CN1477184A - Disinfectant sterilization washing powder and its production process - Google Patents
Disinfectant sterilization washing powder and its production process Download PDFInfo
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- CN1477184A CN1477184A CNA021365873A CN02136587A CN1477184A CN 1477184 A CN1477184 A CN 1477184A CN A021365873 A CNA021365873 A CN A021365873A CN 02136587 A CN02136587 A CN 02136587A CN 1477184 A CN1477184 A CN 1477184A
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Abstract
The present invention relates to a disinfectant sterilization washing powder and its production process. It formula adopts safe, stable, high-effective and proper stable-state solid chlorine dioxide as disinfectant, so that said product not only has strong detersive power, but also has the functions of bleaching and removing blot, also has the function of killing bacteria and virus.
Description
Affiliated technical field
The invention belongs to a kind of chemical daily necessities and manufacture method thereof, especially a kind of washing powder and the production technique thereof that can finish the double effects of cleaning and disinfection rapidly.
The prior art situation
At present, according to washing powder prescription characteristics, technical requirements, production cost and washing habits, the sterilizing agent that can directly allocate the washing powder product into is not a lot.This is because used sterilizing agent must stable performance in washing powder, stores easily, and is easy to use, nontoxic to human body, and has the high-effective disinfecting germicidal action.Washing parameters such as the wash concentration of disinfectant detergent powder and washing time will meet human consumer's washing habits and mode of washing, under this wash conditions, not only require disinfectant detergent powder can effectively remove the difficult dirt of washing on the clothing, but also pathogenic bacterium and infectious hepatitis A or hepatitis B viruss such as intestinal bacteria, streptococcus aureus, Candida albicans can be effectively killed in requirement.In general, the sterilizing agent that can be used for washing powder has following several, it comprises cats product such as quaternary ammonium salt, chlorine-containing compound such as Babysafe (Surchlor GR 60), triclosan (2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether, triclosan DP-300), peralcohol such as SPC-D and Sodium peroxoborate etc.But the anion surfactant in cats product and the washing powder prescription can not compatibility, if use separately, then scourability is relatively poor and cost is higher.For chlorine-containing disinfectant, though, domestic have add Surchlor GR 60 in the washing powder prescription report and patent (patent publication No. CN 1113943A), but because chlorine-containing disinfectant large usage quantity in the washing powder prescription wants to reach certain germicidal efficacy, proportioning will reach more than 30%, therefore it is relatively poor to wash clean effect, and existing smell bigger, poor storage stability has shortcomings such as damage to fabric.As for triclosan, because this raw materials cost is higher, and belongs to low effect disinfectants, under general wash concentration condition, can not kill intestinal bacteria and staphylococcus, therefore be not suitable for the washing powder sterilizing agent yet.And contain the superoxide sterilizing agent, and because the oxygen release temperature is higher, generally need more than 60 ℃, not too be fit to human consumer's normal temperature washing habits, and superoxide stability in storage in washing powder is relatively poor.Therefore, still not having disinfectant sterilization washing powder on the market occurs.
The purpose of invention
The invention provides a kind of safely, stable, efficient, convenient, the washing clean effect is strong, and can effectively kill the washing powder and the production technique thereof of pathogenic bacterium such as intestinal bacteria, streptococcus aureus, Candida albicans and infectious hepatitis A or hepatitis B virus.
The content of invention
Dioxide peroxide has obtained using widely in developed country as a kind of novel sterilization oxygenant.At present, stability chlorine dioxide is classified as the agent of A1 level efficiently and safely disinfecting by The World Health Organization (WHO), have wide spectrum, quick-acting, nontoxic, advantage such as consumption is few, drug effect is long and decontamination is strong, can reach 100%, damage Mierocrystalline cellulose hardly as SYNTHETIC OPTICAL WHITNER to the killing rates of some bacteriums.According to washing powder prescription characteristics, the present invention has adopted performance safety, stable, efficient, suitable stable state solid chlorine dioxide as sterilizing agent.Product of the present invention for this reason adopts following prescription:
A. tensio-active agent weight percentage: 5-430% adopts the two combination of anion surfactant or nonionogenic tenside or its.Wherein:
Anion surfactant adopts: Sodium dodecylbenzene sulfonate or √-thiazolinyl (hydrocarbon) sulfonate is AOS or C
10-24Fatty acid soaps or its two above mixing.
Nonionogenic tenside adopts: fatty alcohol-polyoxyethylene ether AEO-9 or fatty alcohol-polyoxyethylene ether AEO-7.
B. washing auxiliary detergent: 5-90% adopts: tripoly phosphate sodium STPP or zeolite or lamina sodium silicate or Trisodium Citrate or yellow soda ash or water glass or Starso or paratoluenesulfonic acid sodium salt or its two above mixing.
C. auxiliary material:
0.1-10% adopts: white dyes or high molecular polymer or Xylo-Mucine or essence or its two above mixing;
D. sterilizing agent: the stable state solid chlorine dioxide is 1-20%.
E. stopping composition: surplus is filled with sodium sulfate
Production technique is:
1.) anion surfactant, washing auxiliary detergent, stopping composition and auxiliary material (except the essence) are made slip according to prescription and processing requirement, high temperature countercurrent spray then, and cool aging, again the stable state solid chlorine dioxide is added respectively according to proportioning, thorough mixing is even, sprays into essence according to proportioning simultaneously and promptly gets the finished product.
2.) requirement according to Recipe of nonionogenic tenside, washing auxiliary detergent, stopping composition and auxiliary material is directly mixed, then stable state solid dioxide peroxide is added respectively according to proportioning, thorough mixing evenly gets final product.
3.) at first anion surfactant, washing auxiliary detergent, stopping composition and auxiliary material (except the essence) are made slip, high temperature countercurrent spray, and cool aging then according to prescription and processing requirement.Secondly, the washing powder original washing powder of gained is got for example 50 parts of corresponding umbers, and then the requirement according to Recipe of corresponding nonionogenic tenside, washing auxiliary detergent, stopping composition and auxiliary material directly mixed, at last stable state solid dioxide peroxide is added respectively according to proportioning, thorough mixing evenly gets final product.The effect of invention
Product of the present invention can be finished the double effects of cleaning and disinfection rapidly, also has the function that bleaching removes stain simultaneously concurrently.Detect through Shanghai City preventive medicine research institute of institute and Shanghai Yi Kang sterilization institute and to show, during effect product sterilization washing powder solution chlorine dioxide content 40ppm of the present invention, can kill the intestinal bacteria more than 99.9% in 10 minutes; During 80ppm, 99.9% above streptococcus aureus can be killed in 10 minutes, 99.9% above Candida albicans can be killed in 20 minutes; During 150ppm, can be to hepatitis B surface antigen(HBsAg) HBsAg effect 30 minutes with its deactivation.Site test results shows, uses chlorine dioxide content to be 100ppm disinfectant detergent powder solution soaking clothing 20 minutes, is 94.44-100% to the killing rate of the natural bacteria on the clothing, and average kill ratio is 96.65%.Easy to use, safe and reliable, be widely used in the cleaning and disinfecting of clothings such as family, hotel, hospital and other article, for the cleaning and disinfecting of ordinary clothing provides simple and practical novel method.Use product of the present invention can effectively remove the difficult dirt of washing on the clothing, but also can effectively kill pathogenic bacterium and infectious hepatitis A or hepatitis B viruss such as intestinal bacteria, streptococcus aureus, Candida albicans.Product of the present invention is easy to use, and is safe and reliable, is widely used in the washing and the sterilization of clothings such as family, hotel, hospital and other article.
Inventive embodiment:
Embodiment one: adopt following weight percentage
A. anion surfactant: Sodium dodecylbenzene sulfonate 20%;
B. washing auxiliary detergent: tripoly phosphate sodium STPP 22%,
Yellow soda ash 9.6%,
Water glass 8%,
C. auxiliary material: Xylo-Mucine 2.0%,
Whitening agent 0.10%,
Essence 0.10%.
D. sterilizing agent: the solid chlorine dioxide 12% of stable state.
E. stopping composition: surplus
Embodiment two:
Adopt following weight percentage:
A. anion surfactant: Sodium dodecylbenzene sulfonate 19.0%
B. nonionogenic tenside: fatty alcohol-polyoxyethylene ether AEO-9 1.5%
C. washing auxiliary detergent: zeolite 28%
Yellow soda ash 15%
Water glass 8%
D. auxiliary material: high molecular polymer 0.7%,
Whitening agent 0.20%
Essence 0.20%
E. sterilizing agent: stable state solid chlorine dioxide 10%
F. stopping composition: surplus
Embodiment three: adopt following weight percentage:
A. nonionogenic tenside: fatty alcohol-polyoxyethylene ether-9 11.0%
B. washing auxiliary detergent: tripoly phosphate sodium STPP 37%
Yellow soda ash 15%
Metasilicate pentahydrate sodium 7%
C. auxiliary material: Xylo-Mucine 2.0%
Whitening agent 0.30%
Essence 0.20%
D. sterilizing agent: stable state solid chlorine dioxide 12%
E. stopping composition: surplus embodiment one and embodiment two production technique:
Tensio-active agent, washing auxiliary detergent, stopping composition and auxiliary material (except the essence) are made slip according to prescription and processing requirement, high temperature countercurrent spray then, and cool aging, again the stable state solid chlorine dioxide is added respectively according to proportioning, thorough mixing is even, sprays into essence according to proportioning simultaneously and promptly gets the finished product.
Embodiment three production technique:
Nonionogenic tenside, washing auxiliary detergent, stopping composition and auxiliary material are required directly to mix according to prescription, then stable state solid dioxide peroxide is added respectively according to proportioning, thorough mixing evenly gets final product.
Claims (7)
1. disinfectant sterilization washing powder, its weight percent content is:
A. tensio-active agent: 5-40%
B. washing auxiliary detergent:
5-90%
C. auxiliary material:
0.1-10%
D. sterilizing agent: the solid chlorine dioxide of stable state
1-20%
E. stopping composition: surplus is filled with sodium sulfate
2. a kind of disinfectant sterilization washing powder according to claim 1 is characterized in that: tensio-active agent adopts Sodium dodecylbenzene sulfonate LAS or √-thiazolinyl (hydrocarbon) sulfonate AOS or C
10-24Fatty acid soaps or fatty alcohol-polyoxyethylene ether AEO-9 or fatty alcohol-polyoxyethylene ether AEO-7 or its two above mixing.
3. a kind of disinfectant sterilization washing powder according to claim 1 is characterized in that: washing auxiliary detergent adopts: tripoly phosphate sodium STPP or lamina sodium silicate or zeolite or Trisodium Citrate or yellow soda ash or water glass or metasilicate pentahydrate sodium or paratoluenesulfonic acid sodium salt or its two above mixing.
4. a kind of disinfectant sterilization washing powder according to claim 1 is characterized in that: auxiliary material is Xylo-Mucine or high molecular polymer or whitening agent or essence or the mixing more than the two.
5. the production technique of a kind of disinfectant sterilization washing powder according to claim 1, it is characterized in that anion surfactant, washing auxiliary detergent and auxiliary material (except the essence) are made slip according to prescription, high temperature countercurrent spray then, and cool aging, again the stable state solid chlorine dioxide is added respectively according to proportioning, thorough mixing is even, sprays into essence according to proportioning simultaneously and promptly gets the finished product.
6. the production technique of a kind of disinfectant sterilization washing powder according to claim 1, it is characterized in that the requirement according to Recipe of nonionogenic tenside, washing auxiliary detergent and auxiliary material is directly mixed, then stable state solid dioxide peroxide is added respectively according to proportioning, thorough mixing evenly gets final product.
7. the production technique of a kind of disinfectant sterilization washing powder according to claim 1, it is characterized in that at first anion surfactant, washing auxiliary detergent, stopping composition and auxiliary material (except the essence) being made slip according to prescription and processing requirement, high temperature countercurrent spray, and cool aging then.Secondly, the washing powder original washing powder of gained is got corresponding umber as 50 parts, and then with corresponding nonionogenic tenside, washing auxiliary detergent, stopping composition and auxiliary material according to the prescription directly mix, at last stable state solid dioxide peroxide is added respectively according to proportioning, thorough mixing evenly gets final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021365873A CN1477184A (en) | 2002-08-20 | 2002-08-20 | Disinfectant sterilization washing powder and its production process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021365873A CN1477184A (en) | 2002-08-20 | 2002-08-20 | Disinfectant sterilization washing powder and its production process |
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| CN1477184A true CN1477184A (en) | 2004-02-25 |
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| CNA021365873A Pending CN1477184A (en) | 2002-08-20 | 2002-08-20 | Disinfectant sterilization washing powder and its production process |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101255383B (en) * | 2008-03-27 | 2010-12-01 | 中国石油化工股份有限公司 | Highly effective ferrous sulfide deactivation cleaning agent |
| CN102851126A (en) * | 2012-09-14 | 2013-01-02 | 江苏正泰医药化工有限公司 | Low-foam washing powder |
| CN103865669A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Heavy-duty laundry detergent |
| CN104479899A (en) * | 2014-12-31 | 2015-04-01 | 威莱(广州)日用品有限公司 | Super-concentration fabric cleaning agent formula and preparing method thereof |
| CN105838518A (en) * | 2016-05-13 | 2016-08-10 | 周家仁 | Antibacterial laundry detergent |
| CN106085608A (en) * | 2015-11-25 | 2016-11-09 | 西北农林科技大学 | A kind of portable wine stain cleanser and preparation method thereof |
| CN107287051A (en) * | 2017-07-31 | 2017-10-24 | 王瑜琳 | A kind of high-efficiency disinfection washing powder and preparation method thereof |
-
2002
- 2002-08-20 CN CNA021365873A patent/CN1477184A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101255383B (en) * | 2008-03-27 | 2010-12-01 | 中国石油化工股份有限公司 | Highly effective ferrous sulfide deactivation cleaning agent |
| CN102851126A (en) * | 2012-09-14 | 2013-01-02 | 江苏正泰医药化工有限公司 | Low-foam washing powder |
| CN103865669A (en) * | 2014-02-15 | 2014-06-18 | 上海方木精细化工有限公司 | Heavy-duty laundry detergent |
| CN104479899A (en) * | 2014-12-31 | 2015-04-01 | 威莱(广州)日用品有限公司 | Super-concentration fabric cleaning agent formula and preparing method thereof |
| CN106085608A (en) * | 2015-11-25 | 2016-11-09 | 西北农林科技大学 | A kind of portable wine stain cleanser and preparation method thereof |
| CN105838518A (en) * | 2016-05-13 | 2016-08-10 | 周家仁 | Antibacterial laundry detergent |
| CN107287051A (en) * | 2017-07-31 | 2017-10-24 | 王瑜琳 | A kind of high-efficiency disinfection washing powder and preparation method thereof |
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