CN1554789A - Process for preparing tungsten-cobalt hard alloy - Google Patents
Process for preparing tungsten-cobalt hard alloy Download PDFInfo
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- CN1554789A CN1554789A CNA2003101208193A CN200310120819A CN1554789A CN 1554789 A CN1554789 A CN 1554789A CN A2003101208193 A CNA2003101208193 A CN A2003101208193A CN 200310120819 A CN200310120819 A CN 200310120819A CN 1554789 A CN1554789 A CN 1554789A
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 23
- 239000000956 alloy Substances 0.000 title claims abstract description 23
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000843 powder Substances 0.000 claims abstract description 72
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000005245 sintering Methods 0.000 claims abstract description 11
- 238000001238 wet grinding Methods 0.000 claims abstract description 11
- 239000011362 coarse particle Substances 0.000 claims description 18
- 239000010419 fine particle Substances 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 230000003179 granulation Effects 0.000 claims description 10
- 238000005469 granulation Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 2
- 229910008947 W—Co Inorganic materials 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005453 pelletization Methods 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 7
- 238000009413 insulation Methods 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 229910000531 Co alloy Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
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- Powder Metallurgy (AREA)
Abstract
The process of preparing hard W-Co alloy includes compounding material with WC powder and Co powder in 4-6 wt%, wet milling, drying, pelletizing after mixing with excipient, pressing to form, eliminating excipient, sintering and other steps. During compounding material, two kinds of WC powder, including great granularity component of 20-30 micron and fine granularity component of 1.2-1.8 micron in the weight ratio of 1.5-4.0, are used. The said process can compromise the wear resistance and toughness of hard alloy effectively to raise the comprehensive performance of alloy and expand the application range.
Description
One, technical field
The present invention relates to a kind of preparation method's of tungsten-cobalt hard alloy, particularly mining tungsten-cobalt hard alloy preparation method.
Two, background technology
At present, a series hard alloy of using in the rock drilling field is that cobalt contents is the middle coarse grain tungsten cobalt alloy of (4～6) wt%.The preparation method of such alloy generally comprise with WC powder and Co powder through batching, wet-milling, drying, mix binder granulation, press forming, take off steps such as forming agent, sintering, wherein the size range of WC powder is at (4～13) μ m, the Co content range is controlled at (4～6) wt%, the alloy of producing like this, its hardness value is for being generally (89.0～91.0) HRA, intensity level is generally (1600～2400) MPa, and notched bar impact strength is generally (2.5～3.5) J/cm
2The wear resistance of such alloy is fabulous, but toughness is too low, and therefore, the use range of this alloy is restricted, and generally is applicable to the rock stratum such as colliery that the f=8 level is following.
Three, summary of the invention
The present invention aims to provide a kind of preparation method of tungsten cobalt alloy, coordinates its wear resistance and toughness effectively, improves the over-all properties of alloy, enlarges the range of application of mine alloy, and the alloy of super quality and competitive price is provided for the rock drilling field.
In order to reach this purpose, technical scheme of the present invention comprise Co powder with WC powder and (4～6) wt% through batching, wet-milling, drying, mix binder granulation, press forming, take off steps such as forming agent, sintering, select two kinds of particulate WC of thickness powder during batching for use, wherein the granularity of coarse particles WC powder is (20～30) μ m, the granularity of fine particle WC powder is (1.2～1.8) μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 60: 40～80: 20.
Owing to adopted the WC grain heterogeneous texture, alloy structure improves: the WC grain adjacent degree reduces, and Co is more evenly distributed mutually, and porosity reduces, and formation of crack significantly reduces.Make the wear resistance of this alloy and toughness all be better than the coarse grain alloy with cobalt, this hardness of alloy value is (89.0～90.5) HRA, and intensity level is (1800～2600) MPa, and notched bar impact strength is (3.0～4.0) J/cm
2Because this alloy has the high-wearing feature and the high toughness of low cobalt alloy simultaneously,, can be used for the following rock stratum of f=10 level so its range of application obtains expanding.
As a further improvement on the present invention, adopt thin cobalt powder (1.0～1.5) μ m than better with the performance of common cobalt powder (2～3) μ m, its tough performance improves about 5%, and after adding the TaC of (0.3～0.6) wt%, its hardness (HRA) improves 0.2～0.3, and promptly its wear resistance also can be enhanced.
Four, embodiment
Embodiment 1: the Co powder of two kinds of WC powder of thickness and 6.0wt% is prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 24.0 μ m when batching, and the granularity of fine particle WC powder is 1.4 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 70: 30, and Co powder degree is 2.0 μ m.
Embodiment 2: the Co powder of two kinds of WC powder of thickness and 5.0wt% is prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 28.4 μ m when batching, and the granularity of fine particle WC powder is 1.2 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 70: 30, and Co powder degree is 1.0 μ m.
Embodiment 3: the Co powder of two kinds of WC powder of thickness and 4.0wt% is prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 20.0 μ m when batching, and the granularity of fine particle WC powder is 1.8 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 70: 30, and Co powder degree is 1.5 μ m.
Embodiment 4: the Co powder of two kinds of WC powder of thickness, 6.0wt% and the TaC of 0.3wt% are prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 30.0 μ m when batching, and the granularity of fine particle WC powder is 1.4 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 60: 40, and Co powder degree is 2.6 μ m.
Embodiment 5: the Co powder of two kinds of WC powder of thickness and 6.0wt% is prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 24.0 μ m when batching, and the granularity of fine particle WC powder is 1.4 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 80: 20, and Co powder degree is 3.0 μ m.
Embodiment 6: the Co powder of two kinds of WC powder of thickness, 5.0wt% and the TaC of 0.5wt% are prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 24.0 μ m when batching, and the granularity of fine particle WC powder is 1.4 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 70: 30, and Co powder degree is 3.0 μ m.
Embodiment 7: the Co powder of two kinds of WC powder of thickness, 4.0wt% and the TaC of 0.6wt% are prepared burden by certain requirement, wet-milling discharging after 20～23 hours, precipitate 5～8 hours, drying shake sieve, mix binder granulation, press forming, take off forming agent and 1450 ℃ the insulation 50 minutes steps such as sintering make Wimet.Wherein, the granularity of coarse particles WC powder is 24.0 μ m when batching, and the granularity of fine particle WC powder is 1.4 μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 70: 30, and Co powder degree is 1.34 μ m.
Table 1 has been listed the granularity and the concrete proportioning of powder when embodiment 1 prepares burden in 7, table 2 provides hardness, intensity and the notched bar impact strength of the Wimet of the method preparation of adopting embodiment 1 to 7.
Table 1
| Numbering | ??Co ??Wt％ | ??WC ??Wt％ | Wc grain size (μ m) | Co powder degree (μ m) | ??TaC ??Wt％ | WC thickness ratio (weight ratio) | |
| Slightly | Carefully | ||||||
| ??1 | ??6.0 | Surplus | ??24.0 | ??1.4 | ??2.0 | ??0 | ??70∶30 |
| ??2 | ??5.0 | Surplus | ??28.4 | ??1.2 | ??1.0 | ??0 | ??70∶30 |
| ??3 | ??4.0 | Surplus | ??20 | ??1.8 | ??1.5 | ??0 | ??70∶30 |
| ??4 | ??6.0 | Surplus | ??30 | ??1.4 | ??2.6 | ??0.3 | ??60∶40 |
| ??5 | ??6.0 | Surplus | ??24.0 | ??1.4 | ??3.0 | ??0 | ??80∶20 |
| ??6 | ??5.0 | Surplus | ??24.0 | ??1.4 | ??3.0 | ??0.5 | ??70∶30 |
| ??7 | ??4.0 | Surplus | ??24.0 | ??1.4 | ??1.34 | ??0.6 | ??70∶30 |
Table 2
Claims (3)
1, a kind of preparation method of tungsten-cobalt hard alloy, comprise Co powder with WC powder and (4～6) wt% through batching, wet-milling, drying, mix binder granulation, press forming, take off steps such as forming agent, sintering, it is characterized in that: select two kinds of particulate WC of thickness powder during batching for use, wherein the granularity of coarse particles WC powder is (20～30) μ m, the granularity of fine particle WC powder is (1.2～1.8) μ m, and the weight ratio of coarse particles WC powder and fine particle WC powder is 60: 40～80: 20.
2, the preparation method of tungsten-cobalt hard alloy according to claim 1 is characterized in that: the Co powder of selecting (1.0～1.5) μ m during batching for use.
3, according to the preparation method of claim 1 or 2 described tungsten-cobalt hard alloys, it is characterized in that: the TaC that adds (0.3～0.6) wt% during batching.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310120819 CN1236091C (en) | 2003-12-29 | 2003-12-29 | Process for preparing tungsten-cobalt hard alloy |
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|---|---|---|---|
| CN 200310120819 CN1236091C (en) | 2003-12-29 | 2003-12-29 | Process for preparing tungsten-cobalt hard alloy |
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| CN1554789A true CN1554789A (en) | 2004-12-15 |
| CN1236091C CN1236091C (en) | 2006-01-11 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338382B (en) * | 2007-07-06 | 2010-05-12 | 湖南世纪特种合金有限公司 | Method for preparing high strength cemented carbide |
| CN101851718A (en) * | 2010-05-18 | 2010-10-06 | 邬国平 | Carbon-adding hard alloy material and preparation method thereof |
| US8075661B2 (en) | 2007-09-19 | 2011-12-13 | Industrial Technology Research Institute | Ultra-hard composite material and method for manufacturing the same |
| CN101768679B (en) * | 2010-01-29 | 2012-07-04 | 株洲硬质合金集团有限公司 | Method for manufacturing hard alloy with nonuniform structure |
| CN102732766A (en) * | 2012-07-06 | 2012-10-17 | 四川大学 | Coarse grain hard alloy material and preparation method thereof |
| CN103643100A (en) * | 2013-12-11 | 2014-03-19 | 中国神华能源股份有限公司 | Nanocrystalline hard alloy and preparation method thereof |
| CN103667844A (en) * | 2013-12-31 | 2014-03-26 | 株洲硬质合金集团有限公司 | Hard alloy for low-load high-speed punching precision mold and preparation method thereof |
| CN104372227A (en) * | 2014-10-14 | 2015-02-25 | 遵义中铂硬质合金有限责任公司 | Hard alloy for hot-working die and production method thereof |
| CN105803288A (en) * | 2016-05-23 | 2016-07-27 | 株洲钻石切削刀具股份有限公司 | Non-homogeneous gradient hard alloy and preparation method thereof |
| CN109249030A (en) * | 2018-09-06 | 2019-01-22 | 晋城鸿刃科技有限公司 | The preparation method of tungsten-cobalt series hard alloy |
| WO2020038414A1 (en) * | 2018-08-22 | 2020-02-27 | 株洲欧科亿数控精密刀具股份有限公司 | Cemented carbide indexable cutting insert of layered structure and manufacturing method therefor |
| CN115584423A (en) * | 2022-11-04 | 2023-01-10 | 株洲硬质合金集团有限公司 | Composition for preparing low-cobalt ultra-coarse-grain hard alloy, and preparation method and application thereof |
-
2003
- 2003-12-29 CN CN 200310120819 patent/CN1236091C/en not_active Expired - Lifetime
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338382B (en) * | 2007-07-06 | 2010-05-12 | 湖南世纪特种合金有限公司 | Method for preparing high strength cemented carbide |
| US8075661B2 (en) | 2007-09-19 | 2011-12-13 | Industrial Technology Research Institute | Ultra-hard composite material and method for manufacturing the same |
| CN101768679B (en) * | 2010-01-29 | 2012-07-04 | 株洲硬质合金集团有限公司 | Method for manufacturing hard alloy with nonuniform structure |
| CN101851718A (en) * | 2010-05-18 | 2010-10-06 | 邬国平 | Carbon-adding hard alloy material and preparation method thereof |
| CN102732766A (en) * | 2012-07-06 | 2012-10-17 | 四川大学 | Coarse grain hard alloy material and preparation method thereof |
| CN103643100B (en) * | 2013-12-11 | 2016-02-03 | 中国神华能源股份有限公司 | A kind of Nanograin Cemented Carbide and preparation method thereof |
| CN103643100A (en) * | 2013-12-11 | 2014-03-19 | 中国神华能源股份有限公司 | Nanocrystalline hard alloy and preparation method thereof |
| CN103667844A (en) * | 2013-12-31 | 2014-03-26 | 株洲硬质合金集团有限公司 | Hard alloy for low-load high-speed punching precision mold and preparation method thereof |
| CN104372227A (en) * | 2014-10-14 | 2015-02-25 | 遵义中铂硬质合金有限责任公司 | Hard alloy for hot-working die and production method thereof |
| CN105803288A (en) * | 2016-05-23 | 2016-07-27 | 株洲钻石切削刀具股份有限公司 | Non-homogeneous gradient hard alloy and preparation method thereof |
| CN105803288B (en) * | 2016-05-23 | 2017-11-14 | 株洲钻石切削刀具股份有限公司 | A kind of non-homogeneous gradient hard alloy and preparation method thereof |
| WO2020038414A1 (en) * | 2018-08-22 | 2020-02-27 | 株洲欧科亿数控精密刀具股份有限公司 | Cemented carbide indexable cutting insert of layered structure and manufacturing method therefor |
| CN109249030A (en) * | 2018-09-06 | 2019-01-22 | 晋城鸿刃科技有限公司 | The preparation method of tungsten-cobalt series hard alloy |
| CN115584423A (en) * | 2022-11-04 | 2023-01-10 | 株洲硬质合金集团有限公司 | Composition for preparing low-cobalt ultra-coarse-grain hard alloy, and preparation method and application thereof |
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| CN1236091C (en) | 2006-01-11 |
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