CN1349019A - Inorganic light-colored antistatic fabric finishing agent - Google Patents
Inorganic light-colored antistatic fabric finishing agent Download PDFInfo
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- CN1349019A CN1349019A CN 01132263 CN01132263A CN1349019A CN 1349019 A CN1349019 A CN 1349019A CN 01132263 CN01132263 CN 01132263 CN 01132263 A CN01132263 A CN 01132263A CN 1349019 A CN1349019 A CN 1349019A
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- finishing agent
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Abstract
An inorganic pale-colour antistatic fabric finishing agent includes pale-colour antistatic inorganic powder, disperser, stabilizer, levelling agent and adhesive. The said inorganic pale-colour antistatic fabric finishing agent is an emulsion which can be mixed by using the conventional physical mixing method and used for antistatic treatment of fabric. This invented finishing agent has very significant advantages: (1) good flowability; (2) high stability; (3) good antistatic durability up to 50 times for face material, pH at 6.5-7.5, good compatibility, and it can be compounded with surfactant category softening agent (such as parafin), reactive softening agent (such as softening agent VS) and organic silicon softening agent (such as Dow Curning Q2-8865).
Description
Technical field
The present invention relates to a kind of inorganic antistatic fabric finishing agent, being specifically related to a kind of is the light-colored antistatic fabric finishing agent of active component with ATO (stibium doping stannic oxide).
Background technology
Develop rapidly along with science and technology, increasing industry has proposed more urgent requirement to the exploitation of anti-static fabric, the utmost point need a kind of replace metal, in light weight, quality is soft, be easy to make, conduct electricity good material, makes the research of antistatic additive become focus thus.
A kind of static that prevents synthetic fiber more enduringly that occurs the earliest in the world be a kind of antistatic resin.This resin possess hydrophilic property, structure is similar to the fiber that is organized, and can be adhered to fiber surface by soaking, roll, melt, drying by the fire, and increases the electric conductivity of fiber by moisture absorption.Be such antistatic resin as the epoxy alkyl derivative of polyamide and the product of polyisocyanate.Only in the environment of relative humidity more than 50%, its antistatic effect is just preferable for this class antistatic resin.
Another kind of for can add the antistatic additive of polymer inside to, as surfactants such as phosphate, sulfonate.Such antistatic additive has polar group, combines with the water in air branch at polymeric outer layer formation conductive layer or by hydrogen bond, and condensate resistance is reduced.As epoxy ethane-epoxy propane copolymerization phosphate, add in the polyamide, after being spun to carpet, its antistatic property is very good.Because this type of antistatic additive is not the generation that suppresses static, but quicken the dissipation of electrostatic charge, so antistatic effect is relevant with the static of environment, wearer's electric capacity and clothes to a certain extent.
More than two classes all are organic antistatic agentses.Along with the appearance of inorganic antistatic powder, the inorganic antistatic finishing agent becomes new research direction.Japan Patent JP8325478 has reported a kind of preparation method of antistatic finishing agent, the antistatic solid suspension that it is that at least a resin and ATO particle mix in acrylic acid, epoxy, the polyester with containing, make after disperseing.The polyester fabric that adopts this finishing agent to handle has antistatic property (electrostatic half-life is 1 second), but the antistatic composition ATO that this patent adopts is the avy blue material, and fabric color is had considerable influence.Poland Patent PL178064 has reported a kind of preparation method of antistatic finishing agent, and it is to make antistatic fabric finishing agent after conductive materials such as carbon black, graphite or metal dust and cross-linking reagent and thickener are mixed, disperse.The cotton fiber that adopts this finishing agent to handle has antistatic property, and (sheet resistance 4.3s, 106W), but antistatic composition carbon black, graphite or metal dust that this patent adopts are dark matter, and fabric color is had considerable influence.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of inorganic light-colored antistatic fabric finishing agent, with what overcome that prior art exists fabric color are had the defective of considerable influence.
Inorganic light-colored antistatic fabric finishing agent of the present invention is a kind of composition, and its component and weight percentage comprise:
Light-colored antistatic inorganic particle 2-50%
Dispersant 0.1-5%
Stabilizing agent 0.1-2%
Levelling agent 0.1-2%
Adhesive 10-50%
Water surplus
(1) light-colored antistatic inorganic particle: this inorganic matter is a carrier with titanium dioxide, silica or zinc oxide etc., and the surface is coated with antistatic active components A TO.The weight percentage of ATO is 15～50%, can adopt the method for bibliographical information synthetic, as the flat 2-194064 of Japan Patent (1990.7.14), the flat 2-248489 of Japan Patent (1990.10.4), BP GB2252551 (1992.8.12), Japanese patent laid-open 6-207118 (1994.7.6), powder specific insulation ρ is at 10-300 Ω cm.The weight percentage of powder is 2-50%;
(2) dispersant: make antistatic particle be suspended in aqueous phase.The dispersant that adopts is electrolytes dispersant or macromolecule hyper-dispersant, can preferably adopt in triethanolamine, calgon, Sodium Polyacrylate, poly amic acid, polyvinylpyrrolidone or the polyethylene glycol one or more, addition is counted 0.1-5% with weight percentage.Preferred DP-18, DP-518, the DP-512 that adopts Deuchem Co., Ltd. (DECHEM CO.LTD.).
(3) stabilizing agent: make that powder granule after the dispersion is no longer reunited, flocculation and sedimentation.Can adopt in cellulose derivative (as sodium carboxymethylcellulose CMC, sodium hydroxyethyl cellulose HEC etc.), the polyacrylate (acrylate and acrylic acid copolymer sodium salt, acrylic acid and vinyl acetate copolymer sodium salt etc.) one or more, addition is counted 0.1-2% with weight percentage.Preferred CMC, ROHM AND HAAS (the Rohm ﹠amp of adopting; Haas) the Acrysol ASE-60 or the Acrysol G-110 of company's production.
(4) levelling agent: make the suspension of stable dispersion have good flowability, can on fabric, form uniform coat.Can adopt in acrylic resin, polyvinyl butyral resin, acetylbutyrylcellulose CAB, the organic modified polyorganosiloxane etc. one or more, addition is counted 0.1-2% with weight percentage.The preferred DC-14 that adopts Dow corning (DowCorning) company to produce.
(5) adhesive: the fastness that combines that can promote antistatic composition and fiber.Can adopt in natural glue (as starch, modified starch, casein etc.), the composite adhesives (as polyvinyl alcohol (PVA), polyvinyl acetate glue breast (PVAC), styrene-acrylic latex (styrene and acrylate copolymer), vinegar third latex (vinyl acetate and acrylate copolymer) etc.) one or more simultaneously, the adhesive addition is counted 10-50% with weight percentage.Preferred adopt Changshu low temperature irradiation technology KG-101 of factory, the Hefei low-temperature adhesive AH-1 of factory and AH-2, join the CROSLENE2M-85A of chemical industry Co., Ltd (Taiwan) for a long time.
(6) water: surplus.
Inorganic light-colored antistatic fabric finishing agent of the present invention is a kind of suspension, can adopt conventional physical mixed method to mix, and can be used for the antistatic treatment of fabric.
Finishing agent of the present invention uses through actual, has very significant advantage:
(1) good fluidity;
(2) stability is high: get the 10ml finishing agent, on centrifuge in 4000 rev/mins centrifugal 30 minutes down, test supernatant liquor height H is 0cm;
(3) the antistatic property persistence is good: it is 2% that finishing agent is diluted with water to powder content, adopts padding method that antistatic finishing agent is coated on fabric face then, dries by the fire 10 minutes down in 105 ℃, bakes under 180 ℃ 1 minute again, makes anti-static fabric.This fabric is at room temperature carried out once washing with soap, and the clean back of rinsing is oven dry back test surfaces resistance under 105 ℃, if sheet resistance is less than 1 * 10
10Ω, then persistence is 1 time; So repeatedly to measure durability.After tested, the antistatic persistence of lining is for 50 times;
(4) of light color: white or canescence;
(5) intermediate acid basicity: pH is at 6.5-7.5;
(6) compatibility is good: can be with surfactant-based softener (as paraffin), reactive softener (as softener VS), (as DOW CORNING Q2-8865) is composite for silicone softening agent.
The specific embodiment
By the following examples the concrete embodiment of the present invention is narrated, but embodiment does not limit protection scope of the present invention.
Embodiment 1
Adopt following proportioning to prepare finishing agent of the present invention: wherein, the method that the light-colored antistatic powder adopts the flat 2-194064 of Japan Patent (1990.7.14) to provide is prepared.
Light-colored antistatic powder (ρ=80 Ω cm) 20%
Dispersant DP-18 1%
Stabilizing agent CMC 2%
Levelling agent DC-14 1%
Adhesive KG-101 40%
Water 36%
The pH of this prescription gained finishing agent is 6.8, stable H=0cm, and the antistatic persistence of the polyester fabric of arrangement is more than 50 times.Through composite with Q2-8865, compatibility is good.
Embodiment 2
Adopt following proportioning to prepare finishing agent of the present invention: wherein, the method that the light-colored antistatic powder adopts BP GB2252551 (1992.8.12) to provide is prepared.
Light-colored antistatic powder (ρ=200 Ω cm) 5%
Dispersant DP-18 1%
DP-518 1％
Stabilizing agent Acrysol G-110 2%
Levelling agent DC-14 1%
Adhesive KG-101 30%
Water 60%
The pH of this prescription gained finishing agent is 7.0, stable H=0cm, and the antistatic persistence of the polyester fabric of arrangement is more than 50 times.Through composite with softener VS, compatibility is good.
Claims (7)
1. an inorganic light-colored antistatic fabric finishing agent is characterized in that, the component and the weight percentage of this fabric finishing agent comprise:
Light-colored antistatic inorganic particle 2-50%
Dispersant 0.1-5%
Stabilizing agent 0.1-2%
Levelling agent 0.1-2%
Adhesive 10-50%
Water surplus.
2. fabric finishing agent as claimed in claim 1, it is characterized in that, said light-colored antistatic inorganic particle is for being carrier with titanium dioxide, silica or zinc oxide, and the surface is coated with antistatic active components A TO, and powder specific insulation ρ is at 10-300 Ω cm;
Said dispersant is one or more in triethanolamine, calgon, Sodium Polyacrylate, poly amic acid, polyvinylpyrrolidone or the polyethylene glycol;
Said stabilizing agent is one or more in cellulose derivative or the polyacrylate;
Said levelling agent is one or more in acrylic resin, polyvinyl butyral resin, acetylbutyrylcellulose CAB, the organic modified polyorganosiloxane;
Said adhesive is one or more in starch, modified starch, casein, polyvinyl alcohol, polyvinyl acetate glue breast, styrene-acrylic latex, vinegar third latex;
3. fabric finishing agent as claimed in claim 2 is characterized in that, the weight percentage of ATO is 15～50%.
4. fabric finishing agent as claimed in claim 2 is characterized in that, said dispersant is DP-18, DP-518 or the DP-512 of Deuchem Co., Ltd. (DECHEM CO.LTD.).
5. fabric finishing agent as claimed in claim 2 is characterized in that, said stabilizing agent is CMC, ROHM AND HAAS (Rohm ﹠amp; Haas) the Acrysol ASE-60 or the Acrysol G-110 of company's production.
6. fabric finishing agent as claimed in claim 2 is characterized in that, said levelling agent is the DC-14 that Dow corning (DowComing) company produces.
7. fabric finishing agent as claimed in claim 2 is characterized in that, said adhesive is the AH-1 of KG-101, Hefei low-temperature adhesive factory of Changshu low temperature irradiation technology factory and AH-2, joins the CROSLENE2M-85A of chemical industry Co., Ltd for a long time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01132263 CN1349019A (en) | 2001-11-22 | 2001-11-22 | Inorganic light-colored antistatic fabric finishing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01132263 CN1349019A (en) | 2001-11-22 | 2001-11-22 | Inorganic light-colored antistatic fabric finishing agent |
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| CN1349019A true CN1349019A (en) | 2002-05-15 |
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| CN 01132263 Pending CN1349019A (en) | 2001-11-22 | 2001-11-22 | Inorganic light-colored antistatic fabric finishing agent |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102719981A (en) * | 2012-03-28 | 2012-10-10 | 上海嘉乐股份有限公司 | Light and thin pollen resisting finished fabric and processing method thereof |
| CN103726331A (en) * | 2013-11-30 | 2014-04-16 | 江苏常朔针纺纱科技有限公司 | After-finishing method of textile fabric |
| CN103774436A (en) * | 2014-01-24 | 2014-05-07 | 南通惠通纺织器材有限公司 | Antistatic finishing agent and preparation method thereof |
| CN103981697A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Static electricity-removed softening agent and preparation method thereof |
| CN104452301A (en) * | 2014-12-23 | 2015-03-25 | 常熟市周行毛巾厂 | Finishing liquid for double-side terry fabric |
| CN104452276A (en) * | 2014-12-23 | 2015-03-25 | 常熟市周行毛巾厂 | Finishing liquid for jacquard terry cloth |
| CN104480709A (en) * | 2014-12-23 | 2015-04-01 | 常熟市中宏针织厂 | Coat fabric finishing process |
| CN104790207A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Durable fabric odor-resisting and antistatic finishing agent |
| CN105088793A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Non-woven fabric, and preparation method and application thereof |
| CN105220476A (en) * | 2015-10-16 | 2016-01-06 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of preparation method of the PET polyester electric conduction fiber based on tin-antiomony oxide |
| CN105386302A (en) * | 2015-12-22 | 2016-03-09 | 常熟市博凡针纺织有限公司 | Berber fleece dyeing and finishing process |
| CN107201651A (en) * | 2017-05-31 | 2017-09-26 | 句容市恒鑫遮阳科技有限公司 | A kind of antistatic window curtain fabric and preparation method thereof |
| CN107217470A (en) * | 2017-05-31 | 2017-09-29 | 句容市恒鑫遮阳科技有限公司 | A kind of preparation method of ultraviolet protection curtain fabric |
| CN107869057A (en) * | 2017-11-30 | 2018-04-03 | 英泰时尚服饰（苏州）有限公司 | A kind of preparation method of antibacterial antistatic finishing agent |
| CN108360261A (en) * | 2018-02-05 | 2018-08-03 | 李秀珍 | A kind of spring and autumn antistatic women's dress and its production technology |
| CN108951111A (en) * | 2018-06-06 | 2018-12-07 | 苏州印丝特纺织数码科技有限公司 | A kind of antistatic finishing agent and preparation method thereof for dacron |
| CN109023920A (en) * | 2018-08-22 | 2018-12-18 | 安徽利思达网业有限公司 | A method of waterproof and oilproof antistatic terylene needled felt is made with magnetron sputtering-plasma |
| CN110041635A (en) * | 2019-04-19 | 2019-07-23 | 金旸（厦门）新材料科技有限公司 | A kind of antistatic photodiffusion material and preparation method thereof |
-
2001
- 2001-11-22 CN CN 01132263 patent/CN1349019A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102719981A (en) * | 2012-03-28 | 2012-10-10 | 上海嘉乐股份有限公司 | Light and thin pollen resisting finished fabric and processing method thereof |
| CN103726331A (en) * | 2013-11-30 | 2014-04-16 | 江苏常朔针纺纱科技有限公司 | After-finishing method of textile fabric |
| CN103774436A (en) * | 2014-01-24 | 2014-05-07 | 南通惠通纺织器材有限公司 | Antistatic finishing agent and preparation method thereof |
| CN103981697A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Static electricity-removed softening agent and preparation method thereof |
| CN103981697B (en) * | 2014-05-16 | 2015-12-30 | 吴江市英力达塑料包装有限公司 | One destatics softener and preparation method thereof |
| CN104452301A (en) * | 2014-12-23 | 2015-03-25 | 常熟市周行毛巾厂 | Finishing liquid for double-side terry fabric |
| CN104452276A (en) * | 2014-12-23 | 2015-03-25 | 常熟市周行毛巾厂 | Finishing liquid for jacquard terry cloth |
| CN104480709A (en) * | 2014-12-23 | 2015-04-01 | 常熟市中宏针织厂 | Coat fabric finishing process |
| CN104790207A (en) * | 2015-05-14 | 2015-07-22 | 宣海成 | Durable fabric odor-resisting and antistatic finishing agent |
| CN105088793A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Non-woven fabric, and preparation method and application thereof |
| CN105220476A (en) * | 2015-10-16 | 2016-01-06 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of preparation method of the PET polyester electric conduction fiber based on tin-antiomony oxide |
| CN105220476B (en) * | 2015-10-16 | 2017-11-28 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of preparation method of the PET polyester electric conduction fibers based on tin-antiomony oxide |
| CN105386302A (en) * | 2015-12-22 | 2016-03-09 | 常熟市博凡针纺织有限公司 | Berber fleece dyeing and finishing process |
| CN107201651A (en) * | 2017-05-31 | 2017-09-26 | 句容市恒鑫遮阳科技有限公司 | A kind of antistatic window curtain fabric and preparation method thereof |
| CN107217470A (en) * | 2017-05-31 | 2017-09-29 | 句容市恒鑫遮阳科技有限公司 | A kind of preparation method of ultraviolet protection curtain fabric |
| CN107869057A (en) * | 2017-11-30 | 2018-04-03 | 英泰时尚服饰（苏州）有限公司 | A kind of preparation method of antibacterial antistatic finishing agent |
| CN108360261A (en) * | 2018-02-05 | 2018-08-03 | 李秀珍 | A kind of spring and autumn antistatic women's dress and its production technology |
| CN108951111A (en) * | 2018-06-06 | 2018-12-07 | 苏州印丝特纺织数码科技有限公司 | A kind of antistatic finishing agent and preparation method thereof for dacron |
| CN109023920A (en) * | 2018-08-22 | 2018-12-18 | 安徽利思达网业有限公司 | A method of waterproof and oilproof antistatic terylene needled felt is made with magnetron sputtering-plasma |
| CN110041635A (en) * | 2019-04-19 | 2019-07-23 | 金旸（厦门）新材料科技有限公司 | A kind of antistatic photodiffusion material and preparation method thereof |
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