CN1690009A - Super-light hard heat insulating plate and its production process - Google Patents
Super-light hard heat insulating plate and its production process Download PDFInfo
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- CN1690009A CN1690009A CN 200410022386 CN200410022386A CN1690009A CN 1690009 A CN1690009 A CN 1690009A CN 200410022386 CN200410022386 CN 200410022386 CN 200410022386 A CN200410022386 A CN 200410022386A CN 1690009 A CN1690009 A CN 1690009A
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Abstract
The present invention is super hard heat insulating plate and its production process. The super hard heat insulating plate consists of inorganic reinforcing material in 1 weight portions, compound high temperature adhesive in 0.1-3 weight portions, light aggregate in 5-15 weight portions and active agent in 0.01-0.5 weight portions. The inorganic reinforcing material consists of magnesium silicate and brucite in certain ratio. The compound high temperature adhesive consists of aluminum dihydrogen phosphate and water glass in certain ratio. The active agent consists of penetrant T and surfactant NNO in certain ratio. The super hard heat insulating plate has light weight, high strength, high incombustibility, etc. and is especially suitable for use as sandwiched material in heat insulating sandwich color steel plate.
Description
Affiliated technical field: the invention belongs to building material field, be specifically related to hard heat-insulated sheet material of a kind of ultralight and production technique thereof.
Background technology: in lagging material, expanded perlite product is of a great variety at present, and perlitic caking agent is: materials such as water glass, cement, pitch, phosphoric acid salt, goods exist unit weight bigger, generally all are higher than 180kg/m
3, yet there are no unit weight and be lower than 130kg/m
3Hard heat-insulated plate; Limit the Application Areas of expanded perlite product, particularly be applied to the heat insulating sandwich specially (require unit weight little and for non-fire material) of color steel insulation sandwich board.The document of relevant expanded perlite thermal-nsulation production of articles is a lot, as: " development research of building roof thermal insulation thermal insulation board " literary composition provides the technology of the bonding pearlstone making sheet of urea-formaldehyde resin in 2000 the 6th phases " investigation of materials ", product adopts hot pressing, time is: 25~30 minutes, product unit weight was 180~220kg/m
3, use temperature is lower; And for example: CN1415568A discloses with the bonding pearlstone of high-alumina cement and has made ceiling board, and unit weight is bigger, has limited its Application Areas; CN1161944A discloses the used pearlite composite heat-insulation plate of a kind of building roof, is formed through the moulding that is mixed by magnesium oxide, magnesium chloride, pearlstone, sawdust and material waters such as other auxiliary material such as flyash, and material unit weight is also bigger; CN1424274 discloses with sepiolite, pearlstone, caking agent and has mixed production insulation heat-insulating plate, material unit weight 170~230kg/m
3Learn that from the inquiry of related data also not producing unit weight at present is lower than 130kg/m
3The report of pearlstone, so, produce unit weight and be lower than 130kg/m
3Perlite sheet material can enlarge the Application Areas of pearlite thermal insulation product.
The objective of the invention is in order to overcome the defective of prior art, for the public provides a kind of unit weight light, intensity is good, fire-fighting grade height, the material combustion performance reaches does not fire the A level, is specially adapted to do the hard heat-insulated sheet material of ultralight and the production technique thereof of the heat insulating sandwich specially of color steel insulation sandwich board.
The objective of the invention is to realize by following technical proposals.
Summary of the invention: hard heat-insulated sheet material of ultralight of the present invention and production technique thereof is characterized in that consist of (by weight) of the hard heat-insulated sheet material of ultralight:
1 part of inorganic reinforcement, 0.1~3 part of composite high-temperature adhesive, 2~15 parts of aglites, 0.01~0.5 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 5~20 parts of fibrous magnesium silicates, 0~10 part of brucite, 0~10 part in glass fibre, 0~10 part of aluminum silicate fiber, 0~10 part of montmorillonite; The consisting of of composite high-temperature adhesive (by weight): 1~10 part of water glass, 1~10 part of aluminium dihydrogen phosphate, 5~50 parts in silicone resin glue, 0~20 part of silicon sol; The consisting of of promoting agent (by weight): 0.1~2 part of penetrant t (succinate sodium sulfonate), 0.03~1 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product).
In the such scheme, aglite is swelling perlite powder, diatomite, hollow glass bead.
In the such scheme, the production technique of the hard heat-insulated sheet material of ultralight is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 1~10 part of water glass, 1~10 part of aluminium dihydrogen phosphate, 5~50 parts in silicone resin glue, 0~20 part of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 0~10 part in glass fibre, 0~10 part of aluminum silicate fiber, 5~20 parts of fibrous magnesium silicates, 0~10 part of brucite, 0~10 part of montmorillonite;
Prepare the various materials of promoting agent standby by following formula rate (by weight): 0.1~2 part of penetrant t (succinate sodium sulfonate), 0.03~1 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 30~60 parts in water, 0.01~0.5 part of promoting agent, 0.1~3 part of composite high-temperature adhesive;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: the ratio of aglite=1: 2~15 (by weight) is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
The hard heat-insulated sheet material unit weight of ultralight that the present invention produces is light, is 60~130kg/m
3The intensity height, thermal conductivity is little, combustionproperty reaches does not fire the A level, effectively use temperature can reach more than 600 ℃, overcome the defective of present chromatic steel sandwich plate heat insulating sandwich commonly used from performance, that is: organic foamed products intensity height, thermal conductivity is little but the material combustion performance can only reach difficult combustion B1 or B2 level, can't satisfy the requirement of relevant criterion; Rock wool (glass wool) product thermal conductivity is less, and combustionproperty also can reach and not fire the A level, but intensity is lower.
The present invention has expanded the Application Areas of chromatic steel sandwich plate for chromatic steel sandwich plate provides the heat insulating sandwich that a kind of unit weight is light, performance is excellent.The present invention can produce the product of all size according to mould, especially is fit to produce thickness greater than 50mm, and length is lower than 1500mm, and width is lower than the product of all size of 1200mm.
Therefore, the hard heat-insulated sheet material unit weight of ultralight of the present invention is light, and intensity is good, fire-fighting grade height, the material combustion performance reaches does not fire the A level, is specially adapted to do the heat insulating sandwich specially of color steel insulation sandwich board, has expanded the Application Areas of ultralight matter aggregate goods such as pearlstone; Its production technique is simple, and production cost is low, constant product quality.
Embodiment:
The invention is further illustrated by the following examples, and the present invention is not limited only to described embodiment.
Embodiment one
The consisting of of the hard heat-insulated sheet material of ultralight that this is routine (by weight):
1 part of inorganic reinforcement, 0.1 part of composite high-temperature adhesive, 2 parts of aglites, 0.01 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 5 parts of fibrous magnesium silicates, 2 parts of brucites; The consisting of of composite high-temperature adhesive (by weight): 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 5 parts in silicone resin glue; The consisting of of promoting agent (by weight): 0.1 part of penetrant t (succinate sodium sulfonate), 0.03 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product); Aglite is a swelling perlite powder.
The production technique of the hard heat-insulated sheet material of ultralight that this is routine is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 5 parts in silicone resin glue;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 5 parts of fibrous magnesium silicates, 2 parts of brucites;
Prepare the various materials of promoting agent standby by following formula rate (by weight): 0.1 part of penetrant t (succinate sodium sulfonate), 0.03 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 30 parts in water, 0.01 part of promoting agent, 0.1 part of composite high-temperature adhesive;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: aglite=ratio (by weight) of 1: 2 is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
Embodiment two
The consisting of of the hard heat-insulated sheet material of ultralight that this is routine (by weight):
1 part of inorganic reinforcement, 3 parts of composite high-temperature adhesives, 15 parts of aglites, 0.5 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 20 parts of fibrous magnesium silicates, 10 parts of brucites, 10 parts in glass fibre, 10 parts of aluminum silicate fibers, 10 parts of montmorillonites; The consisting of of composite high-temperature adhesive (by weight): 10 parts of water glass, 10 parts of aluminium dihydrogen phosphates, 50 parts in silicone resin glue, 20 parts of silicon sol; The consisting of of promoting agent (by weight): 2 parts of penetrant ts (succinate sodium sulfonate), 1 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product); Aglite is a diatomite.
The production technique of the hard heat-insulated sheet material of ultralight that this is routine is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 10 parts of water glass, 10 parts of aluminium dihydrogen phosphates, 50 parts in silicone resin glue, 20 parts of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 10 parts in glass fibre, 10 parts of aluminum silicate fibers, 20 parts of fibrous magnesium silicates, 10 parts of brucites, 10 parts of montmorillonites;
Prepare the various materials of promoting agent standby by following formula rate (by weight): 2 parts of penetrant ts (succinate sodium sulfonate), 1 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 60 parts in water, 0.5 part of promoting agent, 3 parts of composite high-temperature adhesives;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: aglite=ratio (by weight) of 1: 15 is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
Embodiment three
The consisting of of the hard heat-insulated sheet material of ultralight that this is routine (by weight):
1 part of inorganic reinforcement, 1.5 parts of composite high-temperature adhesives, 10 parts of aglites, 0.3 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 12 parts of fibrous magnesium silicates, 6 parts of brucites, 5 parts in glass fibre, 5 parts of aluminum silicate fibers, 5 parts of montmorillonites; The consisting of of composite high-temperature adhesive (by weight): 5 parts of water glass, 6 parts of aluminium dihydrogen phosphates, 30 parts in silicone resin glue, 10 parts of silicon sol; The consisting of of promoting agent (by weight): 1 part of penetrant t (succinate sodium sulfonate), 0.5 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product); Aglite is a hollow glass bead.
The production technique of the hard heat-insulated sheet material of ultralight that this is routine is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 5 parts of water glass, 6 parts of aluminium dihydrogen phosphates, 30 parts in silicone resin glue, 10 parts of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 5 parts in glass fibre, 5 parts of aluminum silicate fibers, 12 parts of fibrous magnesium silicates, 6 parts of brucites, 5 parts of montmorillonites;
Prepare the various materials of promoting agent standby by following formula rate (by weight): 1 part of penetrant t (succinate sodium sulfonate), 0.5 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 45 parts in water, 0.3 part of promoting agent, 1.5 parts of composite high-temperature adhesives;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: aglite=ratio (by weight) of 1: 10 is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
Embodiment four
The consisting of of the hard heat-insulated sheet material of ultralight that this is routine (by weight):
1 part of inorganic reinforcement, 2.13 parts of composite high-temperature adhesives, 3.27 parts of aglites, 0.13 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 10 parts of fibrous magnesium silicates, 3 parts of brucites, 2 parts of aluminum silicate fibers; The consisting of of composite high-temperature adhesive (by weight): 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 20 parts in silicone resin glue, 10 parts of silicon sol; The consisting of of promoting agent (by weight): 1.5 parts of penetrant ts (succinate sodium sulfonate), 0.5 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product); The consisting of of aglite (by weight): 45 parts of pearlstones, 4 parts of hollow glass beads.
The production technique of the hard heat-insulated sheet material of ultralight that this is routine is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 20 parts in silicone resin glue, 10 parts of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 2 parts of aluminum silicate fibers, 10 parts of fibrous magnesium silicates, 3 parts of brucites.
Prepare the various materials of promoting agent standby by following formula rate (by weight): 1.5 parts of penetrant ts (succinate sodium sulfonate), 0.5 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 45 parts in water, 0.13 part of promoting agent, 2.13 parts of composite high-temperature adhesives;
Prepare the various materials of aglite standby by following formula rate (by weight): 45 parts of pearlstones, 4 parts of hollow glass beads;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: aglite=ratio (by weight) of 1: 3.27 is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
Embodiment five
The consisting of of the hard heat-insulated sheet material of ultralight that this is routine (by weight):
1 part of inorganic reinforcement, 1.8 parts of composite high-temperature adhesives, 2.67 parts of aglites, 0.13 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 10 parts of fibrous magnesium silicates, 3 parts in glass fibre, 2 parts of aluminum silicate fibers; The consisting of of composite high-temperature adhesive (by weight): 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 10 parts in silicone resin glue, 15 parts of silicon sol; The consisting of of promoting agent (by weight): 1.6 parts of penetrant ts (succinate sodium sulfonate), 0.4 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product); The consisting of of aglite (by weight): 30 parts of pearlstones, 5 parts of hollow glass beads, 5 parts in diatomite.
The production technique of the hard heat-insulated sheet material of ultralight that this is routine is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 1 part of water glass, 1 part of aluminium dihydrogen phosphate, 10 parts in silicone resin glue, 15 parts of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 2 parts of aluminum silicate fibers, 10 parts of fibrous magnesium silicates, 3 parts in glass fibre.
Prepare the various materials of promoting agent standby by following formula rate (by weight): 1.6 parts of penetrant ts (succinate sodium sulfonate), 0.4 part of NNO (naphthalene sulfonic acidformaldehyde condensation product);
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 50 parts in water, 0.13 part of promoting agent, 1.8 parts of composite high-temperature adhesives;
Prepare the various materials of aglite standby by following formula rate (by weight): 30 parts of pearlstones, 5 parts of hollow glass beads, 5 parts in diatomite;
With the good bonding slurry of blending dispersion and aglite by inorganic reinforcement: the mixed of aglite=1: 2.67 (by weight) evenly becomes to have the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
Claims (3)
1. hard heat-insulated sheet material of ultralight and production technique thereof is characterized in that consist of (by weight) of the hard heat-insulated sheet material of ultralight:
1 part of inorganic reinforcement, 0.1~3 part of composite high-temperature adhesive, 2~15 parts of aglites, 0.01~0.5 part of promoting agent; Wherein, the consisting of of inorganic reinforcement (by weight): 5~20 parts of fibrous magnesium silicates, 0~10 part of brucite, 0~10 part in glass fibre, 0~10 part of aluminum silicate fiber, 0~10 part of montmorillonite; The consisting of of composite high-temperature adhesive (by weight): 1~10 part of water glass, 1~10 part of aluminium dihydrogen phosphate, 5~50 parts in silicone resin glue, 0~20 part of silicon sol; The consisting of of promoting agent (by weight): 0.1~2 part of penetrant t (succinate sodium sulfonate), 0.03~1 part of tensio-active agent NNO (naphthalene sulfonic acidformaldehyde condensation product).
2. hard heat-insulated sheet material of ultralight according to claim 1 and production technique thereof is characterized in that aglite is swelling perlite powder, diatomite, hollow glass bead.
3. hard heat-insulated sheet material of ultralight according to claim 1 and 2 and production technique thereof, the production technique that it is characterized in that the hard heat-insulated sheet material of ultralight is: it is standby by following formula rate (by weight) the various materials of composite high-temperature adhesive to be joined the back that stirs in the stirrer: 1~10 part of water glass, 1~10 part of aluminium dihydrogen phosphate, 5~50 parts in silicone resin glue, 0~20 part of silicon sol;
Prepare the various materials of inorganic reinforcement standby by following formula rate (by weight): 0~10 part in glass fibre, 0~10 part of aluminum silicate fiber, 5~20 parts of fibrous magnesium silicates, 0~10 part of brucite, 0~10 part of montmorillonite;
Prepare the various materials of promoting agent standby by following formula rate (by weight): 0.1~2 part of penetrant t, 0.03~1 part of tensio-active agent NNO;
The above-mentioned mixed glue solution for preparing and inorganic reinforcement, promoting agent, water are joined batch mixing in the mixer by following formula rate (by weight), blending together has the liquid of certain cementability and denseness standby: 1 part of inorganic reinforcement, 30~60 parts in water, 0.01~0.5 part of promoting agent, 0.1~3 part of composite high-temperature adhesive;
With the good bonding slurry of blending dispersion and aglite in inorganic reinforcement: the ratio of aglite=1: 2~15 (by weight) is mixed into the moulding slurry of certain cementability; The moulding slurry is injected in the forming mould, promptly obtains the hard heat-insulated plate product of ultralight after the compression moulding after demoulding drying, the finishing.
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- 2004-04-26 CN CN 200410022386 patent/CN1283582C/en not_active Expired - Fee Related
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CN118290114B (en) * | 2024-05-29 | 2024-09-03 | 天津开发区科泰化工新材料开发有限公司 | Non-cement-based inorganic fireproof heat-insulating material and preparation method and application thereof |
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