CN1562865A - High pure attapulgite clay and preparation method - Google Patents
High pure attapulgite clay and preparation method Download PDFInfo
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- CN1562865A CN1562865A CN 200410014477 CN200410014477A CN1562865A CN 1562865 A CN1562865 A CN 1562865A CN 200410014477 CN200410014477 CN 200410014477 CN 200410014477 A CN200410014477 A CN 200410014477A CN 1562865 A CN1562865 A CN 1562865A
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- purity
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- attapulgite
- recessed
- purificant
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- 229960000892 attapulgite Drugs 0.000 title claims abstract description 25
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004927 clay Substances 0.000 title claims abstract description 7
- 239000002689 soil Substances 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract 3
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000010453 quartz Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 4
- 230000010355 oscillation Effects 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 238000000975 co-precipitation Methods 0.000 claims 1
- 230000036571 hydration Effects 0.000 claims 1
- 238000006703 hydration reaction Methods 0.000 claims 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 238000009777 vacuum freeze-drying Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 238000000746 purification Methods 0.000 abstract description 6
- 239000011022 opal Substances 0.000 abstract description 5
- 229910021532 Calcite Inorganic materials 0.000 abstract description 4
- 239000013078 crystal Substances 0.000 abstract description 3
- 239000010459 dolomite Substances 0.000 abstract description 2
- 229910000514 dolomite Inorganic materials 0.000 abstract description 2
- 239000006004 Quartz sand Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- GNKTZDSRQHMHLZ-UHFFFAOYSA-N [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] Chemical compound [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] GNKTZDSRQHMHLZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- -1 rhombspar Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
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- Silicates, Zeolites, And Molecular Sieves (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
本发明公开了一种高纯凹凸棒土及其制备方法，是对天然凹凸棒粘土矿通过物理化学法进行除杂提纯制备高纯凹土的方法，属于矿物资源深加工技术领域。该方法适用于以含白云石、石英砂、方解石或蛋白石等杂质为主的凹土矿，它是以一种化学试剂为提纯分散剂，配制成一定浓度的水溶液，在一定温度和机械力的作用下，加入待处理的凹土，经充分分散和反应后，再经分离、干燥，制得晶形完好、色白、纯度达99％以上的凹土。该土可作为添加剂，用于彩色油墨、印染浆料、化妆品等。
The invention discloses a high-purity attapulgite and a preparation method thereof, which is a method for preparing high-purity attapulgite by removing impurities and purifying natural attapulgite clay ore through a physical and chemical method, and belongs to the technical field of deep processing of mineral resources. This method is suitable for attapulgite ore mainly containing impurities such as dolomite, quartz sand, calcite or opal. It uses a chemical reagent as a purification dispersant and prepares an aqueous solution of a certain concentration. Under the action, the attapulgite to be treated is added, fully dispersed and reacted, and then separated and dried to obtain the attapulgite with intact crystal form, white color and a purity of more than 99%. The soil can be used as an additive for color inks, printing and dyeing pastes, cosmetics, etc.
Description
Affiliated technical field
The present invention relates to a kind of high-purity attapulgite and preparation method thereof, belong to nonmetalliferous ore deep processing field.
Background technology
Attapulgite clay is called for short the silicate that recessed soil is a kind of rich magnesium, its molecular formula [Mg
5S
I8O
2o] (OH)
2(OH
2)
4.4H
2O, crystalline structure belong to 2: 1 type layer chain clay minerals, thereby give its very high use value because of its special structure and character.But because recessed soil usually and symbiosis such as rhombspar, calcite, quartz, opal, thereby directly influence its result of use and use range.
The U.S. is the state of discovery the earliest of recessed soil, also be the major country of production and the most widely used general state of research of recessed soil, purification its patent of invention U.S.Pat.No:6446601 and 6130179 about recessed Tu Kuang utilizes dispersion agent sodium polyacrylate (molecular weight 4000～5000) that recessed soil has been carried out effective dispersion purification, the domestic report that does not also have at present in this respect.
Summary of the invention
Purpose of the present invention just provides a kind of high-purity attapulgite and preparation method thereof, with the use value that improves recessed soil, expand its use range.
Technical solution of the present invention is: select for use inorganic salts as disperseing purificant, as silicate or poly-phosphate, not only with electrochemical action rhombspar, quartz etc. are effectively separated with recessed soil by absorption, also can form the titanium phosphate or the titanium silicate precipitation of black simultaneously with the band colour content titanium ion in the recessed soil by chemical reaction, make recessed soil change fish sperm look into from beige, whiteness is brought up to more than 85 from 0--40.
Purification principle of the present invention: because recessed native crystal has the good cleavage parallel with fibre axis, and layer-chain crystalline structure and fibrous fine crystals profile, Biao Mian noble potential helps aquation in addition, particularly Al
3+And Mg
2+Between extensively the having to be beneficial to and produce the active surface position and strengthen hydratability of different valency isomorphous replacement, therefore make recessed soil under impressed pressure, can fully disperse as system's shearing force or supersound process.The imbalance of surperficial inherent pore passage structure of recessed soil and surface charge forms adsorption center on recessed soil surface, therefore recessed native good adsorption performance makes and himself adsorbs big water gaging and dispersion agent and have good suspension property, thereby effectively separates with other materials such as rhombspar, quartz, calcite, opal etc.
Simultaneously, Ti
2++ Na
3PO
4Or NaSiO
3→ TiPO
4↓ or TiSiO
3↓+Na
+
The method of the high-purity recessed soil of recessed Tu Kuang purification preparation is:
The recessed Tu Kuang of recessed native content＞50% just is broken to 200～325 orders, is mixed with homogeneous phase solution with deionized water and dispersion purificant simultaneously, wherein disperseing the purificant consumption is 0.5%～3% of recessed Tu Kuang; Under stirring state, recessed Tu Kuang after just broken is added in the homogeneous phase solution, keeping temperature is 40～80 ℃, recessed native ore deposit add-on is 1 with the ratio of disperseing the purificant aqueous solution: 20-1: 10, alternately shear agitation and ultra-sonic oscillation repeatedly after, separate with gravity settling equipment or separating centrifuge, remove sedimentary impurity, the recessed native thickness body that obtains purifying makes loose recessed soil particle through lyophilize or vacuum-drying or spraying drying again.
Adopt the purify advantage of recessed Tu Kuang of the present invention to be:
1, purifying technique is simple and easy to do, and raw material is easy to get.
2, purification back product purity height can reach 99%, and whiteness can reach more than 85.
China Soviet Union recessed native mine belt type in Anhui mainly contains recessed soil type (impurity is for a small amount of quartzy), dolomite type, opal type, montmorillonite type, and in the class of above-mentioned various ore deposits, the massfraction of recessed soil is 10%～90%.Present method is applicable to that impurities is quartz, calcite, rhombspar, opal, and the recessed Tu Kuang of recessed native content＞50%.
Description of drawings
X-diffraction before and after Fig. 1 example 1 recessed soil is purified detects figure
Scanning electron microscope detected figure before and after Fig. 2 example 1 recessed soil was purified
X-diffraction before and after Fig. 3 example 2 recessed soil are purified detects figure
Scanning electron microscope detected figure before and after Fig. 4 example 2 recessed soil were purified
Embodiment
Example 1: contain quartz 17.2%, the recessed Tu Kuang of recessed native 83.8% greyish-green, just be broken to 200 orders, by adding 40 ℃ at 1: 20, containing in the homogeneous phase aqueous solution of sodium polyphosphate 1%, after 20min mechanical stirring and 10min ultra-sonic oscillation replace each 3 times, leave standstill 30min, produce tangible canescence suspension and black precipitate layering, extract out or incline and upper strata suspension, under 80～100 ℃, carry out vacuum spray drying, make recessed native content and be 99.5%, whiteness is 87 recessed soil particle.
X-diffraction, scanning electron microscope before and after recessed soil is purified detect as depicted in figs. 1 and 2.
Example 2: the recessed Tu Kuang of the canescence filter just that contains rhombspar, quartz 47.5% is to 300 orders, contain in water glass 2.5%, 60 ℃ the homogeneous phase aqueous solution by adding at 1: 15, after 30min mechanical stirring and 20min ultra-sonic oscillation replace each 2 times, leave standstill 60min earlier, upper strata suspension is inclined to, carry out centrifugation, obtain recessed native magma, again through 40 ℃ of vacuum lyophilizations, promptly obtain recessed native content and be 90%, whiteness is 91 recessed soil particle.
X-diffraction, scanning electron microscope before and after recessed soil is purified detect as shown in Figure 3 and Figure 4.
Claims (10)
1, the preparation method of high-purity attapulgite, it is characterized in that: the clay pit that with impurity component mainly is quartz, rhombspar, lime carbonate, proteinic natural Attapulgite is after filter just, under mechanical force, its adding is mixed with in the certain density dispersion purificant aqueous solution, at a certain temperature, be prepared into the clay ore pulp of certain density Attapulgite, after fully disperseing reaction, again through the clay or the concentrated clay ore pulp of making high-purity Attapulgite that separate, drying makes high-purity Attapulgite.
2, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: it is 200～325 orders that natural recessed Tu Kuang just filters fineness.
3, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: disperseing purificant is chemical pure or analytical pure, and its composition is poly-phosphate or silicate.
4, the preparation method of high-purity attapulgite according to claim 3 is characterized in that: disperse preferred sodium polyphosphate of purificant or water glass.
5, the preparation method of high-purity attapulgite according to claim 1, it is characterized in that: the dispersion purificant aqueous solution of preparation is homogeneous phase aqueous solution, institute's water is a deionized water, temperature remains on 40～80 ℃, and disperseing the purificant consumption is 0.5%～3% of handled recessed Tu Kuang according to foreign matter content in the recessed native ore deposit.
6, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: recessed native ore deposit add-on is 1: 20～1: 10 with the ratio of disperseing the purificant aqueous solution.
7, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: the mechanical force mode that recessed native ore pulp applied is middling speed shearing force or ultra-sonic oscillation.
8, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: recessed soil fully disperses under mechanical force and under the hydration, wherein is with color substance Ti
3+With dispersion purificant generation chemical reaction, generate black TiPO
4With other impurity coprecipitation in container bottom.
9, the preparation method of high-purity attapulgite according to claim 1 is characterized in that: disperseed to adopt the mode of centrifugation or gravity settling to separate with formed impurity with the recessed soil of purifying.
10, the preparation method of high-purity attapulgite according to claim 1, it is characterized in that: the high-purity recessed soil after the separation makes required high-purity recessed soil particle by air stream drying or vacuum freezedrying or spraying drying, or makes the high-purity recessed earth material slurry of desired concn by vacuum concentration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410014477 CN1248984C (en) | 2004-03-27 | 2004-03-27 | High pure attapulgite clay and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410014477 CN1248984C (en) | 2004-03-27 | 2004-03-27 | High pure attapulgite clay and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1562865A true CN1562865A (en) | 2005-01-12 |
| CN1248984C CN1248984C (en) | 2006-04-05 |
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ID=34478394
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410014477 Expired - Fee Related CN1248984C (en) | 2004-03-27 | 2004-03-27 | High pure attapulgite clay and preparation method |
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| Country | Link |
|---|---|
| CN (1) | CN1248984C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1321934C (en) * | 2005-06-02 | 2007-06-20 | 洛阳工业高等专科学校 | Compounding for cray of playgorskite (concave-convex bar stone) and its preparation (carbonizing) process |
| CN101519209B (en) * | 2009-03-30 | 2011-05-18 | 中国科学院等离子体物理研究所 | Method for constructing attapulgite nanometer network by utilizing ion beam |
| CN102874826A (en) * | 2012-10-18 | 2013-01-16 | 南京信息工程大学 | Purification technical method for attapulgite clay |
| CN101787224B (en) * | 2010-01-19 | 2013-07-17 | 江苏工业学院 | Compound of high-whiteness clay and preparation method thereof |
| CN104772107A (en) * | 2015-03-23 | 2015-07-15 | 广州优克日用品有限公司 | Modified attapulgite material, preparation method and application thereof |
| CN105271270A (en) * | 2014-07-01 | 2016-01-27 | 蒋寿悟 | High-purity attapulgite preparation method |
| CN108002400A (en) * | 2017-12-06 | 2018-05-08 | 潮州市华中陶瓷实业有限公司 | A kind of attapulgite clay product and preparation method thereof |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
-
2004
- 2004-03-27 CN CN 200410014477 patent/CN1248984C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1321934C (en) * | 2005-06-02 | 2007-06-20 | 洛阳工业高等专科学校 | Compounding for cray of playgorskite (concave-convex bar stone) and its preparation (carbonizing) process |
| CN101519209B (en) * | 2009-03-30 | 2011-05-18 | 中国科学院等离子体物理研究所 | Method for constructing attapulgite nanometer network by utilizing ion beam |
| CN101787224B (en) * | 2010-01-19 | 2013-07-17 | 江苏工业学院 | Compound of high-whiteness clay and preparation method thereof |
| CN102874826A (en) * | 2012-10-18 | 2013-01-16 | 南京信息工程大学 | Purification technical method for attapulgite clay |
| CN105271270A (en) * | 2014-07-01 | 2016-01-27 | 蒋寿悟 | High-purity attapulgite preparation method |
| CN104772107A (en) * | 2015-03-23 | 2015-07-15 | 广州优克日用品有限公司 | Modified attapulgite material, preparation method and application thereof |
| CN104772107B (en) * | 2015-03-23 | 2018-03-16 | 广州优克日用品有限公司 | A kind of modified attapulgite soil material and its preparation method and application |
| CN108002400A (en) * | 2017-12-06 | 2018-05-08 | 潮州市华中陶瓷实业有限公司 | A kind of attapulgite clay product and preparation method thereof |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
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| Publication number | Publication date |
|---|---|
| CN1248984C (en) | 2006-04-05 |
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