CN1765836B - Ceramic glaze with metal sense of reality - Google Patents
Ceramic glaze with metal sense of reality Download PDFInfo
- Publication number
- CN1765836B CN1765836B CN 200510037052 CN200510037052A CN1765836B CN 1765836 B CN1765836 B CN 1765836B CN 200510037052 CN200510037052 CN 200510037052 CN 200510037052 A CN200510037052 A CN 200510037052A CN 1765836 B CN1765836 B CN 1765836B
- Authority
- CN
- China
- Prior art keywords
- glaze
- screen printing
- ceramic
- product
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
- C03C3/105—Glass compositions containing silica with 40% to 90% silica, by weight containing lead containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a ceramic glaze with metal texture effect, which comprises the basic metal surface glaze and the cover-printing glaze, both with constituents as: SiO2 5-60%, Al2O33-50%, P2O5 3-50%, CaO 0.5-20%, Fe2O3 0-50%, Na2O 0-30%, ZrO2 0-50%, BaO 0-50%, PbO 0-30%, and ZnO 0-30%. Wherein, the said glazes can has same or different said constituents. The product has various color, well quality, strong mechanical properties and high stability.
Description
Technical field
The present invention relates to the technical field of ceramic production technology and products innovation, the glaze that a kind of pottery is used specifically relates to have the using method of the glaze preparation pottery of metal-like effect.
Background technology
The existing ceramic product that possesses technology content, it generally all is to adopt ceramic glaze to modify processing on the surface, and metal glaze belongs to more special product, except that presenting at surface energy the different metal gloss, the printing of can arranging in pairs or groups shows other and plants the style product, as series modelled after an antique, effects such as imitative stone material make ceramic tile effect field more colourful.For considering that this product can be in the general usefulness of production line, convenience is simple and easy again, does not need to put before interpolation equipment, and the production line of selecting present brick modelled after an antique and vitreous brick is main, and can produce in simple glazing mode is principle, with regard to positive metal-lustrous glaze of this emulation thereby birth.Though also the someone imagined the glaze of multiple function, as luminescent glaze, application number 99123083, the applying date are that December 15, denomination of invention in 1999 are the patent application of luminescent glaze, and this light-accumulating luminescent glaze is made up of different kinds of ions activated long after glow luminous material and basic flux.The weight ratio of long after glow luminous material and basic flux is: 45-2% can make luminescent ceramic, luminescent enamel and fluorescent glass goods than 55-98% with this luminescent glaze, has illumination effect, but can't embody the effect of metal-like equally.
Summary of the invention
The objective of the invention is to products innovation, increase existing ceramic product usability, a kind of market frontier that has is provided, the color variation, glaze quality is good, and mechanical property is strong, the preparation method of the ceramic glaze with metal-like that chemical stability is high.
Ceramic glaze preparation method with metal-like of the present invention is to be made of with covering screen printing glaze two portions underlying metal cover-coat enamel or underlying metal cover-coat enamel, and the component of basis overglaze and covering screen printing glaze is as follows: SiO
25-60% Al
2O
33-50% P
2O
53-50% CaO 0.5-20% Fe
2O
30-50% Na
2O 0-30% ZrO
20-50% BaO 0-50% PbO 0-30% ZnO 0-30%; Basis overglaze and cover screen printing glaze and can adopt identical or different above-mentioned component to prepare wherein sprays the underlying metal cover-coat enamel on the ceramic semi-finished product surface earlier or after covering screen printing glaze again, burns till to get final product.
When above-mentioned preparation, carry out ball milling after adding the CMC of 0.5-1%, increase the glaze viscosity, tail over and be controlled at≤1g/100ml/325mesh.
The present invention adopts the characteristic of above-mentioned prescription to be:
1, product surface has metalluster texture, has decorative effect preferably;
2, basis overglaze that can be by above-mentioned prescription and the collocation that covers screen printing glaze various combination and different ingredients and different deals can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc.;
3, adopt its glaze quality of product of above-mentioned prescription and technology good, mechanical property is strong, the chemical stability height;
4, the product after the glazing can carry out revenue stamp process equally, makes product more rich and varied; For considering the product usability, wall ground can be shared, so increase printing again at the metal glaze, reaches wear-resisting effect, makes the use field of metal glaze more extensive.
Embodiment
The present invention can be according to the collocation of various combination with different ingredients and different deals, can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc., below be example with the gold look: with the basis overglaze prescription is SiO
220% Al
2O
317% P
2O
510%CaO 5% Fe
2O
310% Na
2O 20% ZrO
2It is 1.5g/ml that 10% BaO5% PbO, 1% ZnO 2% is deployed into proportion, at 30 * 30cm
2The heavy 30-40g of ceramic tile face glazing.
Again the covering screen printing glaze of same recipe being deployed into proportion is 1.5g/ml, at above-mentioned 30 * 30cm
2The heavy 10-20g of ceramic tile face glazing; Burn till and promptly form the gold color and luster.
Above-mentioned covering screen printing glaze also can not need be prepared, and directly executes basis overglaze and burns till and get final product.
Claims (1)
1. glaze with metal-like of a use prepares the method for pottery, it is characterized in that, at first prepares the underlying metal cover-coat enamel and covers screen printing glaze, underlying metal cover-coat enamel and to cover the chemical composition of screen printing glaze as follows: SiO
220%Al
2O
317%P
2O
510%CaO 5%Fe
2O
310%Na
2O20%ZrO
210%BaO5%PbO 1%ZnO 2%; Carry out ball milling after adding the CMC of 0.5-1% again, tail over and be controlled at≤the 1g/100ml/325 order; The underlying metal cover-coat enamel is inserted the ceramic semi-finished product surface, and then coat the covering screen printing glaze, burn till and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510037052 CN1765836B (en) | 2005-09-07 | 2005-09-07 | Ceramic glaze with metal sense of reality |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510037052 CN1765836B (en) | 2005-09-07 | 2005-09-07 | Ceramic glaze with metal sense of reality |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1765836A CN1765836A (en) | 2006-05-03 |
| CN1765836B true CN1765836B (en) | 2010-05-12 |
Family
ID=36741982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510037052 Expired - Fee Related CN1765836B (en) | 2005-09-07 | 2005-09-07 | Ceramic glaze with metal sense of reality |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1765836B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101265941B1 (en) * | 2010-11-30 | 2013-05-21 | 한국세라믹기술원 | Manufacturing method of glaze |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101148369B (en) * | 2006-09-20 | 2010-06-23 | 毛海燕 | Glaze material with metal texture for ceramic and ceramic prepared from the same |
| CN100410197C (en) * | 2007-02-02 | 2008-08-13 | 南安协进建材有限公司 | Method for producing metal enamel |
| CN101880178B (en) * | 2010-07-13 | 2012-03-28 | 广东道氏技术股份有限公司 | Ceramic glazed tile with gold metal effect and preparation method thereof |
| CN102515865B (en) * | 2011-12-14 | 2014-02-05 | 广东长城集团股份有限公司 | Glaze with golden luster and preparation method thereof |
| CN105110643A (en) * | 2015-07-24 | 2015-12-02 | 福建省德化环宇陶瓷有限公司 | Formula for metal glaze with high-gloss copper golden effect, preparation and usage method |
| CN105440796A (en) * | 2015-12-10 | 2016-03-30 | 广东道氏技术股份有限公司 | Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof |
| CN105646009B (en) * | 2016-02-23 | 2018-01-09 | 中国科学院上海硅酸盐研究所 | A kind of composite decoration glaze prepared using plant ass as raw material and preparation method thereof |
| CN110357429A (en) * | 2019-08-09 | 2019-10-22 | 信益陶瓷(中国)有限公司 | A kind of metal-like Imitation Rock Porcelain Tiles and preparation method thereof |
| CN111499396B (en) * | 2020-04-27 | 2022-04-01 | 德清诺贝尔陶瓷有限公司 | Metal texture porcelain plate with prominent bright/matte contrast |
| CN111689759A (en) * | 2020-06-29 | 2020-09-22 | 河北岳如信息科技有限公司 | Ceramic product with metallic bronze wear-resistant glaze and preparation method thereof |
| CN111792844B (en) * | 2020-08-11 | 2022-05-27 | 鲁山花瓷股份有限公司 | Gold glaze material and glazing method thereof |
| CN115340414B (en) * | 2022-10-18 | 2023-03-24 | 陶丽西(苏州)陶瓷釉色料有限公司 | Metal particle for ceramic tile and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5393714A (en) * | 1992-12-30 | 1995-02-28 | Ferro Italia S.R.L. | Free-flowing, chemically resistant color granulates, their preparation and use |
-
2005
- 2005-09-07 CN CN 200510037052 patent/CN1765836B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5393714A (en) * | 1992-12-30 | 1995-02-28 | Ferro Italia S.R.L. | Free-flowing, chemically resistant color granulates, their preparation and use |
Non-Patent Citations (4)
| Title |
|---|
| 刘强.所甲基纤维在釉料中的使用.陶瓷工程 3.2000,(3),32-33. |
| 刘强.所甲基纤维在釉料中的使用.陶瓷工程 3.2000,(3),32-33. * |
| 李晓池等.金光釉产生金黄色金属光泽的机理研究.西安科技学院学报24 2.2004,24(2),193-195. |
| 李晓池等.金光釉产生金黄色金属光泽的机理研究.西安科技学院学报24 2.2004,24(2),193-195. * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101265941B1 (en) * | 2010-11-30 | 2013-05-21 | 한국세라믹기술원 | Manufacturing method of glaze |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1765836A (en) | 2006-05-03 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Foshan Mingzhao Technology Development Co., Ltd. Assignor: Mao Haiyan Contract record no.: 2012440000281 Denomination of invention: Ceramic glaze with metal sense of reality Granted publication date: 20100512 License type: Exclusive License Open date: 20060503 Record date: 20120601 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100512 Termination date: 20200907 |