CN1398517A - Herbicide composition containing nicosulfuron and its prepn and use - Google Patents
Herbicide composition containing nicosulfuron and its prepn and use Download PDFInfo
- Publication number
- CN1398517A CN1398517A CN 01123486 CN01123486A CN1398517A CN 1398517 A CN1398517 A CN 1398517A CN 01123486 CN01123486 CN 01123486 CN 01123486 A CN01123486 A CN 01123486A CN 1398517 A CN1398517 A CN 1398517A
- Authority
- CN
- China
- Prior art keywords
- nicosulfuron
- compound
- herbicidal combinations
- humulone
- atrazine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An improved herbicide composition is one kind of mixture comprising 2-(4,6-dimethoxy pyrimidyl-2-aminoformamidosulfonyl)-N,N-dimethyl nicotinamide and at least one of 1,4-D butylate, metribuzin, sulcotrione and atrazine. It has high herbicidal effect to crab grass, green bristle grass, goose grass, etc. in corn field, and its herbicidal effect is higher than that of its single component.
Description
Technical field
The present invention relates to it Herbicidal combinations that improves performance is arranged.Wherein compound (A) and at least a specific other Herbicidal combinations (B) of active principle formula (1) representative
Background technology
(cigarette sulphur is grand for the niscosulfuron general by name of compound (A), the Chinese common name), chemistry 2-(4 by name, 6-dimethoxypyridin-2-base carbamyl aminosulfonyl)-N, the N-dimethyl nicotinamide is a kind of new herbicides, can be used for corn field and prevents and treats single broadleaf weed, but it is limited that it kills the grass spectrum, not very good to the control efficiency of broad leaved weed common in the corn field such as Siberian cocklebur, piemarker, japanese bearbind, acalypha copperleaf etc.In addition, the domestic and international composition of also not mentioned it and other specific compound of patent.Therefore it is unforeseen with the effect of other compound use.
Summary of the invention
The objective of the invention is to find out the effectiveness that Herbicidal combinations showed of compound (A) and some specific compound composition or the stack that activity level has exceeded each composition activity, this exercising result is called synergistic effect.The present invention is that compound (A) has synergistic effect with the Herbicidal combinations that some specific compound forms, and therefore one group of Herbicidal combinations is provided.Another object of the present invention finds the new purposes of composition.
Herbicidal combinations provided by the invention, it is characterized in that comprising component (A) 2-(4,6-dimethoxypyridin-2-base carbamyl aminosulfonyl)-N, N-dimethyl nicotinamide (niscosulfuron) and at least one group are selected from 2, one group of compound (B) that 4-d butyl ester (2,4-D butylate), piperazine humulone (metribuzln), sulphur humulone, atrazine (afrazine) are formed.Their chemical name is respectively:
2,4 d butyl esters: 2,4 dichloro benzene ethoxyacetic acid n-butyl (B
1)
Piperazine humulone: 4-amino-6-tertiary butyl-4,5-dihydro methyl mercapto-1,2,4-triazine-5-ketone (B
3)
Sulphur humulone: 2-(2-chloro-4-methylsulfonyl benzoyl) cyclohexane-1,3-diketone (B
3)
Atrazine: 2-chloro-4-ethylamino--6-isopropyl amino-1,3,5-triazines (B
4)
Weight ratio between compound in Herbicidal combinations of the present invention (A) and the compound (B) generally is:
For (A) and 2,4-d butyl ester (B
1) be preferably 0.05-10 for 0.01-50
For (A) and piperazine humulone (B
2) be preferably 0.05-10 for 0.01-50
For (A) and sulphur humulone (B
3) be preferably 0.05-10 for 0.01-50
For (A) and atrazine (B
4) be preferably 0.05-10 for 0.01-50
The effective component content of the present composition is 2-80%
Herbicidal combinations provided by the present invention possesses the characteristics of broad weed-killing spectrum, effectively the common single broadleaf weed in control of maize field.Preventive effect to broadleaved herb such as three-coloured amaranth, kitchen garden, lamb's-quarters, piemarker, ivy glorybind, black nightshade, Siberian cocklebur etc. is significantly higher than the preventive effect of compound alone (A), and has reduced the application dosage of every kind of active substance.This characteristic has important ecological significance, and it can delay the drug-fast generation of weeds and the succession of community, and is also significant to the protection environment.
The present invention is used for early stage dispenser behind the seedling.Term " early stage dispenser behind the seedling " expression is carried out cauline leaf spraying processing to the weeds of 2-5 leaf phase.The method of handling can be by using the composition that has tried the processing of spraying.
Herbicidal combinations involved in the present invention is suspending agent and wetting powder preferably.Also can be missible oil, pulvis, and other formulation such as granule.
Adoptable surface-active has anionic surfactant and nonionic surface active agent.The aliphatic alcohol sulfate that comprises Sulfates, alkylol polyoxyethylene groups ether sodium sulfate etc., the sodium alkyl sulfonate of Sulfonates, alkylbenzenesulfonate, alkylnaphthalene sulfonate, dialkyl succinylsuccinate sulfonate, monoalkyl phenyl polyoxyethylene groups ether succinic acid sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol formaldehyde condensation product ethylene oxide adduct sulfonate, fatty alcohol epoxy vinyl ether, alkylphenol-polyethenoxy base ether, the anhydrous sorbitol fatty acid ester, anhydrous sorbitol aliphatic acid polyethenoxy base ether, alkylphenol formaldehyde condensation product polyoxyethylene groups ether, sulfonation castor-oil plant alkoxide, quaternary ammonium salt derivative, the condensation product of oxirane and nonyl or octyl phenol is main product or hydroxyl and the oxirane that does not dissociate by esterification, the alkalies and alkaline earth salt of sulfuric ester and sulfonic acid is as sulphonyl amber ester dinonyl and dioctyl sodium and such as the alkali of the macromolecule sulfonic acid derivative of sodium lignin sulfonate and calcium and carboxylate of the anhydrous sorbierite that the alkali salt condensation forms solubility etc.That can give an example has farming breast No. 2000 series, petroleum sodium sulfonate, dodecyl sodium sulfates, draws back powder, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, tween series etc.
The present invention contains mixture, inert carrier and filler and one or more wetting agents and the dispersant that contains each active component in the Herbicidal combinations wetting powder of nicosulfuron.Carrier is generally mineral inert substance such as potter's clay, kaolin, bentonite, talcum powder, diatomite etc.The wetting powder of the Herbicidal combinations of this invention contains the active component mixture of 0.5-90% (weight) (the more excellent 5-80% of being) usually, the dispersant of 0.25-25% (more excellent is 1-25%) (weight), (more excellent be 5-80% zero and inert solid carrier and filler to 5-95% (weight).Form Herbicidal combinations jointly by them.
The suspending agent of Herbicidal combinations of the present invention is that water-soluble relatively poor active component is constantly stirred in water with emulsifier, dispersant, wetting agent etc., makes it evenly to disperse and suspend, so that spraying is used.Can suitably add thickener, antifreezing agent, defoamer etc. as required.Suitable suspending agent comprises the active component of 0.1-90% (weight) (the more excellent 0.5-60% of being).The upper limit is decided by the solubility limit of active component in solvent.
Herbicidal combinations missible oil of the present invention is that the active ingredient with Herbicidal combinations is dissolved in as in a certain solvent in butanols, cyclohexanone, dimethyl formamide, dimethylbenzene or high boiling aromatic series or the hydro carbons, adds one or more emulsifier again and is prepared from.Active constituent content is approximately 0.1-90% (weight) in the missible oil, and more excellent is 5-80%.
Herbicidal combinations pulvis of the present invention is through abrasive dust processing and make with active ingredient and fine grain dispergated solid matter such as talcum powder, natural clay and kaolin, bentonite, pyrophyllite or the diatomite of being.Pulvis contains effective composition and is approximately 0.1-50% (weight), and more excellent is 2-40%.
The preparation of granule of the present invention is that active ingredient is sprayed at particulate inert material surface with absorption property or active ingredient is adhered to sand, first-class carrier mass surface, high mountain range or particulate inert material surface with adhesives such as polyvinyl alcohol, Sodium Polyacrylate or mineral oil, also can the active ingredient that some is suitable be processed into granule with the method for common manufacturing granular fertilizer.Its active constituent content of dispersible granules agent (weight) between 5-90% in the water spreads fertilizer over the fields active constituent content (weight) between 1-50% in the granule, is preferably between the 1-25%.
Embodiment
Following examples describe the present invention in detail.Embodiment mainly is for the present invention is described, but not is used for limiting the present invention.
Embodiment 1 is the formulation preparation example, and embodiment 2-5 is a biological Examples.
Embodiment 1:
The a suspending agent
Active component A with 2% (purity≤90%) and 20% active component B (purity 81%) and 0201B as emulsifier 5%, 5% JFC as wetting agent, 3% draw back powder and, in colloid mill, be ground to particle diameter and get final product below 5 microns as dispersant as 3% n-butanol of defoamer mixing successively.
The b wetting powder:
40 parts of heavy compositions usefuls and the 2 parts heavy neopelex as wetting agent, the sodium lignin sulfonate that is used as dispersant of 5 parts of lifes and the kaolin of 53 parts of weights are formed through ultramicro grinding in airslide disintegrating mill.
The c pulvis
With mixing of 10 parts of heavy compositions usefuls and 90 parts of weights, in high speed disintegrator, pulverize and evenly form as the talcum powder of inert substance.
D missible oil
The active ingredient composition of 50 parts of weights is dissolved in toluene as solvent, forms among the agricultural newborn 0201B as emulsifier of 10 parts of weights.
The e granule: by the active ingredient composition of 20 parts of weights, the sodium lignin sulfonate of 30 parts of weights, the dodecyl sodium sulfate of 15 parts of weights, the kaolin of 15 parts of heavy polyvinyl alcohol and 15 parts of weights is made.Embodiment 2: nicosulfuron and 2,4-d butyl ester are used the control efficiency (%) to corn field weed with
Place: Xinyi sowing: June 15 calendar year 2001
Dispenser period: the corn 3-4 leaf phase is investigated: behind the medicine 30 days
| Medicament | 30 days strain preventive effects behind the medicine | |||||
| Effective ingredient (gram/mu) | Lady's-grass | Acalypha copperleaf | Siberian cocklebur | Piemarker | Lamb's-quarters | |
| Nicosulfuron | ????2 | ????75.3 | ????69.3 | ????71.2 | ????69.2 | ????65.2 |
| Nicosulfuron | ????4 | ????81.3 | ????75.2 | ????70.3 | ????75.3 | ????80.3 |
| 2, the 4-d butyl ester | ????15 | ????50.3 | ????78..3 | ????65.3 | ????60.2 | ????63.4 |
| 2, the 4-d butyl ester | ????30 | ????60.4 | ????85.4 | ????80.2 | ????75.3 | ????84.5 |
| Nicosulfuron+2, the 4-d butyl ester | ????2+15 | ????91.8 | ????92.5 | ????93.7 | ????89.5 | ????94.5 |
| Nicosulfuron+2, the 4-d butyl ester | ????4+30 | ????95.7 | ????96.7 | ????98.5 | ????93.4 | ????98.7 |
Conclusion: nicosulfuron and 2, the preventive effect of using with of 4-d butyl ester is higher than it and uses the expectancy theory preventive effect with, proves nicosulfuron and 2, and the 4-d butyl ester has been used synergistic effect with.Embodiment 3: nicosulfuron and piperazine humulone are used the control efficiency (%) to corn field weed with
Place: Xinyi sowing: June 15 calendar year 2001
Dispenser period: the corn 3-4 leaf phase is investigated: 30 is big behind the medicine
| Agent | 30 days strain preventive effects behind the medicine | |||||
| Effective ingredient (gram/mu) | Lady's-grass | Acalypha copperleaf | Siberian cocklebur | Piemarker | Lamb's-quarters | |
| Nicosulfuron | ????2 | ??74.8 | ??70.3 | ??63.4 | ??65.2 | ??50.2 |
| Nicosulfuron | ????4 | ??80.7 | ??79.5 | ??79.8 | ??70.2 | ??67.5 |
| The piperazine humulone | ????30 | ??53.4 | ??40.3 | ??61.3 | ??60.8 | ??47.3 |
| The piperazine humulone | ????60 | ??64.5 | ??45.2 | ??70.2 | ??71.2 | ??53.4 |
| Nicosulfuron+piperazine humulone | ????2+30 | ??92.3 | ??89.3 | ??91.3 | ??92.3 | ??89.2 |
| Nicosulfuron+piperazine humulone | ????4+60 | ??95.7 | ??92.5 | ??95.8 | ??96.7 | ??91.3 |
Conclusion: the preventive effect of using with of nicosulfuron and piperazine humulone is higher than it and uses the expectancy theory preventive effect with, proves that nicosulfuron and piperazine humulone used synergistic effect with.Embodiment 4: nicosulfuron and sulphur humulone are used the control efficiency (%) to corn field weed with
Place: Xinyi sowing: June 15 calendar year 2001
Dispenser period: the corn 3-4 leaf phase is investigated: behind the medicine 30 days
| Medicament | 30 days strain preventive effects behind the medicine | |||||
| Effective ingredient (gram/mu) | Lady's-grass | Acalypha copperleaf | Siberian cocklebur | Piemarker | Lamb's-quarters | |
| Nicosulfuron | ????2 | ??75.2 | ??78.3 | ??65.3 | ??69.8 | ??71.3 |
| Nicosulfuron | ????4 | ??80.3 | ??82.1 | ??78.4 | ??79.2 | ??83.5 |
| The sulphur humulone | ????4 | ??63.4 | ??65.3 | ??52.3 | ??65.3 | ??61.2 |
| The sulphur humulone | ????8 | ??78.2 | ??81.2 | ??64.5 | ??79.7 | ??75.3 |
| Nicosulfuron+sulphur humulone | ????2+4 | ??90.3 | ??95.4 | ??92.5 | ??89.3 | ??90.5 |
| Nicosulfuron+sulphur humulone | ????4+8 | ??95.7 | ??98.7 | ??93.4 | ??94.3 | ??96.7 |
Conclusion: the preventive effect of using with of nicosulfuron and sulphur humulone is higher than it and uses the expectancy theory preventive effect with, proves that nicosulfuron and sulphur humulone used synergistic effect with.Embodiment 5: nicosulfuron and atrazine are used with the control efficiency of sugarcane field weeds (%)
Place: Xinyi sowing: July 15 (potted plant) in 2000
Dispenser period: the sugarcane 3-4 leaf phase is investigated: behind the medicine 30 days
| Medicament | 30 days strain preventive effects behind the medicine | |||||
| Effective ingredient (gram/mu) | Lady's-grass | Acalypha copperleaf | Siberian cocklebur | Piemarker | Lamb's-quarters | |
| Nicosulfuron | ????2 | ??71.3 | ??65.3 | ??63.4 | ??67.8 | ??57.2 |
| Nicosulfuron | ????4 | ??82.5 | ??78.9 | ??75.2 | ??71.3 | ??69.3 |
| Atrazine | ????60 | ??65.3 | ??50.2 | ??67.3 | ??64.3 | ??65.4 |
| Atrazine | ????120 | ??73.4 | ??63.4 | ??75.4 | ??70.2 | ??77.2 |
| Nicosulfuron+atrazine | ????2+60 | ??85.7 | ??889.5 | ??92.5 | ??90.3 | ??89.3 |
| Nicosulfuron+atrazine | ????4+120 | ??92.3 | ??94.3 | ??95.2 | ??95.5 | ??96.3 |
Conclusion: the preventive effect of using with of nicosulfuron and atrazine is higher than it and uses the expectancy theory preventive effect with, proves that nicosulfuron and atrazine used synergistic effect with.
Claims (5)
1. a Herbicidal combinations that contains nicosulfuron is characterized in that comprising compound (A) (nicosulfuron) and at least a compound (B) that is selected from following one group of compound
The structural formula of A is:
Compd B is respectively
2,4-d butyl ester: 2-4-dichlorophenoxyacetic acid n-butyl (B
1)
Piperazine humulone: 4-amino-6-tertiary butyl-4,5-dihydro methyl mercapto-1,2,4-triazine-5-ketone (B
2)
Sulphur humulone: 2-(2-chloro-4-methylsulfonyl benzoyl) cyclohexane-1,3-diketone (B
3)
Atrazine: 2-chloro-4-ethylamino--6-isopropyl amino-1,3,5-triazines (B
4)
2 Herbicidal combinations according to claim 1 is characterized in that the weight ratio between compound in the Herbicidal combinations (A) and the compound (B) is:
(A) with 2,4-d butyl ester (B
1) be preferably 0.02-0.2 for 0.01-1
(A) with piperazine humulone (B
2) be preferably 0.02-0.1 for 0.02-2
(A) with sulphur humulone (B
3) be preferably 0.05-1 for 0.01-5
(A) with atrazine (B
4) be preferably 0.01-0.5 for 0.005-0.1
3 compositions according to claim 1, the effective component content that it is characterized in that composition are 2-80% (weight).
4 one kinds of preparation methods that contain the Herbicidal combinations of nicosulfuron is characterized in that, the formulation that medicament can be processed into conventional plant protection product is a suspending agent, wetting powder, pulvis, missible oil, granule etc.
5 one kinds of purposes that contain nicosulfuron herbicide composition is characterized in that composition A+B
1, A+B
2, A+B
3, A+B
4Corn field or sugarcane field be can be respectively applied for and single broadleaf weed and broadleaved herb such as three-coloured amaranth, kitchen garden, lamb's-quarters, piemarker, ivy glorybind, black nightshade, Siberian cocklebur prevented and kill off.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01123486 CN1398517A (en) | 2001-07-27 | 2001-07-27 | Herbicide composition containing nicosulfuron and its prepn and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01123486 CN1398517A (en) | 2001-07-27 | 2001-07-27 | Herbicide composition containing nicosulfuron and its prepn and use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1398517A true CN1398517A (en) | 2003-02-26 |
Family
ID=4665090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01123486 Pending CN1398517A (en) | 2001-07-27 | 2001-07-27 | Herbicide composition containing nicosulfuron and its prepn and use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1398517A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005092101A2 (en) | 2004-03-26 | 2005-10-06 | Syngenta Participations Ag | A herbicidal combination |
| CN102599181A (en) * | 2012-02-20 | 2012-07-25 | 王从爱 | Oil suspension agent composition containing nicosulfuron and 2,4-d isooctyl ester |
| CN102680594A (en) * | 2012-04-28 | 2012-09-19 | 浙江大学 | Method for testing toxicity of residual nicosulfuron on corn |
| WO2012141277A1 (en) * | 2011-04-14 | 2012-10-18 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal composition comprising flazasulfuron and metribuzin |
| CN104663659A (en) * | 2014-01-26 | 2015-06-03 | 山东先达农化股份有限公司 | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic |
| WO2015078243A1 (en) * | 2013-11-28 | 2015-06-04 | Rotam Agrochem International Company Limited | Herbicidal compositions comprising triazinone herbicide and als inhibitor herbicide and uses thereof |
| CN104970034A (en) * | 2015-06-03 | 2015-10-14 | 赵志平 | Herbicide composition |
| EP3183966A1 (en) * | 2015-12-23 | 2017-06-28 | Rotam Agrochem International Co., Ltd | Method of controlling growth of als-tolerant plants |
-
2001
- 2001-07-27 CN CN 01123486 patent/CN1398517A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005092101A3 (en) * | 2004-03-26 | 2006-01-26 | Syngenta Participations Ag | A herbicidal combination |
| EA011352B1 (en) * | 2004-03-26 | 2009-02-27 | Зингента Партисипейшнс Аг | A herbicidal combination |
| AU2005226886B2 (en) * | 2004-03-26 | 2010-06-03 | Syngenta Participations Ag | A herbicidal combination |
| WO2005092101A2 (en) | 2004-03-26 | 2005-10-06 | Syngenta Participations Ag | A herbicidal combination |
| CN103607893B (en) * | 2011-04-14 | 2015-03-11 | 石原产业株式会社 | Herbicidal composition comprising flazasulfuron and metribuzin |
| WO2012141277A1 (en) * | 2011-04-14 | 2012-10-18 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal composition comprising flazasulfuron and metribuzin |
| CN103607893A (en) * | 2011-04-14 | 2014-02-26 | 石原产业株式会社 | Herbicidal composition comprising flazasulfuron and metribuzin |
| US8921271B2 (en) | 2011-04-14 | 2014-12-30 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal composition comprising flazasulfuron and metribuzin |
| AU2012243715B2 (en) * | 2011-04-14 | 2015-02-05 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal composition comprising flazasulfuron and metribuzin |
| CN102599181A (en) * | 2012-02-20 | 2012-07-25 | 王从爱 | Oil suspension agent composition containing nicosulfuron and 2,4-d isooctyl ester |
| CN102680594A (en) * | 2012-04-28 | 2012-09-19 | 浙江大学 | Method for testing toxicity of residual nicosulfuron on corn |
| WO2015078243A1 (en) * | 2013-11-28 | 2015-06-04 | Rotam Agrochem International Company Limited | Herbicidal compositions comprising triazinone herbicide and als inhibitor herbicide and uses thereof |
| CN105792649A (en) * | 2013-11-28 | 2016-07-20 | 龙灯农业化工国际有限公司 | Herbicidal composition containing triazone herbicide and ALS inhibitor herbicide and use thereof |
| CN105792649B (en) * | 2013-11-28 | 2021-05-07 | 龙灯农业化工国际有限公司 | Herbicidal composition containing triazinone herbicide and ALS inhibitor herbicide and use thereof |
| CN104663659A (en) * | 2014-01-26 | 2015-06-03 | 山东先达农化股份有限公司 | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic |
| WO2015109423A1 (en) * | 2014-01-26 | 2015-07-30 | 山东先达农化股份有限公司 | Cornfield compounded herbicide composition |
| CN104970034A (en) * | 2015-06-03 | 2015-10-14 | 赵志平 | Herbicide composition |
| EP3183966A1 (en) * | 2015-12-23 | 2017-06-28 | Rotam Agrochem International Co., Ltd | Method of controlling growth of als-tolerant plants |
| EP3329776A1 (en) * | 2015-12-23 | 2018-06-06 | Rotam Agrochem International Co., Ltd | Method of controlling growth of als-tolerant plants |
| CN108601359A (en) * | 2015-12-23 | 2018-09-28 | 江苏龙灯化学有限公司 | The method for controlling the growth of ALS tolerant plants |
| CN108601359B (en) * | 2015-12-23 | 2021-08-10 | 江苏龙灯化学有限公司 | Methods of controlling ALS-tolerant plant growth |
| US11272708B2 (en) | 2015-12-23 | 2022-03-15 | Rotam Agrochem International Co., Ltd. | Method of controlling growth of ALS-tolerant plants |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1247452A (en) | Agrochemical surfactant compsns. | |
| CN1052852C (en) | Herbicidal composition contg. prpisochlor | |
| CN1229019C (en) | Herbicidal agents containing post-emergency herbicides for soil application | |
| CN1398517A (en) | Herbicide composition containing nicosulfuron and its prepn and use | |
| CN101473830A (en) | Sterilizing agricultural chemical composition containing amistar | |
| CN1129358C (en) | Pesticide composition containing fipronil | |
| CN1253083C (en) | Inoulant tolerant fungicidal compositions | |
| CN1293895A (en) | Disposable herbiciding composition for rice field | |
| CN1401232A (en) | Herbicidal composition contg. fenoxaprop-P-ethyl, its preparation method and use | |
| CN1297195C (en) | Herbicide composition of fomesafen and imazethapyr | |
| CN1222214C (en) | Herbicide composition containing KIH 9201 | |
| CN104145965A (en) | Insecticidal and fungicidal composition containing hymexazol | |
| CN113100250B (en) | Acaricidal composition containing mitochondrial oxidative phosphorylation inhibitor and application thereof | |
| CN1088554C (en) | Propisochlor containing herbicide composition | |
| CN1073349C (en) | Pesticidy formulations and process for mfg. same | |
| CN101601393A (en) | The Herbicidal combinations of Han oxadiazon | |
| CN103380781A (en) | Insecticidal composition of lambda-cyhalothrin and diafenthiuron | |
| CN1256021C (en) | Herbicide composition contg. tribenuron | |
| CN1413462A (en) | Herbicide composition containing monosulfmeturon | |
| CN1189085C (en) | Insecticide composition contg. carbosulfan and imidecloprid | |
| CN1402978A (en) | Herbicide composition containing ethachlor | |
| CN1153595A (en) | Composite rice field phytocide | |
| CN104920412B (en) | A kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide | |
| CN1066611C (en) | Herbicide composition | |
| CN113854311B (en) | Synergistic weeding composition and preparation and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |