CN1508185A - Antimicrobial injection-molded and method for producing same - Google Patents
Antimicrobial injection-molded and method for producing same Download PDFInfo
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- CN1508185A CN1508185A CNA2003101181010A CN200310118101A CN1508185A CN 1508185 A CN1508185 A CN 1508185A CN A2003101181010 A CNA2003101181010 A CN A2003101181010A CN 200310118101 A CN200310118101 A CN 200310118101A CN 1508185 A CN1508185 A CN 1508185A
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- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000000654 additive Substances 0.000 claims abstract description 40
- 230000000996 additive effect Effects 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004033 plastic Substances 0.000 claims abstract description 11
- 229920003023 plastic Polymers 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 229920005992 thermoplastic resin Polymers 0.000 claims description 23
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 238000002347 injection Methods 0.000 claims description 14
- 239000007924 injection Substances 0.000 claims description 14
- 229920002292 Nylon 6 Polymers 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 239000004677 Nylon Substances 0.000 claims description 10
- 229920001778 nylon Polymers 0.000 claims description 10
- 235000004443 Ricinus communis Nutrition 0.000 claims description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 244000005700 microbiome Species 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- CEDZFAONRDZJKJ-UHFFFAOYSA-N [O].ClC1=CC=CC(=C1)Cl Chemical compound [O].ClC1=CC=CC(=C1)Cl CEDZFAONRDZJKJ-UHFFFAOYSA-N 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 239000002033 PVDF binder Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000002952 polymeric resin Substances 0.000 claims 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000002991 molded plastic Substances 0.000 abstract description 20
- 238000001746 injection moulding Methods 0.000 abstract description 19
- 239000000088 plastic resin Substances 0.000 abstract description 11
- 239000003365 glass fiber Substances 0.000 abstract description 6
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004599 antimicrobial Substances 0.000 abstract 3
- 238000000151 deposition Methods 0.000 abstract 1
- 239000011342 resin composition Substances 0.000 abstract 1
- 229940105289 carbon black Drugs 0.000 description 7
- 235000019241 carbon black Nutrition 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 230000003115 biocidal effect Effects 0.000 description 6
- 241000233866 Fungi Species 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000001717 pathogenic effect Effects 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- 230000001052 transient effect Effects 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 206010011409 Cross infection Diseases 0.000 description 1
- 244000287680 Garcinia dulcis Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 244000227633 Ocotea pretiosa Species 0.000 description 1
- 235000004263 Ocotea pretiosa Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000002599 biostatic effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002989 phenols Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to injection-molded plastic products having an antimicrobial additive incorporated into the plastic resin from which the injection-molded plastic products are formed. A preferred antimicrobial additive comprises 5-chloro-2-(2,4-dichlorophenoxy) phenol. The injection-molded plastic products are formed by selecting an antimicrobial additive and an antimicrobial additive carrier system compatible with a plastic resin, combining the carrier system with the selected antimicrobial additive, incorporating the antimicrobial additive/carrier system into the plastic resin, depositing the plastic resin composition, including glass fibers or other high modulus fibers if desired, within the feed system of an injection-molding process and injecting the resin composition into a desired product-forming mold to form an injection-molded antimicrobial plastic product.
Description
Technical field
Generally speaking, the present invention relates to antibiotic injection-molded plastic products, and more particularly, relate to and have the antimicrobial compounds that is dispersed in the Plastic Resin that forms product or the injection-molded plastic products of pharmaceutical chemicals.
Background technology
Injection-molded plastic products is widely used in the various consumer's goods, in order to the structure of the firm plastic with ideal surfaced outward appearance to be provided.For example, injection-molded plastic products comprises furniture and the functional furniture components that is used for household, hotel, hospital, restaurant, school and other shelter or commercial location.Before can taking any self-protection measure, only be to have touched same vectorial two people just some diseases to be infected to another person by the carrier.Especially medical personnel, owing to touch object, for example furniture is the high risk population who is easy to infect disease, because may have various viruses, fungi and pathogenic bacterium on the object of described touch.Food food and drink practitioner places the dangerous condition of various viruses, fungi and pathogenic bacterium with himself and human consumer.In punishment mechanism, the office worker and the person of accommodating are owing to the situation of all same possible cross infections is in hazardous environment.In educational institution, for example school and day care facility, many facilities that it provided may be touched by many children, and propagate microorganism thus.
In example more specifically, injected-formative plastic is used to form the plastic components that is used for the seat, be the chair back and chair panel, seat, stadium, office chair, chair base, armrests and apparatus for adjusting position, and chair castor and other commercial and industrial articles for use, they all are used for one or more aforementioned environment.Yet the surface of these injection-molded plastic products is exposed in bacterium, fungi and the microorganism that is present in the aforementioned environment always.For example, injected-formative plastic chair base, chair castor and other plastic components are used for hospital and other environment, and these environment are relevant with breeding with pathogenic growth especially.In these environment, or the existence of moisture and moisture all is of value to the growth of pathogenic agent in any environment.These bacteriums, fungi and other pathogenic agent can be in surface growth and the breedings based on the product of injected-formative plastic, and can produce tangible microbial contamination as time goes by.A kind of method of microorganism growth of antagonism injection-molded product surface of suggestion is an application of disinfectant from the teeth outwards, for example smears the surface by spraying or sassafras and applies.Unfortunately, the just temporary transient removal of microorganisms of application of disinfectant with the surface, but as previously mentioned, relevant environment is the continuous source of further polluting.Repeat application of disinfectant cost height, time-consuming, lasting and be the existence and the growth of temporary transient combating microorganisms.In addition,, the resistates of sterilizing agent or biocide is entered in the environment, may cause negative impact to environment, particularly in hospital environment by surface applied sterilizing agent or other biocide at product.Therefore, need such injection-molded plastic products, it has the antiseptic-germicide of sneaking into wherein, and it shows antibacterial properties, does not have toxic action, and in the usage period of this injection-molded plastic products durable.Yet, by other material is sneaked in the injection-molded plastic products, can expect that the physical and mechanical property of this injection-molded product reduces, this is the mechanical composition because of a great deal of, for example glass fibre or fluoropolymer resin are substituted by other material.Therefore, further demand is exactly to have the antimicrobial compounds of sneaking in the Plastic Resin or the injection-molded plastic products of pharmaceutical chemicals, and it has physics and the mechanical characteristics that is similar to the injection-molded plastic products of not sneaking into antimicrobial compounds or pharmaceutical chemicals in the product.
Summary of the invention
The present invention relates to have antimicrobial characteristic, suppress the injection-molded plastic products of bacterium, fungi, microorganism and other pathogenic growth, and the production method of this injection-molded plastic products.This antiseptic-germicide, compound or pharmaceutical chemicals are sneaked in this injection-molded plastic products at production period.And, the present invention relates to have the antimicrobial compounds of sneaking in the product or the injection-molded plastic products of pharmaceutical chemicals, it has to be similar to does not have antimicrobial compounds or pharmaceutical chemicals to sneak into the physical and mechanical property of the injection-molded plastic products in the product.Antimicrobial additive is sneaked in the Plastic Resin that forms this injection-molded plastic products, thereby antiseptic-germicide is sneaked in this injection-molded plastic products.Preferred antimicrobial additive comprises 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol.Product by the injected-formative plastic resin formation comprises ad lib, the parts that are used for the seat, be the chair back and chair panel, seat, stadium, office chair, chair base, armrests and apparatus for adjusting position, and chair castor and other commercial and industrial articles for use etc.The following formation of injection molding plastic prod: select antimicrobial additive and the antimicrobial additive carrier system compatible with Plastic Resin, this carrier system is combined with selected antimicrobial additive, and antimicrobial additive/carrier system sneaked in the Plastic Resin, the Plastic Resin composition that will comprise glass fibre or other high modulus fibre if desired is deposited in the feed system of injection moulding method, and this resin combination injected the mould that forms desired product, to form injection molding antibiotic plastic product.
Specific embodiments
In basic form of the present invention, provide the injection molded article of the thermoplastic material that contains the significant quantity antimicrobial additive.The moulding prescription that will comprise thermoplastic resin and antimicrobial additive prescription mixes, and injection molding, forms this product.This thermoplastic resin is preferably selected from polyamide thermoplastic resin (for example nylon 6, nylon 6,6), polythene thermoplastic resin, polyurethane thermoplastic resin, polypropylene thermoplastic resin, polyvinyl chloride thermoplastic resin and aforesaid mixture.Nylon resin or polymeric amide are preferred, and be It is generally accepted have good mechanical strength, wear resistance and flexible one analog thermoplastic resin.Commercially important nylon prepares by conventional melt polymerization process, and comprises most preferred resin, nylon 6, and it prepares by caprolactam polymerization.This thermoplastic resin can be by comprising processing aid, tinting material or mechanical modifying agent, for example glass fibre or well known to a person skilled in the art other high modulus fibre and be improved.
This antimicrobial formulation comprises antimicrobial additive, and preferably also comprises vector resin.This antimicrobial additive is nontoxic, and does not contain heavy metal, and it is chlorinated phenol preferably, and for example 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol is also referred to as triclosan.Also can adopt and have known antibiotic, kill livestock thing or biological other compound that suppresses (biostatic) trend.Preferably, antimicrobial additive closes with suitable carriers is resin premixed, and described vector resin for example is a polyester, and is more preferably polyethylene terephthalate (PET).Preferred antimicrobial additive is IRGAGUARD
B1325 (the 25wt.%5-chloro-2-in the pet vector resin (2,4 dichloro benzene oxygen base) phenol) can be purchased by the Ciba Specialty Chemicals Corporation of USA New York Tarrytown.This antimicrobial additive is preferably about 0.1wt.% of total product composition to about 1.25wt.%.
The present invention relates more specifically to antimicrobial additive and sneaks into wherein injection molding nylon product, and described antimicrobial additive is given antimicrobial characteristic to product.Specifically, this product comprises functional furniture components, and more specifically saying so is used for the parts at seat, i.e. the chair back and chair panel, seat, stadium, office chair, chair base, armrests and apparatus for adjusting position, and chair castor and other are used for the commercial and industrial articles for use of commercial furniture.Unexpectedly be, the present inventor has been found that when comparing with the analogous products that do not contain antimicrobial additive the antimicrobial additive that adds 0.1wt.% to 1.25wt.% according to the present invention does not reduce physics, machinery and the appearance character of products obtained therefrom basically.The antimicrobial additive of sneaking into appropriate amount in nylon resin is important.Because the antimicrobial additive that uses has been replaced a part of nylon resin in the injection molding prescription, so obviously use antimicrobial additive will cause the pro rata reduction of physical properties of finished product.Surprisingly, situation is not such.The antimicrobial additive of sneaking into injection molding nylon product shows the physical properties that is similar to same product surprisingly, although replaced nylon resin by antimicrobial additive.
Following embodiment is in order to further specify the present invention.
1.01 joint
Embodiment 1
Use conventional injection moulding method that chair base of the present invention is carried out injection molding.This injection molding prescription is as follows: the not carbon black-filled impact modification nylon 6 of 39wt.%, its mean specific gravity is 1.13 (ASTM D792), average notch shock grade is 1.5ft-lb/in (ASTMD256), average tensile yield strength is 10500psi (ASTM D638) and average modulus in flexure is 400000psi (ASTM D790), for example can be purchased by the Matrix Group of the Evansville of U.S. Indiana State; The glass-filled nylon 6 of 57.5wt.%, average content of glass fiber is 43%, mean specific gravity is 1.49 (ASTM D792), average notch shock grade is 2.0ft-lb/in (ASTM D256), average tensile yield strength is that 243500psi (ASTM D638) and average modulus in flexure (tangent) are 1500000psi (ASTM D790), can be that ProductName is purchased with FP62E43 by MatrixGroup for example; The carbonblack master batch of 2wt.% (the 50wt.% carbon black in acrylic resin, its median size are 60 millimicrons), for example the Tech Master that can be purchased by the L.C.Plastics Inc of Montreal, CAN; IRGAGUARD with 1.5wt.%
B1325.This prescription is sent in the injection forming equipment, and under the maximum injection pressure of about 490 and 60-95%, injected die cavity.
From mould, take out the product and the cooling of gained.
Two samples to the injection molding chair base carry out bacterial growth inhibition test.Two samples all demonstrate ideal to the growth of bacterium and suppress effect.Also measure the physical properties of injection molding chair base by two samples being carried out statical load and drop shutter test, require to test according to AmericanNational Standards Institute/Business and Institutional FurnitureManufacturer ' s Association (ANSI/BIFMA), and these tests the results are shown in Table 1.
Table 1
| Sample | Statical load (ANSI/BIFMA X5.1-2002-basic test-static state) | Drop shutter test (ANSI/BIFMA X5.1-2002-fall test-dynamically) |
| 1 | ＞2500lb | ＞7in |
| 2 | ＞2500lb | ＞7in |
Embodiment 2
Except not using antimicrobial additive, adopt same moulding prescription, the method and apparatus preparation contrast chair base of embodiment 1.The injection molding prescription is as follows: the not carbon black-filled impact modification nylon 6 of 40wt.%; The glass-filled nylon 6 of 58wt.%, average content of glass fiber are 43% and the carbonblack master batch of 2wt.%.
Get two contrast chair base samples, and as carrying out the mensuration of physical properties as described in the embodiment 1.The results are shown in Table 2.
Table 2
| Sample | Statical load (ANSI/BIFMA X5.1-2002-basic test-static state) | Drop shutter test (ANSI/BIFMA X5.1-2002-fall test-dynamically) |
| 1 | ＞2500lb | ＞7in |
| 2 | ＞2500lb | ＞7in |
Surprisingly, antimicrobial additive replaces the physical properties that nylon resin does not reduce the injection molding nylon product.
Embodiment 3
The Coinjection molding apparatus production injection molding castor of use standard.Castor of the present invention, be called sample No. 1, make by following injection molding prescription: the not carbon black-filled impact modification nylon 6 of 98.5wt.%, its mean specific gravity is 1.13 (ASTM D792), average notch shock grade is 1.5ft-lb/in (ASTM D256), average tensile yield strength is 10500psi (ASTMD638) and average modulus in flexure is 400000psi (ASTM D790), for example can be purchased by the Matrix Group of the Evansville of Indiana, USA; IRGAGUARD with 1.5wt.%
B1325.Prescription is carried out injection molding under about 516 and 80% maximum injection pressure.Then castor is taken out from mould and cool off.In prescription, do not contain (100% not carbon black-filled impact modification nylon 6) the antimicrobial additive, make the preparation comparative sample that uses the same method, No. 2 samples.
Physical properties to two samples is measured, and the results are shown in Table 3.By 5 " fall on the castor weight of 30lbs of height carries out the shock resistance test, and note whether taking place mechanical failure and take place.
Table 3
| The sample sequence number | Durability test ANSI/BIFMA in April, 2002 draft | Impact test (150in-lb.) |
| 1 (the present invention) | Hard＞100000 cycles of wheel | Hard wheel passes through |
| 2 (contrasts) | Hard＞100000 cycles of wheel | Hard wheel passes through |
Find surprisingly again, in the injection molding prescription, add antiseptic-germicide the physical properties of products obtained therefrom is descended.
Although the present invention has obtained detailed description for illustrational purpose, but should be appreciated that, such detailed description only is for purpose of explanation, under the prerequisite that does not deviate from the spirit and scope of the invention, those skilled in the art can make various changes to it, and scope of the present invention is defined by the following claims.
Claims (17)
1. injected-formative plastic goods, it has the susceptibility of reduction to the microorganism growth on it, and described injection molded article is made by the moulding prescription, and described prescription comprises:
Be selected from the thermoplastic resin of polyamide thermoplastic resin, polythene thermoplastic resin, polyurethane thermoplastic resin, polypropylene thermoplastic resin, polyvinyl chloride thermoplastic resin and aforesaid mixture, and antimicrobial additive.
2. the injection molded article of claim 1, wherein thermoplastic resin comprises polyamide thermoplastic resin.
3. the injection molded article of claim 2, wherein polyamide thermoplastic resin comprises nylon 6.
4. the injection molded article of claim 1, wherein antimicrobial additive comprises 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol.
5. the injection molded article of claim 4, wherein antimicrobial additive is that about 0.1wt.% of this goods gross weight is to about 1.25wt.%.
6. the injection molded article of claim 1, wherein this prescription also comprises high modulus fibre.
7. the injection molded article of claim 1, wherein this prescription also comprises carbon black.
8. the injection molded article of claim 1, wherein these goods comprise chair base.
9. the injection molded article of claim 1, wherein these goods comprise castor.
10. the injection molded article of claim 1, wherein said thermoplastic resin is a nylon 6, and described moulding prescription also comprises high modulus fibre; Described antimicrobial additive comprises 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol; And wherein said antimicrobial additive is about 0.1wt.% about 1.25wt.% extremely of moulding prescription gross weight.
11. a formation has the method for the goods of antibacterial properties, described method comprises:
A kind of moulding prescription is provided, it comprises: the thermoplastic resin that (i) is selected from nylon resin, polyvinylidene fluoride polymer resin, polyvinyl resin and aforesaid mixture, (ii) a kind of antimicrobial additive prescription, it comprises the antimicrobial additive that is dispersed in the vector resin, described vector resin is compatible with described thermoplastic resin, and described antimicrobial additive comprises 5-chloro-2-(2,4 dichloro benzene oxygen base) phenol;
With the heating of described moulding prescription, obtain the plasticizing resin prescription; With
Should plastify prescription and inject mould, form described goods.
12. the method for claim 11, wherein said thermoplastic resin are nylon 6.
13. the method for claim 11, wherein said vector resin comprises polyethylene terephthalate.
14. the method for claim 11, wherein said antimicrobial additive prescription comprise 5-chloro-2-(the 2,4 dichloro benzene oxygen base) phenol of about 25wt.% and about 75% polyethylene terephthalate.
15. about 0.5wt.% that the method for claim 11, wherein said antimicrobial formulation are moulding fills a prescription is to about 5wt.%.
16. the method for claim 11, wherein said moulding prescription also comprises high modulus fibre.
17. the method for claim 11, wherein said thermoplastic resin is a nylon 6, described moulding prescription also comprises high modulus fibre, and described antimicrobial formulation comprises the 5-chloro-2-(2 of about 25wt.%, the 4-dichlorophenoxy) polyethylene terephthalate of phenol and about 75wt.%, wherein said antimicrobial formulation are about 0.5wt.% about 5wt.% extremely of moulding prescription.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26644702A | 2002-10-08 | 2002-10-08 | |
| US10/266,447 | 2002-10-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1508185A true CN1508185A (en) | 2004-06-30 |
Family
ID=32392343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2003101181010A Pending CN1508185A (en) | 2002-10-08 | 2003-10-08 | Antimicrobial injection-molded and method for producing same |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN1508185A (en) |
| CA (1) | CA2444711A1 (en) |
| MX (1) | MXPA03009162A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382273A (en) * | 2012-05-03 | 2013-11-06 | 辽宁辽杰科技有限公司 | Far-infrared antibacterial thermoplastic composite sheet material and its preparation method and use |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201217159D0 (en) * | 2012-09-26 | 2012-11-07 | Titan Furniture Uk Ltd | Furniture |
-
2003
- 2003-10-08 CN CNA2003101181010A patent/CN1508185A/en active Pending
- 2003-10-08 CA CA 2444711 patent/CA2444711A1/en not_active Abandoned
- 2003-10-08 MX MXPA03009162 patent/MXPA03009162A/en not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382273A (en) * | 2012-05-03 | 2013-11-06 | 辽宁辽杰科技有限公司 | Far-infrared antibacterial thermoplastic composite sheet material and its preparation method and use |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2444711A1 (en) | 2004-04-08 |
| MXPA03009162A (en) | 2004-09-10 |
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