CN1596299A - Process for the treatment of textile fibre materials - Google Patents
Process for the treatment of textile fibre materials Download PDFInfo
- Publication number
- CN1596299A CN1596299A CNA038016044A CN03801604A CN1596299A CN 1596299 A CN1596299 A CN 1596299A CN A038016044 A CNA038016044 A CN A038016044A CN 03801604 A CN03801604 A CN 03801604A CN 1596299 A CN1596299 A CN 1596299A
- Authority
- CN
- China
- Prior art keywords
- alkyl
- unsubstituted
- compound
- hydrogen
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 23
- 239000000463 material Substances 0.000 title claims description 9
- 239000000835 fiber Substances 0.000 title description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 148
- 239000000203 mixture Substances 0.000 claims abstract description 136
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 56
- 239000001257 hydrogen Substances 0.000 claims abstract description 56
- 239000003599 detergent Substances 0.000 claims abstract description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 26
- 125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 25
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 6
- 150000002367 halogens Chemical class 0.000 claims abstract description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims description 93
- 125000000217 alkyl group Chemical group 0.000 claims description 43
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 37
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 31
- -1 4Be hydrogen Chemical class 0.000 claims description 30
- 102000004190 Enzymes Human genes 0.000 claims description 23
- 108090000790 Enzymes Proteins 0.000 claims description 23
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 23
- 229940088598 enzyme Drugs 0.000 claims description 23
- 150000003053 piperidines Chemical class 0.000 claims description 23
- 102000035195 Peptidases Human genes 0.000 claims description 20
- 108091005804 Peptidases Proteins 0.000 claims description 20
- 108010059892 Cellulase Proteins 0.000 claims description 17
- 229940106157 cellulase Drugs 0.000 claims description 17
- 150000002978 peroxides Chemical class 0.000 claims description 17
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 16
- 229920000742 Cotton Polymers 0.000 claims description 13
- 239000012190 activator Substances 0.000 claims description 13
- 239000004382 Amylase Substances 0.000 claims description 12
- 102000013142 Amylases Human genes 0.000 claims description 12
- 108010065511 Amylases Proteins 0.000 claims description 12
- 239000004367 Lipase Substances 0.000 claims description 12
- 102000004882 Lipase Human genes 0.000 claims description 12
- 108090001060 Lipase Proteins 0.000 claims description 12
- 235000019418 amylase Nutrition 0.000 claims description 12
- 235000019421 lipase Nutrition 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 238000004061 bleaching Methods 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 8
- 239000002657 fibrous material Substances 0.000 claims description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 8
- 210000002268 wool Anatomy 0.000 claims description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
- 229910052728 basic metal Inorganic materials 0.000 claims description 6
- 150000003818 basic metals Chemical class 0.000 claims description 6
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 238000005282 brightening Methods 0.000 claims 1
- 150000001768 cations Chemical group 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 229910052799 carbon Inorganic materials 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000975 dye Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 239000011541 reaction mixture Substances 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 150000004696 coordination complex Chemical class 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 4
- 238000007429 general method Methods 0.000 description 4
- 210000000050 mohair Anatomy 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000003513 alkali Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002191 fatty alcohols Chemical group 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical group [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 241000208202 Linaceae Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 210000000085 cashmere Anatomy 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
- REJHVSOVQBJEBF-UHFFFAOYSA-N DSD-acid Natural products OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 230000010748 Photoabsorption Effects 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- SRBFZHDQGSBBOR-LECHCGJUSA-N alpha-D-xylose Chemical compound O[C@@H]1CO[C@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-LECHCGJUSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229940067597 azelate Drugs 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- VMKJWLXVLHBJNK-UHFFFAOYSA-N cyanuric fluoride Chemical compound FC1=NC(F)=NC(F)=N1 VMKJWLXVLHBJNK-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- JHUXOSATQXGREM-UHFFFAOYSA-N dodecanediperoxoic acid Chemical class OOC(=O)CCCCCCCCCCC(=O)OO JHUXOSATQXGREM-UHFFFAOYSA-N 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical class OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000012209 glucono delta-lactone Nutrition 0.000 description 1
- 229960003681 gluconolactone Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- HPEUEJRPDGMIMY-IFQPEPLCSA-N molybdopterin Chemical class O([C@H]1N2)[C@H](COP(O)(O)=O)C(S)=C(S)[C@@H]1NC1=C2N=C(N)NC1=O HPEUEJRPDGMIMY-IFQPEPLCSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- 150000003921 pyrrolotriazines Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Detergent compositions comprising at least one compound of formula 1, wherein R1 and R2 are, independently of each other, hydrogen or unsubstituted or substituted C1-C8alkyl, X1, X2, X3 and X4 are, independently of each other, -NR3R4 or -OR5, wherein R3 and R4 are hydrogen, cyano, unsubstituted or substituted C1-C8alkyl or C5-C7cycloalkyl, or R3 and R4, together with the nitrogen atom linking them, form a heterocyclic ring, and R5 is unsubstituted or substituted C1-C8alkyl, and M is hydrogen or a cation, together with at least one compound of formula 2, wherein R6 and R7, independently of each other, are hydrogen, C1-C8alkyl, C1-C8alkoxy or halogen, and M is as defined above under formula 1, the novel mixtures of compounds of formulae 1 and 2 and detergent compositions containing compounds embraced by formula 1.
Description
The present invention relates to comprise the detergent formulation of the mixture of some white dyes or white dyes, and the mixture that relates to white dyes.
Usually, knownly can in detergent formulation, use white dyes.During handling, they are released to is washed on the material, relies on their special photoabsorption/emission characteristics, eliminates yellow tone.
Yet, still need to find improved white dyes for this application.Have now found that, below the mixture of compound of formula (1) and (2), perhaps the compound of formula (1a) has superior character aspect for example solubleness, washing aid performance, white light resistance, and has fabulous white appearance when solid-state.Even can be by in the washing composition that comprises cellulase, proteolytic enzyme, amylase or lipase, the mixture of use formula (1) and (2) compound or the compound of formula (1a) increase white character, keep as white.Even under low wash temperature, also can obtain satisfied result.
Therefore, on the one hand, the invention provides a kind of detergent composition, comprise the compound of at least a following formula
Wherein
R
1And R
2Be hydrogen or C unsubstituted or that replace with being mutually independent
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen, cyano group, the unsubstituted or C that replaces
1-C
8Alkyl or C
5-C
7Cycloalkyl, perhaps R
3And R
4The nitrogen-atoms that connects with them forms heterocycle, and R
5Be C unsubstituted or that replace
1-C
8Alkyl, and
M is hydrogen or positively charged ion,
Compound with at least a following formula
R wherein
6And R
7Be hydrogen, C each other independently
1-C
8Alkyl, C
1-C
8Alkoxy or halogen, and M in the above-mentioned formula (1) definition.
In the scope of above-mentioned definition, C
1-C
8Alkyl can be methyl, ethyl, n-propyl, sec.-propyl, normal-butyl, sec-butyl or the tertiary butyl, or amyl group straight chain or side chain, hexyl, heptyl or octyl group.C preferably
1-C
4Alkyl.If alkyl replaces, possible substituent example is a hydroxyl, halogen such as fluorine, chlorine or bromine, sulfo group, sulfato, carboxyl and C
1-C
4Alkoxyl group such as methoxyl group and oxyethyl group.Other substituting group of such alkyl be for example cyano group ,-CONH
2And phenyl.Preferred substituted be hydroxyl, carboxyl, cyano group ,-CONH
2And phenyl, especially hydroxyl and carboxyl.In addition, substituting group very preferably is hydroxyl and C
1-C
4Alkoxyl group, especially hydroxyl.Alkyl can also be uninterruptedly or quilt-O-(when alkyl comprises two or more carbon atoms) of being interrupted.
C
5-C
7The example of cycloalkyl is a cyclopentyl, especially cyclohexyl.These groups can be unsubstituted or by C for example
1-C
4Alkyl such as methyl substituted.Corresponding unsubstituted cycloalkyl is preferred.
In the above-mentioned range of definition, C
1-C
8Alkoxyl group can be senior alkoxyl group methoxyl group, oxyethyl group, propoxy-, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert.-butoxy or straight chain or side chain.C preferably
1-C
4Alkoxyl group, especially methoxy or ethoxy.It is most preferred that methoxyl group.
Halogen can be fluorine, chlorine, bromine or iodine, preferably chlorine.
If R
3And R
4Form heterocycle with nitrogen-atoms, such ring system can be for example morpholine, piperidines or pyrrolidine ring.Heterocycle can be unsubstituted or replace.Substituent example like this is C
1-C
4Alkyl, especially methyl.
Positively charged ion M is alkali metal atom, alkaline earth metal atom, ammonium or the positively charged ion that generated by amine preferably.Na preferably, K, Ca, Mg, ammonium, single-, two-, three-or four-(C
1-C
4Alkyl) ammonium, single-, two-or three-(C
2-C
4-hydroxyalkyl) ammonium or by C
1-C
4-alkyl and C
2-C
4The ammonium of the mixture two of-hydroxyalkyl-or three-replace.It is most preferred that sodium.
R
1And R
2Preferably hydrogen or C
1-C
4Alkyl, especially hydrogen.
R
3And R
4Hydrogen preferably; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or phenyl replace, especially by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl, especially cyclohexyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.
R
3And R
4Be more preferably hydrogen, C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl, unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl, perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.R
3And R
4Very preferably be hydrogen, C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl, perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4The morpholine of alkyl-replacement, piperidines or pyrrolidine ring.Most preferably by R
3And R
4It is unsubstituted or by C that the nitrogen-atoms that connects with their forms
1-C
4The morpholine of alkyl-replacement, piperidines or pyrrolidine ring, especially morpholine ring.
-N (R
3) R
4The example of group is-NH
2,-NHCH
3,-NHC
2H
5,-NH (n-C
3H
7) ,-NH (i-C
3H
7) ,-NH (i-C
4H
9) ,-N (CH
3)
2,-N (C
2H
5)
2,-N (i-C
3H
7)
2,-NH (CH
2CH
2OH) ,-N (CH
2CH
2OH)
2,-N (CH
2CH (OH) CH
3)
2,-N (CH
3) (CH
2CH
2OH) ,-N (C
2H
5) (CH
2CH
2OH) ,-N (i-C
3H
7) (CH
2CH
2CH
2OH) ,-NH (CH
2CH (OH) CH
3) ,-N (C
2H
5) (CH
2CH (OH) CH
3) ,-NH (CH
2CH
2OCH
3) ,-NH (CH
2CH
2OCH
2CH
2OH) ,-NH (CH
2COOH) ,-NH (CH
2CH
2COOH) ,-N (CH
3) (CH
2COOH) ,-NH (CN),
R
5C preferably
1-C
8Alkyl, especially C
1-C
4Alkyl, it is unsubstituted or by C
1-C
4Alkoxyl group or especially hydroxyl replace.R
5Very preferably be methyl or ethyl, especially methyl.
X
1, X
2, X
3And X
4Formula-N (R preferably
3) R
4Group.
X
1And X
3Preferably has identical implication.In addition, X
2And X
4Preferably has identical implication.In addition, preferred X
1, X
2, X
3And X
4Four groups do not have identical implication.
The compound of preferred formula (1), wherein
R
1And R
2Be hydrogen or C
1-C
4Alkyl,
R
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces; With
R
5Be C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl.
As for R
3, R
4And R
5Be suitable for above-mentioned preferable range.
It is most preferred that the compound of formula (1), wherein
X
1And X
3Be amino, and
X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen; Cyano group; Unsubstituted or by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The cyclohexyl that alkyl replaces; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.
As for R
3And R
4Be suitable for above-mentioned preferred definition.
Interested especially is the compound of formula (1), wherein X
1And X
3Be amino, and X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen, C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl, unsubstituted or by C
1-C
4Cyclopentyl or cyclohexyl that alkyl replaces, perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.The compound of most interested formula (1) is R wherein
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4The compound of morpholine, piperidines or pyrrolidine ring that alkyl replaces.As for R
3And R
4Be suitable for above-mentioned preferred definition.
The compound of other interested formula (1) is the compound of formula given below (1a).
R
6And R
7Hydrogen preferably.Each sulfo group in the formula (2) preferably is connected the ortho position.The compound of interested formula (2) is R wherein
6And R
7Be that each sulfo group in hydrogen and the formula (2) is connected the adjacent compound.
M is hydrogen, alkali or alkaline-earth metal or ammonium preferably, especially sodium.
In the mixture of the compound of formula (1) and (2), the mol ratio of compound (1) and compound (2) is usually 0.1: 99.9-99.9: in 0.1 the scope, preferably 1: 99-99: in 1 the scope, more preferably 5: 95-95: in 5 the scope.Mol ratio is very preferably 10: 90-90: in 10 the scope, especially 20: 80-80: in 20 the scope.Most important mol ratio is 30: 70-70: in 30 the scope, especially 40: 60-60: in 40 the scope.
The compound of formula (1) and (2) is known or can be by preparing with the similar method of currently known methods.
Can make cyanuryl chloride successively by under known reaction conditions, with any desired order with 4,4 '-diaminostilbene-2,2 '-disulfonic acid and can introduce radicals X
1, X
2, X
3And X
4Aminocompound reaction, come the compound of preparation formula (1).Preferably, initial, make 2 moles cyanuryl chloride with 1 mole 4,4 '-diaminostilbene-2, the reaction of 2 '-disulfonic acid, the intermediate that makes acquisition then is with any order and can introduce radicals X
1, X
2, X
3And X
4Aminocompound reaction.For preparing wherein X
1And X
3Have identical meanings and X
2And X
4Compound with identical meanings, the intermediate that preferably makes acquisition at first with can introduce X
1And X
3The reaction of the aminocompound of group, last with can introduce X
2And X
4The aminocompound reaction of group.Also can in a step, be undertaken with the reaction of aminocompound by the mixture reaction that makes intermediate and aminocompound; In this case, obtain the respective mixtures of the compound of formula (1) usually.
Comprise a formula-OR
5The formula of group (1) compound for example can prepare by following method: at first make cyanuryl chloride and corresponding pure HOR
5Reaction makes the product and 4 that obtains, and 4 '-diaminostilbene-2,2 '-disulfonic acid react, make then intermediate further with can introduce X
1, X
2, X
3And X
4The compound reaction of residue group.Last reaction is preferably carried out with corresponding amine.
In addition, the present invention relates to the mixture of the compound of formula (1) and (2).As for the compound of formula (1) and (2), be suitable for the above-mentioned preferred definition that provides.The compound of preferred formula (2), wherein R
6And R
7Be that each sulfo group in hydrogen and the formula (2) is connected the ortho position.In such mixture, the mol ratio of compound (1) and compound (2) is usually 0.1: 99.9-99.9: in 0.1 the scope, preferably 1: 99-99: in 1 the scope, more preferably 5: 95-95: in 5 the scope.Very preferably mol ratio is 10: 90-90: in 10 the scope, especially 20: 80-80: in 20 the scope.Most important mol ratio is 30: 70-70: in 30 the scope, especially 40: 60-60: in 40 the scope.
Employed detergent composition preferably includes
I) anion surfactant of 1-70% and/or nonionogenic tenside;
The ii) washing assistant of 0-75%;
The iii) superoxide of 0-30%;
The iv) peroxide activator of 0-10%; And
The v) mixture of the compound of the formula of 0.001-5% (1) and (2), each component are calculated by weight and based on the gross weight of washing composition.
Employed detergent composition more preferably comprises
I) anion surfactant of 5-70% and/or nonionogenic tenside;
The ii) washing assistant of 5-70%;
The iii) superoxide of 0.5-30%;
The iv) bleaching catalyst of the peroxide activator of 0.5-10% and/or 0.1-2%; With
The v) mixture of the compound of the formula of 0.01-5% (1) and (2), each component are calculated by weight and based on the gross weight of washing composition.
Usually, the amount of the mixture of the compound of formula (1) and (2) is 0.001-5%, especially 0.01-5%.Consumption very preferably is in the scope of 0.05-5%, especially in the scope of 0.05-2%.Usually, the quantity that provides with per-cent will be understood that the weight percentage based on gross weight, except as otherwise noted.
Washing composition can be mixed with solid, comprise for example aqueous solution of the water of 5-50%, preferred 10-35%, perhaps comprise at the most 5, the non-aqueous liquid detergent of the water of preferred 0-1wt%, and based on the suspension of the washing assistant in nonionogenic tenside, for example those as describing among the GB-A-2158454.
The anionic surfactant component can be for example alkylbenzene sulfonate, alkyl-sulphate, sulfated alkyl ether, alkene sulfonate, alkylsulfonate, soap, alkyl or alkenyl ether carboxylic acid salt or alpha-sulfo-fatty acid salt or its ester.Preferably moieties have 10-20 carbon atom alkylbenzene sulfonate, have 8-18 carbon atom alkyl-sulphate, have the sulfated alkyl ether of 8-18 carbon atom and by plam oil or butter deutero-and have the soap of 8-18 carbon atom.The average mol that joins the oxyethane in the sulfated alkyl ether is 1-20, preferred 1-10.These salt preferably derive from basic metal such as sodium and potassium, especially derive from sodium.Carboxylate salt very preferably is formula R-CO (R
1) CH
2COOM
1The sarkosine an alkali metal salt, wherein R is alkyl or the alkenyl that partly has 9-17 carbon atom at moieties or alkenyl, R
1Be C
1-C
4Alkyl and M
1Be basic metal, sodium especially.
Non-ionic surfactant component can be, for example, and primary and secondary alcohol ethoxylate, the especially C of the oxyethane ethoxylation of every mole of average 1-20 mole of quilt
8-C
20Fatty alcohol, the more particularly C of the oxyethane ethoxylation of every mole of average 1-10 mole of quilt
10-C
15The primary and secondary Fatty Alcohol(C12-C14 and C12-C18).The ionic surfactant pack of non-ethoxylatedization is drawn together alkyl polyglycoside, glycerol monoethers and polyhydroxyamide (glucamide).
The total amount of anionic surfactant and nonionogenic tenside is 5-50wt% preferably, and preferably 5-40wt% is more preferably 5-30wt%.The lower limit of preferred these tensio-active agents is 10wt%.
Builder component can be alkali metal phosphate, especially tri-polyphosphate; Carbonate or supercarbonate, especially its sodium salt; Silicate or bisilicate; Silico-aluminate; The multi-carboxylate; Polycarboxylic acid; Organic phosphonate; Or amino alkylidenyl poly-(alkylene phosphonic acids salt); Or the mixture of these compounds.Preferred silicate is formula NaHSimO
2m+1.pH
2O or Na
2SimO
2m+1.pH
2The crystalline layered sodium silicate of O, wherein m is the number of 1.9-4, p is 0-20.Preferred aluminosilicate is commercial available synthetic materials, is called zeolite A, B, X and HS or these mixture.Zeolite A is preferred.Preferred multi-carboxylate comprises hydroxypolycarboxylic acid's salt, particularly Citrate trianion, the multipolymer of polyacrylic ester and they and maleic anhydride.Preferred polycarboxylic acid comprises nitrilotriacetic acid(NTA) and ethylenediamine tetraacetic acid (EDTA).
Preferred organic phosphonate or amino alkylidenyl poly-(alkylene phosphonic acids salt) are alkali-metal ethane 1-hydroxyl diphosphonate, nitrilo trimethylene phosphonic salt, ethylenediamine tetramethylene phosphonic acid salt and diethylenetriamine pentamethylenophosphonic acid(DTPP) salt.
The consumption of washing assistant is 5-70wt%, and preferably 5-60wt% is more preferably 10-60wt%.For the preferred lower limit of washing assistant is 15wt%, especially 20wt%.
Suitable peroxide component comprises for example known in the literature and the commercial available organic and inorganic peroxide (as sodium peroxide) that for example can bleach textile materials in the wash temperature of routine under 5-95 ℃.Interested especially is organo-peroxide, and for example single superoxide or have at least 3 carbon atoms preferably has many superoxide of the alkyl chain of 6-20 carbon atom; For example diperoxy is crossed azelate, diperoxy is crossed sebacate, diperoxy phthalate and/or diperoxy dodecanedioic acid salt, especially their corresponding free acid particularly to have the diperoxy dicarboxylate of 6-12 carbon atom.Yet, preferred very active inorganic peroxide, for example persulphate, perborate and/or the percarbonate of using.Certainly, also can use the mixture of organo-peroxide and/or inorganic peroxide.
The consumption of superoxide is 0.5-30wt%, and preferably 1-20wt% is more preferably 1-15wt%.When using superoxide, lower limit is 2wt% preferably, especially 5wt%.
Superoxide, especially inorganic peroxide preferably activate by a kind of bleach-activating agent that mixes.Preferably cross produce under the hydrolysising condition unsubstituted or replace have a 1-10 carbon atom, especially have the mistake benzene of 2-4 carbon atom-and/or the compound of peroxidation-carboxylic acid.Suitable compound comprises those compounds of the benzoyl group that has O-and/or N-carboxyl groups and/or unsubstituted or replacement with described carbonatoms.The Alkylenediamine of preferred many acylations, especially tetra-acetylated ethylene diamine (TAED); acidylate glycoluril, especially tetra-acetylated glycoluril (TAGU); N, N-diacetyl-N, N-dimethyl-urea (DDU); acidylate pyrrolotriazine derivatives, especially 1; 5-diacetyl-2,4-dioxy six hydrogen-1,3; 5-triazine (DADHT), the compound of following formula
Wherein R is sulfonate groups, hydroxy-acid group or carboxylate groups, and wherein R ' is (C of straight or branched
7-C
15) alkyl; Activator also is known; name is called SNOBS, SLOBS, NOBS and DOBA; the acidylate polyvalent alcohol; especially triacetin, glycol diacetate and 2; 5-diacetoxyl-2; the two hydrogen furans of 5-and acetylizad Sorbitol Powder and mannitol; and the sugar derivatives of acidylate, especially penta-acetyl glucose (PAG), sucrose polyacetic acid ester (SUPA), penta-acetyl fructose, tetra-acetylated wood sugar and octoacetyl lactose, and acetylizad, optional alkylating glycosamine of N-and glucono-lactone.Also can use the combination of the conventional bleaching activator that is disclosed among the DE-A-44 43 177.The nitrile compound that forms the peroxide imido acid with superoxide also is suitable as bleach-activating agent.Preferred tetra acetyl ethylene diamine and nonanoly acyloxy benzene sulfonate.
The amount of bleach-activating agent is 0-10wt%, preferably 0-8wt%.Under the situation of using bleach-activating agent, lower limit is 0.5wt% preferably, especially 1wt%.
The bleaching catalyst that can add comprises for example enzyme peroxide precursor and/or metal complex.Preferred metal complex is the complex compound of manganese, cobalt or iron, for example the complex compound of describing among the phthalocyanine complex of manganese or iron or the EP-A-0509787.Under the situation of using bleaching catalyst, its consumption is 0.005-2wt% preferably, is more preferably 0.01-2wt%, especially 0.05-2wt%.It is most preferred that it is 0.1-2wt%.
The example of the bleaching catalyst that can mention is as follows:
-WO-A-95/30681 (referring to formula (I) and under the capable definition of page 1 7-30; Especially formula (I) and under the definition that provides of 11 page of the 11st row of page 2 the 29th row-Di).Preferred part is those that provide at 26 page of the 11st row of the 13rd page of the 12nd row-Di.
-WO-A-01/09276 (promptly referring to formula (1), (2) and (3) and under page 2 and the definition that provides of page 3).
-WO-A-01/05925 (promptly referring to formula (1) and under first section definition that provides of page 1 final stage-page 2.Metal complex is preferred, especially referring to those of page 3 formula (2) and page 4 formula (3)).
-WO-A-02/088289 (promptly referring to formula (1) and under the definition of page 2.Metal complex is preferred, and especially referring to the part of formula (3), and the definition of the 7th section of the fourth paragraph on page three-page 4 is preferred).
In addition, washing composition can be chosen wantonly and comprise enzyme.Enzyme can join in the washing composition to remove spot.Enzyme improves usually based on the performance on the spot of protein or starch, for example those spots that caused by blood, milk, grass or fruit juice.Enzyme is cellulase, proteolytic enzyme, amylase and lipase preferably.Enzyme is cellulase and proteolytic enzyme preferably, especially proteolytic enzyme.Cellulase is that Mierocrystalline cellulose and its derivative are worked, and they are hydrolyzed into the enzyme of glucose, cellobiose, cell-oligosaccharide.Cellulase is removed dirt and is had the effect that alleviates roughness when touching.The example of employed enzyme comprises but is confined to following enzyme never in any form:
At US 6,242,405, the 14 hurdles, the proteolytic enzyme that provides during 21-32 is capable;
At US 6,242,405, the 14 hurdles, the lipase that provides during 33-46 is capable;
At US 6,242,405, the 14 hurdles, the amylase that provides during 47-56 is capable;
At US 6,242,405, the 14 hurdles, the cellulase that provides during 57-64 is capable.
Enzyme can be chosen wantonly and be present in the washing composition.When using, the amount of enzyme is generally the 0.01-5wt% based on the gross weight of washing composition, is preferably 0.05-5wt%, more preferably 0.1-4wt%.
In washing composition of the present invention, other preferred additives is a polymkeric substance, it suppresses by the caused spot of the dyestuff in washing lotion during the washing textiles, and these dyestuffs have removed (laking agent, dye transfer inhibiting agent) from textiles under wash conditions.Such polymkeric substance is polyvinylpyrrolidone, polyvinyl imidazole or polyvinyl pyridine N-oxide preferably, they may carry out modification by introducing negatively charged ion or cationic substituent, especially molecular weight is in the 5000-60000 scope, and more particularly molecular weight is at those polymkeric substance of 10 000-50,000 scope.Based on the gross weight of washing composition, the consumption of such polymkeric substance is generally 0.01-5wt%, is preferably 0.05-5wt%, especially 0.1-2wt%.Preferred polymkeric substance is those that provide in WO-A-02/02865 (especially referring to page 1, final stage and page 2, first section).
Employed washing composition comprises for example soil-suspending agent of one or more auxiliary agents, for example Xylo-Mucine usually; Regulate the salt of pH value, for example alkali or alkaline earth metal silicate; Foaming regulator, for example soap; Regulate the salt of spraying drying and granulation character, for example sodium sulfate; Spices; And, if suitable, static inhibitor and tenderizer; Montmorillonitic clay for example; Optical white; Pigment; And/or toner (shading agent).Certainly, these components should be stable in any employed bleach system.Based on the gross weight of washing composition, the consumption of such auxiliary agent is preferably 0.5-10wt% for for example 0.1-20wt%, especially 0.5-5wt%.
Detergent composition can take various physical aspects to comprise powder, particulate state, small pieces and liquid state.Its example is strong detergent and the small pieces such as the strong detergent small pieces of traditional strong detergent powder, concentrated type and hyperconcentration type.A kind of important outward appearance is so-called concentrated granular, and it is suitable for joining in the washing machine.
So-called concentrated type (or hyperconcentration type) washing composition also is important.In the production of detergents field, a kind of trend of latest developments is concentrated type Betengent products that preparation comprises the active substance of increasing amount.Reduce to minimumly for consumption of energy in washing process, require the concentrated type washing composition being lower than under 40 ℃ the temperature, even at room temperature for example under 25 ℃, can operate effectively.Such washing composition mostly just comprises a spot of filler or processing material, as sodium sulfate or sodium-chlor.Based on the gross weight of washing composition, the consumption of such filler is generally 0-10wt%, is preferably 0-5wt%, especially 0-1wt%.The tap density of such washing composition is generally 650-1000g/l, is preferably 700-1000g/l, especially 750-1000g/l.
Washing composition can also exist with the form of small pieces.The individual features of small pieces is to prepare easily and be convenient to handle.Small pieces are the forms that the most closely give of solid detergent, its tap density for for example 0.9-1.3 kilogram/liter.For disintegration fast, the detergent for washing clothes small pieces comprise special disintegrating agent usually:
-effervescent is carbonate/citric acid for example;
-swelling agent such as Mierocrystalline cellulose, carboxymethyl cellulose, crosslinked poly-(N-V-Pyrol RC);
-quick dissolved material is sodium acetate (potassium acetate), perhaps Trisodium Citrate (or Tripotassium Citrate) for example;
-rapid water-soluble the hard coatings of dissolved is the omega-dicarboxylic acids compound for example.
Small pieces can also comprise the combination of any above-mentioned disintegrating agent.
Washing composition also can be mixed with the water of a kind of 5-50% of comprising, preferably comprise water liquid, aqueous of 10-35% or be mixed with the non-aqueous liquid detergent of the water that comprises the water that is no more than 5wt%, preferred 0-1wt%.Non-aqueous liquid detergent compositions can comprise other solvent as carrier.Low-molecular-weight uncle or secondary alcohol for example methyl alcohol, ethanol, propyl alcohol and Virahol are fit to.For the solvability tensio-active agent, monohydroxy-alcohol is preferred, and (for example, 1, ammediol, ethylene glycol, glycerine and propylene glycol) also can use but polyvalent alcohol for example comprises about 6 carbon atoms of 2-and 2 polyvalent alcohols to about 6 hydroxyls.Composition can comprise 5%-90%, is generally such carrier of 10%-50%.Washing composition can also exist with so-called " unit liquid dosages " form.
Handling textiles with these washing composition can handle in common washing machine at home.
Textile fibres to be processed can be natural or synthon or its mixture.The example of natural fiber comprises vegetable fibre for example cotton, viscose yarn, flax, artificial silk or linen, and preferably cotton, and animal fibre is wool, mohair, cashmere, mohair and silk for example, preferred wool.Synthon comprise polyester, polymeric amide and polyacrylonitrile fibre.Preferred textile fibres is cotton, polymeric amide and wool fiber, especially cotton fibre.The textile fibres that the inventive method is handled preferably has less than 200g/cm
3Density.
According to this method, based on the weight of textile fiber material, the consumption of the mixture of the compound of formula (1) and (2) is generally 0.01-3.0wt%, especially 0.05-3.0wt%.
Method is carried out under 5-100 ℃ temperature usually, especially carries out under 5-60 ℃ temperature.Preferably under 5-40 ℃ temperature, carry out, especially under 5-35 ℃ temperature, carry out, more preferably under 5-30 ℃ temperature, carry out.
Detergent composition herein is preferably as follows preparation: between the usage period, the pH value of bath water is between about 6.5-about 11, preferably between about 7.5-11 in the washing operation.The pH value of laundry product is 9-11.The technology of control pH value comprises and uses buffer reagent, alkali, sour or the like on the consumption of recommending, and those skilled in the art know those.
The machine clothes washing method typically is included in the washing machine with aqueous cleaning solution-treated dirty linen, wherein contain dissolving in the washing machine or be allocated in wherein significant quantity according to machine washing detergent composition of the present invention.The detergent composition of significant quantity for example is meant that in the machine washing method of routine the product (as typical product consumption) with 20g-300g dissolves or is dispersed in volume is in the washing soln (as common washing soln volume) that rises of 5-85.Example is
-top adds washing composition, Z-axis American version automatic washing machine, and the water of the about 45-83 litre of use in washing tub, wash(ing)cycle, about 10-was about 14 minutes, about 50 ℃ of the about 10-of washing water temperature;
-front adds washing composition, transverse axis Europe class automatic washing machine, and the water of the about 8-15 litre of use in washing tub, wash(ing)cycle, about 10-was about 60 minutes, about 95 ℃ of the about 30-of washing water temperature;
-front adds washing composition, Z-axis Japan type automatic washing machine, and the water of the about 26-52 litre of use in washing tub, wash(ing)cycle, about 8-was about 15 minutes, about 25 ℃ of the about 5-of washing water temperature.
Bath raio preferably 1: 4-1: 40, especially 1: 4-1: 15.Bath raio very preferably is 1: 4-1: 10, especially 1: 5-1: 9.
In addition, the present invention relates to a kind of detergent composition, it comprises the compound of at least a following formula
R wherein
1And R
2Be hydrogen or C unsubstituted or that replace each other independently
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces;
R
5Be C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl, and
M is hydrogen or positively charged ion,
And wherein washing composition comprises at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase.
As for compound and its substituting group of formula (1a), be suitable for the definition and the preferable range of the compound of above-mentioned formula (1).
The compound of interested formula (1a) is: R wherein
1And R
2Be hydrogen or C unsubstituted or that replace each other independently
1-C
8Alkyl,
X
4, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen, C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl, unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl, perhaps R
3And R
4The nitrogen-atoms that connects with them forms morpholine, piperidines or pyrrolidine ring, and R
5Be unsubstituted or the C of hydroxyl replacement
1-C
8Alkyl, and
M is hydrogen or positively charged ion.
The corresponding washing agent composition that very preferably comprises enzyme and superoxide, peroxide activator and/or bleaching catalyst.
Preferred detergent composition comprises
I) anion surfactant of 1-70% and/or nonionogenic tenside;
The ii) washing assistant of 0-75%;
The iii) superoxide of 0-30%;
The iv) peroxide activator of 0-10%;
The v) compound of the formula of 0.001-5% (1a); With
The vi) at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase, especially proteolytic enzyme of 0.05-5%.
Detergent composition very preferably comprises
I) anion surfactant of 5-70% and/or nonionogenic tenside;
The ii) washing assistant of 5-70%;
The iii) superoxide of 0.5-30%;
The iv) bleaching catalyst of the peroxide activator of 0.5-10% and/or 0.1-2%;
The v) compound of the formula of 0.01-5% (1a); With
The vi) at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase, especially proteolytic enzyme of 0.05-5%.
As for enzyme, washing composition and its component, be suitable for above-mentioned definition that provides and preferable range.The compound of formula (1a) can be to use with the same use-pattern of the mixture of the compound of the formula that provides above (1) and (2).
Further aim of the present invention provides a kind of home washings treatment process of textile fiber material, the water-detergent solution of the compound of definition (1a) contacts with comprising as above wherein to make textile fiber material, and wherein washing composition comprises at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase, and wherein in the entire treatment process, the temperature of solution is between 5 ℃-40 ℃, preferably between 5 ℃-30 ℃.
As for compound and the washing composition and the washing process of formula (1a), be suitable for above-mentioned definition that provides and preferable range.
The carrying out washing treatment of above-mentioned textile fiber can also use the mixture of formula (1) and (2) compound to carry out.
Compound and mixture that the present invention uses are particularly advantageous, because they not only demonstrate very high whitening capacity, and also show very the ideal water solubility under many circumstances and have fabulous white appearance down solid-state.Additional advantages of the present invention are that detergent composition has improved white performance and textile feel.In addition, these compounds and particularly mixture show extraordinary effect in nature in energy consumption.
These compounds have the following advantages: they are at the reactive chlorine donor, for example also are effectively under the existence of hypochlorite, and can be in washing tub and nonionic detergent, and for example alkyl phenol polyoxyethylene glycol ether uses together, and effect not loss basically.This external perborate or peracid and activator, for example tetrem acyl glycoluril or ethylenediamine tetraacetic acid (EDTA) exist down, and the mixture of these compounds and compound is in powder detergent and all be stable in the washing tub.In addition, they give a kind of beautiful outward appearance under daylight.
Also the mixture of the compound of discoverable type (1) and formula (1) and (2) compound can be effective to the fluorescent bleach textile materials, and wherein relevant with polymeric amide, wool and cotton should select especially.According to embodiment of the present invention, the textile fibres of processing can be natural or synthon or its mixture.The example of natural fiber comprises vegetable fibre for example cotton, viscose yarn, flax, artificial silk or linen, and preferably cotton, and animal fibre is wool, mohair, cashmere, mohair and silk for example, preferred wool.Synthon comprise polyester, polymeric amide and polyacrylonitrile fibre.Preferred textile fibres is cotton, polymeric amide and wool fiber.Preferably, the density of the textile fibres of handling according to the present invention is less than 1000g/m
2, especially less than 500g/m
2, most preferably less than 250g/m
2
Following examples are used for illustrating the present invention; Except as otherwise noted, part and per-cent are represented with weight.
Preparation embodiment 1:
In 1 liter of flask, with the compound of 0.05 mole following formula
Mix with 600ml water, be heated to 60 ℃.The 2-ethylaminoethyl alcohol that adds 9.2g then is heated to 98 ℃ with reaction mixture; During heating, by the aqueous sodium hydroxide solution that adds 4-mole (concentration) the pH value is remained between the 8.5-9.Reaction mixture is cooled to 50 ℃, the pH value is adjusted to 4.5 by the aqueous hydrochloric acid that adds 6-mole (concentration).Leach precipitation, also dry in a vacuum with the sodium chloride aqueous solution washing of 100ml 10%.In this way, obtain the light yellow product of 30.5g.
Preparation embodiment 2-15:
Can prepare the compound that the method that provides among the embodiment 1 prepares following formula according to being similar to,
The 2-ethylaminoethyl alcohol that replaces 9.2g with the corresponding amine of equimolar amount.X such as in the following Table 1 definition.Can directly separate with the form of sodium salt being cooled to the compound of separating out after 50 ℃, need not add hydrochloric acid, dry in a vacuum then.
Table 1
Preparation embodiment 16:
In 1 liter of flask, with the compound of 0.05 mole following formula
Mix with 600ml water, be heated to 60 ℃.Add the 9.5g morpholine then, reaction mixture is heated to 98 ℃; During heating, by the aqueous sodium hydroxide solution that adds 4-mole (concentration) the pH value is remained between the 8.5-9.Make reaction mixture be cooled to 40 ℃, leach throw out, also dry in a vacuum with the sodium chloride aqueous solution washing of 100ml 10%.In this way, obtain the yellow product of 30g.
Preparation embodiment 17-19:
Can prepare the compound that the method that provides among the embodiment 16 prepares following formula according to being similar to,
The morpholine that replaces 9.5g with the corresponding amine of equimolar amount.X in the following table 2 definition.Be cooled to before 50 ℃, the compound that will have high-dissolvability is handled with the aqueous hydrochloric acid of 6-mole (concentration), and the pH value is adjusted to 4.5.
Table 2
Preparation embodiment 20:
In 2 liters of flasks, 130ml methylethylketone, 80ml deionized water, 150g ice and 18.5g cyanuric fluoride are mixed.In 30 minutes, to wherein dripping 185ml 4,4 '-diaminostilbene-2, in the aqueous solution of 2 '-disulfonic acid (with the form of disodium salt) (concentration is 100g/l), temperature remains between-8 to+5 ℃.By adding aqueous sodium carbonate, the pH value is remained between 4.5 to 5.Obtain a kind of light yellow suspension.Then, use dropping funnel, add 27.2g thanomin (99%).The pH value increases to 10, drops to a lower value then, and temperature increases to 10-15 ℃.Reaction mixture is warmed to 45 ℃ then, and kept 20 minutes in this temperature.In being heated to 98 ℃ process, in 30 minutes, steam the mixture of methylethylketone and water; By adding aqueous sodium hydroxide solution the pH value is remained between the 8.5-9.Just can keep the pH value behind constant numerical value need not to add aqueous sodium hydroxide solution in addition, reaction mixture is cooled to 50 ℃.The pH value is adjusted to 5.5, leaches light yellow crystalline precipitate.After the drying, obtain the light yellow product of 29g.
Preparation embodiment 21:
Boost in the force container 1, with 0.037 mole N, N '-two-(4-morpholinyl-6-chloro-1,3,5-triazines-2-yl)-4,4 '-diaminostilbene-2,2 '-disulfonic acid (with the disodium salt form) is suspended in the 500ml water.Add the aqueous solution of 15g ethamine (70%), reaction mixture is heated to 100-105 ℃, and stirred 4.5 hours.Reaction mixture is cooled to 25 ℃, leaches throw out, also under 70 ℃, carry out drying in a vacuum with the sodium chloride aqueous solution washing of 100ml 10%.In this way, obtain the 25.8g buff powder.
Preparation embodiment 22:
Replace ethamine (70%) aqueous solution of 15g with the solution of the diethylamine that comprises equimolar amount accordingly, can be according to the compound of the similar approach preparation formula (107) of preparation embodiment 21.
Preparation embodiment 23:
In 1 liter of flask, with 0.05 mole N, N '-two-(4-morpholinyl-6-chloro-1,3,5-triazines-2-yl)-4,4 '-diaminostilbene-2,2 '-disulfonic acid (with the disodium salt form) is suspended in the 600ml water, is heated to 60 ℃ then.Add the 6.4g thanomin, reaction mixture is heated to 98 ℃.By adding the aqueous sodium hydroxide solution of 4-mole (concentration), the pH value is remained between 8.9 to 9.Reaction mixture is cooled to 25 ℃, adds the sodium-chlor of 10 volume %.Leach throw out, also under 70 ℃, carry out drying in a vacuum with the sodium chloride aqueous solution washing of 100ml 10%.In this way, obtain the 41.8g buff powder.
Application Example 1:
General method:
With 0.8 the gram detergent dissolving in the 200ml tap water with preparing washing solution.The cotton that 10g bleached joins in the groove, washed 15 minutes down at 40 ℃, and rinsing then, Rotary drying is 160 ℃ of ironings down.
Use following washing powder A and B (quantity provides, and is unit with g) in table 3a and 3b:
Table 3a(component of washing powder A and B)
| A | ?B | |
| Sodium dodecylbenzene sulfonate (LAS) | 10g | ?10g |
| Zetesol NL (AES) | 3g | ?3g |
| Dobanol 23-6.5 (non-ionic type fatty alcohol ethoxylate) | 4g | ?4g |
| Tripoly phosphate sodium STPP | 30g | ?---- |
| Zeolite A | ---- | ?20g |
| Yellow soda ash | 15g | ?15g |
| Water glass | 5g | ?5g |
| Sodium sulfate | 11g | ?11g |
| Cellulase | 1.5g | ?---- |
| Proteolytic enzyme | ---- | ?1.5g |
| Polycarboxylate (washing assistant altogether) | ---- | ?4g |
| Carboxymethyl cellulose | 2g | ?2g |
| Spices | 0.1g | ?0.1g |
| Water | 5g | ?5g |
| The mixture of white dyes or white dyes | Xg | ?Xg |
Table 3b(employed washing powder)
| The consumption of the mixture of employed white dyes or white dyes | Washing powder | |
| The compound of preparation embodiment 1 | 0.2g | ?A |
| The compound of preparation embodiment 2 | 0.1g | ?B |
| The compound of preparation embodiment 3 | 0.3g | ?A |
| The compound of preparation embodiment 4 | 0.2g | ?A |
| The compound of preparation embodiment 5 | 0.4g | ?A |
| The compound of preparation embodiment 12 | 0.15g | ?B |
| The compound of preparation embodiment 13 | 0.1g | ?B |
| The compound of preparation embodiment 16 | 0.3g | ?B |
| The mixture [weight ratio is 7: 3] of the compound of preparation embodiment 6 and the compound of formula (109) | 0.2g | ?A |
| The mixture [weight ratio is 7: 3] of the compound of preparation embodiment 12 and the compound of formula (109) | 0.4g | ?B |
| The mixture [weight ratio is 7: 3] of the compound of preparation embodiment 14 and the compound of formula (109) | 0.3g | ?A |
| The mixture [weight ratio is 1: 1] of the compound of preparation embodiment 17 and the compound of formula (109) | 0.2g | ?B |
| The mixture [weight ratio is 1: 2] of the compound of preparation embodiment 18 and the compound of formula (109) | 0.5g | ?B |
| The mixture [weight ratio is 1: 5] of the compound of preparation embodiment 1 and the compound of formula (109) | 0.3g | ?B |
| The mixture [weight ratio is 5: 1] of the compound of preparation embodiment 2 and the compound of formula (109) | 0.2g | ?B |
| The mixture [weight ratio is 1: 1] of the compound of preparation embodiment 3 and the compound of formula (109) | 0.2g | ?B |
| The mixture [weight ratio is 3: 7] of the compound of preparation embodiment 20 and the compound of formula (109) | 0.1g | ?A |
| The mixture [weight ratio is 1: 9] of the compound of preparation embodiment 21 and the compound of formula (109) | 0.1g | ?B |
| The mixture [weight ratio is 9: 1] of the compound of preparation embodiment 22 and the compound of formula (109) | 0.2g | ?B |
| The mixture [weight ratio is 1: 1] of the compound of preparation embodiment 23 and the compound of formula (109) | 0.4g | ?B |
| The mixture of the compound of the compound of formula (110) and formula (109) [weight ratio is 1: 1] | 0.3g | ?B |
The structure of formula (109) compound:
The structure of formula (110) compound:
Cotton fabric is washed according to general method with the washing composition that provides among the table 3b, the result shows good whiteness character.
Application Example 2:
General method:
With 0.8 the gram detergent dissolving in the 200ml tap water with preparing washing solution.The cotton that 10g was bleached joins in the groove, washed 15 minutes down at 30 ℃, and rinsing then, Rotary drying is 160 ℃ of ironings down.
Use following washing powder (quantity provides, and represents with weight percent, based on the gross weight of washing composition) in table 4a and 4b:
Table 4a(component of washing powder C and D)
| C | D | |
| Sodium dodecylbenzene sulfonate (LAS) | 8％ | 8％ |
| Zetesol NL (AES) | 3％ | 3％ |
| Dobanol 23-6.5 (non-ionic type fatty alcohol ethoxylate) | 5％ | 5％ |
| Zeolite A | 20％ | 20％ |
| Polycarboxylate (washing assistant altogether) | 5％ | 5％ |
| SODA ASH LIGHT 99.2 | 18％ | 18％ |
| Water glass | 4％ | 4％ |
| Sodium sulfate | 5％ | 5％ |
| Hydroxyl ethane di 2 ethylhexyl phosphonic acid (complexing agent) | 0.5％ | 0.5％ |
| Cellulase | 1.5％ | ---- |
| Proteolytic enzyme | ---- | 1.5％ |
| Carboxymethyl cellulose | 1％ | 1％ |
| The Sodium peroxoborate monohydrate | 15％ | 15％ |
| TAED | 5％ | 5％ |
| Soap | 2％ | 2％ |
| The mixture of used white dyes or white dyes | X％ | X％ |
In the washing composition, use the water of capacity to add to 100% in the above.
Table 4b(employed washing powder)
| The consumption of the mixture of employed white dyes or white dyes | Washing powder | |
| The compound of preparation embodiment 1 | 0.2％ | C |
| The compound of preparation embodiment 3 | 0.2％ | C |
| The compound of preparation embodiment 7 | 0.2％ | D |
| The compound of preparation embodiment 8 | 0.2％ | C |
| The compound of preparation embodiment 9 | 0.4％ | C |
| The compound of preparation embodiment 10 | 0.2％ | C |
| The compound of preparation embodiment 11 | 0.2％ | C |
| The compound of preparation embodiment 17 | 0.4％ | C |
| The compound of preparation embodiment 20 | 0.5％ | C |
| The compound of formula (110) | 0.3％ | D |
| The mixture [weight ratio is 10: 1] of the compound of preparation embodiment 1 and the compound of formula (109) | 0.2％ | D |
| The mixture [weight ratio is 5: 1] of the compound of preparation embodiment 3 and the compound of formula (109) | 0.4％ | C |
| The mixture [weight ratio is 1: 5] of the compound of preparation embodiment 5 and the compound of formula (109) | 0.15％ | C |
| The mixture [weight ratio is 1: 1] of the compound of preparation embodiment 11 and the compound of formula (109) | 0.2％ | C |
| The mixture [weight ratio is 1: 9] of the compound of preparation embodiment 15 and the compound of formula (109) | 0.4％ | C |
| The mixture [weight ratio is 9: 1] of the compound of preparation embodiment 16 and the compound of formula (109) | 0.3％ | D |
| The mixture [weight ratio is 1: 5] of the compound of preparation embodiment 19 and the compound of formula (109) | 0.2％ | D |
As for the structure of the compound of formula (109) and (110), referring to Application Example 1.
Cotton is washed according to general method with the washing composition that provides among the table 4b, the result shows good whiteness character.
Claims (32)
1. detergent composition comprises the compound of at least a following formula
Wherein
R
1And R
2Be hydrogen or C unsubstituted or that replace with being mutually independent
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen, cyano group, the unsubstituted or C that replaces
1-C
8Alkyl or C
5-C
7Cycloalkyl, perhaps R
3And R
4The nitrogen-atoms that connects with them forms heterocycle, and R
5Be C unsubstituted or that replace
1-C
8Alkyl, and
M is hydrogen or positively charged ion,
Compound with at least a following formula
R wherein
6And R
7Be hydrogen, C each other independently
1-C
8Alkyl, C
1-C
8Alkoxy or halogen, and M in the above-mentioned formula (1) definition.
2. according to the composition of claim 1, wherein
R
1And R
2Be hydrogen or C
1-C
4Alkyl,
R
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen that connects with their is former in forming unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces; With
R
5Be C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl.
3. according to the composition of claim 1 or 2, wherein
X
1, X
2, X
3And X
4Be formula-N (R
3) R
4Group.
4. the composition any according to claim 1-3, wherein
X
1And X
3Be amino and
X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen; Cyano group; Unsubstituted or by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The cyclohexyl that alkyl replaces; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.
5. according to the composition of claim 4, wherein
R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces, preferred morpholine ring.
6. the composition any according to claim 1-5, wherein
R
6And R
7Be that each sulfo group in hydrogen and the formula (2) is connected the ortho position.
7. the composition any according to claim 1-6, wherein
M is a hydrogen, basic metal or alkaline-earth metal, or ammonium, preferably sodium.
8. the composition any according to claim 1-7 comprises
I) anion surfactant of 1-70% and/or nonionogenic tenside;
The ii) washing assistant of 0-75%;
The iii) superoxide of 0-30%;
The iv) peroxide activator of 0-10%; With
The v) mixture of the formula of 0.001-5% (1) and (2) compound.
9. composition according to Claim 8 comprises
I) anion surfactant of 5-70% and/or nonionogenic tenside;
The ii) washing assistant of 5-70%;
The iii) superoxide of 0.5-30%;
The iv) bleaching catalyst of the peroxide activator of 0.5-10% and/or 0.1-2%; With
The v) mixture of the formula of 0.01-5% (1) and (2) compound.
10. the composition any according to claim 1-9, wherein detergent composition comprises at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase, preferably proteolytic enzyme.
11. a detergent composition comprises
The compound of at least a following formula
Wherein
R
1And R
2Be hydrogen or C unsubstituted or that replace each other independently
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces;
R
5Be C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl and
M is hydrogen or positively charged ion,
And wherein washing composition comprises at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase.
12. according to the composition of claim 11, wherein
X
1, X
2, X
3And X
4Be formula-N (R
3) R
4Group.
13. according to claim 11 and 12 any one compositions, wherein
X
1And X
3Be amino,
X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen; Cyano group or unsubstituted or by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The cyclohexyl that alkyl replaces; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or the pyrrolidine ring that alkyl replaces and
M is a hydrogen, basic metal or alkaline-earth metal, or ammonium, preferably sodium.
14. according to the composition of claim 13, wherein
R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces, preferred morpholine ring.
15. the composition any according to claim 11-14, wherein said composition comprises superoxide, peroxide activator and/or bleaching catalyst.
16. the composition any according to claim 11-15 comprises
I) anion surfactant of 1-70% and/or nonionogenic tenside;
The ii) washing assistant of 0-75%;
The iii) superoxide of 0-30%;
The iv) peroxide activator of 0-10%;
The v) compound of the formula of 0.001-5% (1a); With
The vi) at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase of 0.05-5%.
17. the composition any according to claim 11-16 comprises
I) anion surfactant of 5-70% and/or nonionogenic tenside;
The ii) washing assistant of 5-70%;
The iii) superoxide of 0.5-30%;
The iv) bleaching catalyst of the peroxide activator of 0.5-10% and/or 0.1-2%;
The v) compound of the formula of 0.01-5% (1a); With
The vi) at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase of 0.05-5%.
18. the composition any according to claim 11-17, wherein enzyme is a proteolytic enzyme.
19. a home washings is handled the method for textile fiber material, and textile fiber material is contacted with the aqueous solution of the washing composition of the compound that comprises following formula
Wherein
R
1And R
2Be hydrogen or C unsubstituted or that replace each other independently
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces;
R
5Be C unsubstituted or that replaced by hydroxyl
1-C
8Alkyl and
M is hydrogen or positively charged ion,
And wherein washing composition comprises at least a enzyme that is selected from cellulase, proteolytic enzyme, amylase and lipase, and wherein in the entire treatment process, the temperature of solution is between 5 ℃-40 ℃, preferably between 5 ℃-30 ℃.
20. according to the method for claim 19, wherein
X
1, X
2, X
3And X
4Be formula-N (R
3) R
4Group.
21. according to claim 19 and 20 any one methods, wherein
X
1And X
3Be amino,
X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen; Cyano group or unsubstituted or by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The cyclohexyl that alkyl replaces; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or the pyrrolidine ring that alkyl replaces and
M is hydrogen, basic metal or alkaline-earth metal or ammonium, preferably sodium.
22. according to the method for claim 21, wherein
R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces, preferred morpholine ring.
23. the method any according to claim 19-22 wherein used formula (1a) the compound treatment textile fiber material based on the weight 0.05-3.0wt% of textile fiber material.
24. the mixture of compound comprises the compound of at least a following formula
Wherein
R
1And R
2Be hydrogen or C unsubstituted or that replace with being mutually independent
1-C
8Alkyl,
X
1, X
2, X
3And X
4Be independently each other-N (R
3) R
4Or-OR
5, R wherein
3And R
4Be hydrogen, cyano group, the unsubstituted or C that replaces
1-C
8Alkyl or C
5-C
7Cycloalkyl, perhaps R
3And R
4The nitrogen-atoms that connects with them forms heterocycle, and R
5Be C unsubstituted or that replace
1-C
8Alkyl and
M is hydrogen or positively charged ion,
Compound with at least a following formula
Wherein, R
6And R
7Be hydrogen with being mutually independent, C
1-C
8Alkyl, C
1-C
8Alkoxy or halogen and M are as being defined so that following formula (1) is middle.
25. according to the mixture of the compound of claim 24, wherein
R
1And R
2Be hydrogen or C
1-C
4Alkyl,
R
3And R
4Be hydrogen; Cyano group; Unsubstituted or by hydroxyl, carboxyl, cyano group ,-CONH
2Or the C of phenyl replacement
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The C that alkyl replaces
5-C
7Cycloalkyl; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces; With
R
5Come C substituted or that replaced by hydroxyl
1-C
8Alkyl.
26. according to claim 24 and 25 each the mixtures of compound, wherein
X
1, X
2, X
3And X
4Be formula-N (R
3) R
4Group.
27. according to the mixture of any one compound of claim 24-26, wherein
X
1And X
3Be amino and
X
2And X
4Be formula-N (R
3) R
4Group, R wherein
3And R
4Be hydrogen; Cyano group or unsubstituted or by the C of hydroxyl or carboxyl substituted
1-C
8Alkyl, and C wherein
1-C
8Alkyl is continual or quilt-O-is interrupted; Unsubstituted or by C
1-C
4The cyclohexyl that alkyl replaces; Perhaps R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces.
28. according to the mixture of the compound of claim 27, wherein
R
3And R
4The nitrogen-atoms that connects with their forms unsubstituted or by C
1-C
4Morpholine, piperidines or pyrrolidine ring that alkyl replaces, preferred morpholine ring.
29. according to the mixture of any one compound of claim 24-28, wherein
R
6And R
7Be that each sulfo group in hydrogen and the formula (2) is connected the ortho position.
30. according to the mixture of any one compound of claim 24-29, wherein
M is hydrogen, basic metal or alkaline-earth metal or ammonium, preferably sodium.
31. the method for optically brightening of a textile materials comprises that the formula (1) that makes definition in textile materials and the claim 1 and the mixture of (2) compound contact.
32. according to the method for claim 31, wherein textile materials is polymeric amide, wool or cotton.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405136 | 2002-02-25 | ||
| EP02405136.9 | 2002-02-25 | ||
| EP02405876 | 2002-10-11 | ||
| EP02405876.0 | 2002-10-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1596299A true CN1596299A (en) | 2005-03-16 |
| CN1294247C CN1294247C (en) | 2007-01-10 |
Family
ID=27758773
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038016044A Expired - Lifetime CN1294247C (en) | 2002-02-25 | 2003-02-18 | Process for the treatment of textile fibre materials |
| CNB038016168A Expired - Lifetime CN1294248C (en) | 2002-02-25 | 2003-02-18 | Process for the treatment of textile fibre materials |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038016168A Expired - Lifetime CN1294248C (en) | 2002-02-25 | 2003-02-18 | Process for the treatment of textile fibre materials |
Country Status (12)
| Country | Link |
|---|---|
| EP (4) | EP1478724B1 (en) |
| JP (2) | JP4567975B2 (en) |
| CN (2) | CN1294247C (en) |
| AR (3) | AR038583A1 (en) |
| AT (2) | ATE340242T1 (en) |
| AU (2) | AU2003208870B2 (en) |
| BR (3) | BR0306184B1 (en) |
| DE (2) | DE60308661T2 (en) |
| ES (3) | ES2271534T3 (en) |
| TW (2) | TWI332045B (en) |
| WO (2) | WO2003070869A1 (en) |
| ZA (2) | ZA200402941B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104801511A (en) * | 2014-01-26 | 2015-07-29 | 艺康美国股份有限公司 | In-situ cleaning technology and system |
| CN105001671A (en) * | 2015-06-29 | 2015-10-28 | 纳爱斯丽水日化有限公司 | Compound brightening agent and washing agent composition containing compound brightening agent |
| CN107857738A (en) * | 2017-11-28 | 2018-03-30 | 贺州学院 | The synthesis and application of hexadecylamino pyrrolotriazine derivatives |
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| JP4567975B2 (en) * | 2002-02-25 | 2010-10-27 | チバ ホールディング インコーポレーテッド | Method of processing fiber material |
| JP4791955B2 (en) * | 2003-03-24 | 2011-10-12 | チバ ホールディング インコーポレーテッド | Detergent composition |
| BRPI0506979A (en) | 2004-01-20 | 2007-07-03 | Ciba Sc Holding Ag | triazinylamino stilbene disulfonic acid mixtures |
| AU2005235734A1 (en) * | 2004-04-20 | 2005-11-03 | Ciba Specialty Chemicals Holding Inc. | Amphoteric fluorescent whitening agents in detergent formulations |
| ES2404533T3 (en) * | 2004-08-30 | 2013-05-28 | Basf Se | Matting Process |
| MX2008014440A (en) * | 2006-05-23 | 2008-11-26 | Ciba Holding Inc | A detergent composition for textile fibre materials. |
| US9885095B2 (en) | 2014-01-31 | 2018-02-06 | Goldcorp Inc. | Process for separation of at least one metal sulfide from a mixed sulfide ore or concentrate |
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| US4364845A (en) * | 1978-07-17 | 1982-12-21 | Ciba-Geigy Corporation | Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners which are stable on storage |
| JPS5817199A (en) * | 1981-07-23 | 1983-02-01 | 花王株式会社 | Detergent composition |
| US4460485A (en) * | 1983-07-15 | 1984-07-17 | Lever Brothers Company | Polyester fabric conditioning and whitening composition |
| GB2158454B (en) | 1984-04-06 | 1988-05-18 | Colgate Palmolive Co | Liquid laundry detergent composition |
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-
2003
- 2003-02-18 JP JP2003569763A patent/JP4567975B2/en not_active Expired - Fee Related
- 2003-02-18 AU AU2003208870A patent/AU2003208870B2/en not_active Ceased
- 2003-02-18 AT AT03706527T patent/ATE340242T1/en active
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104801511A (en) * | 2014-01-26 | 2015-07-29 | 艺康美国股份有限公司 | In-situ cleaning technology and system |
| CN104801511B (en) * | 2014-01-26 | 2018-09-18 | 艺康美国股份有限公司 | Ex-situ cleaning process and clean-in-place system |
| CN105001671A (en) * | 2015-06-29 | 2015-10-28 | 纳爱斯丽水日化有限公司 | Compound brightening agent and washing agent composition containing compound brightening agent |
| CN107857738A (en) * | 2017-11-28 | 2018-03-30 | 贺州学院 | The synthesis and application of hexadecylamino pyrrolotriazine derivatives |
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