invention | 0.01 | Can | Can | Can | Can | Can |
| 4# of the present invention | 0.003 | Can | Can | Can | Can | Can |
Therefore the present invention obviously is better than common marble, granite, Ceramic Tiles, crystallite brick aspect antipollution. For example be all the 0.3-0.4% scope at water absorption rate, the present invention is also strong than common marble, granite, Ceramic Tiles at antipollution, and the antifouling property of the water absorption rate 0.3 of the present invention also antifouling property than the water absorption rate 0.12 of crystallite brick is stronger.
Pore opening and the quantity on ornament materials surface have determined water absorption rate, pore opening and quantity and contamination resistance direct correlation. The high meaning of water absorption rate pore quantity is many, receives easily sewage.
The contamination resistance of ornament materials is the important indicator that affects product quality.
In public ground and metope particularly, the dirts such as lemon, tomato juice, bleaching agent, coffee, fruit syrup wine, urine and corrosivity ceramic tile cleaner are dropped in the surface of ornament materials, and the possibility that waiter processed immediately in the short time is far below the possibility in the family. If nonvolatil the pollution behind marble, granite, Ceramic Tiles, the crystallite brick of dirt can be brought bad impact to the owner after a few hours or a couple of days.
And adopt ornament materials of the present invention can significantly eliminate this bad impact, ornament materials of the present invention antifouling property superior.
Because of the advantage applies of product of the present invention in many aspects, in order better to estimate the present invention, ornament materials of the present invention can be described from different perspectives.
The ornament materials that a kind of density is high:
(1) a kind of ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-80％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The density 2.52-3.2 of this ornament materials g/cc.
(2) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-78％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The density 2.52-3.2 of this ornament materials g/cc.
(3) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The density 2.52-3.2 of this ornament materials g/cc.
The ornament materials that a kind of mechanical strength is good:
(1) a kind of ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-80％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. 6 grades-8 grades of the Mohs' hardness of this ornament materials; The modulus of rupture: 60--180Mpa; Compressive strength: 280-800Mpa after dry.
(2) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-78％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. 6 grades-8 grades of the Mohs' hardness of this ornament materials; The modulus of rupture: 60--180Mpa; Compressive strength: 280-800Mpa after dry.
(3) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. 6 grades-8 grades of the Mohs' hardness of this ornament materials; The modulus of rupture: 60--180Mpa; Compressive strength: 280-800Mpa after dry.
The ornament materials that a kind of contamination resistance is strong:
(1) a kind of ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-80％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. Water absorption rate 0-0.4% or water absorption rate 0.001-0.3% or water absorption rate 0.01-0.2% or water absorption rate 0.03-0.1%.
(2) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-78％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. Water absorption rate 0-0.4% or water absorption rate 0.001-0.3% or water absorption rate 0.01-0.2% or water absorption rate 0.03-0.1%.
(3) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. Water absorption rate 0-0.4% or water absorption rate 0.001-0.3% or water absorption rate 0.01-0.2% or water absorption rate 0.03-0.1%.
The ornament materials that a kind of energy consumption is less:
(1) a kind of ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-80％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The end-product of this material also comprises with fluorine element net content percetage by weight: F 0.0001-7% or F 0.05-6%. Or F 0.1-5%. Or F 0.2-4%. Or F0.4-3.5%.
(2) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-78％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The end-product of this material also comprises with fluorine element net content percetage by weight: F 0.0001-7% or F 0.05-6%. Or F 0.1-5%. Or F 0.2-4%. Or F 0.4-3.5%.
(3) ornament materials, wherein: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal. The end-product of this material also comprises with fluorine element net content percetage by weight: F 0.0001-7% or F 0.05-6%. Or F 0.1-5%. Or F 0.2-4%. Or F 0.4-3.5%.
The specific embodiment
Embodiment 1
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：45％；
R
2O：10％；RO：40％；Al
2O
3: 5%; R wherein2Be alkali metal, R is alkali earth metal.
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.2 g/ccs blank for pressurization compacting under 1100 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature is at 1250 ℃, and firing time 100 hours must burn till material; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
Embodiment 2
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：65％；
R
2O：20％；RO：5％；Al
2O
3: 10%; R wherein2Be alkali metal, R is alkali earth metal.
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.4 g/ccs blank for pressurization compacting under 1400 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature is at 1 400 ℃, and firing time 20 hours must burn till material; Stopped heating again treats that kiln temperature is down to below 6 00 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
Embodiment 3
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：60％；
R
2O:2%; RO:38%; R wherein2Be alkali metal, R is alkali earth metal.
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Be broken into Powderedly by the raw meal that will mix, to obtain density be 2.5 g/ccs blank for pressurization compacting under 1300 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature is at 1600 ℃, and firing time 2 hours must burn till material; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
Embodiment 4
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：60％；
Li
2O：5％；BeO：30％；Al
2O
3：5％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw material that mixes is put into stove, and temperature is controlled at 1300 ℃, until melting, again clarification; Under 600 ℃ of temperature, use roll-forming, progressively be cooled to room temperature from 600 ℃ again, obtain transparent semi-finished product end-product; Cut into again all lengths specification, advance kiln, under 400 ℃ of conditions, carry out nucleation and processed 2 hours, make crystallization at 1120 ℃ again and processed 10 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 5
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：55％；
Na
2O：10％；MgO：32％；Al
2O
3：3％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw material that mixes is put into stove, and temperature is controlled at 1600 ℃, until melting, again clarification; Under 1200 ℃ of temperature, use roll-forming, progressively be cooled to room temperature from 600 ℃ again, obtain transparent semi-finished product end-product; Cut into again all lengths specification, advance kiln, under 550 ℃ of conditions, carry out nucleation and processed 10 hours, make crystallization at 1400 ℃ again and processed 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 6
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：49％；
K
2O：10％；CaO：40％；Al
2O
3：1％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw material that mixes is put into stove, and temperature is controlled at 1500 ℃, until melting, again clarification; Under 900 ℃ of temperature, use roll-forming, progressively be cooled to room temperature from 600 ℃ again, obtain transparent semi-finished product end-product; Cut into again all lengths specification, advance kiln, under 500 ℃ of conditions, carry out nucleation and processed 8 hours, make crystallization at 1180 ℃ again and processed 7 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 7
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：55％；K
2O：3％；Na
2O：2％；CaO：6％；MgO：9％；Fe
2O
3：7％；ZnO：7％；BaO：7％；
ZrO
2：2％；HfO
2: 2%. The physical and chemical index of this ornament materials: 2.86 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 67MPa. Compressive strength: 321Mpa after dry. All the other are with embodiment 1.
Embodiment 8
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：65％；K
2O：8％；Na
2O：7％；CaO：15％；Al
2O
3: 5%. The physical and chemical index of this ornament materials: 2.66 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 70MPa. Compressive strength: 300Mpa after dry. All the other are with embodiment 2.
Embodiment 9
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：58％；K
2O：5％；Na
2O：4％；CaO：6％；MgO：25％；Al
2O
3: 2%. The physical and chemical index of this ornament materials: 2.66 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 107MPa. Compressive strength: 500Mpa after dry. All the other are with embodiment 3.
Embodiment 10
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：55％；Li
2O：5％；K
2O：3％；Na
2O：2％；BeO：7％；CaO：2％；MgO：10％；Fe
2O
3：4％；ZnO：
2％；BaO：1％；ZrO
2：1％；HfO
2：1％；B
2O
3: 7%. The physical and chemical index of this ornament materials: 2.66 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 60MPa. Compressive strength: 280Mpa after dry. All the other are with embodiment 2.
Embodiment 11
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：58.9999％；Li
2O：5％；K
2O：3％；Na
2O：2％；BeO：7％；CaO：2％；MgO：10％；Fe
2O
3：
0.0001％；ZnO：2％；BaO：4％；ZrO
2：1％；HfO
2：1％；B
2O
3: 4%. All the other are with embodiment 3.
Embodiment 12
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：58％；K
2O：8％；Na
2O：6.9999％；Fe
2O
3：7％；CaO：15％；Al
2O
3：5％；
BaF
2: 0.0001%. All the other are with embodiment 3.
Embodiment 13
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：65％；K
2O：6％；Na
2O：6.8％；CaO：17％；Al
2O
3：5％；MgF
2: 0.2%. All the other are with embodiment 2.
Embodiment 14
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：58％；K
2O：8％；Na
2O：7％；CaO：15％；Al
2O
3：5％；MgF
2：2％；CaF
2: 5%. The physical and chemical index of this ornament materials: 3.2 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 180MPa. Compressive strength 800Mpa after dry. All the other are with embodiment 1.
Embodiment 15
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：60％；K
2O：8％；Na
2O：7％；CaO：15％；Al
2O
3：5％；SrF
2: 5%. The physical and chemical index of this ornament materials: 3.12 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 150MPa. Compressive strength: 678Mpa after dry. All the other are with embodiment 4.
Embodiment 16
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62％；K
2O：10％；Na
2O：7％；CaO：13％；Al
2O
3：5％；ZnF
2: 3%. The physical and chemical index of this ornament materials: 3.0 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 145MPa. Compressive strength: 562Mpa after dry. All the other are with embodiment 5.
Embodiment 17
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：60％；K
2O：10％；Na
2O：7％；CaO：13％；Al
2O
3：5％；BaF
2：1％；MgF
2：1％；
CaF
2：1％；SrF
2：1％；ZnF
2: 1%. The physical and chemical index of this ornament materials: 2.83 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 87MPa. Compressive strength: 486Mpa after dry. All the other are with embodiment 3.
Embodiment 18
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62％；K
2O：10％；Na
2O：7％；CaO：13％；Al
2O
3：5％；GaF
3：3％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, send in the large-size ball mill mixedly through Belt Conveying, grind evenly, put into stirring pool and stir, send in the spray tower about 600 ℃ material dry with plunger displacement pump, it is old that material is put into feed bin, compressing with large-scale brick machine, sends in the roller way drying kiln below 200 ℃ dry 40 minutes, send in the roller kilns again and burn till, firing temperature 900--1200 ℃, firing time polished, cuts, packs about 8 hours.
Embodiment 19
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：65％；K
2O：8％；Na
2O：6.9999％；CaO：15％；Al
2O
3：5％；AlF
3：0.0001％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, even in airtight stirrer for mixing, join gradually that fusing evenly lasts more than 2 days in the two string kilns of 1200 ℃ high-temperature melting furnace or glass or horseshoe flame furnace or the cross fire furnace etc., through the moulding of float glass process moulding process, cut into the semi-finished product end-product at the kiln tail again. The semi-finished product end-product is put into roller kilns or tunnel cave or shuttle kiln heat treatment again, 400 ℃ of nucleation temperatures, and 600 ℃ of crystallization temperatures last 8 hours, are cooled to normal temperature again, polishing, cutting, packing.
Embodiment 20
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：58％；K
2O：10％；Na
2O：7％；CaO：15％；Al
2O
3：5％；GaF
3：2％；AlF
3：
2％；InF
3：1％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, even in airtight stirrer for mixing, join gradually that fusing evenly lasts more than 2 days in the two string kilns of 1600 ℃ high-temperature melting furnace or glass or horseshoe flame furnace or the cross fire furnace etc., through the moulding of float glass process moulding process, cut into the semi-finished product end-product at the kiln tail again. The semi-finished product end-product is put into roller kilns or tunnel cave or shuttle kiln heat treatment again, 1000 ℃ of nucleation temperatures, and 1200 ℃ of crystallization temperatures last 8 hours, are cooled to normal temperature again, polishing, cutting, packing.
Embodiment 21
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：60％；K
2O：8％；Na
2O：7％；CaO：15％；Al
2O
3：5％；ZrF
4：2％；HfF
4：
3％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, even in airtight stirrer for mixing, join gradually that fusing evenly lasts more than 2 days in the two string kilns of 1400 ℃ high-temperature melting furnace or glass or horseshoe flame furnace or the cross fire furnace etc., through the moulding of float glass process moulding process, cut into the semi-finished product end-product at the kiln tail again. The semi-finished product end-product is put into roller kilns or tunnel cave or shuttle kiln heat treatment again, 900 ℃ of nucleation temperatures, and 1000 ℃ of crystallization temperatures last 8 hours, are cooled to normal temperature again, polishing, cutting, packing.
Embodiment 22
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62％；K
2O：8％；Na
2O：7％；CaO：15％；Al
2O
3：5％；HfF
4: 3%. All the other are with embodiment 1.
Embodiment 23
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62.9999％；K
2O：10％；Na
2O：7％；CaO：15％；Al
2O
3：5％；ZrF
4：0.0001％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; It is liquation that raw material is put into the melting under 1500 ℃ of temperature of high temperature kiln, then this liquation is emitted from the stove mouth, cool off rapidly with high-pressure pump input cooling water, make liquid become the shrend particulate material, the shrend particulate material mould of packing into is put into stove carry out sintering, sintering temperature under nitrogen atmosphere, programming rate is 20 ℃/minute, be warming up to 1300 ℃, be incubated 2 hours, then be cooled to below 600 ℃ and come out of the stove; 600 ℃ of lower insulations 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 24
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：50％；R
2O：12％；RO：30％；Al
2O
3：8％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; It is liquation that raw material is put into the melting under 1650 ℃ of temperature of high temperature kiln, then this liquation is emitted from the stove mouth, cool off rapidly with high-pressure pump input cooling water, make liquid become the shrend particulate material, the shrend particulate material mould of packing into is put into stove carry out sintering, sintering temperature under nitrogen atmosphere, programming rate is 15 ℃/minute, be warming up to 1600 ℃, be incubated 4 hours, then be cooled to below 600 ℃ and come out of the stove; 600 ℃ of lower insulations 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 25
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：65％；R
2O：15％；RO：12％；Al
2O
3：8％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; It is liquation that raw material is put into the melting under 1650 ℃ of temperature of high temperature kiln, then this liquation is emitted from the stove mouth, cool off rapidly with high-pressure pump input cooling water, make liquid become the shrend particulate material, the shrend particulate material mould of packing into is put into stove carry out sintering, sintering temperature under nitrogen atmosphere, programming rate is 10 ℃/minute, be warming up to 1500 ℃, be incubated 3 hours, then be cooled to below 600 ℃ and come out of the stove; 600 ℃ of lower insulations 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product.
Embodiment 26
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：63％；R
2O：4％；RO：28％；Al
2O
3: 5%. All the other are with embodiment 2.
Embodiment 27
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：62％；R
2O:13%; RO:25%. All the other are with embodiment 3.
Embodiment 28
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：55％；K
2O：8％；Na
2O：7％；CaO：15％；MgO：25％；Al
2O
3：5％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Raw material squeezes in 800 ℃ intervals, presses, draws moulding through 1300 ℃ temperature melting 5 hours, cooling, 300 ℃ interval heat treatments 8 hours, obtains transparent semi-finished product end-product; Cut into all lengths specification again, advance kiln, make nucleation and processed 2-10 hour under 480 ℃ of conditions, make crystallization at 1180 ℃ again and processed 7 hours, then cooling is polished, cuts, is packed.
The physical and chemical index of this ornament materials: 2.52 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 60MPa. Compressive strength: 280Mpa after dry.
Embodiment 29
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：65％；K
2O：3％；Na
2O：2％；CaO：5％；MgO：25％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Raw material squeezes in 1200 ℃ intervals, presses, draws moulding through 1600 ℃ temperature melting 2 hours, cooling, 600 ℃ interval heat treatments 1 hour, progressively is cooled to room temperature from 600 ℃ again, obtains transparent semi-finished product end-product; Cut into all lengths specification again, advance kiln, make nucleation and processed 10 hours under 400 ℃ of conditions, make crystallization at 1120 ℃ again and processed 10 hours, then cooling is polished, cuts, is packed.
The physical and chemical index of this ornament materials: 2.71 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 80MPa. Compressive strength 300Mpa after dry.
Embodiment 30
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：63％；K
2O：6％；Na
2O：6％；CaO：10％；MgO：12％；Al
2O
3：3％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Raw material squeezes in 1100 ℃ intervals, presses, draws moulding through 1510 ℃ temperature melting 45 hours, cooling, 500 ℃ interval heat treatments 6 hours, progressively is cooled to room temperature from 500 ℃ again, obtains transparent semi-finished product end-product; Cut into all lengths specification again, advance kiln, make nucleation and processed 2 hours under 550 ℃ of conditions, make crystallization at 1400 ℃ again and processed 2 hours, then cooling is polished, cuts, is packed.
The physical and chemical index of this ornament materials: 3.2 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 170MPa. Compressive strength: 448Mpa after dry. All the other are with embodiment 6.
Embodiment 31
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：60％；K
2O：7％；Na
2O：6％；CaO：14％；MgO：9％；Al
2O
3: 4%. All the other are with embodiment 5.
Embodiment 32
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：72％；
R
2O:2%; RO:26%; R wherein2Be alkali metal, R is alkali earth metal.
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.42 g/ccs blank for pressurization compacting under 1400 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature is at 1580 ℃, and firing time 2 hours must burn till material; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
Embodiment 33
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：60％；K
2O：7％；Na
2O：6％；CaO：14％；MgO：9％；TiO
2: 4%. All the other are with embodiment 5.
Embodiment 34
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：55％；K
2O：4％；Na
2O：11％；CaO：14％；MgO：9％；TiO
2: 7%. All the other are with embodiment 5.
Embodiment 35
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：51％；K
2O：3％；Na
2O：2％；CaO：6％；MgO：9％；Fe
2O
3：7％；ZnO：7％；BaO：7％；
ZrO
2: 8%. The physical and chemical index of this ornament materials: 2.86 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 98MPa. Compressive strength: 388Mpa after dry. All the other are with embodiment 1.
Following examples are that the end-product in ornament materials comprises with the ratio of oxide and fluoride net content percetage by weight and selects raw material:
Embodiment 36
Measure the content of oxide in the raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Get 300 parts of feldspars, 2000 parts of clays, 3000 parts of boraxs, 3300 parts in potash, 2000 parts of dolomites, 1500 parts in zinc oxide, with the melting furnaces melting that the raw material that mixes is put into uniform temperature, clarification is at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 4.
Embodiment 37
Measure the content of oxide in the raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Get 2000 parts of diopsides, 3000 parts of wollastonites, 2500 parts of feldspars, 2800 parts in potassium nitrate, 2000 parts of boric acid, the melting furnaces melting of the raw material that mixes being put into uniform temperature, clarification, at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 5.
Embodiment 38
Measure the content of oxide in the raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Get 5000 parts in magnesite, 1000 parts in talcum, 1800 parts in calcite, 1500 parts of kaolin, 3000 parts of boric acid, 2000 parts in potash, 800 parts of phosphorus pentoxides, 1000 parts of alumina silicate, with the melting furnaces melting that the raw material that mixes is put into uniform temperature, clarification is at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 6.
Embodiment 39
Measure the content of oxide in the raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Get 1200 parts in fluorite, 7000 parts in talcum, 1300 parts of clays, quartzy 2000 parts, 1100 parts of soda ash, 1500 parts in potassium nitrate, 1800 parts of boraxs, the melting furnaces melting of the raw material that mixes being put into uniform temperature, clarification, at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 4.
Embodiment 40
Measure the content of oxide in the raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Get 3000 parts of dolomites, 2000 parts in fluorite, 1300 parts in aluminium hydroxide, quartzy 2000 parts, 3500 parts of soda ash, 1500 parts of brium carbonates, 1200 parts of phosphorus pentoxides, the melting furnaces melting of the raw material that mixes being put into uniform temperature, clarification, at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other together
Embodiment 17.
Embodiment 41
The content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Get 800 parts of clays, 10000 parts in magnesite, 1500 parts in calcirm-fluoride, 5000 parts of feldspar powders, 3000 parts of boraxs, 2000 parts in zinc oxide, 1500 parts of brium carbonates, quartzy 1200 parts, with the melting furnaces melting that the raw material that mixes is put into uniform temperature, clarification is at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 6.
Embodiment 42
The content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Get 1500 parts in aluminium oxide, 3000 parts of white clouds quartz clocks, 3000 parts of prodans, 1000 parts in lime stone, quartzy 2500 parts, 2500 parts of soda ash, 1000 parts in zinc oxide, 1500 parts of boraxs, with the melting furnaces melting that the raw material that mixes is put into uniform temperature, clarification is at the interval of certain temperature pair roller roll-forming, the product of this fabrication process, its thickness are the sheet material of the arbitrary thickness of 3-40mm. All the other are with embodiment 5.
Embodiment 43
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：66.2％；K
2O：7.4％；Na
2O：6.9％；CaO：14.6％；Al
2O
3: 4.9%. The physical and chemical index of this ornament materials: 2.69 g/ccs of density. Mohs' hardness is 6. The modulus of rupture: 74MPa. Compressive strength: 320Mpa after dry. All the other are with embodiment 2. The water absorption rate 0.3% of this ornament materials.
Embodiment 44
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：61.8％；K
2O：8.9％；Na
2O：6.3％；CaO：13.2％；Al
2O
3：4.1％；GaF
3：
2.7％；AlF
3：1.7％；InF
3：1.3％。
The preparation method of ornament materials, the content of oxide and fluoride in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; Raw material is put into feeding machine, even in airtight stirrer for mixing, join gradually that fusing evenly lasts more than 2 days in the two string kilns of 1600 ℃ high-temperature melting furnace or glass or horseshoe flame furnace or the cross fire furnace etc., through the moulding of float glass process moulding process, cut into the semi-finished product end-product at the kiln tail again. The semi-finished product end-product is put into roller kilns or tunnel cave or shuttle kiln heat treatment again, 1000 ℃ of nucleation temperatures, and 1200 ℃ of crystallization temperatures last 8 hours, are cooled to normal temperature again, polishing, cutting, packing. The water absorption rate 0.03% of this ornament materials.
Embodiment 45
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：65.7％；K
2O：5.7％；Na
2O：7.2％；CaO：14.3％；Al
2O
3：4.2％；HfF
4: 2.9%. All the other are with embodiment 1. All the other are with embodiment 1. The water absorption rate 0.01% of this ornament materials.
Embodiment 46
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：63.9％；R
2O：13.7％；RO：14.7％；Al
2O
3：7.7％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; It is liquation that raw material is put into the melting under 1650 ℃ of temperature of high temperature kiln, then this liquation is emitted from the stove mouth, cool off rapidly with high-pressure pump input cooling water, make liquid become the shrend particulate material, the shrend particulate material mould of packing into is put into stove carry out sintering, sintering temperature under nitrogen atmosphere, programming rate is 10 ℃/minute, be warming up to 1500 ℃, be incubated 3 hours, then be cooled to below 600 ℃ and come out of the stove; 600 ℃ of lower insulations 2 hours, then be cooled to room temperature, polish again, cut, pack and to get the finished product end-product. The water absorption rate 0.03% of this ornament materials.
Embodiment 47
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：67.5％；K
2O：4.6％；Na
2O：5.7％；CaO：8.7％；MgO：10.2％；Al
2O
3：3.3％。
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; Raw material squeezes in 1080 ℃ intervals, presses, draws moulding through 1540 ℃ temperature melting 30 hours, cooling, 500 ℃ interval heat treatments 6 hours, progressively is cooled to room temperature from 500 ℃ again, obtains transparent semi-finished product end-product; Cut into all lengths specification again, advance kiln, make nucleation and processed 2 hours under 550 ℃ of conditions, make crystallization at 1400 ℃ again and processed 2 hours, then cooling is polished, cuts, is packed.
The physical and chemical index of this ornament materials: 3.15 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 194MPa. Compressive strength: 479Mpa after dry. All the other are with embodiment 6. The water absorption rate 0.001% of this ornament materials.
Embodiment 48
Ornament materials, the end-product of this material comprise with oxide net content percetage by weight: SiO2：78％；
R
2O:1.9%; RO:20.1%; R wherein2Be alkali metal, R is alkali earth metal.
The preparation method of ornament materials, the content of oxide in the measurement raw material, more in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.66 g/ccs blank for pressurization compacting under 1400 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature is at 1620 ℃, and firing time 2 hours must burn till material; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product. The water absorption rate 0.4% of this ornament materials.
Embodiment 49
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：80％；K
2O：5.3％；Na
2O：5.2％；CaO：8.3％；Al
2O
3：1.2％。
The preparation method of ornament materials provides by the method for embodiment 32. The water absorption rate 0% of this ornament materials.
Embodiment 50
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：81.1％；K
2O：2.3％；Na
2O：5.2％；CaO：7.9％；Al
2O
3: 1.9%; F element 1.6%.
The preparation method of ornament materials provides by the method for embodiment 32. The water absorption rate 0% of this ornament materials.
Embodiment 51
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：79.3％；K
2O：3.8％；Na
2O：4.1％；CaO：10.7％；Al
2O
3: 0.4%; F element 1.7%.
The preparation method of ornament materials provides by the method for embodiment 25. The water absorption rate 0.01% of this ornament materials.
Embodiment 52
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：75.7％；K
2O：3.0％；Na
2O：4.2％；CaO：5.1％；MgO：5.6％；Al
2O
3: 0.4%; F element 6.0%.
The preparation method of ornament materials provides by the method for embodiment 30. The water absorption rate 0.1% of this ornament materials.
Embodiment 53
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide net content percetage by weight2：73.7％；K
2O：1.1％；Na
2O：4.5％；CaO：3.3％；MgO：5.5％；Al
2O
3: 6.4%; F element 5.5%.
The preparation method of ornament materials provides by the method for embodiment 22. The water absorption rate 0.2% of this ornament materials.
Embodiment 54
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：74.1％；K
2O：3.3％；Na
2O：2.1％；CaO：13.65％；Al
2O
3：6.8％；MgF
2：
0.02％；CaF
2: 0.03%. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.032% of this ornament materials.
Embodiment 55
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：71.9％；K
2O：7.4％；Na
2O：8.9％；CaO：1.1％；Al
2O
3：4.7％；SrF
2：
0.12％；ZnF
2：2.2％；CaF
2: 3.68%. The physical and chemical index of this ornament materials: 3.06 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 167MPa. Compressive strength 794Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 19. The water absorption rate 0.072% of this ornament materials.
Embodiment 56
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：67.6％；K
2O：8.1％；Na
2O：6.7％；CaO：7.9％；Al
2O
3：2.7％；MgF
2：
1.74％；CaF
2: 5.26%. The physical and chemical index of this ornament materials: 3.12 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 129MPa. Compressive strength: 663Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 18. The water absorption rate 0.006% of this ornament materials.
Embodiment 57
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：67.1％；K
2O：12.4％；Na
2O：5.6％；CaO：11.0％；MgO：1.5％；Al
2O
3：
2.3％；CaF
2: 0.1%. The physical and chemical index of this ornament materials: 2.89 g/ccs of density. Mohs' hardness is 7. The preparation method of ornament materials provides by the method for embodiment 18. The water absorption rate 0.22% of this ornament materials.
Embodiment 58
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：66.1％；K
2O：10.1％；Na
2O：7.8％；CaO：7.4％；MgO：5.5％；Al
2O
3：2.7％；
BaF
2：0.13％；CaF
2: 0.27%. The physical and chemical index of this ornament materials: 2.83 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 94MPa. Compressive strength: 503Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.07% of this ornament materials.
Embodiment 59
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：60.7％；K
2O：7.5％；Na
2O：9.5％；CaO：12.5％；Al
2O
3：9.6％；CaF
2: 0.2%. The physical and chemical index of this ornament materials: 2.66 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 76MPa. Compressive strength: 367Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 19. The water absorption rate 0.19% of this ornament materials.
Embodiment 60
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：69.8％；K
2O：5.6％；Na
2O：5.0％；CaO：11.7％；Al
2O
3：4.4％；ZnF
2：
0.3％；CaF
2: 3.2%. The physical and chemical index of this ornament materials: 2.66 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 189MPa. Compressive strength: 352Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 19. The water absorption rate 0.13% of this ornament materials.
Embodiment 61
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：68.9％；K
2O：4.6％；Na
2O：2.8％；CaO：11.8％；Al
2O
3：7.9％；MgF
2：
1.36％；CaF
2: 2.64%. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.077% of this ornament materials.
Embodiment 62
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：73.1％；K
2O：9.8％；Na
2O：2.15％；CaO：8.6％；Al
2O
3：6.3％；GaF
3：
0.01％；AlF
3: 0.04%. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.018% of this ornament materials.
Embodiment 63
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：77.4％；K
2O：8.6％；Na
2O：5.4％；CaO：6.8％；Al
2O
3：1.7％；AlF
3: 0.1%. The physical and chemical index of this ornament materials: 3.12 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 176MPa. Compressive strength: 695Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 18. The water absorption rate 0.009% of this ornament materials.
Embodiment 64
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：76.3％；K
2O：10.7％；Na
2O：3.5％；CaO：3.8％；MgO：1.3％；Al
2O
3：4.2％；
AlF
3: 0.2%. The physical and chemical index of this ornament materials: 2.70 g/ccs of density. Mohs' hardness is 7. The preparation method of ornament materials provides by the method for embodiment 19. The water absorption rate 0.004% of this ornament materials.
Embodiment 65
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：69.0％；K
2O：7.5％；Na
2O：7.8％；CaO：7.4％；MgO：3.8％；Al
2O
3：4.1％；
AlF
3：0.33％；InF
3: 007%. The physical and chemical index of this ornament materials: 2.83 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 95MPa. Compressive strength: 462Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.001% of this ornament materials.
Embodiment 66
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：73.8％；K
2O：3.3％；Na
2O：2.5％；CaO：12.0％；Al
2O
3：4.4％；AlF
3：
2.27％；GaF
3：1.73％。
The physical and chemical index of this ornament materials: 2.98 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 143MPa. Compressive strength: 388Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.042% of this ornament materials.
Embodiment 67
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：73.6％；K
2O：5.4％；Na
2O：5.4％；CaO：7.7％；Al
2O
3：4.4％；AlF
3：
2％；InF
3：1.5％。
The physical and chemical index of this ornament materials: 2.59 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 98MPa. Compressive strength: 408Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 19. The water absorption rate 0.08% of this ornament materials.
Embodiment 68
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：77.6％；K
2O：8.8％；Na
2O：4.7％；CaO：6.6％；Al
2O
3：2.2％；ZrF
4：
0.06％；HfF
4：0.04％。
The physical and chemical index of this ornament materials: 2.81 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 94MPa. Compressive strength: 471Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.011% of this ornament materials.
Embodiment 69
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62.34％；K
2O：8.61％；Na
2O：7.7％；CaO：14.7％；Al
2O
3：5.4％；
MgO：1.2％；HfF
4：0.05％。
The physical and chemical index of this ornament materials: 2.86 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 76MPa. Compressive strength: 364Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.09% of this ornament materials.
Embodiment 70
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：78.6％；K
2O：7.2％；Na
2O：5.7％；CaO：2.1％；MgO：5.1％；Al
2O
3：1.1％；
ZrF
4：0.2％。
The physical and chemical index of this ornament materials: 2.57 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 91MPa. Compressive strength: 361Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.054% of this ornament materials.
Embodiment 71
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：54.5％；K
2O：15.7％；Na
2O：2.4％；CaO：18.4％；MgO：3.5％；Al
2O
3：5.1％；
ZrF
4：0.4％。
The physical and chemical index of this ornament materials: 2.55 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 132MPa. Compressive strength: 398Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 18. The water absorption rate 0.27% of this ornament materials.
Embodiment 72
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：62.1％；K
2O：9.6％；Na
2O：5.2％；CaO：14.1％；MgO：2.0％；Al
2O
3：3.5％；
ZrF
4：2.2％；HfF
4：1.3％。
The physical and chemical index of this ornament materials: 2.59 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 77MPa. Compressive strength: 460Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.33% of this ornament materials.
Embodiment 73
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluoride net content percetage by weight2：79.1％；K
2O：6.0％；Na
2O：4.3％；CaO：2.7％；MgO：1.8％；Al
2O
3：2.1％；
HfF
4：4.0％。
The physical and chemical index of this ornament materials: 3.17 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 139MPa. Compressive strength: 521Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.003% of this ornament materials.
Embodiment 74
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：45％；K
2O：9.0％；Na
2O：6.3％；CaO：14.6％；MgO：20.2％；Al
2O
3: 4.8%; F element 0.1%.
The physical and chemical index of this ornament materials: 2.52 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 60MPa. Compressive strength: 280Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.18% of this ornament materials.
Embodiment 75
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：49.0％；K
2O：8.6％；Na
2O：6.75％；CaO：14.7％；Al
2O
3: 5.4%; MgO:15.5%; F element: 0.05%.
The physical and chemical index of this ornament materials: 2.64 g/ccs of density. Mohs' hardness is 7. The modulus of rupture: 65MPa. Compressive strength: 329Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.4% of this ornament materials.
Embodiment 76
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：54.6％；K
2O：8.3％；Na
2O：5.7％；CaO：14.8％；MgO：15.1％；Al
2O
3: 1.3%; F element: 0.2%.
The physical and chemical index of this ornament materials: 2.75 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 72MPa. Compressive strength: 394Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.33% of this ornament materials.
Embodiment 77
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：66.6％；K
2O：7.7％；Na
2O：2.4％；CaO：8.4％；MgO：10.5％；Al
2O
3: 4%; F element: 0.4%.
The physical and chemical index of this ornament materials: 2.92 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 159MPa. Compressive strength: 425Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 18. The water absorption rate 0.23% of this ornament materials.
Embodiment 78
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：67.2％；K
2O：7.6％；Na
2O：4.2％；CaO：10.1％；MgO：5.6％；Al
2O
3: 1.8%; F element: 3.5%.
The physical and chemical index of this ornament materials: 2.95 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 167MPa. Compressive strength: 552Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 20. The water absorption rate 0.13% of this ornament materials.
Embodiment 79
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：77.3％；K
2O：6.1％；Na
2O：3.4％；CaO：2.2％；MgO：4.9％；Al
2O
3: 2.1%; F element: 4.0%.
The physical and chemical index of this ornament materials: 3.01 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 153MPa. Compressive strength: 640Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.012% of this ornament materials.
Embodiment 80
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：79.1％；K
2O：6.5674％；Na
2O：4.4325％；CaO：5.7％；MgO：1.8％；
Al
2O
3: 2.4%; F element: 0.0001%.
The physical and chemical index of this ornament materials: 3.09 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 127MPa. Compressive strength: 568Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.002% of this ornament materials.
Embodiment 81
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：78.0％；K
2O：3.0％；Na
2O：4.1％；CaO：3.1％；MgO：2.8％；Al
2O
3: 2.0%; F element: 7.0%.
The physical and chemical index of this ornament materials: 3.16 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 132MPa. Compressive strength: 730Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0.0016% of this ornament materials.
Embodiment 82
Ornament materials, wherein: the end-product of this material comprises the composition SiO with oxide and fluorine element net content percetage by weight2：80.0％；K
2O：6.0％；Na
2O：1.4％；CaO：2.7％；MgO：1.8％；Al
2O
3: 2.1%; F element: 6.0%.
The physical and chemical index of this ornament materials: 3.20 g/ccs of density. Mohs' hardness is 8. The modulus of rupture: 180MPa. Compressive strength 800Mpa after dry. The preparation method of ornament materials provides by the method for embodiment 21. The water absorption rate 0% of this ornament materials.
Claims (10)
1, a kind of ornament materials is characterized in that: the end-product of this material comprises with oxide net content percetage by weight: SiO2：45-72％；R
2O：2-20％；RO：5-40％；Al
2O
3: 0-10%; R wherein2Be alkali metal, R is alkali earth metal.
2, ornament materials as claimed in claim 1 is characterized in that: R2For among the Li in the alkali metal, Na, the K any one or more than one.
3, ornament materials as claimed in claim 1 is characterized in that: R be among Be, Mg, the Ca in the alkali earth metal any one or more than one.
4, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material also comprises with oxide net content percetage by weight: Fe2O
3：0.0001-7％；ZnO：0-7％；BaO：0-7％；TiO
2：
0-7％；ZrO
2：0-8％；HfO
2：0-2％；B
2O
3：0-7％。
5, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material also comprises with fluoride net content percetage by weight: LF20.0001-7%, wherein L be among Ba, Mg, Ca, Sr, the Zn any one or more than one.
6, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material also comprises with fluoride net content percetage by weight: MF30.0001-5%, wherein M be among Ga, Al, the In any one or more than one.
7, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material also comprises with fluoride net content percetage by weight: NF40.0001-5%, wherein N be among Zr, the Hf any one or more than one.
8, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material comprises with oxide net content percetage by weight: SiO2：50-65％；R
2O：4-15％；RO：12-30％；Al
2O
3：0-8％。
9, ornament materials as claimed in claim 1 is characterized in that: the end-product of this material comprises with oxide net content percetage by weight: SiO2：55-65％；K
2O：3-8％；Na
2O：2-7％；CaO：5-15％；
MgO：9-25％；Al
2O
3：0-5％。
10, the preparation method of claim 1,2,3,4,5,6,7,8,9 described any one ornament materials, it is characterized in that: the content of oxide and fluoride in the measurement raw material, again in proportion conversion is selected the raw material proportioning in end-product with the ratio of oxide and fluoride net content percetage by weight; The raw meal that mixes is broken into Powdered, to obtain density be 2.6-3.2 g/cc blank for pressurization compacting under 1100-1400 ℃ of temperature; Blank is sent into drying unit dry, must dry material; To dry and expect that sending into stove fires, firing temperature firing time 2-100 hour, must burn till material at 1250 ℃-1600 ℃; Stopped heating again treats that kiln temperature is down to below 600 ℃ naturally, with the material kiln discharge, then is cooled to room temperature, polishes, cuts, packs and to get the finished product end-product.
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| CNB200510082981XA CN100562507C (en) | 2005-04-11 | 2005-07-11 | A kind of finishing material and preparation method thereof |
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| CN200510018532 | 2005-04-11 | ||
| CN200510018532.9 | 2005-04-11 | ||
| CNB200510082981XA CN100562507C (en) | 2005-04-11 | 2005-07-11 | A kind of finishing material and preparation method thereof |
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| CN100562507C CN100562507C (en) | 2009-11-25 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962288A (en) * | 2010-09-19 | 2011-02-02 | 江西金枫玉石有限公司 | Decorating material |
| CN102409821A (en) * | 2011-08-09 | 2012-04-11 | 大连铭源全建材有限公司 | Preparation method of ultralight heat-insulation decorative plate |
| CN102795770A (en) * | 2012-09-06 | 2012-11-28 | 北京大有盛和科技有限公司 | Method for producing color pattern type glass ceramics through rolling process or casting process |
| CN103641319A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
| CN103641323A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
| CN104030698A (en) * | 2014-05-26 | 2014-09-10 | 浙江立鑫高温耐火材料有限公司 | Magnesium zirconium brick |
| CN112340995A (en) * | 2017-11-28 | 2021-02-09 | 福建省德化县晖德陶瓷有限公司 | Low-temperature frit for matt ceramic glaze and preparation process for preparing matt glaze ceramic product by using low-temperature frit |
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2005
- 2005-07-11 CN CNB200510082981XA patent/CN100562507C/en active Active
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962288A (en) * | 2010-09-19 | 2011-02-02 | 江西金枫玉石有限公司 | Decorating material |
| CN102409821A (en) * | 2011-08-09 | 2012-04-11 | 大连铭源全建材有限公司 | Preparation method of ultralight heat-insulation decorative plate |
| CN102409821B (en) * | 2011-08-09 | 2013-01-16 | 大连铭源全建材有限公司 | Method for preparing ultra-light heat insulation decorative plate |
| CN102795770A (en) * | 2012-09-06 | 2012-11-28 | 北京大有盛和科技有限公司 | Method for producing color pattern type glass ceramics through rolling process or casting process |
| CN103641319A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
| CN103641323A (en) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
| CN103641319B (en) * | 2013-12-06 | 2016-10-19 | 辽宁红山玉科技有限公司 | A kind of low-fluorine microcrystalline glass |
| CN104030698A (en) * | 2014-05-26 | 2014-09-10 | 浙江立鑫高温耐火材料有限公司 | Magnesium zirconium brick |
| CN112340995A (en) * | 2017-11-28 | 2021-02-09 | 福建省德化县晖德陶瓷有限公司 | Low-temperature frit for matt ceramic glaze and preparation process for preparing matt glaze ceramic product by using low-temperature frit |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100562507C (en) | 2009-11-25 |
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