CN1401695A - Antibacterial moldproof polyethylene foam plastic - Google Patents
Antibacterial moldproof polyethylene foam plastic Download PDFInfo
- Publication number
- CN1401695A CN1401695A CN 02131316 CN02131316A CN1401695A CN 1401695 A CN1401695 A CN 1401695A CN 02131316 CN02131316 CN 02131316 CN 02131316 A CN02131316 A CN 02131316A CN 1401695 A CN1401695 A CN 1401695A
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- Prior art keywords
- antibacterial
- foam plastic
- polyethylene foam
- mouldproof
- butane
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- Molding Of Porous Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
An antibacterial antimildew foam polyothylene plastics is prepared from polyethylene rsin, butane, monoglyceride, talk powder and antibacterial and antimildew mother particles through direct extruding out and foaming. Its advantages are high performance and low cost.
Description
Affiliated technical field
The present invention relates to polyethylene foams, particularly antibacterial moldproof polyethylene foam plastic adopts direct extrusion foaming preparation to have the manufacture method of the uncrosslinked highly foaming polyethylene sheet material of antibacterial and mouldproof performance.The highly foaming polyethylene extrusion sheet is a kind of uncrosslinked polyethylene foams, its production technique advanced person, and product performance are good, and the cost performance height is widely used as wrapping material and floor mat material.
Background technology
Along with people life enhancing along with the improving constantly of people's living standard, health perception, people also more and more pay attention to the comfortableness of living environment and sanitary condition, create life, study and the Working environment of comfortable, clean, antibiotic, mildew-resistant, the propagation that wards off disease and are the growing pursuits of people.Regrettably, follow people for own when building a living environment cool in summer and warm in winter, also for the breeding of microorganism, grow and created advantageous conditions.
Bacterium and mould are two kinds of main types of microorganism, have characteristics such as of a great variety, that distributed pole is wide, vitality is vigorous, when envrionment conditions is a relative humidity greater than 65%, when temperature 20-30 ℃, pH value 3.0-6.0, the nutritive substance on absorbing material surface and growing rapidly causes going mouldy and destroying of material.The mycelium that forms during mould-growth is a conductor, can make the decreasing insulating of material, and changes in weight the material peeling phenomenon can occur when serious.The metabolite that forms during mould-growth contains organic acid and toxin, can make phenomenons such as goods surfaces of tacky, variable color occur, become fragile, smooth finish reduction, and the people of long-term these mould curd products of contact is gone down with.Therefore, growth and the breeding of control and elimination unwanted bacteria, mould, the protection human health is the major subjects of current sciemtifec and technical sphere, and receives publicity day by day.
As the relevant prior art that contains the resin combination manufacture method of antibacterial mildew inhibitor, CN1294145A is for example arranged, it adopts polyolefin resin, inorganic antiseptic and organic mould inhibitor to prepare the antibacterial and mouldproof masterbatch.
Summary of the invention
The purpose of this invention is to provide a kind of antibacterial moldproof polyethylene foam plastic, system adopts the resin combination among the CN1294145A to join in the polyethylene raw material as anti-bacterium mildewproof additive, by changing processing parameter, preparation has antibacterial and mouldproof performance and highly foaming polyethylene extrusion sheet, it is a closed pore formula foamy structure, has the antibacterial and mouldproof performance, this section bar is to utilize forcing machine that the direct extrusion foaming typing of raw material is prepared, the highly foaming polyethylene extrusion sheet is a kind of uncrosslinked polyethylene foams, its production technique advanced person, product performance are good, and the cost performance height is widely used as wrapping material and floor mat material.
Weight of the present invention is formed and is mainly comprised:
100 parts of polyvinyl resins
Butane 10-20 part
Mono-glycerides 0.8-2 part
Talcum powder 0.4-1.2 part
Antibacterial and mouldproof masterbatch 1-5 part.
Main weight of the present invention is formed:
100 parts of polyvinyl resins
Butane 12-18 part
Mono-glycerides 1-1.8 part
Talcum powder 0.5-1.0 part
Antibacterial and mouldproof masterbatch 2-4 part.
Described resin is a new LDPE (film grade), and the melt flow rate (MFR) of new LDPE (film grade) is between 1.5-7.Multiple mixture is as mould inhibitor.
Antibacterial moldproof polyethylene foam plastic of the present invention production method, comprise the steps:
(1) by metering talcum powder, antibacterial and mouldproof masterbatch and 100 parts of polyethylene are mixed;
Described antibacterial and mouldproof masterbatch is with Ag
+, Zn
2+, Cu
2+Or their two or more mixtures wherein
As antiseptic-germicide, or with thiabendazole, m-tetrachlorophthalodinitrile, No. 75 industrial fungicides, copper 8-quinolinolate, many
Bacterium spirit or they wherein two or more mixtures as antiseptic-germicide.
(2) compound forcing machine extrusion foaming injects corresponding weight by volume pump simultaneously in forcing machine
Butane and mono-glycerides, the temperature of forcing machine is controlled at 140-230 ℃;
(3) typing is cut, and flattens, and traction is batched, packing.
The present invention has antibacterial and mouldproof performance and highly foaming polyethylene extrusion sheet, it is a closed pore formula foamy structure, has the antibacterial and mouldproof performance, this section bar is to utilize forcing machine that the direct extrusion foaming typing of raw material is prepared, the highly foaming polyethylene extrusion sheet is a kind of uncrosslinked polyethylene foams, its production technique advanced person, and product performance are good, the cost performance height is widely used as wrapping material and floor mat material.
Embodiment
Embodiment 1
Will be by new LDPE (film grade) (Daqing Petrochemical head factory, 18D) 100 weight parts and antibacterial and mouldproof masterbatch 2 weight parts, talcum powder 1 weight part, the raw material of forming mixes, join and carry out extrusion foaming in the forcing machine, the temperature of forcing machine is 160-225 ℃, the rotating speed of main frame is 650rpm, and the rotating speed of screw rod is 21.6rpm.The injection rate of butagas is 12 weight parts in extruding, and the injection rate of Tegin 55G is 1.6 weight parts.The foam of extruding rolling after cooling off, finalize the design, cut, flatten, drawing, the speed of traction are 22.6rpm, and the specification of products obtained therefrom is: thickness 3mm, and width 1000mm, per 100 meters long product weights are at the 12-12.5 kilogram.Product antibacterial and mouldproof performance: to intestinal bacteria and streptococcus aureus: antibiotic rate＞99%; Aspergillus niger, terreus etc. are mixed mould for 8 kinds: fungicidal properties is 0 grade.
Embodiment 2
Identical among the amount of new LDPE (film grade) and antibacterial and mouldproof masterbatch and the embodiment 1 in the compound, talcous consumption is kept to 0.6 weight part, and the temperature of forcing machine still is 160-225 ℃, and the rotating speed of main frame is 700rpm, and the rotating speed of screw rod is 23.9rpm.The injection rate of butagas is 18 weight parts in extruding, and the injection rate of Tegin 55G is 1 weight part.The foam of extruding rolling after cooling off, finalize the design, cut, flatten, drawing, the speed of traction are 34rpm, and the specification of products obtained therefrom is: thickness 3mm, and width 1100mm, per 100 meters long product weights are at the 7.9-8.2 kilogram.Product antibacterial and mouldproof performance: to intestinal bacteria and streptococcus aureus: antibiotic rate＞99%; Aspergillus niger, terreus etc. are mixed mould for 8 kinds: fungicidal properties is 0 grade.
Claims (5)
1, a kind of antibacterial moldproof polyethylene foam plastic is characterized in that its weight composition mainly comprises:
100 parts of polyvinyl resins
Butane 10-20 part
Mono-glycerides 0.8-2 part
Talcum powder 0.4-1.2 part
Antibacterial and mouldproof masterbatch 1-5 part.
2,, it is characterized in that its weight composition mainly comprises according to the described antibacterial moldproof polyethylene foam plastic of claim 1:
100 parts of polyvinyl resins
Butane 12-18 part
Mono-glycerides 1-1.8 part
Talcum powder 0.5-1.0 part
Antibacterial and mouldproof masterbatch 2-4 part.
3, according to the described antibacterial moldproof polyethylene foam plastic of claim 1, it is characterized in that described resin is a new LDPE (film grade), the melt flow rate (MFR) of new LDPE (film grade) is between 1.5-7.
4,, it is characterized in that described antibacterial and mouldproof masterbatch is with Ag according to the described antibacterial moldproof polyethylene foam plastic of claim 1
+, Zn
2+, Cu
2+Or they wherein two or more mixtures as antiseptic-germicide, or with thiabendazole, m-tetrachlorophthalodinitrile, No. 75 industrial fungicides, copper 8-quinolinolate, derosal or they wherein two or more mixtures as mould inhibitor.
5, the described antibacterial moldproof polyethylene foam plastic of claim 1 production method, comprise the steps:
(1) by metering talcum powder, antibacterial and mouldproof masterbatch and 100 parts of polyethylene are mixed;
(2) compound forcing machine extrusion foaming injects the butane and the mono-glycerides of corresponding weight simultaneously in forcing machine by volume pump, the temperature of forcing machine is controlled at 140-230 ℃;
(3) typing is cut, and flattens, and traction is batched, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02131316 CN1401695A (en) | 2002-09-27 | 2002-09-27 | Antibacterial moldproof polyethylene foam plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02131316 CN1401695A (en) | 2002-09-27 | 2002-09-27 | Antibacterial moldproof polyethylene foam plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1401695A true CN1401695A (en) | 2003-03-12 |
Family
ID=4746640
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02131316 Pending CN1401695A (en) | 2002-09-27 | 2002-09-27 | Antibacterial moldproof polyethylene foam plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1401695A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100393785C (en) * | 2004-12-23 | 2008-06-11 | 郭鹏毅 | Mould-proof and antibacterial foaming body |
| CN101805474A (en) * | 2010-03-04 | 2010-08-18 | 国家农产品保鲜工程技术研究中心（天津） | Fruit and vegetable shelf small package bag film and manufacture method |
| CN101831119A (en) * | 2010-03-17 | 2010-09-15 | 扬州凯尔化工有限公司 | Antibacterial PVC hard sheet suitable for packing medicament |
| CN102558647A (en) * | 2011-12-06 | 2012-07-11 | 厦门三德信电子科技有限公司 | Preparation method of high performance expanded polyethylene product |
| CN104401076A (en) * | 2014-11-25 | 2015-03-11 | 苏州九鼎珍珠棉有限公司 | HDPE(high-density polyethylene) membrane composited by high foaming of LDPE(Low-Density Polyethylene) and preparation method of HDPE membrane |
| CN105500829A (en) * | 2015-11-27 | 2016-04-20 | 太仓清宇特种塑料有限公司 | Antibacterial and mildewproof heat insulation material |
| WO2017198841A1 (en) | 2016-05-19 | 2017-11-23 | Trocellen Gmbh | Decorative wall panel and method for producing decorative wall panel |
| CN109467786A (en) * | 2018-11-23 | 2019-03-15 | 四川航天机电工程研究所 | Antimicrobial halogen-free flame polyethylene functional agglomerate and high-performance foam material and their preparation method |
| CN111117028A (en) * | 2019-11-22 | 2020-05-08 | 平湖市富利源塑业有限公司 | High-density pearl cotton and preparation method thereof |
| CN111806022A (en) * | 2020-06-23 | 2020-10-23 | 厦门三德信防护用品有限公司 | Portable antibacterial pad |
-
2002
- 2002-09-27 CN CN 02131316 patent/CN1401695A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100393785C (en) * | 2004-12-23 | 2008-06-11 | 郭鹏毅 | Mould-proof and antibacterial foaming body |
| CN101805474A (en) * | 2010-03-04 | 2010-08-18 | 国家农产品保鲜工程技术研究中心（天津） | Fruit and vegetable shelf small package bag film and manufacture method |
| CN101831119A (en) * | 2010-03-17 | 2010-09-15 | 扬州凯尔化工有限公司 | Antibacterial PVC hard sheet suitable for packing medicament |
| CN102558647A (en) * | 2011-12-06 | 2012-07-11 | 厦门三德信电子科技有限公司 | Preparation method of high performance expanded polyethylene product |
| CN102558647B (en) * | 2011-12-06 | 2013-08-07 | 厦门三德信电子科技有限公司 | Preparation method of high performance expanded polyethylene product |
| CN104401076A (en) * | 2014-11-25 | 2015-03-11 | 苏州九鼎珍珠棉有限公司 | HDPE(high-density polyethylene) membrane composited by high foaming of LDPE(Low-Density Polyethylene) and preparation method of HDPE membrane |
| CN104401076B (en) * | 2014-11-25 | 2016-09-07 | 苏州宜安诺包装科技有限公司 | A kind of LDPE high-foaming is combined HDPE film and preparation method thereof |
| CN105500829A (en) * | 2015-11-27 | 2016-04-20 | 太仓清宇特种塑料有限公司 | Antibacterial and mildewproof heat insulation material |
| WO2017198841A1 (en) | 2016-05-19 | 2017-11-23 | Trocellen Gmbh | Decorative wall panel and method for producing decorative wall panel |
| CN109467786A (en) * | 2018-11-23 | 2019-03-15 | 四川航天机电工程研究所 | Antimicrobial halogen-free flame polyethylene functional agglomerate and high-performance foam material and their preparation method |
| CN111117028A (en) * | 2019-11-22 | 2020-05-08 | 平湖市富利源塑业有限公司 | High-density pearl cotton and preparation method thereof |
| CN111806022A (en) * | 2020-06-23 | 2020-10-23 | 厦门三德信防护用品有限公司 | Portable antibacterial pad |
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