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CN1587180A - High performance cement base self leveling material - Google Patents

High performance cement base self leveling material Download PDF

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Publication number
CN1587180A
CN1587180A CNA2004100530305A CN200410053030A CN1587180A CN 1587180 A CN1587180 A CN 1587180A CN A2004100530305 A CNA2004100530305 A CN A2004100530305A CN 200410053030 A CN200410053030 A CN 200410053030A CN 1587180 A CN1587180 A CN 1587180A
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leveling
leveling material
performance cement
slag
self
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CN1238295C (en
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陈兵
陈龙珠
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Shanghai Jiao Tong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
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    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The high performance self-leveling cement base material used in building engineering consists of portland cement 25-35 wt%, flyash 3.2-4.5 wt%, fine silica powder 0-3.0 wt%, slag 2.8-4.0 wt%, building sand 50-63 wt%, expanding agent 3.27-3.7 wt% and high efficiency water reducing agent 0.23-0.40 wt%. The present invention has the advantages of wide material source, low cost and capacity of reducing environmental pollution, and the hardened material has high density, high anti-seepage performance and high adhesion.

Description

高性能水泥基自流平材料High-performance cement-based self-leveling material

技术领域technical field

本发明涉及的是一种水泥基自流平材料,具体地讲,涉及一种用于地面找平或建筑结构修补加固的高性能水泥基自流平材料。用于建筑材料技术领域。The invention relates to a cement-based self-leveling material, in particular to a high-performance cement-based self-leveling material used for ground leveling or building structure repair and reinforcement. Used in the technical field of building materials.

背景技术Background technique

地面作为建筑的一个重要的组成部分,其质量已引起了人们极大的关注。建筑地面在施工时,常出现以下通病:因抢工期或未按规定要求使用原材料及操作规程施工,或未按规定养护,过早上人,交叉作业,造成地面凹凸不平、起砂、麻面、地面毁坏等,在已完工后的地面上,抹砂浆或转运砂浆和混凝土,造成地面很多灰疙瘩等。以往通常的处理方法是将地面凿毛,然后再在其上抹一层2cm厚的砂浆,费工、费时、费料,既不能保证地面平整度,又增加了地面楼板的自重。针对上述问题,对传统地面材料进行了一次改革,提出了一种新的材料——地面自流平材料。最初,自流平材料主要是石膏系的,但其耐水性比较差,且由于是中性或酸性,对钢筋有锈蚀的危险,因而使用范围受到限制。于是水泥系自流平材料的开发研究在国际上引起重视,并相继有产品问世。As an important part of the building, the quality of the ground has attracted great attention. During the construction of the building ground, the following common problems often occur: the ground is uneven, sandy, pockmarked, Ground damage, etc., on the completed ground, plaster or transfer mortar and concrete, resulting in a lot of ash bumps on the ground. In the past, the usual treatment method was to chisel the ground, and then spread a layer of 2cm thick mortar on it, which was labor-intensive, time-consuming, and material-intensive. It could not guarantee the flatness of the ground, and increased the weight of the ground floor. In response to the above problems, a reform was carried out on the traditional ground materials, and a new material - self-leveling material for the ground was proposed. Initially, self-leveling materials were mainly gypsum-based, but their water resistance was relatively poor, and because they were neutral or acidic, there was a risk of corrosion to steel bars, so their scope of use was limited. Therefore, the development and research of cement-based self-leveling materials has attracted international attention, and products have come out one after another.

经对现有技术的文献检索发现,王学森等在《建筑技术开发》第29卷,第4期2002.4,P33-35撰文《低热超级自流平砂浆研究》,该文提出了一种通过适量掺入粒化高炉矿渣和硅粉的超级自流平砂浆,主要用于注浆补强工程,这种自流平砂浆由于掺加了大量的粒化高炉矿渣,有效地降低了水化热,因此避免了由于水化温度高而引起收缩裂缝。但此种自流平砂浆不宜用于地面找平。另外这种自流平砂浆存在着新拌砂浆扩展度经时损失大,抗离析、泌水能力较差,不能完全满足砂浆搅拌运输、泵送和施工的要求,与传统的抹面砂浆相比,原材料要求较高,价格非常昂贵,且难以大面积推广使用。After searching the literature of the prior art, it was found that Wang Xuesen et al. wrote the article "Research on Low-heat Super Self-Leveling Mortar" in "Building Technology Development" Volume 29, No. 4, 2002.4, P33-35. The super self-leveling mortar of granulated blast furnace slag and silicon powder is mainly used for grouting reinforcement projects. This self-leveling mortar effectively reduces the heat of hydration due to the addition of a large amount of granulated blast furnace slag, thus avoiding the High hydration temperature causes shrinkage cracks. But this kind of self-leveling mortar is not suitable for ground leveling. In addition, this kind of self-leveling mortar has a large loss of fresh mortar expansion over time, poor segregation resistance and bleeding ability, and cannot fully meet the requirements of mortar mixing, transportation, pumping and construction. Compared with traditional plastering mortar, raw materials The requirements are high, the price is very expensive, and it is difficult to promote and use it in a large area.

发明内容Contents of the invention

本发明的目的在于针对现有技术中存在不足和缺陷,提供一种高性能水泥基自流平材料,使其能用于地面自流找平,旧地面、起砂地面及施工不合格地面修补和一些特殊建筑结构的加固和修补,适当调整该材料的配方与生产工艺,其可以作为灌浆料进行使用。The purpose of the present invention is to provide a high-performance cement-based self-leveling material for the deficiencies and defects in the prior art, so that it can be used for self-leveling of the ground, old ground, sandy ground and unqualified ground repair and some special For the reinforcement and repair of building structures, the formula and production process of the material can be adjusted appropriately, and it can be used as a grouting material.

本发明是通过以下技术方案实现的,本发明各组分及其重量百分比为:The present invention is achieved through the following technical solutions, each component of the present invention and weight percentage thereof are:

普通硅酸盐水泥                    25~35%Ordinary Portland cement 25~35%

粉煤灰                            3.2~4.5%Fly ash 3.2~4.5%

微硅粉                            0~3.0%Micro silica fume 0~3.0%

矿渣                              2.8~4.0%Slag 2.8~4.0%

建筑用砂                          50~63%Construction sand 50~63%

膨胀剂                            3.27~3.7%Expansion agent 3.27~3.7%

高效减水剂                        0.23~0.40%Superplasticizer 0.23~0.40%

本发明由普通硅酸盐水泥、粉煤灰、矿渣、微硅粉、建筑用砂、膨胀剂和高效减水剂按一定比例混合均匀袋装而成。主要是利用市售普通建筑材料来实现高性能水泥基自流平材料基本性能:The invention is prepared by uniformly mixing ordinary Portland cement, fly ash, slag, microsilica fume, building sand, expansion agent and high-efficiency water reducing agent in a certain proportion and packing them in bags. The basic performance of high-performance cement-based self-leveling materials is mainly achieved by using commercially available common building materials:

1.采用粉煤灰、矿渣和微硅粉部分取代硅酸盐水泥,利用粉煤灰和矿渣改善拌和物的流动性能,采用微硅粉改善拌和物的保水性和提高自流平砂浆强度和密实性。这样可以大大降低了成本,而且减少环境污染,有效利用废物。水泥宜选用425.强度等级的硅酸盐水泥,粉煤灰宜选用I级粉煤灰,矿渣宜选用磨细矿渣,微硅粉宜选用Elken公司提供的,其颗粒粒径约0.01~0.1μm。1. Use fly ash, slag and micro-silica fume to partially replace Portland cement, use fly ash and slag to improve the flow performance of the mixture, and use micro-silica fume to improve the water retention of the mixture and improve the strength and compactness of the self-leveling mortar sex. In this way, the cost can be greatly reduced, and the environmental pollution can be reduced, and the waste can be effectively used. Portland cement with a strength grade of 425 should be used for cement, grade I fly ash should be used for fly ash, finely ground slag should be used for slag, and micro silica fume should be provided by Elken Company, with a particle size of about 0.01-0.1 μm .

2.采用符合JGJ52-92《普通混凝土用砂质量标准和试验方法》要求的普通建筑用砂,通过严格控制砂子的级配将砂子分级后再混合,以大大改善砂浆的流动性和减少价格昂贵的有机外加剂的用量。本发明自流平砂浆中用的砂子应符合如下粒径和级配要求:2. Use ordinary construction sand that meets the requirements of JGJ52-92 "Quality Standards and Test Methods for Ordinary Concrete Sand". Strictly control the gradation of the sand and then mix the sand after grading to greatly improve the fluidity of the mortar and reduce the price. The amount of organic admixtures. The sand used in the self-leveling mortar of the present invention should meet the following particle size and gradation requirements:

2.500~5.000mm                        0~6%(重量比)2.500~5.000mm 0~6% (weight ratio)

1.250~2.500mm                        20~35%(重量比)1.250~2.500mm 20~35% (weight ratio)

0.315~1.250mm                        55~65%(重量比)0.315~1.250mm 55~65% (weight ratio)

<0.315mm                             10~15%(重量比)<0.315mm 10~15% (weight ratio)

即砂子的细度模数在2.7~2.9范围内。That is, the fineness modulus of the sand is in the range of 2.7 to 2.9.

3.所述的膨胀剂为掺入非引气型膨胀剂铝酸钙类,通过化学反应产生体积膨胀,从而使砂浆的干缩得到补偿并使砂浆更密实。膨胀剂的掺量应控制在能补偿砂浆的干缩并稍有膨胀的范围,其掺量为胶凝材料的5~10%。3. The expansion agent is mixed with non-air-entraining expansion agent calcium aluminate, which produces volume expansion through chemical reaction, so that the drying shrinkage of the mortar is compensated and the mortar is denser. The amount of expansion agent should be controlled within the range that can compensate for the dry shrinkage of the mortar and a slight expansion, and its amount is 5-10% of the cementitious material.

4.所述的高效减水剂为本发明中掺加萘磺酸盐系高效减水剂粉末,掺加量为胶凝材料的0.50~1.2%。为使砂浆能实现自流平,具有较大的流动度,需要掺入适量高效减水剂。4. The high-efficiency water reducer is the powder of naphthalenesulfonate-based high-efficiency water reducer in the present invention, and the addition amount is 0.50-1.2% of the gelling material. In order for the mortar to achieve self-leveling and have greater fluidity, it is necessary to add an appropriate amount of high-efficiency water reducer.

本发明的制备方法是:按配方比例称所需的取普通硅酸盐水泥、粉煤灰、矿渣、微硅粉、建筑用砂、膨胀剂和高效减水剂,在搅拌机中充分搅拌均匀,形成产品,进行装袋。现场使用时,加入胶凝材料重量40~45%的拌和水。The preparation method of the present invention is: according to the proportion of the formula, the required ordinary Portland cement, fly ash, slag, microsilica fume, construction sand, expansion agent and high-efficiency water reducer are weighed, fully stirred in a mixer, The product is formed and bagged. When used on site, add mixing water with 40-45% of the weight of the cementitious material.

本发明的优点在于:使用常规建筑材料,具有原料来源广泛,成本低的优点;在原材料中采用粉煤灰和矿渣部分取代水泥,一方面为废物利用,可减少对环境的污染和减少水泥用量,节省能,另外一方面,掺加粉镁灰和矿渣,利用其玻璃微珠效应,提高拌和物流动性,减少化学外加剂掺量,降低成本;采用微硅粉部分取代水泥,提高自流平砂浆保水性和硬化后的强度及密实性;袋装现场拌和,降低环境污染,操作简便,实现自流平,降低人工成本;通过掺加非引气型膨胀剂达到补偿并稍有微膨胀的作用,使硬化后的材料具有高致密、高抗渗、高粘结力的特点且安定性、保水性良好。The invention has the advantages of: using conventional building materials, it has the advantages of wide source of raw materials and low cost; in the raw materials, fly ash and slag are used to partially replace cement, on the one hand, waste utilization can reduce environmental pollution and reduce cement consumption , to save energy, on the other hand, by adding powder magnesium ash and slag, using its glass bead effect to improve the fluidity of the mixture, reduce the amount of chemical admixtures, and reduce costs; use silica fume to partially replace cement to improve self-leveling Mortar water retention and hardened strength and compactness; bagged on-site mixing, reducing environmental pollution, easy operation, self-leveling, reducing labor costs; compensation and slight expansion by adding non-air-entraining expansion agent , so that the hardened material has the characteristics of high density, high impermeability, high adhesion, and good stability and water retention.

具体实施方式Detailed ways

结合本发明内容提供以下实施例:The following embodiments are provided in conjunction with the contents of the present invention:

高性能水泥基自流平砂浆由普通硅酸盐水泥、粉煤灰、矿渣、微硅粉、建筑用砂、膨胀剂和高效减水剂按一定比例混合均匀砂组成,根据工程应用需要,通过调整发明配方,可以获得所需要的性能。High-performance cement-based self-leveling mortar is composed of ordinary Portland cement, fly ash, slag, microsilica fume, construction sand, expansion agent and high-efficiency water reducing agent. By inventing the formula, the required properties can be obtained.

实施例1Example 1

普通硅酸盐水泥                           25Ordinary Portland cement 25

粉煤灰                                   3.2Fly ash 3.2

微硅粉                                   2.0Micro silica fume 2.0

矿渣                                     2.8Slag 2.8

建筑用砂                                 63.0Construction sand 63.0

膨胀剂                                   3.7Expansion agent 3.7

高效减水剂                               0.30High-efficiency water reducer 0.30

上述组分按前述工艺制备得高性能水泥基自流平砂浆干粉,加入胶凝材料质量的0.45的自来水,进行搅拌,测得其性能如下:扩展度为280mm,抗压强度(7天)38.5MPa,抗折强度(7天)6.52MPa;The above components are prepared according to the aforementioned process to prepare high-performance cement-based self-leveling mortar dry powder, add tap water with a mass of 0.45 of the cementitious material, and stir. The measured properties are as follows: the degree of expansion is 280mm, and the compressive strength (7 days) is 38.5MPa , flexural strength (7 days) 6.52MPa;

           抗压强度(28天)59.3MPa,抗折强度(28天)8.76MPa;膨胀率    7天:0.024%,28天  0.026%,56天  0.027%   Compressive strength (28 days) 59.3MPa, flexural strength (28 days) 8.76MPa; expansion rate 7 days: 0.024%, 28 days 0.026%, 56 days 0.027%

实施例2Example 2

普通硅酸盐水泥                    30.0Ordinary Portland cement 30.0

粉煤灰                            3.04Fly ash 3.04

微硅粉                            0Micro silica fume 0

矿渣                              3.04Slag 3.04

建筑用砂                          60.0Construction sand 60.0

膨胀剂                            3.5Expander 3.5

高效减水剂                        0.42Superplasticizer 0.42

上述组分按前述工艺制备得高性能水泥基自流平砂浆干粉,加入胶凝材料质量的0.45的自来水,进行搅拌,测得其性能如下:扩展度为290mm,抗压强度(7天)34.0MPa,抗折强度(7天)6.28MPa;The above components are prepared according to the aforementioned process to prepare high-performance cement-based self-leveling mortar dry powder, add tap water with a mass of 0.45 of the cementitious material, and stir. The measured properties are as follows: the degree of expansion is 290mm, and the compressive strength (7 days) is 34.0MPa , flexural strength (7 days) 6.28MPa;

           抗压强度(28天)50.5MPa,抗折强度(28天)8.54MPa;膨胀率    7天:0.026%,28天  0.028%,56天  0.029%  Compressive strength (28 days) 50.5MPa, flexural strength (28 days) 8.54MPa; expansion rate 7 days: 0.026%, 28 days 0.028%, 56 days 0.029%

实施例3(实例中均为质量比)Embodiment 3 (all are mass ratio in the example)

普通硅酸盐水泥                        35.0Ordinary Portland cement 35.0

粉煤灰                                4.5Fly ash 4.5

微硅粉                                3.0Micro silica fume 3.0

矿渣                                  4.0Slag 4.0

建筑用砂                              50.0Construction sand 50.0

膨胀剂                                3.27Expanding agent 3.27

高效减水剂                            0.23Superplasticizer 0.23

上述组分按前述工艺制备得高性能水泥基自流平砂浆干粉,加入胶凝材料质量的0.45的自来水,进行搅拌,测得其性能如下:扩展度为290mm,抗压强度(7天)37.0MPa,抗折强度(7天)6.50MPa;The above components are prepared according to the aforementioned process to prepare high-performance cement-based self-leveling mortar dry powder, add tap water with a mass of 0.45 of the cementitious material, and stir. The measured properties are as follows: the degree of expansion is 290mm, and the compressive strength (7 days) is 37.0MPa , flexural strength (7 days) 6.50MPa;

           抗压强度(28天)60.5MPa,抗折强度(28天)9.0MPa膨胀率    7天:0.025%,28天  0.028%,56天  0.030%  Compressive strength (28 days) 60.5MPa, flexural strength (28 days) 9.0MPa Expansion rate 7 days: 0.025%, 28 days 0.028%, 56 days 0.030%

Claims (4)

1, a kind of high-performance cement based self-leveling material is characterized in that, each component and weight percent thereof are:
Ordinary Portland cement 25~35%
Flyash 3.2~4.5%
SILICA FUME 0~3.0%
Slag 2.8~4.0%
Building sand 50~63%
Swelling agent 3.27~3.7%
High efficiency water reducing agent 0.23~0.40%.
2, the described high-performance cement based self-leveling material of claim 1 is characterized in that, described building sand must meet following particle diameter and grating requires:
2.500~5.000mm 0~6% weight ratio
1.250~2.500mm 20~35% weight ratios
0.315~1.250mm 55~65% weight ratios
<0.315mm 10~15% weight ratios.
3, the described high-performance cement based self-leveling material of claim 1 is characterized in that, it is Powdered that described high efficiency water reducing agent is that naphthalenesulfonate is.
4, the described high-performance cement based self-leveling material of claim 1 is characterized in that, described swelling agent is the calcium aluminate class.
CNB2004100530305A 2004-07-22 2004-07-22 High performance cement base self leveling material Expired - Fee Related CN1238295C (en)

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CN1318345C (en) * 2005-10-09 2007-05-30 李凌伟 Self-leveling cement and its production process
CN100432003C (en) * 2007-05-11 2008-11-12 计慷 Fluorine-silicon self-leveling antistatic material
CN100462324C (en) * 2007-02-08 2009-02-18 上海交通大学 Fly ash expansive self-compacting concrete for filling square steel pipes
CN101985392A (en) * 2010-08-24 2011-03-16 江苏尼高科技有限公司 Plastering mortar using high-volume slag and preparation method thereof
CN102503305A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 Injectable garbage covering material
CN104402330A (en) * 2014-11-04 2015-03-11 潍坊德霖建材科技有限公司 Dry-mixed self-leveling mortar
CN104496320A (en) * 2014-12-18 2015-04-08 南京工业大学 Cement-based self-leveling mortar and preparation method thereof
CN105236894A (en) * 2015-10-29 2016-01-13 华南理工大学 Anti-shrinkage self-leveling mortar with good self-healing property for bedding layer and preparation method thereof
CN105481316A (en) * 2015-12-24 2016-04-13 邢台建工商品混凝土有限公司 Anti-oil-seepage mortar and preparation method thereof
CN105585281A (en) * 2014-10-20 2016-05-18 天津林山水泥制品有限公司 Corrosion-resistant cement fence and preparation method thereof
CN105622029A (en) * 2015-12-25 2016-06-01 江苏蓝圈新材料有限公司 Cement-based self-leveling mortar
CN106116421A (en) * 2016-06-28 2016-11-16 浙江共创建材科技有限公司 A kind of house ornamentation thick-layer gravity flowing levelling mortar and preparation method thereof
CN106587874A (en) * 2016-11-22 2017-04-26 闫博文 Method for preparing ground self-leveling mortar
CN109422506A (en) * 2017-09-04 2019-03-05 山东路联交通材料有限公司 A kind of fast solidifying, high-intensitive cement pavement conserving material
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CN100462324C (en) * 2007-02-08 2009-02-18 上海交通大学 Fly ash expansive self-compacting concrete for filling square steel pipes
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CN104496320A (en) * 2014-12-18 2015-04-08 南京工业大学 Cement-based self-leveling mortar and preparation method thereof
CN105236894A (en) * 2015-10-29 2016-01-13 华南理工大学 Anti-shrinkage self-leveling mortar with good self-healing property for bedding layer and preparation method thereof
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CN105622029A (en) * 2015-12-25 2016-06-01 江苏蓝圈新材料有限公司 Cement-based self-leveling mortar
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CN106587874A (en) * 2016-11-22 2017-04-26 闫博文 Method for preparing ground self-leveling mortar
CN109422506A (en) * 2017-09-04 2019-03-05 山东路联交通材料有限公司 A kind of fast solidifying, high-intensitive cement pavement conserving material
CN109422506B (en) * 2017-09-04 2021-07-13 山东路联交通材料有限公司 Quick-setting and high-strength cement pavement maintenance material
CN112573870A (en) * 2019-09-29 2021-03-30 华新水泥股份有限公司 Self-leveling terrace material and preparation method thereof
CN113213862A (en) * 2021-06-24 2021-08-06 山东业安建材有限公司 Yean self-leveling super early strength rapid hardening material and preparation method thereof
CN113213862B (en) * 2021-06-24 2024-02-09 山东业安建材有限公司 Self-leveling super-early-strength rapid hardening material and preparation method thereof

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