CN1492920A - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
- Publication number
- CN1492920A CN1492920A CNA018229093A CN01822909A CN1492920A CN 1492920 A CN1492920 A CN 1492920A CN A018229093 A CNA018229093 A CN A018229093A CN 01822909 A CN01822909 A CN 01822909A CN 1492920 A CN1492920 A CN 1492920A
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- detergent composition
- weight
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- 239000000203 mixture Substances 0.000 title claims abstract description 62
- 239000003599 detergent Substances 0.000 title claims abstract description 30
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 28
- 239000000344 soap Substances 0.000 claims abstract description 11
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims description 19
- 229910052791 calcium Inorganic materials 0.000 claims description 18
- 239000011575 calcium Substances 0.000 claims description 18
- -1 sulphate anion Chemical class 0.000 claims description 17
- 238000005406 washing Methods 0.000 claims description 13
- 239000003093 cationic surfactant Substances 0.000 claims description 9
- 150000005215 alkyl ethers Chemical class 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- 241000282326 Felis catus Species 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 229910052728 basic metal Inorganic materials 0.000 claims description 4
- 150000003818 basic metals Chemical class 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 3
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 18
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004615 ingredient Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 15
- 239000010457 zeolite Substances 0.000 description 15
- 238000004061 bleaching Methods 0.000 description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 11
- 102000004190 Enzymes Human genes 0.000 description 9
- 108090000790 Enzymes Proteins 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 238000007046 ethoxylation reaction Methods 0.000 description 8
- 239000013543 active substance Substances 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 108091005804 Peptidases Proteins 0.000 description 5
- 235000019270 ammonium chloride Nutrition 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 5
- 235000019353 potassium silicate Nutrition 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 150000004965 peroxy acids Chemical class 0.000 description 4
- 150000003016 phosphoric acids Chemical class 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 235000013599 spices Nutrition 0.000 description 4
- 229910021532 Calcite Inorganic materials 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 108090000787 Subtilisin Proteins 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000002797 proteolythic effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 208000004434 Calcinosis Diseases 0.000 description 1
- 102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
- 108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 102220536955 Dynein axonemal intermediate chain 4_C33W_mutation Human genes 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical group OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005189 alkyl hydroxy group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- LTZZYVWUGIPISL-UHFFFAOYSA-N ethyl(hydroxy)azanium;chloride Chemical compound [Cl-].CC[NH2+]O LTZZYVWUGIPISL-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000001007 flame atomic emission spectroscopy Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
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Abstract
本发明公开了洗涤剂组合物，其含有：(a)高于10wt％的耐钙非皂阴离子表面活性剂体系；(b)0.1％－10％，优选0.5％－10％，更优选1％－10wt％的选自磷酸盐助洗剂和硅铝酸盐助洗剂和它们的混合物的强助洗剂体系；和(c)如果存在，平衡量的其它洗涤剂组分，其中所述组合物含有少于35wt％，优选少于25wt％，更优选少于15wt％非功能性，非碱性水溶性无机盐。
Description
技术领域
本发明涉及可例如配制成微粒、片剂或液体组合物的洗衣洗涤剂组合物。
发明背景
常规用于手洗的洗衣洗涤剂粉末含有大量的阴离子表面活性剂，最常用的是烷基苯磺酸盐，阴离子表面活性剂理想地适用于手洗，因为它们结合了优异的对广泛污垢的洗涤能力与高泡沫。
然而，在用于手洗的高含量阴离子表面活性剂的情况下，该产品的油渍去除性能仍需要改善。
GB-A-1570128公开了洗涤剂组合物，其含有4-40wt％的耐镁表面活性剂(例如烷基醚硫酸盐，乙氧基化非离子表面活性剂，氧化胺)、13-40wt％的硅酸钠和5-50wt％镁选择性洗涤助剂(例如沸石、柠檬酸钠、次氮基三乙酸酯或方解石/碳酸盐)。
JP-A-09087690公开用于机洗的高堆积密度颗粒洗涤剂组合物，其含有阴离子(5-40wt％)，加上乙氧基化非离子表面活性剂(1-15wt％)，沸石(10-40％)和结晶和无定形硅酸钠(0.5-10wt％)。阴离子表面活性剂任选含有α-烯烃磺酸盐(在实施例中高达10wt％)。
WO-A-97/43366涉及洗涤剂组合物，其含有0.5-60wt％阴离子表面活性剂和0.01-30wt％阳离子表面活性剂。在该文献列举的组合物中，阴离子表面活性剂的含量是组合物的约10-15wt％，阳离子表面活性剂的含量是约1-4wt％。在某些实施例中，阴离子表面活性剂组分含有少量的烷基醚硫酸盐表面活性剂，通常为总组合物的0.76-2.5wt％。
含有少量烷基醚硫酸盐阴离子表面活性剂(至多1.75wt％)和在一种情况下，低含量沸石(1.5wt％)的组合物在WO-A-98/01521中公开，然而，这些组合物是喷雾干燥的，因此，含有高含量的硫酸钠，它是非碱性，非功能性的水溶性盐(电解质)。
其它含有高含量硫酸钠和含有α-烯烃硫酸盐阴离子表面活性剂，与12-15wt％沸石助洗剂的喷雾干燥的组合物在JP-A-62218499中公开。
WO-A-00/40682公开了组合物，其含有高于40％的阴离子表面活性剂体系，至少某些含有耐钙表面活性剂，例如α-烯烃磺酸盐或烷基醚硫酸盐。含有耐钙表面活性剂的实施例不含有磷酸盐或硅铝酸盐助洗剂，或不含有非常高含量的磷酸盐。
我们的UK专利申请No.9925961.6也公开了含有5-30wt％α-烯烃磺酸盐的组合物，这些均基于方解石/碳酸盐助洗剂体系。
含有耐钙表面活性剂的其它组合物在US-A-6,010,996，GB-A-2309 706，US-A-5,415,812，US-A-4,265,777和US-A-4,970,017中公开。
人们仍保持通过本发明满足的对组合物的需要，其含有，但以较低含量，强助洗剂，即磷酸盐或硅铝酸盐助洗剂，并且它们在宽范围的水硬度下仍然是稳定的。
发明定义
洗涤剂组合物，其含有：
(a)高于10wt％的耐钙非皂阴离子表面活性剂体系；
(b)0.1％-10％，优选0.5％-10％，更优选1％-10wt％的选自磷酸盐助洗剂和硅铝酸盐助洗剂和它们的混合物的强助洗剂体系；和
(c)如果存在，平衡量的其它洗涤剂组分，其中所述组合物含有少于35wt％，优选少于25wt％，更优选少于15wt％非功能性、非碱性水溶性无机盐。
发明详述
本发明的组合物基于混合的耐钙阴离子表面活性剂体系，加上适量的磷酸盐和/或硅铝酸盐助洗剂。
阴离子表面活性剂体系
本发明的组合物含有高于10wt％的耐钙阴离子表面活性剂。通常该耐钙阴离子表面活性剂体系的上限含量为75wt％。然而，基于总组合物重量计，阴离子表面活性剂体系优选以15wt％-65wt％，更优选20wt％-60wt％，尤其是30wt％-50wt％存在。
阴离子表面活性剂的钙离子稳定性可用改性的Hart方法(Witkes，等.J.Ind.Encl.Chem.29，1234-1239(1937))在微量滴定板上进行。表面活性剂溶液用钙离子溶液滴定，在室温下振荡几分钟后，开始混浊表示开始形成不溶解的钙沉淀。
用于本文的“耐钙”表面活性剂是指对于高达20°FH(French硬度)，即200ppm钙，在0.4g/L(在0.040M 1∶1盐溶液的离子浓度下)的表面活性剂浓度下不沉淀的表面活性剂。
用于本发明的组合物的优选非皂耐钙阴离子表面活性剂是α-烯烃磺酸盐。
有利的是，可以少于α-烯烃磺酸盐的数量存在烷基醚硫酸盐(另一种非皂耐钙物质)，优选作为辅助表面活性剂。
优选的表面活性剂体系含有重量比为5∶1-15∶1的α-烯烃磺酸盐和烷基醚硫酸盐。
可单独地或与这些或其它耐钙阴离子表面活性剂结合使用的其它耐钙阴离子表面活性剂是烷基烷氧基羧酸盐表面活性剂(例如，Neodox(商标)，来自Shell)、脂肪酸酯磺酸盐(例如，FAES MC-48和ML-40，来自Stepan)，烷基二甲苯磺酸盐、二烷基磺基琥珀酸盐、脂肪酸酯磺酸盐、烷基酰胺硫酸盐、sorpholipids、烷基苷硫酸盐和饱和或不饱和脂肪酸的碱金属(例如钠)盐。
还可存在多于一种的其它阴离子表面活性剂，它们可选自例如一种或多种烷基苯磺酸盐、伯和仲烷基硫酸盐。
当需要完全避免不耐钙的烷基苯磺酸盐表面活性剂时，则阴离子表面活性剂体系可含有(优选以总阴离子表面活性剂70wt％或以上的含量)一种或多种耐钙非皂阴离子表面活性剂或仅由它们组成。
强助洗剂体系
强助洗剂体系选自磷酸盐助洗剂、硅铝酸盐助洗剂和它们的混合物。以组合物重量计，该强助洗剂体系的总量为0.1％-10％，优选0.5％-10％，更优选1％-10％。然而，还可存在一种或多种弱助洗剂，例如方解石/碳酸盐、柠檬酸盐或聚合物助洗剂。
磷酸盐助洗剂(如果存在)可例如选自焦磷酸盐、正磷酸盐和三聚磷酸盐的碱金属，优选钠盐和它们的混合物。
硅铝酸盐可以是，例如，选自一种或多种结晶和非定形硅铝酸盐，例如在GB 1 473 201(Henkel)中公开的沸石、在GB 1 473 202(Henkel)中公开的无定形硅铝酸盐和在GB 1 470 250(Procter & Gamble)中公开的混合结晶/无定形硅铝酸盐；和在EP164 514B(Hoechst)中公开的层状硅酸盐。
碱金属硅铝酸盐可以是通式为0.8-1.5Na2O.Al2O3.0.8-6SiO2的结晶或无定形的或它们的混合物。
这些物质含有部分结合的水，需要具有至少50mg CaO/g的钙离子交换能力。优选的硅铝酸钠含有1.5-3.5SiO2单元(在如上式中)，如文献中充分描述的那样，无定形和结晶物质均可通过硅酸钠和铝酸钠之间的反应容易地制备。合适的结晶硅铝酸盐离子交换洗涤助洗剂在例如GB 1 429 143(Procter & Gamble)中公开，这类优选的硅铝酸钠是已知商业可获得的沸石A和X和它们的混合物。
沸石可以是目前广泛用于洗衣洗涤剂粉的商业可获得的沸石4A。然而，根据本发明的优选实施方案，加入本发明组合物中的沸石助洗剂是如EP 384 070A(Unilever)中描述和要求保护的最大铝沸石P(沸石MAP)。沸石MAP定义为硅铝比不超过1.33，优选在0.90-1.33，更优选在0.90-1.20范围内的沸石P型的碱金属硅铝酸盐。
尤其优选的是硅铝比不超过1.07，更优选约1.00的沸石MAP，沸石MAP的钙结合能力通常为每克无水物质至少150mg CaO。
无机盐
本发明的组合物必须含有少于35wt％，优选少于25wt％，更优选少于15wt％非功能性、非碱性水溶性无机盐，例如水溶性助洗剂和碱性试剂，例如碱金属碳酸盐、硅酸盐、偏硅酸盐等。
阳离子表面活性剂体系
本发明的组合物任选含有至少0.1wt％阳离子表面活性剂体系。通常，阳离子表面活性剂体系可以高达总组合物的15wt％存在，然而，优选它以0.5wt％-5wt％存在于组合物中。
优选的阳离子表面活性剂类型包括下式的物质：
R1R2R3R4N+X-
其中
R1是疏水基团(优选)C12-14烷基，或由椰子基得到；
R2，R3或R4分别是羟基乙基、羟基丙基或C1-4烷基(例如Me，Et)；
X-是增溶阳离子，例如Cl-，Br-或MeSO4 -。
具体实例是：
R 1
R 2 ，R 3 ，R 4
(i)烷基羟基乙基二甲基 C12 2甲基，1羟基乙基
氯化铵HoeS3996(现作
为Praepagen HY销售)
(来自Clariant，prey.
Hoechst)
(ii)烷基二羟基乙基甲 C12 1甲基，2-羟基乙基
基氯化铵Bis-AQA types
(来自Clariant)，例如
Ethoquad C/12型，
(AKZO-Nobel)
(iii)烷基三甲基氯化铵 ＜C16，优选C12 3甲基
Arquad型(例如Arquad
C33W)
阳离子表面活性剂的定义还包括QMEA(季铵化单乙醇胺)或QTEA(季铵化三乙醇胺)。季铵化过程可通过用表面活性剂酸(即LAS酸，脂肪酸，石蜡磺酸＝SAS酸等)就地中和MEA或TEA得到：
R 1
R 2 ，R 3 ，R 4
iv)单羟基乙基氯化铵 H 2H，1
Quaternised MEA羟基乙
基
v)三羟基乙基氯化铵 1-羟基乙基 1H，2-羟基乙基
Quaternised TEA
胺的物理形式是水状液体，它们可以在用于粉末制造浆状物(碱部分替代苛性钠)或后剂量的附加物中提供，在与表面活性剂酸中和后作为抗衡离子存在。
(vi).APA Quats：烷基酰氨基-N-亚丙基二甲基(季-)氯化铵(烷基-CON(X)-(CH2)3NH+(CH3)2Cl-，其中X＝H或Me，Et，Pr更高)
APA Quats C12-C14-CON(X)(CH2)3 2甲基
(vii)醇三乙氧基二甲基氯化铵(烷基(EO)nN+(CH3)3Cl-，其中n是1-10
(viii)Esterquats：单或二(椰子烷基-乙烯基)羟基乙基甲基氯化铵(椰子烷基(CH2)2N+(CH3)(CH2CH2OH)CH3SO4 -
(viii)苄基二甲基椰子烷基氯化铵(例如R(CH3)2N+CH2C6H5Cl-，等)来自AKZO-Nobel，例如Arquad DMCB-80，DMHTB-75 Arquad M2HTB-80)
(ix)椰子烷基苄基-(乙氧基化(2)-氯化铵(例如，EthoquadC12/B)
(x)乙氧基化季铵盐(单烷基乙氧基化物)，即单烷基甲基[乙氧基化(n)]氯化铵
-例如Ethoquat 18/12，即十八烷基甲基[乙氧基化(2)]，Ethoquad 18/25，Ethoquad C/12，C/25，Ethoquad O/12，即油基甲基[乙氧基化(2)]，ethoquad C/12硝酸盐，即椰子甲基[乙氧基化(2)]硝酸铵，Ethoquad T/12，即牛油烷基甲基[乙氧基化(2)]-氯化铵。
任选其它表面活性剂
如果需要，可包括非离子表面活性剂以控制泡沫，这些物质的数量，总共通常应不高于10wt％，优选将不高于5wt％。
优选的非离子表面活性剂是平均乙氧基化平均程度为1-10的C10-C16链烷醇，更优选乙氧基化平均程度为2-8的C12-C15醇。
漂白剂
本发明的洗衣组合物还合适地含有漂白剂体系，织物洗涤组合物理想地可含有在含水溶液中能够产生过氧化氢的过氧漂白化合物，例如无机过酸盐或有机过氧酸。
合适的过氧漂白化合物包括有机过氧化物，例如脲过氧化物和无机过酸盐，例如碱金属过硼酸盐、过碳酸盐、过磷酸盐、过硅酸盐和过硫酸盐，优选的无机过酸盐是过硼酸钠单水合物和四水合物，和过碳酸钠。
尤其优选的是带有防止水分而失稳的保护涂层的过碳酸钠，带有含偏硼酸钠和硅酸钠的保护涂层的过碳酸钠在GB-A-2123044中公开。
过氧漂白化合物合适地以0.1-35wt％，优选0.5-25wt％的数量存在，过氧漂白化合物可与漂白活化剂(漂白前体)结合使用以改善在低洗涤温度下的漂白作用。漂白前体合适地以0.1-8wt％，优选0.5-5wt％的数量存在。
优选的漂白前体是过氧羧酸前体，更具体地是过乙酸前体和过壬酸前体。适用于本发明的尤其优选的漂白前体是N，N，N′，N′，-四乙酰基乙二胺(TAED)和壬酰氧基苯磺酸钠(SNOBS)。在US4,751,015和US4,818,426和EP-A402 971中公开的新型季铵和鏻漂白前体和在EP-A-284 29和EP-A-303 520中公开的阳离子漂白前体也是感兴趣的。
漂白体系可用过氧酸补充或替换，该过氧酸的实例可以在US4,686,06 3和US5,397,501中找到。优选实例是在EP-A-325 288，EP-A-349 940，DE-A-382 3172和EP-A-325 289中描述的过酸的亚酰氨基过氧羧酸种类。尤其优选的实例是邻苯二甲酰亚氨基过氧己酸，这类过酸合适地以0.1-12％，优选0.5-10％存在。
还可存在漂白稳定剂(过渡金属螯合剂)，合适的漂白稳定剂包括乙二胺四乙酸(EDTA)、多膦酸盐，例如Dequest(商标)和非磷酸盐稳定剂，例如EDDS(乙二胺二琥珀酸)。这些漂白稳定剂还用于去污，尤其是在含有低含量漂白物质或不含漂白物质的产品中。
尤其优选的漂白体系含有过氧漂白化合物(优选过碳酸钠，任选含有漂白活化剂)和如EP-A-458 397，EP-A-458 398和EP-A-509 787中描述和保护的过渡金属漂白催化剂。
酶
本发明的洗衣组合物还可含有一种或多种酶。合适的酶包括适合加入洗涤剂组合物的蛋白酶、淀粉酶、纤维素酶、氧化酶、过氧化酶和脂酶。优选的蛋白水解酶(蛋白酶)是在水解反应中降解或改变在织物污渍中存在的污渍的蛋白质类型的催化活性蛋白质物质，它们可以是任何合适来源，例如植物、动物、细菌或酵母来源。
各种质量和来源，在4-12的各种pH范围中具有活性的蛋白水解酶是可获得的，可用于本发明。合适的蛋白水解酶的实例是枯草杆菌蛋白酶，它们由枯草芽胞杆菌和地衣型芽胞杆菌的特殊菌株得到，例如商业上可获得的枯草杆菌蛋白酶Maxatase(商标)，由GistBrocades N.V.，Delft，Holland提供，和Alcalase(商标)，由NovoIndustri A/S，Copenhagen，Denmark提供。
尤其合适的是由在pH8-12范围内具有最大活性的芽胞杆菌的菌株获得的蛋白酶，商业上由例如Novo Industri A/S以注册商业名称Esperase(商标)和Savinase(商标)得到。这些和类似酶的制备方法在GB 1 243 785中描述。其它商业蛋白酶是Kazusase(商标，由Showa-Denko，Japan获得)，Optimase(商标，由Miles Kali-Chemie，Hannover，West Germany获得)和Superase(商标，由Pfizer，USA获得)。
洗涤酶通常以颗粒形式以约0.1-约30wt％的数量使用，然而，可以使用酶的任何合适物理形式。
其它任选少量组分
本发明的组合物可含有碱金属，优选碳酸钠，以增加洗涤能力和易于加工。碳酸钠可合适地以1-60wt％，优选2-40wt％的数量存在。含有较少或不含碳酸盐的组合物也在本发明的范围内。
粉末流动可通过加入少量粉末结构助剂，例如脂肪酸(或脂肪酸皂)、糖，丙烯酸酯或丙烯酸酯/马来酸酯共聚物，或硅酸钠改善。一种优选的粉末结构助剂是脂肪酸皂，合适地以1-5wt％的数量存在。
可存在于本发明的洗涤剂组合物中的其它物质包括硅酸钠；抗再沉淀剂，例如纤维素聚合物；无机盐，例如硫酸钠；根据需要的泡沫控制剂或增泡剂；染料；色斑；香料；泡沫控制剂；荧光和去偶聚合物。列出这些并不是想尽举。
组合物的制备方法
本发明的组合物可通过任何合适的方法制备。
加工路线的选择可部分地通过所包含的表面活性剂的稳定性或热敏性和他们可获得的形式决定。
例如，α-烯烃磺酸盐是稳定的，以粉末、浆料和溶液形式得到。
烷基醚硫酸盐对热最敏感，易于水解，作为含水浓缩(例如约70％活性物质)含水浆料和更稀释的(例如25.8wt％)溶液得到。
在所有情况下，通常单独加入的组分，例如酶，漂白组分，螯合剂，聚合物和香料(例如酶作为颗粒后剂量加入，香料喷洒)可在如下所示的步骤后加入。
合适的方法包括：
(1)转鼓干燥主要组分，任选随后造粒或剂量后的附加组分；
(2)在高速混合器/造粒器，例如Fukae(商标)FS系列混合器所有组分的非塔造粒，优选使用至少一种浆料形式的表面活性剂，从而使表面活性剂浆料中的水可用作粘合剂；
(3)在高速/中速造粒器组合、薄膜快速干燥器/蒸发器或流化床造粒器中的非塔造粒。
实施例
本发明通过如下非限制实施例进一步说明，其中份数和百分数以重量计，除非另有说明。
| A | B | 1 | 2 | 3 | C | D | 4 | 5 | 6 | ||
| LAS | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | |
| PAS | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | |
| AOS | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | |
| SLES(3EO) | 5 | 10 | 12 | 15 | 20 | 5 | 10 | 12 | 15 | 20 | |
| 醇7EO乙氧基化物，非离子表面活性剂 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | |
| 阳离子 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | |
| 表面活性剂 | 7 | 7 | 7 | 7 | 7 | ||||||
| 沸石4A | 10 | 10 | 10 | 10 | 10 | ||||||
| Na2CO3 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | |
| Na2O:2SiO2 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | |
| 酶 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | |
| SCMC | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | |
| 荧光剂 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
| 香料 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |
| 平衡至100％ | 硫酸钠+水 | ||||||||||
实施例1-6是本发明，实施例A-D是对照组。在定量评价中，可以看出本发明的实施例显示了清洁性能的明显增加。
Claims (13)
1.洗涤剂组合物，其含有：
(a)高于10重量％的耐钙非皂阴离子表面活性剂体系；
(b)0.1％-10％，优选0.5％-10％，更优选1％-10重量％的选自磷酸盐助洗剂和硅铝酸盐助洗剂和它们的混合物的强助洗剂体系；和
(c)如果存在，平衡量的其它洗涤剂组分，其中所述组合物含有少于35重量％，优选少于25重量％，更优选少于15重量％非功能性、非碱性水溶性无机盐。
2.权利要求1的洗涤剂组合物，其含有至少5重量％的钙阴离子表面活性剂体系(a)。
3.权利要求1或2的洗涤剂组合物，其还含有一种或多种非耐钙阴离子表面活性剂，例如碱金属烷基苯磺酸盐。
4.权利要求3的洗涤剂组合物，其含有5％-70％，优选10％-50重量％非耐钙表面活性剂。
5.权利要求3的洗涤剂组合物，其中耐钙非皂阴离子表面活性剂含有α-烯烃磺酸盐。
6.上述任一权利要求的洗涤剂组合物，其含有少于1％，优选少于0.1％，更优选0重量％的硫酸盐阴离子表面活性剂。
7.权利要求5的洗涤剂组合物，其中耐钙非皂阴离子表面活性剂含有α-烯烃磺酸盐和烷基醚硫酸盐。
8.权利要求7的洗涤剂组合物，其中耐钙非皂阴离子表面活性剂体系(a)含有重量比为5∶1-15∶1的α-烯烃磺酸盐和烷基醚硫酸盐。
9.上述任一权利要求的洗涤剂组合物，其含有至少0.5重量％的阳离子表面活性剂体系。
10.权利要求9的洗涤剂组合物，其含有0.5-5重量％的阳离子表面活性剂体系。
11.权利要求9的洗涤剂组合物，其中组分(a)与阳离子表面活性剂体系(a)的重量比为3∶1-9∶10，产物为17∶3-1∶1。
12.上述任一权利要求的洗涤剂组合物，其中阳离子表面活性剂体系含有一种或多种选自下式的阳离子表面活性剂：
R1R2R3R4N+X-
其中
R1是疏水基团；
R2、R3或R4独立地选自羟基乙基、羟基丙基或C1-4烷基；
X-是增溶阳离子。
13.粉末洗涤剂组合物，其含有权利要求1的组合物，其中组分(a)和阳离子表面活性剂体系基本上包含在各自排除其它组分的单独颗粒中。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0031827.9 | 2000-12-29 | ||
| GBGB0031827.9A GB0031827D0 (en) | 2000-12-29 | 2000-12-29 | Detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1492920A true CN1492920A (zh) | 2004-04-28 |
Family
ID=9906024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA018229093A Pending CN1492920A (zh) | 2000-12-29 | 2001-12-13 | 洗涤剂组合物 |
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| Country | Link |
|---|---|
| US (1) | US6716807B2 (zh) |
| EP (1) | EP1346017A1 (zh) |
| CN (1) | CN1492920A (zh) |
| BR (1) | BR0116623A (zh) |
| CA (1) | CA2433047A1 (zh) |
| GB (1) | GB0031827D0 (zh) |
| WO (1) | WO2002053691A1 (zh) |
| ZA (1) | ZA200304903B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471733A (zh) * | 2009-07-27 | 2012-05-23 | 宝洁公司 | 洗涤剂组合物 |
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-
2000
- 2000-12-29 GB GBGB0031827.9A patent/GB0031827D0/en not_active Ceased
-
2001
- 2001-12-13 WO PCT/EP2001/014763 patent/WO2002053691A1/en not_active Application Discontinuation
- 2001-12-13 BR BR0116623-9A patent/BR0116623A/pt not_active IP Right Cessation
- 2001-12-13 CA CA002433047A patent/CA2433047A1/en not_active Abandoned
- 2001-12-13 CN CNA018229093A patent/CN1492920A/zh active Pending
- 2001-12-13 EP EP01985406A patent/EP1346017A1/en not_active Ceased
- 2001-12-19 US US10/025,238 patent/US6716807B2/en not_active Expired - Fee Related
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471733A (zh) * | 2009-07-27 | 2012-05-23 | 宝洁公司 | 洗涤剂组合物 |
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| Publication number | Publication date |
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| WO2002053691A1 (en) | 2002-07-11 |
| BR0116623A (pt) | 2003-12-23 |
| US20030045440A1 (en) | 2003-03-06 |
| ZA200304903B (en) | 2004-06-24 |
| CA2433047A1 (en) | 2002-07-11 |
| EP1346017A1 (en) | 2003-09-24 |
| US6716807B2 (en) | 2004-04-06 |
| GB0031827D0 (en) | 2001-02-14 |
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