CN1772828A - Antifouling Coating for marine nesh cage cover - Google Patents
Antifouling Coating for marine nesh cage cover Download PDFInfo
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- CN1772828A CN1772828A CN 200410068028 CN200410068028A CN1772828A CN 1772828 A CN1772828 A CN 1772828A CN 200410068028 CN200410068028 CN 200410068028 CN 200410068028 A CN200410068028 A CN 200410068028A CN 1772828 A CN1772828 A CN 1772828A
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- soluble resin
- water soluble
- capsaicine
- coating
- silicone oil
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Abstract
The antifouling coating for marine mesh cage cover is used for solving the problem of damaging life attachment. The antifouling coating is compounded with water solution of water soluble resin, organic silicon coupler, titania and zinc powder as well as capsaicine solution, silicone oil, superfine silica, zinc oxide, magnesium oxide and sodium silicate in certain weight proportion, and through mixing.
Description
Technical field
The present invention relates to the antifouling paint that cage netting prevents that marine fouling organism from adhering to.
Background technology
Usually stain control agents such as the copper of marine antifouling coating by discharging, tin, mercury, lead, forming around material has the concentration of poisons layer of toxic action to marine plant spore and marine animal larva, thereby reaches anti-fouling effect.These toxic agent such as organotins that play antifouling effect can cause the seawater water pollution, cause biomutation, jeopardize marine food chain, and marine ecology balance and human health are had potential harm.
A lot of in recent years non-harmful marine antifouling coatings of environment-friendly type have good anti-fouling effect in steel plate test, most of antifouling paint is applicable to the antifouling of Offshore Units such as boats and ships, harbour, buoy more.But, be used for then poor effect of cage netting.For example by 48% water soluble resin, 48% water, 1.0% organo-silicon coupling agent, 1.0% titanium dioxide, the preparation of 2.0% zinc powder antifouling paint, be used for the etting material after the shallow sea linked network is tested 2 months, the biological attachment area is more than 20%, the artifact bond area was more than 50% in 6 months, the artifact bond area reached 100% in 8 months, do not reach required antifouling requirement, at present, a great problem in the stained still cage culture of the etting management.
Summary of the invention
It is good that the technical issues that need to address of the present invention provide a kind of sticking power to the etting material, can avoid causing the seawater water pollution, and have the more long-acting environmental protection type anti-pollution paint that prevents that marine fouling organism from adhering to.
Technical scheme of the present invention adopts the water soluble resin aqueous solution, organo-silicon coupling agent, titanium dioxide, zinc powder, color stuffing ground and mixed and solution stirring blending is characterized in that also adding capsaicine liquid solution, silicone oil, superfine silicon dioxide, zinc oxide, magnesium oxide, sodium silicate in coating composition; Each composition weight percentage composition of coating is: capsaicine liquid solution 15.0-30.0%, water soluble resin 20.0-35.0%, water 20.0-35.0%, organo-silicon coupling agent 0.3-1.0%, silicone oil 0.3-1.0%, superfine silicon dioxide 0.5-2.0%, titanium dioxide 0.5-1.0%, zinc oxide 0.5-4.0%, magnesium oxide 0.5-2.5%, zinc powder 0.5-2.0%, sodium silicate 1.0-20.0%; Earlier superfine silicon dioxide, titanium dioxide, zinc oxide, magnesium oxide, zinc powder, sodium silicate ground and mixed are become color stuffing during modulation; The water soluble resin and the water blended water soluble resin aqueous solution add organo-silicon coupling agent and silicone oil auxiliary agent; In the aqueous solution of water soluble resin, progressively add oleoresin capsaicine liquid solution and ground color stuffing then, and fully stirring promptly becomes the antifouling paint that is suitable for the cage netting use.
The present invention has prepared the coating of different proportionings by coating composition, hang to produce between the net cage through brushing try net sheet and test in the test sea area, test duration 12 months, the biological attachment area is below 20%, show that the antifouling paint for preparing by the present invention can play the antifouling effect to cage netting preferably, solved a great problem in the cage culture management.
Embodiment
Embodiment one
The present invention adopts the water soluble resin aqueous solution, organo-silicon coupling agent, titanium dioxide, zinc powder, and adds oleoresin capsaicine liquid solution, silicone oil, superfine silicon dioxide, zinc oxide, light magnesium oxide, sodium silicate in coating composition; The weight percentage of each component is: oleoresin capsaicine liquid solution 24.0%, water soluble resin 30.0%, water 30.0%, organo-silicon coupling agent 0.5%, silicone oil 1.0%, superfine silicon dioxide 1.5%, titanium dioxide 1.0%, zinc oxide 3.5%, light magnesium oxide 2.5%, zinc powder 2.0%, sodium silicate 4.0%; Elder generation is with superfine silicon dioxide during modulation, titanium dioxide, zinc oxide, light magnesium oxide, zinc powder, the sodium silicate ground and mixed becomes color stuffing, the water soluble resin and the water blended water soluble resin aqueous solution add organo-silicon coupling agent and silicone oil auxiliary agent, in the aqueous solution of water soluble resin, progressively add oleoresin capsaicine liquid solution and ground color stuffing then, progressively add at this and to continue in process of capsaicine liquid solution and color stuffing to stir 2 hours, divides progressively to add and continue stirring for 10 times and promptly became the harmless antifouling paint that is applicable to Coating for marine nesh cage cover in 1 hour.
Embodiment two
The present invention adopts the water soluble resin aqueous solution, organo-silicon coupling agent, titanium dioxide, zinc powder, and adds oleoresin capsaicine liquid solution, silicone oil, superfine silicon dioxide, zinc oxide, light magnesium oxide, sodium silicate in coating composition; The weight percentage of each component is: oleoresin capsaicine liquid solution 28.0%, water soluble resin 30.0%, water 30.0%, organo-silicon coupling agent 0.8%, silicone oil 0.7%, superfine silicon dioxide 1.2%, titanium dioxide 0.6%, zinc oxide 3.0%, light magnesium oxide 2.0%, zinc powder 1.7%, sodium silicate 2.0%; Earlier superfine silicon dioxide, titanium dioxide, zinc oxide, light magnesium oxide, zinc powder, sodium silicate ground and mixed are become color stuffing, the water soluble resin and the water blended water soluble resin aqueous solution add organo-silicon coupling agent and silicone oil auxiliary agent, in the aqueous solution of water soluble resin, progressively add oleoresin capsaicine liquid solution and ground color stuffing then, progressively add at this and to continue in process of capsaicine liquid solution and color stuffing to stir 2 hours, divides progressively to add and continue stirring for 10 times and promptly became the harmless antifouling paint that is applicable to Coating for marine nesh cage cover in 1 hour.
Embodiment three
The present invention adopts the water soluble resin aqueous solution, organo-silicon coupling agent, titanium dioxide, zinc powder, and adds oleoresin capsaicine liquid solution, silicone oil, superfine silicon dioxide, zinc oxide, light magnesium oxide, sodium silicate in coating composition; The weight percentage of each component is: oleoresin capsaicine liquid solution 18.0%, water soluble resin 25.0%, water 30.0%, organo-silicon coupling agent 0.8%, silicone oil 0.3%, superfine silicon dioxide 1.5%, titanium dioxide 0.8%, zinc oxide 2.4%, light magnesium oxide 1.6%, zinc powder 1.6%, sodium silicate 18.0%; Earlier superfine silicon dioxide, titanium dioxide, zinc oxide, light magnesium oxide, zinc powder, sodium silicate ground and mixed are become color stuffing, the water soluble resin and the water blended water soluble resin aqueous solution add organo-silicon coupling agent and silicone oil auxiliary agent, in the aqueous solution of water soluble resin, progressively add oleoresin capsaicine liquid solution and ground color stuffing then, progressively add at this and to continue in process of capsaicine liquid solution and color stuffing to stir 2 hours, divides progressively to add and continue stirring for 10 times and promptly became the harmless antifouling paint that is applicable to Coating for marine nesh cage cover in 1 hour.
Coating of the present invention can carry out application with the painting brush brushing method, and coat-thickness is controlled at 100 μ m-150 μ m, and in the time of room temperature 16-25 ℃, do on 8 hours surfaces of paint film, and the complete drying time is 2 days.
The test etting of the antifouling paint brushing made from present method is hung in the test sea area and is produced between the net cage, hanging the degree of depth is 2～3m, keep the spacing about 1.5m between each experimental network sheet, test duration does not have marine organisms substantially and adheres in the time of 2 months, test duration in the time of 6 months the biological attachment area below 10%, test duration in the time of 12 months the biological attachment area below 20%, show that the antifouling paint for preparing by the present invention can play the antifouling effect to cage netting preferably, solved a great problem in the cage culture management.
Claims (4)
1, antifouling Coating for marine nesh cage cover, adopt the water soluble resin aqueous solution, organo-silicon coupling agent, titanium dioxide, zinc powder, color stuffing ground and mixed and solution stirring blending is characterized in that adding in the coating composition oleoresin capsaicine liquid solution, silicone oil, superfine silicon dioxide, zinc oxide, magnesium oxide, sodium silicate; The weight percentage of each component of coating is: oleoresin capsaicine liquid solution 15.0-30.0%, water soluble resin 20.0-35.0%, water 20.0-35.0%, organo-silicon coupling agent 0.3-1.0%, silicone oil 0.3-1.0%, superfine silicon dioxide 0.5-2.0%, titanium dioxide 0.5-1.0%, zinc oxide 0.5-4.0%, magnesium oxide 0.5-2.5%, zinc powder 0.5-2.0%, sodium silicate 1.0-20.0%; Earlier superfine silicon dioxide, titanium dioxide, zinc oxide, magnesium oxide, zinc powder, sodium silicate ground and mixed are become color stuffing during modulation; The water soluble resin aqueous solution adds organo-silicon coupling agent and silicone oil auxiliary agent; In the aqueous solution of water soluble resin, progressively add oleoresin capsaicine liquid solution then and ground color stuffing stirs into antifouling paint.
2, antifouling Coating for marine nesh cage cover according to claim 1, the weight percentage that it is characterized in that each component of coating is: oleoresin capsaicine liquid solution 24.0%, water soluble resin 30.0%, water 30.0%, organo-silicon coupling agent 0.5%, silicone oil 1.0%, superfine silicon dioxide 1.5%, titanium dioxide 1.0%, zinc oxide 3.5%, light magnesium oxide 2.5%, zinc powder 2.0%, sodium silicate 4.0%.
3, antifouling Coating for marine nesh cage cover according to claim 1, the weight percentage that it is characterized in that each component of coating is: oleoresin capsaicine liquid solution 28.0%, water soluble resin 30.0%, water 30.0%, organo-silicon coupling agent 0.8%, silicone oil 0.7%, superfine silicon dioxide 1.2%, titanium dioxide 0.6%, zinc oxide 3.0%, magnesium oxide 2.0%, zinc powder 1.7%, sodium silicate 2.0%.
4, antifouling Coating for marine nesh cage cover according to claim 1, the weight percentage that it is characterized in that each component of coating is: oleoresin capsaicine liquid solution 18.0%, water soluble resin 25.0%, water 30.0%, organo-silicon coupling agent 0.8%, silicone oil 0.3%, superfine silicon dioxide 1.5%, titanium dioxide 0.8%, zinc oxide 2.4%, light magnesium oxide 1.6%, zinc powder 1.6%, sodium silicate 18.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410068028 CN1772828A (en) | 2004-11-10 | 2004-11-10 | Antifouling Coating for marine nesh cage cover |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410068028 CN1772828A (en) | 2004-11-10 | 2004-11-10 | Antifouling Coating for marine nesh cage cover |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1772828A true CN1772828A (en) | 2006-05-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410068028 Pending CN1772828A (en) | 2004-11-10 | 2004-11-10 | Antifouling Coating for marine nesh cage cover |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1772828A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102187825A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and suspending anti-polluting test hanging net of metal woven net for net box |
| CN102187824A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for processing and suspending maritime anti-fouling test hanging net of metal stretched net |
| CN102187826A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and hanging suspending net for sea trial of netting cage antifouling paint |
| CN102187827A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for processing metallic chain link fence hanging net for marine anti-pollution tests and method for tying same |
| CN102584090A (en) * | 2012-01-18 | 2012-07-18 | 厦门理工学院 | Addition agent for preventing marine concrete from being corroded by marine fouling organism and preparation method thereof |
| CN102675946A (en) * | 2012-05-08 | 2012-09-19 | 江苏海上龙源风力发电有限公司 | Capsaicin antifouling paint for preventing marine organisms from growing in intertidal region and construction process thereof |
| CN103598126A (en) * | 2013-11-25 | 2014-02-26 | 中国水产科学研究院东海水产研究所 | Method for assembling aquaculture net between shores |
-
2004
- 2004-11-10 CN CN 200410068028 patent/CN1772828A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102187826B (en) * | 2010-03-01 | 2013-02-06 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and hanging suspending net for sea trial of antifouling paint of netting cage covering |
| CN102187824A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for processing and suspending maritime anti-fouling test hanging net of metal stretched net |
| CN102187826A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and hanging suspending net for sea trial of netting cage antifouling paint |
| CN102187827A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for processing metallic chain link fence hanging net for marine anti-pollution tests and method for tying same |
| CN102187825B (en) * | 2010-03-01 | 2012-11-21 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and suspending anti-polluting test hanging net of metal woven net for net box |
| CN102187827B (en) * | 2010-03-01 | 2012-08-22 | 中国水产科学研究院东海水产研究所 | Method for processing metallic chain link fence hanging net for marine anti-pollution tests and method for tying same |
| CN102187824B (en) * | 2010-03-01 | 2012-11-21 | 中国水产科学研究院东海水产研究所 | Method for processing and suspending maritime anti-fouling test hanging net of metal stretched net |
| CN102187825A (en) * | 2010-03-01 | 2011-09-21 | 中国水产科学研究院东海水产研究所 | Method for manufacturing and suspending anti-polluting test hanging net of metal woven net for net box |
| CN102584090B (en) * | 2012-01-18 | 2013-12-18 | 厦门理工学院 | Addition agent for preventing marine concrete from being corroded by marine fouling organism and preparation method thereof |
| CN102584090A (en) * | 2012-01-18 | 2012-07-18 | 厦门理工学院 | Addition agent for preventing marine concrete from being corroded by marine fouling organism and preparation method thereof |
| CN102675946A (en) * | 2012-05-08 | 2012-09-19 | 江苏海上龙源风力发电有限公司 | Capsaicin antifouling paint for preventing marine organisms from growing in intertidal region and construction process thereof |
| CN102675946B (en) * | 2012-05-08 | 2016-12-14 | 江苏海上龙源风力发电有限公司 | The capsaicin anti-fouling paint of the anti-marine growth in Intertidal zone and construction technology thereof |
| CN103598126B (en) * | 2013-11-25 | 2015-01-14 | 中国水产科学研究院东海水产研究所 | Method for assembling aquaculture net between shores |
| CN103598126A (en) * | 2013-11-25 | 2014-02-26 | 中国水产科学研究院东海水产研究所 | Method for assembling aquaculture net between shores |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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