CN1739820A - Aerosol fire extinguishing agent - Google Patents
Aerosol fire extinguishing agent Download PDFInfo
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- CN1739820A CN1739820A CN 200510105449 CN200510105449A CN1739820A CN 1739820 A CN1739820 A CN 1739820A CN 200510105449 CN200510105449 CN 200510105449 CN 200510105449 A CN200510105449 A CN 200510105449A CN 1739820 A CN1739820 A CN 1739820A
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- aerosol
- fire extinguishing
- extinguishing agent
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- aerosol fire
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Abstract
The aerosol fire extinguishing agent consists of strontium nitrate as oxidant 55-70 wt%, reductant 20-30 wt%, and additive 10-15 wt%. The present invention has raised safety and the insulating performance of the burning product of the fire extinguishing agent. The aerosol fire extinguishing agent has hexamethylene tetraamine as absorbent added into the recipe to absorb the nitrogen oxide produced while the aerosol fire extinguishing agent burns, acting for detoxicating and purifying of the aerosol burning product.
Description
Technical field
The present invention relates to a kind of aerosol fire extinguishing agent, especially a kind of pyrotechnics type aerosol extinguishing agent that can be used for electric equipment.
Background technology
The technology that produces the aerosol fire-extinguishing product with the burning form more and more is subjected to people's attention; and produced the patent achievement of some this respects in succession; as CN97110882.X patent " the aerocolloidal composition and method of making the same of the formation that is used to put out a fire "; the ZL02119648.6 patent " is applicable to the aerosol without toxicity and corrosion extinguishing chemical of electric equipment " etc.; but the oxidant in these aerosol composition prescriptions all contains potassium nitrate; be equipped with phenolic resins and dicyandiamide etc. again and form fire-extinguishing composite; can produce the very strong potassium oxide particulate of a large amount of hygroscopicity during this composition burn; when particulate is deposited in protected equipment surface; can form the very strong potassium hydroxide drop of corrosivity by the airborne moisture of very fast absorption; equipment surface is caused corrosion; simultaneously because drop has strong basicity, can form conductive membrane and cause the electronic equipment circuit to be short-circuited and destroyed.Stability and security meeting are affected during for its burning of the aerosol fire-extinguishing agent prescription that contains guanidine nitrate, because guanidine nitrate is a kind of alternative explosive, inflammable, at high temperature can decompose and explode, mix to be heated also can set off an explosion with the nitrate combustibles, this just greatly threatens the safety in utilization of aerosol fire-fighting equipment.
Summary of the invention
The aerosol fire extinguishing agent that the purpose of this invention is to provide a kind of safe and reliable, nonhazardous that can be used for that the electric equipment place uses.
The present invention is achieved like this, hundred parts of ratios of the composition weight of extinguishing chemical are strontium nitrate 55～70%, reducing agent 20～30%, additive 10～15%, reducing agent comprises fuel and foaming agent, and fuel mainly contains carbon dust, phenolic resins, and foaming agent mainly contains dicyandiamide; Additive comprises combustionregulator and sterilizing and purifying agent, combustionregulator is selected the potassium ferricyanide for use, the mixture of any ratio of one or both in the potassium hyperchlorate, hexa is selected in the sterilizing and purifying agent for use, oxidant strontium nitrate and fuel interaction generate the aerosol based on the inert gas material, play the fire extinguishing effect.Combustionregulator plays catalytic action in fact, be used to improve the burning capacity of this extinguishing chemical, make it have predetermined burn rate, thereby improve the conversion ratio of aerosol composition, the sterilizing and purifying agent then is in order to absorb the nitrogen oxide in the aerosol product, to make it safer harmless nontoxic.
The present invention is a kind of inhibition composition, is made up of oxidant, reducing agent, additive, and oxidant is a strontium nitrate; Its content is up to 55%～70%, do not contain potassium nitrate and guanidine nitrate, the insulating properties of the security when having improved the aerosol extinguishing agent burning and the aerosol product of generation, add hexa in the prescription as absorbent, the nitrogen oxide that produces in the time of can absorbing the aerosol extinguishing agent burning plays the sterilizing and purifying effect to aerosol product.
The specific embodiment
Embodiment 1
Strontium nitrate: 55～70%
Phenolic resins: 5～15%
Dicyandiamide: 3～8%
Hexa: 5～12%
Carbon dust: 5～12%
By the aerosol extinguishing agent that this example formulations is manufactured, it is good to have a fire extinguishing effectiveness, does not have corrosion, no electric spark phenomenon, the nothing phenomenon of detonating, and avirulence is applicable to the electrical equipment place.
Embodiment 2
On the basis of embodiment 1, add the performance improver potassium ferricyanide, can be through obtaining a kind of combustion speed aerosol extinguishing agent faster.
Strontium nitrate: 55～70%
Phenolic resins: 5～10%
Dicyandiamide: 0～10%
Hexa: 4～10%
The potassium ferricyanide: 0～8%
Carbon dust: 5～12%
This prescription aerosol extinguishing agent has all advantages of example 1, and burning velocity is very fast simultaneously, is suitable for bigger powder column (box) technology.
Embodiment 3
On the basis of embodiment 2, add a certain amount of potassium hyperchlorate as catalyst, combustion speed will further improve.
Strontium nitrate: 55～70%
Phenolic resins: 5～10%
Potassium hyperchlorate: 0～5%
Dicyandiamide: 0～5%
Hexa: 4～10%
The potassium ferricyanide: 0～8%
Carbon dust: 5～12%
This prescription aerosol has all advantages of example 1, and burning velocity is faster, and fire extinguishing effectiveness is higher.
The different proportionings of the aerosol extinguishing agent component that the present invention selects and the performance of other typical aerosol extinguishing agents relatively see the following form.
| Composition composition title and performance | Experiment numbers and each component thereof measure degree (%) fully | |||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | ||
| Potassium nitrate | 68 | 25 | 10 | 10 | ||||
| Strontium nitrate | 35 | 45 | 50 | 55 | 70 | 65 | ||
| Guanidine nitrate | 30 | 35 | ||||||
| The potassium ferricyanide | 5 | |||||||
| Hexa | 5 | 5 | 4 | 4 | ||||
| Dicyandiamide | 7 | 30 | 5 | 5 | 5 | |||
| Carbon dust | 6 | 5 | ||||||
| Phenolic resins | 10 | 5 | 5 | 5 | 6 | 6 | 6 | |
| Other material | 5 | 0 | 5 | 5 | 23 | 14 | 19 | |
| Aerosol deposition thing characteristic | PH value | 14 | 13 | 12 | 12 | 8 | 8 | 8 |
| Corrosivity | Heavy corrosion | Heavy corrosion | General corrosion | General corrosion | There is not corrosion | There is not corrosion | There is not corrosion | |
| Insulaion resistance M Ω | 0.05 | 15 | 25 | 28 | More than 200 | More than 200 | More than 200 | |
| The megger test | Spark is arranged | Spark is arranged | Spark is arranged | Spark is arranged | No-spark | No-spark | No-spark | |
| Minimum fire-fighting dose g/M 3 | 40 | 60 | 120 | 100 | 120 | 120 | 120 | |
| Toxicity test (small white mouse) | Do not have death, have no adverse reaction | Do not have death, have no adverse reaction | Dead 2 | Dead 7 | Do not have death, have no adverse reaction | Do not have death, have no adverse reaction | Do not have death, bad reaction is arranged | |
| Detonation sensitivity | Do not have | Have | Have | Do not have | Do not have | Do not have | Do not have | |
Annotate: 1, aerosol deposition thing test is that the red copper test piece of the PVC testing of materials model of 100 * 100 * 1mm and 25 * 80 * 1mm and aluminium test piece and brass breadboard are placed on 1m
3Experiment cabinet in, use 1m
3The test of minimum aerosol fire-extinguishing consumption, aerosol discharges the back and keeps 20min to observe.
(1), pH value test is that moistening pH value test paper is stained with the pH value that shows behind the aerosol deposition thing on the PVC plate, 7 be neutral, is alkaline greater than 7, numeral is big more, alkalescence is strong more; Less than 7 is acid, and numeral is more little, and acidity is strong more.
(2), corrosivity is meant the corrosivity situation of aerosol to copper coin, aluminium sheet.Green or blue corrosion pit does not appear in red copper, brass test piece surface, and corrosion pits such as whiting do not appear in aluminium test piece surface, then thinks general corrosion, if also have metallic luster, then thinks and does not have corrosion; The stain if blue green Staining or aluminium sample board turn white is then thought seriously corroded.
(3), the test of insulaion resistance and megger is the two poles of the earth with 500V megohm meter, the result that will test out behind the maintenance 30min in relative humidity with the PVC plate of aerosol deposition thing at a distance of 10mm greater than 85% environment, numerical value is big more, insulating properties is good more, insulaion resistance is then thought electrical equipment is not had damageability greater than 30M Ω.Then insulation effect is very poor to produce spark during megger between the two poles of the earth, and no-spark thinks that then insulation effect is good.
2, fire-fighting dose is meant 1m recently
3The go out minimum foamite amount of category-B gasoline fire of experiment cabinet.
3, toxicity test is the result who the fire extinguishing smog that 10 small white mouses (5 mothers of 5 public affairs) place minimum foamite amount to produce is placed 20 minutes.
4, detonation sensitivity is meant the aerosol extinguishing agent of minimum foamite amount, is pressed into the powder column of 30, and density is at 1.2g/m
3More than, with the result of No. 8 military blasting cap initiations.Dividing does not have the phenomenon of detonating, partly detonates and the three kinds of phenomenons of detonating is arranged.
From the result of performance comparison, the insulaion resistance that does not contain potassium nitrate is big, no electric spark phenomenon, non-corrosiveness; The nothing that does not the contain guanidine nitrate phenomenon of detonating; The small white mouse that contains hexa does not have death and bad reaction phenomenon.
Claims (3)
1, a kind of aerosol fire extinguishing agent is characterized in that hundred parts of content of composition weight of extinguishing chemical are: strontium nitrate 55%～70%, reducing agent 20%～30%, additive 10%～15%.
2, aerosol fire extinguishing agent according to claim 1 is characterized in that reducing agent comprises fuel and foaming agent, and fuel is carbon dust, phenolic resins, and foaming agent is a dicyandiamide.
3, aerosol fire extinguishing agent according to claim 1, it is characterized in that additive comprises combustionregulator and sterilizing and purifying agent, combustionregulator is selected the mixture of one or both any ratios in the potassium ferricyanide, the potassium hyperchlorate for use, and hexa is selected in the sterilizing and purifying agent for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510105449 CN1739820A (en) | 2005-09-28 | 2005-09-28 | Aerosol fire extinguishing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510105449 CN1739820A (en) | 2005-09-28 | 2005-09-28 | Aerosol fire extinguishing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1739820A true CN1739820A (en) | 2006-03-01 |
Family
ID=36092440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510105449 Pending CN1739820A (en) | 2005-09-28 | 2005-09-28 | Aerosol fire extinguishing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1739820A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100435891C (en) * | 2007-07-10 | 2008-11-26 | 陕西坚瑞化工有限责任公司 | Fire extinguishing aerosol composition suitable for use for electric power equipment |
| WO2009006767A1 (en) | 2007-07-10 | 2009-01-15 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol for common electric appliance |
| WO2009006765A1 (en) | 2007-07-10 | 2009-01-15 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol for precision electric appliance |
| WO2012034493A1 (en) | 2010-09-16 | 2012-03-22 | 陕西坚瑞消防股份有限公司 | Composition generating fire extinguishing substance through chemical reaction of ingredient at high temperature |
| CN102836517A (en) * | 2012-09-28 | 2012-12-26 | 陕西坚瑞消防股份有限公司 | Aerosol propellant |
| CN102949799A (en) * | 2011-08-16 | 2013-03-06 | 陕西坚瑞消防股份有限公司 | Novel fire-extinguishing composition |
| CN103990246A (en) * | 2014-04-25 | 2014-08-20 | 钟远 | Extinguishing agent, engine compartment extinguishing apparatus using it, and engine compartment extinguishing method |
| CN104368118A (en) * | 2014-11-11 | 2015-02-25 | 安徽创业机电设备有限公司 | Aerosol fire-extinguishing agent and preparation method thereof |
| CN109758708A (en) * | 2019-03-14 | 2019-05-17 | 林海龙 | A kind of environment-friendly type insulated extinguishing chemical and preparation method thereof |
| CN111821642A (en) * | 2019-07-05 | 2020-10-27 | 深圳市源烯科技有限公司 | Low-residue high-insulation-strength aerosol fire extinguishing composition |
| WO2024212281A1 (en) * | 2023-04-14 | 2024-10-17 | 湖北及安盾消防科技有限公司 | High-insulation and low-corrosion vaporization propellant for non-pressure-storage perfluorohexanone fire-extinguishing apparatus and preparation method |
-
2005
- 2005-09-28 CN CN 200510105449 patent/CN1739820A/en active Pending
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2481138C2 (en) * | 2007-07-10 | 2013-05-10 | ШААНЬСИ Джей Энд Ар ФАЙР ФАЙТИНГ КО., ЛТД | Fire-extinguishing aerosol composition for precise electric appliances |
| WO2009006767A1 (en) | 2007-07-10 | 2009-01-15 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol for common electric appliance |
| WO2009006766A1 (en) | 2007-07-10 | 2009-01-15 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol for heavy-current electric appliance |
| WO2009006765A1 (en) | 2007-07-10 | 2009-01-15 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol for precision electric appliance |
| US8097667B2 (en) | 2007-07-10 | 2012-01-17 | Shaanxi J&R Fire Fighting Co., Ltd. | Fire-extinguishing aerosol composition for heavy current electric apparatuses |
| CN100435891C (en) * | 2007-07-10 | 2008-11-26 | 陕西坚瑞化工有限责任公司 | Fire extinguishing aerosol composition suitable for use for electric power equipment |
| US8231801B2 (en) | 2007-07-10 | 2012-07-31 | Shaanxi J&R Fire Fighting Co., Ltd. | Fire-extinguishing aerosol composition for precision electric appliances |
| US8652346B2 (en) | 2007-07-10 | 2014-02-18 | Shaanxi J&R Fire Fighting Co., Ltd | Fire-extinguishing aerosol composition for common electric apparatuses |
| US8871110B2 (en) | 2010-09-16 | 2014-10-28 | Xi'an J&R Fire Fighting Equipment Co., Ltd. | Composition generating fire extinguishing substance through chemical reaction of ingredients at high temperature |
| WO2012034493A1 (en) | 2010-09-16 | 2012-03-22 | 陕西坚瑞消防股份有限公司 | Composition generating fire extinguishing substance through chemical reaction of ingredient at high temperature |
| CN102949799A (en) * | 2011-08-16 | 2013-03-06 | 陕西坚瑞消防股份有限公司 | Novel fire-extinguishing composition |
| CN102949799B (en) * | 2011-08-16 | 2015-07-22 | 西安坚瑞安全应急设备有限责任公司 | Novel fire-extinguishing composition |
| CN102836517A (en) * | 2012-09-28 | 2012-12-26 | 陕西坚瑞消防股份有限公司 | Aerosol propellant |
| CN103990246A (en) * | 2014-04-25 | 2014-08-20 | 钟远 | Extinguishing agent, engine compartment extinguishing apparatus using it, and engine compartment extinguishing method |
| CN104368118A (en) * | 2014-11-11 | 2015-02-25 | 安徽创业机电设备有限公司 | Aerosol fire-extinguishing agent and preparation method thereof |
| CN109758708A (en) * | 2019-03-14 | 2019-05-17 | 林海龙 | A kind of environment-friendly type insulated extinguishing chemical and preparation method thereof |
| CN111821642A (en) * | 2019-07-05 | 2020-10-27 | 深圳市源烯科技有限公司 | Low-residue high-insulation-strength aerosol fire extinguishing composition |
| WO2024212281A1 (en) * | 2023-04-14 | 2024-10-17 | 湖北及安盾消防科技有限公司 | High-insulation and low-corrosion vaporization propellant for non-pressure-storage perfluorohexanone fire-extinguishing apparatus and preparation method |
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