CN1818097A - Pelletizing binder with starch and humus acid and production thereof - Google Patents
Pelletizing binder with starch and humus acid and production thereof Download PDFInfo
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- CN1818097A CN1818097A CN 200610012433 CN200610012433A CN1818097A CN 1818097 A CN1818097 A CN 1818097A CN 200610012433 CN200610012433 CN 200610012433 CN 200610012433 A CN200610012433 A CN 200610012433A CN 1818097 A CN1818097 A CN 1818097A
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Abstract
An adhesive is made from the starch and the humate. The outlook is grayish brown to black brown; the dry based material is not less than 90%; 80-150eyes of the grain size is not less than 95%; the expansion hold is not less than 20-50ml/g; The pH of the 1% water solution is 7-11; the content of the water is less than 10%; amyloacetate: humate: the cross linker is 100-120:90-100:0.02-0.04. the weight ratio of the starch and the acetylating agent is 1-1.4:0.06-0.08 to make the amyloacetate solution; the lower calorific power coal: alkali is 0.8-1.1:0.2-0.4 to make humate solution; amyloacetate: humate: the cross linker is 100-120:90-100:0.02-0.04 to make the adhesive. The additive amount is 4 permillage, so it is used for ferrum-smelting to save the cost.
Description
Technical field
The invention belongs to the preconditioning technique field of metallurgical raw material, be specifically related to a kind of pelletizing binder made from starch and humate and preparation method thereof.
Background technology
In the metallurgy industry, the ore reduction that digging is arrived, by methods such as gravity treatment, flotation, magnetic separation obtains the higher fine ore of containing metal amount; The fine iron breeze of " carefully " and tackiness agent and water, uniform mixing in pelletizer is made " green-ball ", obtains pelletizing behind the high temperature sintering, just can smelt operation.
The pelletizing binder that the tradition iron-smelting process uses mainly is a wilkinite, and wilkinite (Bentonite claims otaylite, amargosite or bentonite again) is to be the tonstein-montmorillonitic clay rock of main component with the montmorillonite.To have water absorbability strong because of it, and the swelling coefficient is big, polymolecularity, and specific surface area is big, has characteristics such as plasticity-and cohesiveness.Its intensity and burst temperature that can significantly improve green-ball has enlarged roast area, and bed permeability is good, improves the pelletizing grade, reduces cost, and can significantly improve steel enterprise economic benefit.
But, the wilkinite component is that (its main component is silicon-dioxide, aluminium sesquioxide and water to the mineral substance formed of the oxide compound of multiple inorganics, also contain magnesium oxide, ferric oxide and calcium, sodium, potassium etc.), they transform into waste residue in iron manufacturing process, become solid waste; Elements such as itself contained silicon, calcium are brought in the iron on a small quantity, influence the quality of iron; Wilkinite as the proportioning height of tackiness agent, bring into impurity many, reduce pellet iron grade and influence problem such as other metallurgical performance,
How to select new pelletizing binder for use, change this iron output and reduce, the phenomenon that coke ratio raises is increased economic efficiency, and is that the field of metallurgy technician thirsts for the problem that solves for a long time.
Someone attempts adopting organic binder bonds such as Walocel MT 20.000PV and polyvinyl alcohol to produce pelletizing, but their resistances to elevated temperatures are poor, lose viscosity in the roasting process of pelletizing easily, cause the pelletizing breakage, and is unsatisfactory.
Summary of the invention
The objective of the invention is to look for another way, seek a kind of pelletizing binder made from starch and humate that is suitable for.
Technical scheme of the present invention is: develop a kind of pelletizing binder made from starch and humate, it is characterized in that:
1. the rerum natura of described pelletizing binder is:
Outward appearance beige-chocolate powder; Butt product content 〉=90%; Granularity 80～150 orders 〉=95%; Expansion capacity 〉=20～50ml/g; 1% aqueous ph value 7～11; Moisture %≤10%;
2. described pelletizing binder is a crosslinking condition, and wherein the weight of each component composition is:
Starch acetate: humate: linking agent=100～120: 90～100: 0.02～0.04.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate is characterized in that step is divided into:
1. prepare starch acetate
Weight proportion: starch: acetylizing agent=1～1.4: 0.06～0.08
Under the stirring at room, starch adds water and makes starch milk, adds alkali and transfers to PH 8.0～8.5, keeps this pH value and adds acetylizing agent, finishes, and transfers to PH 6～7 with acid, makes starch acetate solution, and is standby;
2. prepare humate
Weight proportion: low calorific value coal: alkali=0.8～1.1: 0.2～0.4:
Low calorific value coal adds water and makes coal slurry, adds under the alkali stirring to be heated to 90～110 ℃, and reaction 1～3h promptly makes humate solution, and is standby;
3. prepare tackiness agent
Weight proportion: starch acetate solution: humate solution: linking agent=100～120: 90～100: 0.02～0.04
Starch acetate solution that the last step makes and humic acid salt solution mix add the linking agent of its total amount 0.02～0.04, stir 1～2h in 40～50 ℃, solution is spraying drying again, is crushed to 95% and crosses 80～150 orders, gets modified version pelletizing binder of the present invention, check, packing.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate, when it is characterized in that preparing starch acetate, described starch is W-Gum, potato starch or sweet potato starch, and is single or mix and use.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate, when it is characterized in that preparing starch acetate, described acetylizing agent is diacetyl oxide, vinyl acetate or glacial acetic acid, and is single or mix and use.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate, when it is characterized in that preparing humate, described low calorific value coal is weathered coal, brown coal or peat, and is single or mix and use.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate, when it is characterized in that preparing humate, described alkali is sodium hydroxide, yellow soda ash, potassium hydroxide or magnesium hydroxide.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate is characterized in that described humate is sodium humate, potassium humate or humic acid magnesium.
The method for making of above-mentioned a kind of pelletizing binder made from starch and humate, when it is characterized in that preparing pelletizing binder, described linking agent is oxalic acid, propanedioic acid, glycerine, sorbyl alcohol or Xylitol, and is single or mix and use.
Humate (Salt Humate, also claim humate) be the important component that contains in low calorific value coal such as weathered coal, brown coal or the peat, the past main application is that fodder additives, medical material, cosmetics additive, the oil drilling mud of aquaculture is adjusted agent, water-reducing strengthening agent for concrete, coal briquette binding agent, water conditioner etc.
The applicant is by research, and both form the polymer crosslinking condition down through the effect of linking agent with this, and the ironmaking of preparation Steel Plant in order to replace traditional wilkinite, has obtained success with the tackiness agent of pelletizing.
Advantage of the present invention is:
1. modified version pelletizing binder of the present invention, main component are organic combustiblesubstances, in the pelletizing smelting process, brought into play effect after, the after-flame ashing, thus significantly reduced the generation and the discharging of slag, that is reduced solid pollutant; When reducing the slag generation, also improved the quality of iron effectively, reduced the detrimental impurity in the iron.
2. the addition of this pelletizing binder in pelletizing is about 4/1000ths, and its addition only is that traditional tackiness agent is bentonitic 1/10th, more helps the operation of iron-smelting process process and reduces cost.
3. the preparation method is easy, and raw material is easy to get, and non-environmental-pollution is implemented easily, and is cheap, is easy to promotion and application; Be applied to pelletizing binder and will produce bigger social benefit, environmental benefit and economic benefit.
The present invention is further elaborated below in conjunction with embodiment.
Embodiment
Acetate starch-sodium humate the pelletizing binder of embodiment 1 preparation crosslinking condition
Step is divided into:
(1) self-control starch acetate solution
Weight proportion: starch: acetylizing agent=1.4: 0.08
Starch adopts when real estate commercial size W-Gum, the specification of quality: moisture content (%)≤14, and acidity (t)≤20, protein (%)≤0.5, fineness (100 orders, %): 〉=99.5;
Acetylizing agent adopts when the commercially available commercial size diacetyl oxide of real estate (trade(brand)name aceticanhydride), the specification of quality: content 〉=99%;
140kg starch (butt) is scattered in the 100L ordinary water, makes starch milk; Under 25 ℃ of conditions, splash into 3%NaOH solution while stirring, transfer to PH 8.0～8.5, slowly splash into the 8kg aceticanhydride, splash into alkali lye simultaneously and keep PH 8.0～8.5, add aceticanhydride after, keep reaction 1h, transfer to PH 6～7 with dilute hydrochloric acid then, obtain starch acetate solution 240kg, press determination of acid-basetitration, the substitution value of starch acetate (Degree of Substitution is called for short DS) is 0.07%;
This batch of starch acetate yield=must measure/raw material charging capacity sum * 100%=240/248 * 100%=96.77%, standby;
(2) self-control sodium humate solution
Weight proportion: low calorific value coal: alkali=1.1: 0.4
Low calorific value coal uses when the real estate weathered coal, its content of humic acid 〉=50%, ash content≤20%; Alkali adopts solid sodium hydroxide, content 96%, carbonate content 98%;
Weathered coal 55kg stirs bottom on the limit and is added in the 134.44L ordinary water, adds NaOH 7kg then, is warming up to 95～100 ℃, adds yellow soda ash 13kg again, keeps 95～100 ℃ of reaction 2h, and standing sedimentation is removed insolubles, obtains sodium humate solution 200kg;
This batch of sodium humate yield :=must measure/raw material charging capacity sum * 100%=200kg/209.44 * 100%=95.5%; Press HG/T3278-87 and measure sodium humate content 45.5%; Standby;
(3) preparation tackiness agent of the present invention
Weight proportion: starch acetate: sodium humate: linking agent=120: 100: 0.04.
Starch acetate solution, the self-control of sodium humate solution are with working as real estate sorbyl alcohol, liquid, content 50～70%; Or with working as real estate Xylitol, white crystals or crystalline powder, content 〉=99%.
Behind above-mentioned starch acetate solution 240kg and the above-mentioned sodium humate solution 200kg mixing, add sorbyl alcohol or Xylitol 17.6kg (pure), in 40～50 ℃ of stirring 1～2h, solution is spraying drying again, be crushed to 95% and cross 80～150 orders, get modified version pelletizing binder of the present invention; Must measure 472.52kg, press butt product content 92%, be converted to dry product 434.72kg,
This batch of yield: 434.72/457.6 * 100%=95%.
Product detects according to company standard: this batch outward appearance chocolate powder; Butt product content 92% (105 ℃ of weighing methods are measured); Granularity 80～150 orders 95.5% (standard sieve dry screening mensuration); Expansion capacity 40ml/g (graduated cylinder method, the 1g sample makes abundant expansion in 75ml water+25ml hydrochloric acid, leave standstill 24h, calculates with the cylinder scale value difference); 1% aqueous ph value 8～9 (acidometer mensuration); Moisture %8.5% (105 ℃ of weighing methods are measured); Test value meets company standard, packing.
Try out in iron work production through the client, addition only was 0.35% (its addition is less than traditional tackiness agent bentonitic 1/10th), and every technical indicator of green-ball all is better than traditional tackiness agent wilkinite, and effect is satisfied, had reached the goal of the invention of expection.
Acetate starch-potassium humate the pelletizing binder of embodiment 2 preparation crosslinking conditions
(1) self-control starch acetate solution weight proportioning: starch: acetylizing agent=1: 0.06
Starch adopts when real estate commercial size sweet potato starch; The specification of quality: moisture content (%)≤15, acidity (t)≤25, protein (%)≤0.5, fineness (100 orders, %): 〉=99.5;
Acetylizing agent adopts when the commercially available commercial size vinyl acetate of real estate (Vinyl acetate copolymer), the specification of quality: content 〉=99%; Starch consumption 100kg, vinyl acetate consumption 6kg is scattered in the 102.76.L ordinary water, obtains starch acetate solution 200kg, and substitution value is 0.08%;
This crowd of starch acetate yield: 200/208.76 * 100%=95.8%, standby; All the other are with embodiment 1.
(2) self-control potassium humate solution
Weight proportion: low calorific value coal: alkali=0.8: 0.2
Low calorific value coal uses when real estate brown coal or mud coal, its content of humic acid 〉=50%, ash content≤20%; Alkali adopts solid sodium hydroxide, content 96%;
Brown coal consumption 80kg stirs bottom on the limit and is added in the 86.53L ordinary water, adds NaOH 20kg then, is warming up to 95～100 ℃, and 95～100 ℃ of reaction 2h obtain potassium humate solution 180kg;
This batch of potassium humate yield is calculated: (180kg/186.53 * 100%=96.5%; Press HG/T3278-87 and measure content 49.5%; Standby;
(3) preparation tackiness agent of the present invention
Weight proportion: starch acetate: potassium humate: linking agent=100: 90: 0.02.
Starch acetate solution, the self-control of potassium humate solution, oxalic acid is with working as real estate, content 〉=99%.
Behind above-mentioned starch acetate solution 200kg and the sodium humate solution 180kg mixing, add oxalic acid 4kg (pure), in 40～50 ℃ of stirring 1～2h, solution is spraying drying again, is crushed to 95% and crosses 80～150 orders, gets modified version pelletizing binder of the present invention; Must measure 418.41kg, press butt product content 96%, be converted to dry product 401.67kg;
This batch of yield: 401.67/384 * 100%=95.6%;
Product detects according to company standard: this batch outward appearance beige powder; Butt product content 93%; Granularity 80～150 orders 96.0%; Expansion capacity 50ml/g; 1% aqueous ph value 10～11; Moisture %7.4%; All the other are with embodiment 1.
Acetate starch-humic acid magnesium the pelletizing binder of embodiment 3 preparation crosslinking conditions
(1) self-control starch acetate solution weight proportioning: starch: acetylizing agent=1: 0.06
Starch adopts when real estate commercial size potato starch; White or littlely be with light yellow shade to get powder, the specification of quality: moisture content (%)≤18, acidity (t)≤14, protein (%)≤0.15, fineness (100 orders, %): 〉=99.5; (GB/8884-88) acetylizing agent adopts when the commercially available commercial size glacial acetic acid of real estate, the specification of quality: content 〉=99.5%; All the other are with embodiment 1.
(2) self-control humic acid magnesium solution
Weight proportion: low calorific value coal: alkali=0.8: 0.2
Low calorific value coal uses when real estate peat, its content of humic acid 〉=50%, ash content≤20%; Alkali adopts solid hydrogen magnesium oxide, content 94%; All the other are with embodiment 2.
(3) preparation tackiness agent of the present invention
Weight proportion: starch acetate: humic acid magnesium: linking agent=100: 90: 0.02.
Starch acetate solution, the self-control of potassium humate solution, propanedioic acid is with working as real estate, content 〉=99%; All the other are with embodiment 1.
Embodiment 4
Starch is W-Gum and sweet potato starch 1: 1; Acetylizing agent adopts the commercial size vinyl acetate; Low calorific value coal uses when real estate peat, uses yellow soda ash to prepare sodium humate; Linking agent uses industry glycerol; All the other are with embodiment 1.
Embodiment 5
Starch is W-Gum and potato starch 1: 1; Acetylizing agent adopts commercial size vinyl acetate+glacial acetic acid; Low calorific value coal uses when real estate brown coal or weathered coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol+sorbyl alcohol; All the other are with embodiment 1.
Embodiment 6
Starch is sweet potato starch and potato starch 1: 0.8; Acetylizing agent adopts the commercial size glacial acetic acid; Low calorific value coal uses when the real estate weathered coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol+sorbyl alcohol; All the other are with embodiment 1.
Embodiment 7
Starch is sweet potato starch and W-Gum 1: 0.5; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine; All the other are with embodiment 2.
Embodiment 8
Starch is sweet potato starch and potato starch 1: 0.9; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine and sorbyl alcohol; All the other are with embodiment 3.
Embodiment 9
Starch is potato starch and W-Gum 1: 0.7; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine; All the other are with embodiment 2.
Embodiment 10
Starch is potato starch and sweet potato starch 1: 0.6; Acetylizing agent adopts the commercial size glacial acetic acid; Low calorific value coal uses when the real estate mud coal, uses magnesium hydroxide to prepare humic acid magnesium; Linking agent uses propanedioic acid; All the other are with embodiment 1.
Embodiment 11
Starch is W-Gum and sweet potato starch 1: 1; Acetylizing agent adopts the commercial size vinyl acetate; Low calorific value coal uses when the real estate brown coal, uses yellow soda ash to prepare sodium humate; Linking agent uses industry glycerol; All the other are with embodiment 1.
Embodiment 12
Starch is W-Gum and potato starch 1: 1; Acetylizing agent adopts commercial size vinyl acetate+glacial acetic acid; Low calorific value coal uses when real estate brown coal or weathered coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol or sorbyl alcohol; All the other are with embodiment 2.
Embodiment 13
Starch is sweet potato starch and potato starch 1: 0.8; Acetylizing agent adopts the commercial size glacial acetic acid; Low calorific value coal uses when the real estate weathered coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol or sorbyl alcohol; All the other are with embodiment 3.
Embodiment 14
Starch is sweet potato starch and W-Gum 1: 0.5; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate brown coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine; All the other are with embodiment 2.
Embodiment 15
Starch is sweet potato starch and potato starch 1: 0.9; Acetylizing agent adopts the commercial size vinyl acetate; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine and sorbyl alcohol; All the other are with embodiment 3.
Embodiment 16
Starch is potato starch and W-Gum 1: 0.5; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses magnesium hydroxide to prepare humic acid magnesium; Linking agent uses glycerine; All the other are with embodiment 1.
Embodiment 17
Starch is potato starch and W-Gum 0.6: 1; Acetylizing agent adopts the commercial size glacial acetic acid; Low calorific value coal uses when the real estate mud coal, uses magnesium hydroxide to prepare humic acid magnesium; Linking agent uses propanedioic acid; All the other are with embodiment 1.
Embodiment 18
Starch is W-Gum and sweet potato starch 0.8: 1; Low calorific value coal uses when the real estate brown coal, uses yellow soda ash to prepare sodium humate; Linking agent uses industry glycerol; All the other are with embodiment 2.
Embodiment 19
Starch is W-Gum and potato starch 0.9: 1; Acetylizing agent adopts commercial size vinyl acetate+glacial acetic acid; Low calorific value coal uses when real estate brown coal or weathered coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol or sorbyl alcohol; All the other are with embodiment 1.
Embodiment 20
Starch is sweet potato starch and potato starch 1: 0.8; Acetylizing agent adopts the commercial size glacial acetic acid; Low calorific value coal uses when the real estate brown coal, uses sodium hydroxide+yellow soda ash to prepare sodium humate; Linking agent uses Xylitol or sorbyl alcohol; All the other are with embodiment 1.
Embodiment 21
Starch is sweet potato starch and W-Gum 1: 0.5; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine or sorbyl alcohol; All the other are with embodiment 2.
Embodiment 22
Starch is W-Gum and potato starch 1: 0.9; Acetylizing agent adopts the commercial size vinyl acetate; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine and sorbyl alcohol; All the other are with embodiment 3.
Embodiment 23
Starch is sweet potato starch and W-Gum 1: 0.5; Acetylizing agent adopts the commercial size aceticanhydride; Low calorific value coal uses when the real estate weathered coal, uses potassium hydroxide to prepare potassium humate; Linking agent uses glycerine or sorbyl alcohol; All the other are with embodiment 2.
Embodiment 24
Starch is potato starch and W-Gum 1: 1; Acetylizing agent adopts the commercial size vinyl acetate; Low calorific value coal uses when the real estate mud coal, uses magnesium hydroxide to prepare humic acid magnesium; Linking agent uses propanedioic acid; All the other are with embodiment 1.
Claims (8)
1. pelletizing binder made from starch and humate is characterized in that:
1. the rerum natura of described pelletizing binder is:
Outward appearance beige-chocolate powder; Butt product content 〉=90%; Granularity 80～150 orders 〉=95%; Expansion capacity 〉=20～50ml/g; 1% aqueous ph value 7～11; Moisture %≤10%;
2. described pelletizing binder is a crosslinking condition, and wherein the weight of each component composition is:
Starch acetate: humate: linking agent=100～120: 90～100: 0.02～0.04.
2. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 1, it is characterized in that step is divided into:
1. prepare starch acetate
Weight proportion: starch: acetylizing agent=1～1.4: 0.06～0.08
Under the stirring at room, starch adds water and makes starch milk, adds alkali and transfers to PH8.0～8.5, keeps this pH value and adds acetylizing agent, finishes, and transfers to PH6～7 with acid, makes starch acetate solution, and is standby;
2. prepare humate
Weight proportion: low calorific value coal: alkali=0.8～11: 0.2～0.4:
Low calorific value coal adds water and makes coal slurry, adds under the alkali stirring to be heated to 90～110 ℃, and reaction 1～3h promptly makes humate solution, and is standby;
3. prepare tackiness agent
Weight proportion: starch acetate solution: humate solution: linking agent=100～120: 90～100: 0.02～0.04
Starch acetate solution that the last step makes and humic acid salt solution mix add the linking agent of its total amount 0.02～0.04, stir 1～2h in 40～50 ℃, solution is spraying drying again, is crushed to 95% and crosses 80～150 orders, gets modified version pelletizing binder of the present invention, check, packing.
3. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, when it is characterized in that preparing starch acetate, described starch is W-Gum, potato starch or sweet potato starch, and is single or mix and use.
4. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, when it is characterized in that preparing starch acetate, described acetylizing agent is diacetyl oxide, vinyl acetate or glacial acetic acid, and is single or mix and use.
5. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, when it is characterized in that preparing humate, described low calorific value coal is weathered coal, brown coal or peat, and is single or mix and use.
6. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, when it is characterized in that preparing humate, described alkali is sodium hydroxide, yellow soda ash, potassium hydroxide or magnesium hydroxide.
7. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, it is characterized in that described humate is sodium humate, potassium humate or humic acid magnesium.
8. according to the method for making of the described a kind of pelletizing binder made from starch and humate of claim 2, when it is characterized in that preparing pelletizing binder, described linking agent is oxalic acid, propanedioic acid, glycerine, sorbyl alcohol or Xylitol, and is single or mix and use.
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| CNB2006100124334A CN100360691C (en) | 2006-03-14 | 2006-03-14 | Pelletizing binder with starch and humus acid and production thereof |
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| CNB2006100124334A CN100360691C (en) | 2006-03-14 | 2006-03-14 | Pelletizing binder with starch and humus acid and production thereof |
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Cited By (7)
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| CN104357656A (en) * | 2014-11-20 | 2015-02-18 | 湖北丹江口市宝洲冶金材料有限公司 | Organic adhesive and blast furnace ironmaking pellet prepared from same |
| CN106010706A (en) * | 2016-06-28 | 2016-10-12 | 陈建峰 | Preparing method of composite coal binder |
| CN106755984A (en) * | 2017-01-24 | 2017-05-31 | 福州大学 | A kind of method that utilization percolate prepares compound iron ore pellet binder |
| CN110343855A (en) * | 2019-08-20 | 2019-10-18 | 攀钢集团攀枝花钢铁研究院有限公司 | The method of efficient calcification vanadium extraction |
| CN110343856A (en) * | 2019-08-20 | 2019-10-18 | 攀钢集团攀枝花钢铁研究院有限公司 | The method of sodium-ionized vanadium extraction |
| CN111254278A (en) * | 2020-03-30 | 2020-06-09 | 中南大学 | Oxidized pellet binder prepared from low-rank coal and preparation method and application thereof |
| CN112195338A (en) * | 2020-09-23 | 2021-01-08 | 山东金团新材料科技有限公司 | High-efficiency energy-saving composite material additive for metallurgical pellets |
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| US3400179A (en) * | 1965-04-02 | 1968-09-03 | Fritz O. Wienert | Pellet manufacture |
| DE3512420C1 (en) * | 1985-04-04 | 1986-09-11 | Michael 6100 Darmstadt Martin | Wind energy converter |
| CN1035196C (en) * | 1992-12-23 | 1997-06-18 | 中南工业大学 | Direct reduction technology for compound adhesive cool solidifying globus coal base |
| US6342089B1 (en) * | 1997-09-02 | 2002-01-29 | Mcgaa John R. | Direct reduced iron pellets |
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| CN104357656A (en) * | 2014-11-20 | 2015-02-18 | 湖北丹江口市宝洲冶金材料有限公司 | Organic adhesive and blast furnace ironmaking pellet prepared from same |
| CN106010706A (en) * | 2016-06-28 | 2016-10-12 | 陈建峰 | Preparing method of composite coal binder |
| CN106010706B (en) * | 2016-06-28 | 2018-12-28 | 叶静 | A kind of preparation method of composite coal binder |
| CN106755984A (en) * | 2017-01-24 | 2017-05-31 | 福州大学 | A kind of method that utilization percolate prepares compound iron ore pellet binder |
| CN110343855A (en) * | 2019-08-20 | 2019-10-18 | 攀钢集团攀枝花钢铁研究院有限公司 | The method of efficient calcification vanadium extraction |
| CN110343856A (en) * | 2019-08-20 | 2019-10-18 | 攀钢集团攀枝花钢铁研究院有限公司 | The method of sodium-ionized vanadium extraction |
| CN110343856B (en) * | 2019-08-20 | 2021-01-26 | 攀钢集团攀枝花钢铁研究院有限公司 | Efficient sodium treatment vanadium extraction method |
| CN111254278A (en) * | 2020-03-30 | 2020-06-09 | 中南大学 | Oxidized pellet binder prepared from low-rank coal and preparation method and application thereof |
| WO2021197258A1 (en) * | 2020-03-30 | 2021-10-07 | 中南大学 | Oxidized pellet binding agent made from low-rank coal, preparation method for same, and applications thereof |
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