CN1505930A - Smoke agent for sterilizing refrigeration house and processing workshop and its prepn process - Google Patents
Smoke agent for sterilizing refrigeration house and processing workshop and its prepn process Download PDFInfo
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- CN1505930A CN1505930A CNA021556113A CN02155611A CN1505930A CN 1505930 A CN1505930 A CN 1505930A CN A021556113 A CNA021556113 A CN A021556113A CN 02155611 A CN02155611 A CN 02155611A CN 1505930 A CN1505930 A CN 1505930A
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Abstract
The smoke agent for sterilizing refrigeration house and processing workshop consists of disinfectant, oxidant, inflammable carrier, fire retardant, moisture preventing agent and coloring agent. The disinfectant is one or several kinds of trichloro isocyanuric acid and its sodium or potassium salt, dichloro isocyanuric acid and its sodium or potassium salt, tribromo isocyanuric acid and its sodium or potassium salt and dibromo isocyanuric acid and its sodium or potassium salt; the oxidant is one or several kinds of potassium permanganate, potassium chlorite, potassium nitrate and potassium nitrite; the inflammable carrier is flour, rice straw and corn stalk; the fire retardant is one or several kinds of ammonium chloride, sodium carbonate and sodium bicarbonate; the moisture preventing agent is white oil and the coloring agent phthalocyanine green. The present invention has high disinfecting effect, no harm to human body and less corrosion to metal, less production investment and simple production process.
Description
Technical field
The invention belongs to the disinfectant of freezer and job shop, fumicants of particularly a kind of freezer and job shop sterilization usefulness and preparation method thereof.
Background technology
The disinfectant of freezer and process plant application mainly contains following three kinds at present: sulphur dioxide, bleaching powder, formaldehyde, sulphur dioxide has inhibitory action to some fungi but bacterium and saccharomycete is not acted on, and its that the chief drawback is is strong to metal protection, therefore have the sterilization place of metal should not use this disinfectant.Freezer especially for the storage agricultural product has a large amount of metallic facilities and apparatus in the freezer, use the metallic facility of twice freezer of sulphur dioxide to be destroyed continuously.Bleaching powder needs wiring solution-forming then storehouse to be sprayed when using, and has not only lavished labor on sterilization but also not thorough.Formaldehyde has strong bactericidal action, but its use of following drawbacks limit: 1) mucosal tissue to human body has damage, poor stability when therefore easy bumping uses when mixing with potassium permanganate in addition.2) studies show that recently formaldehyde has carcinogenesis to human body.3) residual formaldehyde has injury effect to fresh fruit and vegetables in the storehouse.Therefore be badly in need of having now a kind of to metal protection little harmless, bactericidal effect good, disinfectant easy to use.Dichlord isocyanurice acid and sodium thereof, sylvite, sym-closene and natrium potassium salt thereof at high temperature easily decompose sterilization compositions such as generating chlorine, but present research such as patent CN 1123599A can not be used for freezer by force and the processing factory of metallic facility be arranged or the sterilization in place metal protection.
Summary of the invention
Technical problem to be solved by this invention is: fumicants of a kind of freezer and job shop sterilization usefulness and preparation method thereof is provided.Can be used for freezer and the processing factory of metallic facility be arranged or the sterilization in place.
Technical scheme of the present invention is:
The fumicants of a kind of freezer and job shop sterilization usefulness is characterized in that: be made up of following composition: 30～90 parts in disinfectant, 0～40 part in oxidant, 0～50 part of combustible carriers, 0～50 part of fire retardant, 0～8 part of anti-blushing agent, 0～5 part of colouring agent;
Wherein disinfectant is sym-closene and sodium trichloro-isocyanurate thereof, sym-closene potassium, dichlord isocyanurice acid and sodium dichloro cyanurate thereof, potassium dichloroisocyanurate, the tribromo isocyanuric acid, the tribromo sodium isocyanurate, tribromo isocyanuric acid potassium, dibromo isocyanurate, dibromo isocyanurate sodium, dibromo isocyanurate sylvite, the monobromo dichlord isocyanurice acid, the monobromo sodium dichloro cyanurate, the monobromo potassium dichloroisocyanurate, dibromo one symclosene, dibromo one symclosene sodium, dibromo one symclosene potassium, monobromo one symclosene, monobromo one symclosene sodium, one or more cooperations in the monobromo one symclosene potassium;
Oxidant is one or more cooperations in potassium nitrate, potassium nitrite, potassium permanganate, potassium chlorate, the potassium chlorite;
Combustible carriers is one or more cooperations such as flour rice straw, corn stalk, sawmilling;
Fire retardant is one or more cooperations in ammonium chloride, calcium carbonate, sodium carbonate, sodium bicarbonate, ammonium carbonate, the carbonic hydroammonium etc.;
Anti-blushing agent is one or more cooperations in diesel oil, lubricating oil, white oil, the wax class etc.;
Colouring agent is fast green, peacock green, one or more in viridescent etc. too.
Its preferred version is: disinfectant is with one or more cooperations in sym-closene and sodium, sylvite, dichlord isocyanurice acid and sodium thereof, sylvite, tribromo isocyanuric acid and sodium, sylvite, dibromo isocyanurate and sodium thereof, the sylvite; Oxidant is with one or more cooperations in potassium permanganate and potassium chlorite, potassium nitrate, the potassium nitrite; Combustible carriers is with flour, rice straw and corn stalk; Fire retardant is with ammonium chloride and ammonium chloride and sodium carbonate or one or more cooperations of sodium bicarbonate; Anti-blushing agent is with white oil, and colouring agent is for too dark green.
Best component, by weight: disinfectant: 4～80 parts, combustible carriers: 10～30 parts, fire retardant: 10～30 parts, oxidant: 0～20 part, colouring agent: 0～2 part, anti-blushing agent: 1～5 part.
The fumicants of this freezer and job shop sterilization usefulness, its preparation method is: 1) the combustible carriers powder is become the powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion combustible carriers and anti-blushing agent, colouring agent are mixed fully to such an extent that mix chaff in mixer.4) in proportion disinfectant is mixed chaff with a part and fully mix, in the bag of packing into.As A agent 5) remainder is packed in another bag, as B agent 6) A agent and B agent same packing into is fumicants of the present invention in one bag.
Its preparation method is: with 1) the combustible carriers powder is become powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion combustible carriers and anti-blushing agent, colouring agent are mixed fully to such an extent that mix chaff in mixer, be packaged in the air-locked bag.
Its preparation method is: with 1) the combustible carriers powder is become powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion disinfectant being mixed chaff with a part fully mixes, pack in one bag, surplus person packs in another bag, then in the sack of packing into.
External packing is aluminium foil or tin-plated coating film packing.Also can will dress up after all mixing of materials in one bag or the container.
Effect of the present invention is: disinfectant of the present invention is a kind of fumicants, has good, harmless, safe in utilization, the convenience of Disinfection Effect, the advantage little to the metal non-corrosiveness.Produce this fumicants small investment in addition, production technology is simple.
Embodiment
The fumicants of a kind of freezer and job shop sterilization usefulness, the main composition by weight
30～90 parts in disinfectant, 0～40 part in oxidant, 0～50 part of combustible carriers, 0～50 part of fire retardant, 0～8 part of anti-blushing agent, 0～5 part of colouring agent;
Wherein disinfectant is sym-closene and sodium, sylvite, dichlord isocyanurice acid and sodium thereof, sylvite, one or more cooperations in tribromo isocyanuric acid and sodium thereof, sylvite, dibromo isocyanurate and sodium thereof, sylvite, monobromo dichlord isocyanurice acid and sodium thereof, sylvite, dibromo one symclosene and sodium thereof, sylvite, monobromo one symclosene and sodium thereof, the sylvite.With one or more cooperations in sym-closene and sodium, sylvite, dichlord isocyanurice acid and sodium thereof, sylvite, tribromo isocyanuric acid and sodium, sylvite, dibromo isocyanurate and sodium thereof, the sylvite is preferred version.Oxidant is one or more cooperations in potassium nitrate, potassium nitrite, potassium permanganate, potassium chlorate, the potassium chlorite.With one or more cooperations in potassium permanganate and potassium chlorite, potassium nitrate, the potassium nitrite is preferred version.Combustible carriers is one or more cooperations such as flour rice straw, corn stalk, sawmilling.With flour, rice straw and jade material straw is priority scheme.
Fire retardant is one or more cooperations in ammonium chloride, calcium carbonate, sodium carbonate, sodium bicarbonate, ammonium carbonate, the carbonic hydroammonium etc.With ammonium chloride and ammonium chloride and sodium carbonate or one or more cooperations of sodium bicarbonate is preferred version.
Anti-blushing agent is one or more cooperations in diesel oil, lubricating oil, white oil, the wax class etc.With the white oil is preferred version.
Colouring agent is fast green, peacock green, one or more in viridescent etc. too.The ether viridescent is a preferred version.
Best component, by weight:
Disinfectant: 4～80 parts, combustible carriers: 10～30 parts, fire retardant: 10～30 parts, oxidant: 0～20 part, colouring agent: 0～2 part, anti-blushing agent: 1～5 part;
Preparation method:
1) the combustible carriers powder is become powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders,
3) in proportion combustible carriers and anti-blushing agent, colouring agent are mixed fully to such an extent that mix chaff in mixer.4) in proportion disinfectant is mixed chaff with a part and fully mix, in the bag of packing into.As A agent 5) remainder is packed in another bag, as B agent 6) A agent and B agent same packing into is fumicants of the present invention in one bag.Also can will dress up after all mixing of materials in one bag or the container.
Example 1. becomes 50 purpose powder with corn stalk powder, gets the white oil of 30 parts of corn stalk powders and 2 parts, and 1 part too dark green fully mixes in mixer.Be the mixing chaff and get dibromo isocyanurate, 40 parts are mixed 10 parts of chaffs, fully mix being loaded in the same bag as the A agent.Powder is become 6 parts of 10 parts of ammonium chlorides of 100 purpose potassium nitrate.23 parts in 1 part of carbonic hydroammonium mixes chaff and packs in one bag as the B agent.A agent and B agent are adorned in the same bag, be the fumicants of this patent.
Example 2 get 30 parts of flour (50 order) and 5 parts of paraffin, 2 parts fast greenly in mixer, fully mix, make the mixing chaff.Get 20 parts of sodium trichloro-isocyanurates, mix 30 parts of chaffs, fully mix to step on being loaded in the same bag as the A agent.Powder is become 20 parts in 100 purpose potassium chlorate, and 23 parts of ammonium chlorides mix 7 parts of chaffs, fully mix, and are loaded in the same bag as the B agent.The fumicants that is this patent in the same bag is adorned in A agent and B agent.
Example 3 becomes sawdust more than 50 orders, gets 21 parts of sawmilling, 2 parts of peacock greens, and 5 parts of lubricating oil mix, and make the mixing chaff.Getting 38 part of 100 above dichlord isocyanurice acid of order of 28 parts of mixing chaffs hybrid packed is the A agent.With the 20 part of 100 above potassium nitrate of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 4 becomes sawdust more than 50 orders, gets 25 parts of sawmilling, 40 parts of tribromo isocyanuric acids, and 20 parts of carbonic hydroammonium, 10 part of 100 above potassium nitrite of order, 5 parts of white oils, fully hybrid packed in same bag.Be the fumicants of this patent.
Example 5 becomes corn stalk powder more than 50 orders, gets 26 parts of corn stalk powders, 2 parts of peacock greens, and 2 parts of lubricating oil mix, and make the mixing chaff.Get 30 parts and mix chaffs, the 200 part of 100 above dichloro bromine of order cyanuric acid is hybrid packed to be the A agent.With 20 part of 100 above potassium hyperchlorate of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 6 becomes sawdust more than 50 orders, gets 23 parts of sawmilling, 1 part of peacock green, and 1 part of lubricating oil mixes, and makes the mixing chaff.Getting 10 parts, to mix 30 part of 100 above dichlord isocyanurice acid of order of chaff and 10 parts of dibromo isocyanurates hybrid packed be the A agent.Get 15 parts and mix chaff with the 20 part of 100 above potassium nitrate of order, 15 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 7 becomes sawdust more than 50 orders, gets 21 parts of sawmilling, 2 parts of peacock greens, and 5 parts of lubricating oil mix, and make the mixing chaff.Get 28 parts and mix chaffs, the 22 part of 100 above monobromo one symclosene sodium of order, 10 parts of dichlord isocyanurice acids are hybrid packed to be the A agent.With the 20 part of 100 above potassium nitrate of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 8 becomes sawdust more than 50 orders, gets 5 parts of sawmilling, 2 parts of peacock greens, and 3 parts of lubricating oil mix, and make the mixing chaff.Getting 40 part of 100 above sym-closene of order of 10 parts of mixing chaffs hybrid packed is the A agent.With the 20 part of 100 above potassium nitrate of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 8 becomes sawdust more than 50 orders, gets 5 parts of sawmilling, 2 parts of peacock greens, and 5 parts of lubricating oil mix, and make the mixing chaff.Getting 38 part of 100 above dichlord isocyanurice acid of order of 12 parts of mixing chaffs hybrid packed is the A agent.With 20 part of 100 above potassium chlorite of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 9 becomes sawdust more than 50 orders, gets 21 parts of sawmilling, 2 parts of peacock greens, and 5 parts of lubricating oil mix, and make the mixing chaff.Getting 22 part of 100 above dichlord isocyanurice acid of order of 28 parts of mixing chaffs hybrid packed is the A agent.With the 20 part of 100 above potassium nitrate of order, 30 parts of ammonium carbonates mix and are packaged as the B agent, with A agent and B agent, adorn the fumicants that is this patent in the same bag.
Example 10 becomes sawdust more than 50 orders, gets 5 parts of sawmilling, 2 parts of peacock greens, and 5 parts of lubricating oil mix, and make the mixing chaff.Get 28 parts and mix chaff, 38 part of 100 above dichlord isocyanurice acid of order, the 20 part of 100 above potassium nitrate of order, 30 parts of hybrid packed fumicants that are this patent of ammonium carbonate.
This disinfectant compares with other disinfectant
| Serviceability | To metal protection | Bactericidal effect | Safety | |
| This patent disinfectant | Convenient | Low | By force | High |
| SO2 | Convenient | By force | Stronger | High |
| Formaldehyde | Convenient | Low | By force | Low |
| Bleaching powder | Inconvenient | Low | Low | High |
Claims (8)
1, the fumicants of a kind of freezer and job shop sterilization usefulness is characterized in that: be made up of following composition: 30～90 parts in disinfectant, 0～40 part in oxidant, 0～50 part of combustible carriers, 0～50 part of fire retardant, 0～8 part of anti-blushing agent, 0～5 part of colouring agent;
Wherein disinfectant is a sym-closene, sodium trichloro-isocyanurate, sym-closene potassium, dichlord isocyanurice acid and sodium dichloro cyanurate thereof, potassium dichloroisocyanurate, the tribromo isocyanuric acid, the tribromo sodium isocyanurate, tribromo isocyanuric acid potassium, dibromo isocyanurate, dibromo isocyanurate sodium, dibromo isocyanurate sylvite, the monobromo dichlord isocyanurice acid, the monobromo sodium dichloro cyanurate, the monobromo potassium dichloroisocyanurate, dibromo one symclosene, dibromo one symclosene sodium, dibromo one symclosene potassium, monobromo one symclosene, monobromo one symclosene sodium, one or more cooperations in the monobromo one symclosene potassium; Oxidant is one or more cooperations in potassium nitrate, potassium nitrite, potassium permanganate, potassium chlorate, the potassium chlorite; Combustible carriers is one or more cooperations such as flour, rice straw, corn stalk, sawmilling; Fire retardant is one or more cooperations in ammonium chloride, calcium carbonate, sodium carbonate, sodium bicarbonate, ammonium carbonate, the carbonic hydroammonium; Anti-blushing agent is one or more cooperations in diesel oil, lubricating oil, white oil, the wax class etc.; Colouring agent is fast green, peacock green, one or more in viridescent etc. too.
2, the fumicants of a kind of freezer according to claim 1 and job shop sterilization usefulness, it is characterized in that: its preferred version is: disinfectant is with one or more cooperations in sym-closene and sodium, sylvite, dichlord isocyanurice acid and sodium thereof, sylvite, tribromo isocyanuric acid and sodium, sylvite, dibromo isocyanurate and sodium thereof, the sylvite; Oxidant is with one or more cooperations in potassium permanganate and potassium chlorite, potassium nitrate, the potassium nitrite; Combustible carriers is with flour, rice straw and corn stalk; Fire retardant is with ammonium chloride and ammonium chloride and sodium carbonate or one or more cooperations of sodium bicarbonate; Anti-blushing agent is with white oil, and colouring agent is for too dark green.
3, according to the fumicants of claim or 2 described a kind of freezers and job shop sterilization usefulness, it is characterized in that: best component, by weight, disinfectant: 4～80 parts, combustible carriers: 10～30 parts, fire retardant: 10～30 parts, oxidant: 0～20 part, colouring agent: 0～2 part, anti-blushing agent: 1～5 part.
4, the fumicants of a kind of freezer according to claim 1 and job shop sterilization usefulness, its preparation method is: 1) the combustible carriers powder is become the powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion combustible carriers and anti-blushing agent, colouring agent are mixed fully to such an extent that mix chaff in mixer, 4) in proportion disinfectant being mixed chaff with a part fully mixes, pack in the bag, as A agent 5) remainder is packed in another bag, as B agent 6) A agent and B agent same packing into is fumicants of the present invention in one bag.
5, the fumicants of a kind of freezer according to claim 4 and job shop sterilization usefulness, its preparation method is: with 1) the combustible carriers powder is become powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion combustible carriers and anti-blushing agent, colouring agent are mixed fully to such an extent that mix chaff in mixer, be packaged in the air-locked bag.
6, the fumicants of a kind of freezer according to claim 4 and job shop sterilization usefulness, its preparation method is: with 1) the combustible carriers powder is become powder 2 more than 50 orders) oxidiser powder is become powder more than 100 orders, 3) in proportion disinfectant being mixed chaff with a part fully mixes, pack in one bag, surplus person pack into another the bag in, then in the sack of packing into.
7, the fumicants of a kind of freezer according to claim 4 and job shop sterilization usefulness, its preparation method is: external packing is aluminium foil or tin-plated coating film packing.
8, the fumicants of a kind of freezer according to claim 4 and job shop sterilization usefulness, its preparation method is: will dress up after all mixing of materials in one bag or the container.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021556113A CN1505930A (en) | 2002-12-13 | 2002-12-13 | Smoke agent for sterilizing refrigeration house and processing workshop and its prepn process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021556113A CN1505930A (en) | 2002-12-13 | 2002-12-13 | Smoke agent for sterilizing refrigeration house and processing workshop and its prepn process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1505930A true CN1505930A (en) | 2004-06-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA021556113A Pending CN1505930A (en) | 2002-12-13 | 2002-12-13 | Smoke agent for sterilizing refrigeration house and processing workshop and its prepn process |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1295961C (en) * | 2004-12-20 | 2007-01-24 | 周安兴 | Sodium dibromoisocyanurate as disinfectant and its production process |
| CN101796948A (en) * | 2010-03-16 | 2010-08-11 | 成都奇锐医疗器械用品有限公司 | Smoke type disinfectant, preparation method and application thereof |
| US8017074B2 (en) | 2004-01-07 | 2011-09-13 | Noxilizer, Inc. | Sterilization system and device |
| CN102369960A (en) * | 2010-08-20 | 2012-03-14 | 河南亚卫动物药业有限公司 | Solid fumigation disinfectant and preparation method thereof |
| CN102972407A (en) * | 2011-09-07 | 2013-03-20 | 中国人民解放军疾病预防控制所 | Novel sanitation and epidemic prevention disinfection smoke agent |
| US8425837B2 (en) | 2009-02-23 | 2013-04-23 | Noxilizer, Inc. | Device and method for gas sterilization |
| US8703066B2 (en) | 2004-01-07 | 2014-04-22 | Noxilizer, Inc. | Sterilization system and method |
-
2002
- 2002-12-13 CN CNA021556113A patent/CN1505930A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8017074B2 (en) | 2004-01-07 | 2011-09-13 | Noxilizer, Inc. | Sterilization system and device |
| US8703066B2 (en) | 2004-01-07 | 2014-04-22 | Noxilizer, Inc. | Sterilization system and method |
| US8808622B2 (en) | 2004-01-07 | 2014-08-19 | Noxilizer, Inc. | Sterilization system and device |
| US9180217B2 (en) | 2004-01-07 | 2015-11-10 | Noxilizer, Inc. | Sterilization system and device |
| CN1295961C (en) * | 2004-12-20 | 2007-01-24 | 周安兴 | Sodium dibromoisocyanurate as disinfectant and its production process |
| US8425837B2 (en) | 2009-02-23 | 2013-04-23 | Noxilizer, Inc. | Device and method for gas sterilization |
| US8721984B2 (en) | 2009-02-23 | 2014-05-13 | Noxilizer, Inc. | Device and method for gas sterilization |
| CN101796948A (en) * | 2010-03-16 | 2010-08-11 | 成都奇锐医疗器械用品有限公司 | Smoke type disinfectant, preparation method and application thereof |
| CN101796948B (en) * | 2010-03-16 | 2013-01-16 | 成都奇锐医疗器械用品有限公司 | Smoke type disinfectant, preparation method and application thereof |
| CN102369960A (en) * | 2010-08-20 | 2012-03-14 | 河南亚卫动物药业有限公司 | Solid fumigation disinfectant and preparation method thereof |
| CN102369960B (en) * | 2010-08-20 | 2013-10-02 | 河南亚卫动物药业有限公司 | Solid fumigation disinfectant and preparation method thereof |
| CN102972407A (en) * | 2011-09-07 | 2013-03-20 | 中国人民解放军疾病预防控制所 | Novel sanitation and epidemic prevention disinfection smoke agent |
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