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CN1796008A - Substrate treatment equipment and treatment method thereof - Google Patents

Substrate treatment equipment and treatment method thereof Download PDF

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Publication number
CN1796008A
CN1796008A CNA2005101346154A CN200510134615A CN1796008A CN 1796008 A CN1796008 A CN 1796008A CN A2005101346154 A CNA2005101346154 A CN A2005101346154A CN 200510134615 A CN200510134615 A CN 200510134615A CN 1796008 A CN1796008 A CN 1796008A
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China
Prior art keywords
dry ice
mentioned
substrate
carbon dioxide
carrier gas
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Granted
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CNA2005101346154A
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CN1796008B (en
Inventor
金世镐
朴钟秀
尹哲男
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Kc Ltd By Share Ltd
KCTech Co Ltd
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KC Tech Co Ltd
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Priority claimed from KR1020050049585A external-priority patent/KR100622287B1/en
Priority claimed from KR1020050060565A external-priority patent/KR20070005304A/en
Application filed by KC Tech Co Ltd filed Critical KC Tech Co Ltd
Publication of CN1796008A publication Critical patent/CN1796008A/en
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Publication of CN1796008B publication Critical patent/CN1796008B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • H01L21/67028Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like
    • H01L21/6704Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing
    • H01L21/67051Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing using mainly spraying means, e.g. nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/02Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • H01L21/67028Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Cleaning Or Drying Semiconductors (AREA)
  • Cleaning In General (AREA)
  • Nozzles (AREA)

Abstract

本发明涉及一种基板处理装置,其包括:装载部,用于装载形成有物质膜的基板;干冰供给部,供给干冰粒子或二氧化碳;喷射处理部,包括一个以上的喷管,向上述基板上喷射由上述干冰供给部所提供的干冰粒子,或将二氧化碳固化后喷射到基板上,以对物质膜进行初步表面处理;表面处理部,对上述经过初步表面处理的物质膜进行选择性的去除。本发明使用不留残屑的干冰粒子,对物质膜进行改质或部分去除,并通过清洗或蚀刻等表面处理,去除经改质的物质膜,以此可缩短物质膜去除所需工时。

Figure 200510134615

The present invention relates to a substrate processing device, which includes: a loading part for loading a substrate formed with a material film; a dry ice supply part for supplying dry ice particles or carbon dioxide; Spraying dry ice particles provided by the above-mentioned dry ice supply part, or spraying solidified carbon dioxide onto the substrate to perform preliminary surface treatment on the material film; the surface treatment part selectively removes the above-mentioned material film that has undergone preliminary surface treatment. The invention uses dry ice particles without residues to modify or partially remove the material film, and removes the modified material film through surface treatment such as cleaning or etching, thereby shortening the man-hour required for material film removal.

Figure 200510134615

Description

Substrate board treatment and processing method thereof
Technical field
The present invention relates to substrate board treatment and processing method thereof, especially the material film of removing object is carried out upgrading, by cleaning or etching, can remove substrate board treatment and processing method thereof at an easy rate then through the material film of upgrading.
Background technology
Generally, LCD (LCD) is a kind of as substrate, and it comprises: substrate regions, and it comprises thin film transistor (TFT) and transparency electrode; Liquid crystal region is positioned on the substrate regions and carries out polarisation; The color filter plate zone is positioned on the liquid crystal region and determines color.
Make in the process of above-mentioned LCD, carry out the vacuum evaporation (vacuumevaporation) of film repeatedly and form pattern (Pattern).In vacuum evaporation or pattern forming process, unusual if film occurs, not that it is discarded, but reprocess (Rework).
Existing reprocessing process is, uses Wet-type cleaning equipment or dry type cleaning equipment, and to color filter plate (Color filter), the bad film of polyimides (Polyimide) etc. is optionally removed (Strip), carries out vacuum evaporation again.
At this moment, the chemical agent that is used to remove mainly is potassium hydroxide (KOH).
Above-mentioned polyimides has very strong corrosion resistance to chemicals, for bad film is thoroughly removed, needs the suitable time.
In addition, the Wet-type cleaning equipment volume is big, and because of a large amount of toxic chemical substances that use in the operating process, very harmful to operator ' s health.
Summary of the invention
The present invention is intended to address the above problem, and its purpose is, a kind of substrate board treatment and the processing method thereof that can carry out the removal of material film quickly and easily is provided.
Another object of the present invention is to, provide a kind of equipment volume little, and can reduce the substrate board treatment and the processing method thereof of noxious material use amount.
Another object of the present invention is to, a kind of flat-panel monitors such as LCD that not only are used in are provided, also substrate board treatment and the processing method thereof that can clean various micro-elements.
In addition, another object of the present invention is to, provide a kind of and in the processing substrate process, can improve ejection efficiency, and have the jet pipe of good machinability.
In order to achieve the above object, the present invention includes: loading part, load the substrate that is formed with the material film; The dry ice supply unit is supplied with dry-ice particle or carbon dioxide; Inject process portion comprises more than one jet pipe, and the dry-ice particle that is provided by above-mentioned dry ice supply unit is provided on aforesaid substrate, or with being ejected on the substrate after the carbon dioxide curing, so that the material film is carried out preliminary surface treatment; Surface treating part is optionally removed the preliminary surface-treated material of above-mentioned process film.
In addition, the present invention includes: in the loading stage, load the substrate that is formed with the material film; Pretreatment stage is sprayed dry-ice particle on the substrate of above-mentioned loading, so that the material film on the aforesaid substrate is carried out preliminary surface treatment; In the surface treatment stage, the preliminary surface-treated material of above-mentioned process film is carried out selective removal.
The present invention uses the dry-ice particle that does not stay detritus, the material film is carried out upgrading or part removal, and by surface treatments such as cleaning or etchings, remove the material film, can shorten material film demoulding with this and remove man-hour.
In addition, in the process of removing the material film, damage can not for the lower set ribbon of this material film, and because of the use amount of chemicals is few, both economical, also can reduce operating personnel and be exposed to time and number of times in the poisonous environment, improved security.
In addition, the present invention carries out repeatedly adiabatic expansion in a jet pipe, and uses the high structure of insulation effect, thereby has improved the production rate of dry-ice particle, has improved processing substrate efficient.
In addition, use straight tube shape jet pipe among the present invention, have good machinability, and can reduce the manufacturing expense of jet pipe.
Description of drawings
Fig. 1 is the formation schematic diagram of an embodiment of the present invention's substrate board treatment;
Fig. 2 a to Fig. 2 d is the cutaway view of the procedure of an embodiment in the present invention's the substrate processing method using same;
Fig. 3 is an embodiment schematic diagram of the injection apparatus of Fig. 1;
Fig. 4 is the structural representation of another embodiment of the present invention's substrate board treatment;
Fig. 5 is another embodiment schematic diagram of the dry ice supply unit of Fig. 4;
Fig. 6 to Figure 12 is respectively the cutaway view of another embodiment of the jet pipe among Fig. 5.
10: substrate 11: backplane level
12: remove object layer 20: flat board
21: cylinder 30: the dry ice supply unit
40: injection apparatus 50: the wet type device
60: control panel 70: exhaust portion
The specific embodiment
Below, the embodiment to the present invention is elaborated with reference to the accompanying drawings.
[embodiment 1]
Fig. 1 is the plane pie graph of an embodiment of substrate board treatment among the present invention.
As shown in the figure, the substrate board treatment among the present invention comprises: flat board 20, be provided with a plurality of cylinders 21, and be used to load the substrate 10 that needs demoulding; Dry ice supply unit 30 provides dry-ice particle; Injection apparatus 40 to the whole surface of the removal object film that is loaded in the substrate on above-mentioned dull and stereotyped 20, sprays the dry-ice particle that is provided by above-mentioned dry ice supply unit 30; Wet type device 50 carries out wet-cleaned to the removal destination layer of the substrate 10 that sprays through dry-ice particle on above-mentioned dull and stereotyped 20; Control panel 60 drives control to above-mentioned dull and stereotyped 20, dry ice supply unit 30 and injection apparatus 40.
Below, an embodiment of the substrate board treatment of the present invention with above-mentioned formation is elaborated.
Fig. 2 a to Fig. 2 d is the procedure cutaway view of an embodiment of the present invention's substrate processing method using same.
Shown in Fig. 2 a, be formed with color filter plate, polyimides or protective finish (Overcoating) etc. need the substrate 10 of the material film of removal, are loaded onto on dull and stereotyped 20.
At this moment, above-mentioned dull and stereotyped 20 cylinder 21 is rotated under the control of control panel 60, and aforesaid substrate 10 is loaded into dull and stereotyped 20 tops, and when loading was finished, the rotation of cylinder 21 then can stop.
The practical structures more complicated of aforesaid substrate 10 is simplified to it here, comprises the backplane level 11 of parts such as glass substrate, and is positioned at the removal object layer 12 on this backplane level 11.
Above-mentioned removal object layer 12 can be color filter plate, polyimides or protective finish.
Above-mentioned dull and stereotyped 20 are provided with a plurality of cylinders 21, are used for mounting substrate 10 and to wet type device 50 unloading.
After being formed with the substrate 10 of removing object layer 12 and being loaded on dull and stereotyped 20,30 of dry ice supply units provide dry-ice particle to injection apparatus 40.
At this moment, the dry ice that is provided to injection apparatus 40 by dry ice supply unit 30 has the particle footpath of 0.5~3.0mm.Why dry-ice particle directly being limited, is because when dry-ice particle footpath during less than 0.5mm, be difficult to change and remove the membranous of object layer 12, and particle diameter is when 3.0mm is above, and particle diameter is crossed and may well be brought damage to backplane level 11.
Above-mentioned dry ice supply unit 30 utilizes high pressure nitrogen or the injection dry ice that purifies air, and by the jet pipe on the injection apparatus 40, is ejected into substrate 10 surfaces that are loaded on dull and stereotyped 20.
Use above-mentioned nitrogen or purify air, can prevent that secondary pollution from taking place.
Secondly, shown in Fig. 2 b, whole or part surface evenly sprays dry-ice particle to the removal object layer 12 that is loaded in the substrate 10 on dull and stereotyped 20 by above-mentioned injection apparatus 40.
By this injection, above-mentioned removal object layer 12 sustains damage, thereby forms depression, or chaps, and a part is then removed fully.
Fig. 3 is the front schematic view of above-mentioned injection apparatus 40.
As shown in the figure, above-mentioned injection apparatus 40 comprises: from dull and stereotyped 20 tops apart from the certain distance and the movable stand 41 that can move with this flat board 20; Above above-mentioned dull and stereotyped 20, carry out at least more than one jet pipe 42 of straight reciprocating motion along above-mentioned movable stand 41.
Like this, the dry-ice particle that sprays by above-mentioned injection apparatus 40 evenly is ejected into above-mentioned removal object layer 12 full surfaces, and the depression or the be full of cracks that produce certain depths and area by removal object layer 12 surfaces that dry-ice particle impacted.
At this moment, pass through the above-mentioned depression or the be full of cracks that are taken place, remove object layer 12 and change, a part is then removed fully, exposes the backplane level 11 of removing object layer 12 belows.
The jet pipe 42 of above-mentioned injection apparatus 40 can be movably above-mentioned, also can be to dwindle to be provided with at interval and with stationary state to install, and can obtain identical effect.
After the dry-ice particle that sprays from above-mentioned jet pipe 42 impacted and removes object layer 12 surfaces, literizations and do not stay detritus at the removal object layer, and its volume sharply increases in the liter process made that to peel off effect more outstanding.
For the dry-ice particle that makes above-mentioned injection liter easily, above-mentioned dull and stereotyped 20 conditions such as temperature and pressure should be kept proper level.
Used dry-ice particle in the foregoing description, except dry-ice particle, risen the voltinism solids, also can obtain effect same by using other.
Secondly, shown in Fig. 2 c, remove object layer 12 surfaces and the impaired place substrate 10 in its surface moves to wet type device 50, use chemical agent that it is implemented wet-cleaned through dry ice blasting.
And, use the wet type of various chemical medicaments or dry type to remove (Wet/Dry strip), also can obtain same effect, impact and the removal object layer 12 of variation so long as can effectively remove through above-mentioned dry ice, its method is not limited.
Aforesaid substrate 10 moves to wet type device 50, finishes by dull and stereotyped 20 cylinder 21.
Move to of injection or the immersion of the substrate 10 of above-mentioned wet type device 50, remove object layer 12 by chemical agent.
At this moment, depression has taken place or has chapped and the generation upgrading in above-mentioned removal object layer 12 surfaces, and these depressions or be full of cracks, makes chemical agent and remove object layer 12 contacts area to increase.
Like this, cleaning area increases, and can remove fast, and can reduce the medicament use amount, removes process cost and reduces.
In addition, by reducing the use amount and the service time of toxic chemical substances such as potassium hydroxide, significantly reduce operating personnel and be exposed to time in the noxious material.
Fig. 2 d removes the schematic diagram after object layer 12 is removed fully for through above-mentioned cleaning.
[embodiment 2]
Fig. 4 is another example structure schematic diagram of the present invention's substrate board treatment.
As shown in the figure, the substrate board treatment among the present invention comprises: flat board 20, be provided with a plurality of cylinders 21, and need to remove the substrate of handling 10 to load; Dry-ice particle to the whole surface of removal object film that is loaded in the substrate on above-mentioned dull and stereotyped 20, sprays in injection portion 40; Dry ice particles supply unit 31, storage is also supplied with particle (Pellet) shape dry ice; Pulverizing portion 32, it is 0.5 to 3.0mm particle that the graininess dry ice that dry ice particles supply unit 31 is provided is ground into particle diameter; Injection portion 33 sprays through the dry-ice particle the pulverized jet pipe by above-mentioned injection apparatus 40 above-mentioned; Wet type device 50 carries out wet-cleaned to the removal object layer of the substrate 10 that sprays through dry-ice particle on above-mentioned dull and stereotyped 20; Exhaust portion 70, the carbon dioxide that the foreign material that produced on above-mentioned dull and stereotyped 20 are become with the dry-ice particle literization carries out exhaust; Control panel 60 is controlled above-mentioned various piece.
Pass through said structure, granular dry-ice particle is stored in the dry ice particles supply unit 31, in pulverizing portion 32 dry ice of storage is ground into the dry-ice particle with certain particle diameter then, and uses high pressure to purify air or nitrogen, spray from the jet pipe of above-mentioned injection apparatus 40.
By to removing object layer 12 jet surface dry-ice particles, upgrading takes place in removal object layer 12 surfaces of substrate, like this, can easily remove removing object layer 12 in the wet type device 50, its effect proves absolutely in the foregoing description 1, no longer applies here and states.
Literization takes place in the above-mentioned dry-ice particle of removing object layer 12 that impacts, and by the carbon dioxide of literization generation and the particulate that impacts the removal object layer 12 that produces, discharges from exhaust portion 70 in company with air-flow.
[embodiment 3]
In the foregoing description 1 and embodiment 2, dry ice supply unit 30 is accepted the dry ice of solid shape from the outside, to substrate 10 jet surface dry ice, also can be, liquid or gas shape carbon dioxide and carrier gas (Carrier gas) are provided in dry ice supply unit 30, in jet pipe 42, carbon dioxide are changed over solid then and spray.
Fig. 5 is the structural representation of another embodiment of the substrate board treatment among the present invention.
As shown in the figure, the dry ice supply unit 30 in the present invention's the substrate board treatment comprises: carbon dioxide supply source 34 and carrier gas supply source 35 that carbon dioxide and carrier gas are provided respectively; The carbon dioxide that is provided to above-mentioned carbon dioxide supply source 34 cools off, and is provided to the cooling device 36 of the jet pipe 42 of injection apparatus 40; Detect the temperature of above-mentioned jet pipe 42, and according to its result, the temperature control part 37 that above-mentioned cooling device 36 actions are controlled; Respectively the nebulizer gas pressure and the flow of above-mentioned carrier gas supply source 35 are controlled, and supplied to the pressure regulating part 38 and the flow-control portion 39 of above-mentioned jet pipe 42.
Below, the 26S Proteasome Structure and Function of the embodiment of the invention is elaborated.
Carbon dioxide supply source 34 is the container of storaging liquid carbon dioxide, and carrier gas supply source 35 purifies air or the container of carrier gas such as nitrogen for storing.
When the carbon dioxide that above-mentioned carbon dioxide supply source 34 is provided sprays through jet pipe,, in cooling device 36, carbon dioxide is cooled off and is provided to the jet pipe 42 of injection apparatus 40 in order to convert solid-state dry-ice particle easily to.
Simultaneously, the carrier gas in the carrier gas supply source 35 also supplies on the jet pipe 42 of injection apparatus 40, and in the carrier gas supply, by pressure regulating part 38 and flow-control portion 39 its pressure and flow is controlled.
Like this, accept the jet pipe 42 of carrier gas and carbon dioxide,, utilize adiabatic expansion, make carbon dioxide solidization, thereby generate dry-ice particle, spray this dry-ice particle and carrier gas then by its structure through cooling off.
Fig. 6 is the schematic cross-section of an embodiment of jet pipe 42 among the present invention.
As shown in the figure, when in above-mentioned jet pipe 42, accepting carbon dioxide and carrier gas and spraying dry-ice particle, the carbon dioxide that flows into from carbon dioxide inflow entrance 43 is phase-changed into dry-ice particle during through first spray nozzle part 45, and spray with the state of aerosol (aeroso1), and pass through above-mentioned first spray nozzle part 45 outsides by the carrier gas that carrier gas inflow entrance 44 flows into, and the aerosol of first spray nozzle part, 45 injections together together, sprays from second spray nozzle part 46.
Promptly, above-mentioned jet pipe 42 structures are, be provided with first spray nozzle part 45 in second spray nozzle part, 46 inboards, carbon dioxide by 45 injections of first spray nozzle part and pressurization, form the aerosol that contains dry-ice particle at second spray nozzle part 46 through adiabatic expansion, the carrier gas of this aerosol and inflow second spray nozzle part 46 is injected into substrate 10 together.
The spout of above-mentioned first spray nozzle part 45 and second spray nozzle part 46 is more young than flowing into, so can apply high pressure to carbon dioxide, like this, carbon dioxide carries out adiabatic expansion and is phase-changed into dry-ice particle.
The carbon dioxide of above-mentioned cooling changes through excess pressure in the multiple spray nozzle part structure of jet pipe 42, is phase-changed into dry-ice particle, and is ejected into substrate 10, and substrate 10 surfaces are handled.
Be provided with temperature sensor in the above-mentioned jet pipe 42, temperature control part 37 is controlled the operation of cooling device 36 according to the temperature detection result of said temperature sensor.That is, when the temperature of jet pipe 42 is design temperature when above, start cooling device 36 cooled carbon dioxides, promoting phase transition process, and jet pipe 42 temperature are lower than when setting temperature, then stop cooling device 36 operations, stop up with the jet that prevents jet pipe 42.
Above-mentioned design temperature is that solidfied material generates optimum temperature, promptly-10 ℃ between-100 ℃.
Said structure is the structure that dry-ice particle and carrier gas mix and spray in second spray nozzle part 46, and its nozzle velocity is relatively low.
This weak the cleaning is applicable to the camera lens class with jet pipe, charge coupled device (Charge CoupledDevice:CCD), the strong cleanings of usefulness such as CMOS (Complementary-Metal-Oxide-Semiconductor) camera chip might damage the precise part of cleaning object.
When above-mentioned precise part cleans, behind the injection dry ice, directly unload without wet type device 50.
[embodiment 4]
Fig. 7 is the cutaway view of another embodiment of above-mentioned jet pipe 42.
As shown in the figure, another embodiment of jet pipe 42 described in the present invention's the embodiment 3 comprises: first spray nozzle part 45, the carbon dioxide that flows into by carbon dioxide inflow entrance 43 is carried out pressurized jet, and generate dry-ice particle by adiabatic expansion; Second spray nozzle part 46, the carrier gas that will flow into by carrier gas inflow entrance 44 and mix and spray by the dry ice that first spray nozzle part 45 generates; The 3rd spray nozzle part 47, to the dry ice and the carrier gas of spraying by above-mentioned second spray nozzle part 46, and the carrier gas that enters from second spray nozzle part, 46 outsides mixes the back injection.
Above-mentioned second spray nozzle part 46 porch are provided with, and make carrier gas optionally flow into first path 48 of the second spray nozzle part inboard; Make carrier gas flow into second path 49 of the 3rd spray nozzle part 47 inboards.
Above-mentioned first spray nozzle part 45 and second spray nozzle part 46 have identical function with jet pipe 42 as shown in Figure 6, and in the 3rd spray nozzle part 47, second spray nozzle part 47 is sprayed things and mix and spray by the carrier gas that first path 48 flows into.By said structure, can prevent the i.e. phenomenon of the 3rd spray nozzle part 47 surface generation condensate water in jet pipe 42 surfaces, improved cleaning efficiency.
That is, can prevent that external environment condition from causing the carbon dioxide temperature in the jet pipe 42 to rise, carry out adiabatic expansion easily, thereby improved the production rate of dry-ice particle, improve cleaning efficiency.
[embodiment 5]
Fig. 8 is another example structure figure of jet pipe 42 described in the embodiment 3.
As shown in the figure, its structure comprises: first spray nozzle part 45, second spray nozzle part 46 and three spray nozzle part 47 identical with above-mentioned Fig. 7, and be provided with first path 48 of on the 3rd spray nozzle part 47, supplying with carrier gas and second spray nozzle part 49 from carrier gas to second spray nozzle part 46 that supply with.
Wherein, the port of export bore of second spray nozzle part 46 outwards begins to keep go-no-go from the lining, increases gradually then.
Second spray nozzle part, 46 ports of export have above-mentioned shape, and the aerosol that contains dry ice that is sprayed solidifies uncured aqueous carbon dioxide through adiabatic expansion once more.By this dual adiabatic expansion structure, can generate larger-size dry-ice particle, and the dry-ice particle quantity of spraying increases also, thereby can clean by force.
[embodiment 6]
Fig. 9 is another example structure figure of jet pipe 42 described in the foregoing description 3.
As shown in the figure, jet pipe 42 comprises: first spray nozzle part 45, carbon dioxide and the carrier gas that flows into by carbon dioxide inflow entrance 43 and carrier gas inflow entrance 44 to be mixed, and its inside has most adiabatic expansion structures, thereby can spray the aerosol that contains dry-ice particle; Second spray nozzle part 46, with above-mentioned first spray nozzle part 45 outsides across a space, and the injection thing of the carrier gas supplied with by this space and above-mentioned first spray nozzle part 45 mixed and sprays.
Above-mentioned first spray nozzle part, 45 1 ends are provided with carrier gas inflow entrance 44 and flow into for carrier gas, and along with the inflow of this carrier gas, carbon dioxide flows into from the carbon dioxide inflow entrance 43 of first spray nozzle part, 45 sides.
In above-mentioned first spray nozzle part 45, carrier gas is relative less with the diameter of the part that carbon dioxide mixes, and is provided with most adiabatic expansion structures from these part to the first spray nozzle part 45 ports of export.
That is, the part that part that diameter is big and diameter are little is interlaced, and diameter is ascending.Like this, in first spray nozzle part 45 by adiabatic expansion repeatedly, obtain more, the dry-ice particle that particle diameter is bigger, and the aerosol that contains this dry-ice particle at second spray nozzle part 46 with after carrier gas mixes, be ejected into substrate 10.
This structure had both improved insulation effect, can carry out repeatedly adiabatic expansion again, thereby improve cleaning performance.
[embodiment 7]
Figure 10 is the cutaway view of another embodiment of jet pipe 42 described in the foregoing description 3.
As shown in the figure, jet pipe 42 comprises: mixing tube 81, for carrier gas and carbon dioxide inflow and mixing; Crystallize into long tube 82, be connected above-mentioned mixing tube 81 1 ends, and have than the littler internal diameter of mixing tube 81 internal diameters; Playpipe 83 is connected above-mentioned long tube 82 1 ends that crystallize into, and quickens the growth of wash particle, and with this particle spraying to the surface of substrate 10.
Above-mentioned mixing tube 81, crystallize into being shaped as of long tube 82 and playpipe 83, internal diameter and external diameter keep certain straight tube shape separately for they.
The mixing tube 81 of this straight tube shape crystallizes into long tube 82 and playpipe 83 and compares with nozzle structure described in the foregoing description 3 to embodiment 6, and its processability is good, and manufacturing cost is also low.
Above-mentioned mixing tube 81 is provided with, the inflow entrance 11,12 that carbon dioxide and carrier gas are flowed into respectively.Above-mentioned inflow entrance 43,44 can be provided with one or more respectively.
The position that is provided with of above-mentioned inflow entrance 43,44 is not particularly limited, and is same as Fig. 8, and the pipeline of carrier gas inflow entrance 44 directions being arranged to crystallize into long tube 82 and playpipe 83 is consistent for good.
Carbon dioxide and carrier gas through mixing in mixing tube 81, under the pressure of carrier gas that flows into by inflow entrance 43,44 and carbon dioxide, inflow crystallizes in the long tube 82.
Above-mentioned to crystallize into long tube 82 diameters littler than above-mentioned mixing tube 81 diameters, and along with pressure increases, carbon dioxide is converted to particulate, and its particulate gradually grows up, to form dry-ice particle.
Though with the use carbon dioxide be liquid still gas shape and some difference, along with gas or fluid pressure increase, carbon dioxide becomes the solid shape, this can obtain confirming from the transformation curve of carbon dioxide.
Above-mentionedly crystallize into pressure in the long tube 82 greater than the pressure in the mixing tube 81, by this pressure differential, when using the carbon dioxide of liquid or cryogenic gas shape, the crystallization of generation dry ice.
The above-mentioned diameter that crystallizes into long tube 82 should be within 20% to 50% scope of mixing tube 81 diameters.
Above-mentioned aerosol that contains dry ice and the carrier gas that crystallizes in the long tube 82 is injected into the surface of substrate 10 by playpipe 83.
Wherein, the diameter of playpipe 83 be mixing tube 18 diameters 10% to 30% between, like this, can provide higher pressure, increase once more and be created on the above-mentioned dry-ice particle size that crystallizes in the long tube 82, and liquid or gasiform carbon dioxide is converted into solid.
In addition, can carry out high-voltage high-speed and spray, improve cleaning efficiency.
Above-mentioned mixing tube 81 and crystallizing between the long tube 82, and the internal diameter coupling part that crystallizes between long tube 82 and the playpipe 83 is the inclined plane, thereby can prevent the generation of eddy current.
[embodiment 8]
Figure 11 is an embodiment cutaway view of the foregoing description 3 described jet pipes 42.
As shown in the figure, be provided with first and second between the mixing tube 81 of straight tube shape and the playpipe 83 and crystallize into long tube 84,85.
Second diameter that crystallizes into long tube 85 is connected first of mixing tube 81 to crystallize into the diameter of long tube 84 little than above-mentioned.
By successively straight tube being coupled together with diameter order from large to small, can be to the pressurization of carbon dioxide and carrier gas mixture implementation phase property, promptly crystallize into long tube 84 and second and crystallize into and generate dry ice in the long tube 85 respectively, and increase this dry ice particle diameter first.
Include above-mentioned second in the aerosol and crystallize into the dry ice that generates and increase particle diameter in the long tube 85, and be injected into substrate 10 surfaces by playpipe 83.
At this moment, the pressure increase in the playpipe 83 causes dry ice to generate and particle diameter increases, and the increase of dry ice quantity and the increase of particle diameter can further improve cleaning efficiency.
Above-mentioned mixing tube 81 and first crystallizes between the long tube 84, first crystallize into that long tube 84 and second crystallizes between the long tube 85, the second internal diameter coupling part that crystallizes between long tube 85 and the playpipe 83 is the inclined plane, takes place to prevent eddy current.
[embodiment 9]
Figure 12 is an embodiment cutaway view of jet pipe 42 described in the foregoing description 3.
As shown in the figure, jet pipe 42 basic comprisings are identical with formation among the embodiment 7, in crystallizing into long tube 82, can the temperature of carbon dioxide and carrier gas mist or aerosol be detected.
As can be known, be cooled to of the increase of the cryogenic gas of the following temperature of three phase point in the transformation curve of general material, be phase-changed into solid along with pressure, and a little more than the liquid of three phase point also along with the increase of pressure, can be phase-changed into solid.
To cause phase transformation by pressurization, need come detected temperatures so can increase temperature sensor 86 with the temperature maintenance of carbon dioxide within the specific limits.
Temperature control part 37 in the foregoing description 3 according to 86 detected temperatures of said temperature sensor, is controlled the action of cooling device 36.
More than, preferred embodiment specific among the present invention is illustrated, but the present invention being not limited in the foregoing description, this area professional can carry out various changes to the present invention within the scope of notion of the present invention.

Claims (16)

1、一种基板处理装置,其特征在于,包括:1. A substrate processing device, characterized in that it comprises: 一装载部,用于装载形成有物质膜的基板;a loading part for loading the substrate on which the substance film is formed; 一干冰供给部,供给干冰粒子或二氧化碳;A dry ice supply part, supplying dry ice particles or carbon dioxide; 一喷射处理部,包括一个以上的喷管,向上述基板喷射由上述干冰供给部所提供的干冰粒子,或将二氧化碳固化后喷射到基板上,以对物质膜进行初步表面处理;A blasting treatment section, including more than one nozzle, sprays dry ice particles provided by the dry ice supply section to the substrate, or solidifies carbon dioxide and sprays it onto the substrate, so as to perform preliminary surface treatment on the material film; 一表面处理部,对上述经过初步表面处理的物质膜进行选择性的去除。A surface treatment part selectively removes the substance film that has undergone preliminary surface treatment. 2、如权利要求1所述基板处理装置,其特征在于:2. The substrate processing apparatus according to claim 1, characterized in that: 上述表面处理部对上述基板进行清洗或蚀刻处理,以去除物质膜。The surface treatment unit performs cleaning or etching treatment on the substrate to remove the substance film. 3、如权利要求1所述基板处理装置,其特征在于,上述干冰供给部包括:3. The substrate processing apparatus according to claim 1, wherein the dry ice supply unit comprises: 干冰颗粒供给部,储藏并供给颗粒状干冰;The dry ice pellet supply department stores and supplies granular dry ice; 粉碎部,对干冰颗粒供给部所提供的颗粒状干冰进行粉碎;The crushing part crushes the granular dry ice provided by the dry ice particle supply part; 喷射部,将上述粉碎部中经过粉碎的干冰粒子,通过上述喷射处理部进行喷射。The spraying part sprays the crushed dry ice particles in the crushing part through the blasting processing part. 4、如权利要求1所述基板处理装置,其特征在于,上述干冰供给部包括:4. The substrate processing apparatus according to claim 1, wherein said dry ice supply unit comprises: 提供二氧化碳的二氧化碳供给源;A carbon dioxide supply source that provides carbon dioxide; 提供载气的载气供给源;Provide a carrier gas supply source for the carrier gas; 对上述二氧化碳供给源所提供的二氧化碳进行冷却的冷却装置。A cooling device for cooling carbon dioxide supplied from the above-mentioned carbon dioxide supply source. 5、如权利要求4所述基板处理装置,其特征在于,还包括:5. The substrate processing apparatus according to claim 4, further comprising: 对从上述载气供给源供给到喷管的载气的压力和流量,进行控制的压力控制部及流量控制部。A pressure control unit and a flow rate control unit that control the pressure and flow rate of the carrier gas supplied from the carrier gas supply source to the nozzle. 6、如权利要求4所述基板处理装置,其特征在于,还包括:6. The substrate processing apparatus according to claim 4, further comprising: 检测上述喷射处理部的喷管温度,并根据喷管检测温度对冷却装置的动作进行控制的温度控制部。A temperature control unit that detects the nozzle temperature of the spray processing unit and controls the operation of the cooling device based on the temperature detected by the nozzle. 7、如权利要求1或4所述基板处理装置,其特征在于,上述喷射处理部的喷管包括:7. The substrate processing apparatus according to claim 1 or 4, wherein the nozzle of the above-mentioned spray processing part comprises: 喷嘴部,对二氧化碳进行一次以上的绝热膨胀,以生成干冰或增大干冰粒径;In the nozzle part, the adiabatic expansion of carbon dioxide is performed more than once to generate dry ice or increase the particle size of dry ice; 载气流入口,使上述经过绝热膨胀的干冰和载气混合;The carrier gas inlet is used to mix the adiabatically expanded dry ice with the carrier gas; 最终喷射口,将与上述载气混合的干冰喷射至基板表面。The final injection port sprays the dry ice mixed with the above-mentioned carrier gas onto the surface of the substrate. 8、如权利要求7所述基板处理装置,其特征在于:8. The substrate processing apparatus according to claim 7, characterized in that: 上述载气流入口中,通过位于上述喷嘴部外周面的路径,使载气流入,以防止喷嘴部中生成凝结水。In the carrier gas inlet, the carrier gas flows in through a path located on the outer peripheral surface of the nozzle portion, so that condensed water is prevented from being generated in the nozzle portion. 9、如权利要求1或4所述基板处理装置,其特征在于,上述喷射处理部的喷管包括:9. The substrate processing apparatus according to claim 1 or 4, wherein the spray pipe of the spray processing part comprises: 混合管,对载气和二氧化碳进行混合;Mixing tube for mixing carrier gas and carbon dioxide; 至少一个以上的结晶成长管,连接在上述混合管一端并与混合管相比,直径更小,而且其直径分阶段地减少,以生成干冰同时使该干冰成长;At least one crystal growth tube is connected to one end of the mixing tube and has a smaller diameter than the mixing tube, and its diameter decreases in stages, so as to generate dry ice and grow the dry ice at the same time; 喷射管,连接在上述结晶成长管一端,用于喷射干冰,并具有比上述结晶成长管的末端更小的直径。The injection tube is connected to one end of the above-mentioned crystallization growth tube, is used for spraying dry ice, and has a smaller diameter than the end of the above-mentioned crystallization growth tube. 10、如权利要求1所述基板处理装置,其特征在于,上述喷射处理部包括:10. The substrate processing apparatus according to claim 1, wherein the spray processing unit comprises: 随平板移动的移动架;Mobile frame that moves with the plate; 设在上述移动架,并对去除对象层喷射干冰粒子的一个以上的喷管。One or more nozzles for spraying dry ice particles on the layer to be removed are installed on the movable frame. 11、如权利要求10所述基板处理装置,其特征在于:11. The substrate processing apparatus according to claim 10, characterized in that: 上述喷管可顺着移动架进行直线往复移动。The above-mentioned spray pipe can be moved linearly and reciprocatingly along the moving frame. 12、如权利要求1所述基板处理装置,其特征在于:12. The substrate processing apparatus according to claim 1, characterized in that: 上述喷射处理部还包括,对初步表面处理过程中所产生的副产物进行排气的排气部。The blasting treatment unit further includes an exhaust unit for exhausting by-products generated during the preliminary surface treatment. 13、一种基板处理方法,其特征在于,包括:13. A substrate processing method, comprising: 装载阶段,装载形成有物质膜的基板;In the loading stage, the substrate on which the material film is formed is loaded; 前处理阶段,向上述装载的基板喷射干冰粒子,以对上述基板上的物质膜进行初步表面处理;In the pretreatment stage, dry ice particles are sprayed onto the above-mentioned loaded substrate to perform preliminary surface treatment on the material film on the above-mentioned substrate; 表面处理阶段,对上述经过初步表面处理的物质膜进行选择性去除。In the surface treatment stage, the above-mentioned substance film that has undergone preliminary surface treatment is selectively removed. 14、如权利要求13所述基板处理方法,其特征在于:14. The substrate processing method according to claim 13, characterized in that: 在上述表面处理阶段中,对上述基板进行清洗或蚀刻处理,以去除物质膜。In the above-mentioned surface treatment stage, the above-mentioned substrate is cleaned or etched to remove the substance film. 15、如权利要求13所述基板处理方法,其特征在于:15. The substrate processing method according to claim 13, characterized in that: 上述干冰粒子的粒径处于0.5mm至3.0mm之间。The particle size of the dry ice particles is between 0.5mm and 3.0mm. 16、如权利要求13所述基板处理方法,其特征在于:16. The substrate processing method according to claim 13, characterized in that: 上述干冰粒子是通过以粒子状态提供;或对外部提供的干冰块进行粉碎;或对二氧化碳经过绝热膨胀而获得。The above-mentioned dry ice particles are obtained by supplying in a particle state; or crushing dry ice cubes provided from outside; or adiabatically expanding carbon dioxide.
CN2005101346154A 2004-12-31 2005-12-13 Substrate processing device and processing method thereof Expired - Fee Related CN1796008B (en)

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KR1020040118311A KR100740827B1 (en) 2004-12-31 2004-12-31 Injection nozzle and cleaning system using the same
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KR10-2005-0049585 2005-06-10
KR1020050049585A KR100622287B1 (en) 2005-06-10 2005-06-10 Precision Parts Cleaning Nozzle
KR1020050049585 2005-06-10
KR1020050060565 2005-07-06
KR1020050060565A KR20070005304A (en) 2005-07-06 2005-07-06 Substrate Processing Apparatus and Method
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