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CN1328203C - Additive for saltresistance series concrete - Google Patents

Additive for saltresistance series concrete Download PDF

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Publication number
CN1328203C
CN1328203C CNB2005100206503A CN200510020650A CN1328203C CN 1328203 C CN1328203 C CN 1328203C CN B2005100206503 A CNB2005100206503 A CN B2005100206503A CN 200510020650 A CN200510020650 A CN 200510020650A CN 1328203 C CN1328203 C CN 1328203C
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sodium
concrete
admixture
salt
sodium sulfate
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CN1693264A (en
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刘连新
黄梓平
王潘劳
张伟勤
戴大虎
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Qinghai University
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Qinghai University
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Abstract

本发明涉及一种添加剂,特别是涉及一种用于配制抗盐渍腐蚀混凝土的外加剂。本发明抗盐渍系列混凝土外加剂由下述重量百分含量原料制成:β基萘磺酸钠甲醛缩聚物75~92%;硫酸钠4~15%;松香热聚物0.5~3.5%;镁粉1~2%;烷基苯磺酸盐0.5~3.5%;氟硅酸钠1~3.5%;三乙醇胺1~2%;硅酮0.5~3.5%;消泡剂0.9~1.1%;氯化钙0.9~1.1%;亚硝酸钠+硫酸钠0.9~1.1%;羟基羧酸类1.5~2.5%。本发明与现有技术相比较有如下有益效果:本产品对提高混凝土的抗冻能力、抗渗能力、抗腐蚀能力、延长工程结构使用寿命均有良好的效果。本发明产品原料充足,配制简便,可广泛应用于盐湖地区和盐渍土地区一切工程结构建设中。The present invention relates to an additive, in particular to an admixture for preparing salt corrosion resistant concrete. The anti-salt stain series concrete admixture of the present invention is made of the following raw materials in percentage by weight: β-naphthalene sulfonate sodium formaldehyde condensation polymer 75-92%; sodium sulfate 4-15%; rosin thermal polymer 0.5-3.5%; Magnesium powder 1-2%; alkylbenzene sulfonate 0.5-3.5%; sodium fluorosilicate 1-3.5%; triethanolamine 1-2%; silicone 0.5-3.5%; defoamer 0.9-1.1%; chlorine Calcium 0.9-1.1%; sodium nitrite + sodium sulfate 0.9-1.1%; hydroxycarboxylic acids 1.5-2.5%. Compared with the prior art, the present invention has the following beneficial effects: the product has good effects on improving the frost resistance, impermeability and corrosion resistance of concrete, and prolonging the service life of engineering structures. The product of the invention has sufficient raw materials and is easy to prepare, and can be widely used in the construction of all engineering structures in salt lake areas and saline soil areas.

Description

抗盐渍系列混凝土外加剂Anti-salt series concrete admixture

技术领域technical field

本发明涉及一种添加剂,特别是涉及一种用于配制抗盐渍腐蚀混凝土的外加剂。The present invention relates to an additive, in particular to an admixture for preparing salt corrosion resistant concrete.

背景技术Background technique

众所周知,盐湖资源的开发与利用是21世纪西部开发的重点之一,混凝土已广泛应用于盐湖地区和盐渍土地区铁路和公路的桥梁、隧洞、生产厂房及办公楼等的工程结构之中。而盐湖地区各种盐类对混凝土的腐蚀之严重,已引起了工程界的极大关注。如何采用抗腐蚀外加剂、矿物掺和料配制具备高抗腐蚀性能的混凝土,对工程结构的高耐久性、安全性和延长使用寿命具有重要意义。目前国内混凝土外加剂的种类和品种很多,但专门针对盐湖地区和盐渍土地区混凝土结构工程的防腐蚀外加剂产品,还未见记载。As we all know, the development and utilization of salt lake resources is one of the key points of western development in the 21st century. Concrete has been widely used in engineering structures such as bridges, tunnels, production plants and office buildings for railways and highways in salt lake areas and saline soil areas. The serious corrosion of concrete by various salts in the salt lake area has aroused great concern in the engineering field. How to use anti-corrosion admixtures and mineral admixtures to prepare concrete with high anti-corrosion performance is of great significance to the high durability, safety and service life of engineering structures. At present, there are many types and varieties of concrete admixtures in China, but there are no records of anti-corrosion admixtures specifically for concrete structure engineering in salt lake areas and saline soil areas.

发明内容Contents of the invention

本发明要解决的问题是针对现有技术中存在的不足,提供一种具有减水、抗冻和抗亍渍腐蚀性能的混凝土外加剂。The problem to be solved by the present invention is to provide a concrete admixture with water-reducing, anti-freeze and anti-spot corrosion properties in view of the deficiencies in the prior art.

本发明的技术方案是:本发明抗盐渍系列混凝土外加剂,其特征在于:所述的外加剂由下述重量百分含量原料制成防冻、抗渗、抗盐渍腐蚀型外加剂:β基萘磺酸钠甲醛缩聚物80~90%;硫酸钠4~7%;松香热聚物0.5~3%;烷基苯磺酸盐0.5~3%;氟硅酸钠0.5~3%;硅酮1.5~2.5%;消泡剂0.9~1.1%;氯化钙0.9~1.1%;亚硝酸钠+硫酸钠0.9~1.1%;所述的外加剂各组分百分数之和应当等于100%。The technical solution of the present invention is: the anti-salt stain series concrete admixture of the present invention is characterized in that: the admixture is made of the following raw materials in percentage by weight to prevent freezing, impermeability, and anti-salt corrosion type admixture: Sodium naphthalene sulfonate formaldehyde condensation polymer 80-90%; sodium sulfate 4-7%; rosin thermal polymer 0.5-3%; alkylbenzene sulfonate 0.5-3%; sodium fluorosilicate 0.5-3%; Ketone 1.5-2.5%; defoamer 0.9-1.1%; calcium chloride 0.9-1.1%; sodium nitrite+sodium sulfate 0.9-1.1%; the sum of the percentages of each component of the admixture should be equal to 100%.

本发明与现有技术相比较有如下有益效果:由于本发明是专门针对盐湖地区和盐渍土地区混凝土而研制的抗腐蚀高性能混凝土所用抗盐渍浸蚀混凝土外加剂,本产品对提高混凝土的抗冻能力、抗腐蚀能力、延长工程结构使用寿命均有良好的效果。本发明抗盐渍系列混凝土外加剂可根据高海拔、高寒盐湖地区不同卤水和土质配制原料,取得减水、收缩小、防止裂纹、抗冻和抗盐渍腐蚀能力的混凝土外加剂。本发明产品原料充足,配制简便,可广泛应用于盐湖地区和盐渍土地区一切工程结构建设中。Compared with the prior art, the present invention has the following beneficial effects: since the present invention is a corrosion-resistant high-performance concrete admixture specially developed for concrete in salt lake areas and saline soil areas, the product has a great effect on improving concrete Excellent frost resistance, corrosion resistance, and prolonging the service life of engineering structures have good effects. The salt-resistance series concrete admixture of the present invention can prepare raw materials according to different brines and soil properties in high-altitude and alpine salt lake areas, and obtain concrete admixtures with water reduction, small shrinkage, crack prevention, frost resistance and salt corrosion resistance. The product of the invention has sufficient raw materials and is easy to prepare, and can be widely used in the construction of all engineering structures in salt lake areas and saline soil areas.

具体实施方式Detailed ways

下面结合实施例对本发明作进一步描述。本发明抗盐渍系列混凝土外加剂由下述重量百分含量原料制成:β基萘磺酸钠甲醛缩聚物75~92%;硫酸钠4~15%;松香热聚物0.5~3.5%;镁粉1~2%;烷基苯磺酸盐0.5~3.5%;氟硅酸钠1~3.5%;三乙醇胺1~2%;硅酮0.5~3.5%;消泡剂0.9~1.1%;氯化钙0.9~1.1%;亚硝酸钠+硫酸钠0.9~1.1%;羟基羧酸类1.5~2.5%。The present invention will be further described below in conjunction with embodiment. The anti-salt stain series concrete admixture of the present invention is made of the following raw materials in percentage by weight: β-naphthalene sulfonate sodium formaldehyde condensation polymer 75-92%; sodium sulfate 4-15%; rosin thermal polymer 0.5-3.5%; Magnesium powder 1-2%; alkylbenzene sulfonate 0.5-3.5%; sodium fluorosilicate 1-3.5%; triethanolamine 1-2%; silicone 0.5-3.5%; defoamer 0.9-1.1%; chlorine Calcium 0.9-1.1%; sodium nitrite + sodium sulfate 0.9-1.1%; hydroxycarboxylic acids 1.5-2.5%.

所述的外加剂由下述重量百分含量原料制成抗盐渍、早强的防腐减水型外加剂:β基萘磺酸钠甲醛缩聚物75~85%;硫酸钠11.5~14%;松香热聚物0.5~3.5%;氟硅酸钠1~2%;硅酮1.5~2.5%;消泡剂0.9~1.1%;亚硝酸钠+硫酸钠0.9~1.1%。The admixture is made of the following raw materials in percentage by weight, anti-salt stain, early-strength anti-corrosion and water-reducing admixture: 75-85% of β-naphthalenesulfonate sodium formaldehyde condensation polymer; 11.5-14% of sodium sulfate; Rosin thermal polymer 0.5-3.5%; sodium fluorosilicate 1-2%; silicone 1.5-2.5%; defoamer 0.9-1.1%; sodium nitrite + sodium sulfate 0.9-1.1%.

所述的外加剂由下述重量百分含量原料制成防冻、抗渗、抗盐渍腐蚀型外加剂:β基萘磺酸钠甲醛缩聚物80~90%;硫酸钠4~7%;松香热聚物0.5~3%;烷基苯磺酸盐0.5~3%;氟硅酸钠0.5~3%;硅酮1.5~2.5%;消泡剂0.9~1.1%;氯化钙0.9~1.1%;亚硝酸钠+硫酸钠0.9~1.1%。The admixture is made of the following raw materials in percentage by weight: antifreeze, impermeability, and anti-salt corrosion type admixture: 80-90% of β-naphthalenesulfonate sodium formaldehyde condensation polymer; 4-7% of sodium sulfate; rosin Thermal polymer 0.5-3%; Alkylbenzene sulfonate 0.5-3%; Sodium fluorosilicate 0.5-3%; Silicone 1.5-2.5%; Defoamer 0.9-1.1%; Calcium chloride 0.9-1.1% ; Sodium nitrite + sodium sulfate 0.9 ~ 1.1%.

实施例1。Example 1.

由下述重量百分含量原料制成抗盐渍、防止混凝土裂纹早强的防腐减水I型抗盐渍混凝土外加剂:β基萘磺酸钠甲醛缩聚物80%;硫酸钠12.5%;松香热聚物2.0%;氟硅酸钠1.5%;硅酮2.0%;消泡剂1.0%;亚硝酸钠+硫酸钠1.0%。Anti-corrosion and water-reducing type I anti-salinization concrete admixture made of the following raw materials in percentage by weight: 80% β-naphthalene sulfonate sodium formaldehyde condensation polymer; 12.5% sodium sulfate; rosin Thermopolymer 2.0%; Sodium Fluorosilicate 1.5%; Silicone 2.0%; Defoamer 1.0%; Sodium Nitrite + Sodium Sulfate 1.0%.

实施例2。Example 2.

由下述重量百分含量原料制成缓凝、防腐减水II型抗盐渍混凝土外加剂:β基萘磺酸钠甲醛缩聚物87.5%;镁粉1.5%;烷基苯磺酸盐2.0%;氟硅酸钠2.5%;三乙醇胺1.5%;硅酮1.0%;消泡剂1.0%;亚硝酸钠+硫酸钠1.0%;羟基羧酸类2.0%。The slow-setting, anti-corrosion and water-reducing type II salt-resistant concrete admixture is made from the following raw materials in percentage by weight: 87.5% of sodium formaldehyde condensation polymer of beta-naphthalene sulfonate; 1.5% of magnesium powder; 2.0% of alkylbenzene sulfonate Sodium Fluosilicate 2.5%; Triethanolamine 1.5%; Silicone 1.0%; Defoamer 1.0%; Sodium Nitrite + Sodium Sulfate 1.0%;

实施例3。Example 3.

由下述重量百分含量原料制成防冻、抗渗、抗盐渍腐蚀III型抗盐渍混凝土外加剂:β基萘磺酸钠甲醛缩聚物85%;硫酸钠5.5%;松香热聚物1.5%;烷基苯磺酸盐1.5%;氟硅酸钠1.5%;硅酮2.0%;消泡剂1.0%;氯化钙1.0%;亚硝酸钠+硫酸钠1.0%。Antifreeze, anti-seepage, anti-salt corrosion type III anti-salt concrete admixture is made of the following raw materials in percentage by weight: 85% of β-naphthalene sulfonate sodium formaldehyde condensation polymer; 5.5% of sodium sulfate; 1.5% of rosin thermal polymer %; alkylbenzene sulfonate 1.5%; sodium fluorosilicate 1.5%; silicone 2.0%; defoamer 1.0%; calcium chloride 1.0%; sodium nitrite + sodium sulfate 1.0%.

Claims (1)

1, a kind of additive for saltresistance series concrete is characterized in that: described admixture is made antifreeze, impervious, anti-salt marsh corrosion type admixture: β base sodium naphthalene sulfonate formaldehyde condensation products 80~90% by the following weight percent raw material; Sodium sulfate 4~7%; Colophonium pyrolytic polymer 0.5~3%; Alkylbenzene sulfonate 0.5~3%; Sodium Silicofluoride 0.5~3%; Silicone 1.5~2.5%; Defoamer 0.9~1.1%; Calcium chloride 0.9~1.1%; Sodium Nitrite+sodium sulfate 0.9~1.1%; Each component percentage ratio sum of described admixture should equal 100%.
CNB2005100206503A 2005-03-30 2005-03-30 Additive for saltresistance series concrete Expired - Fee Related CN1328203C (en)

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102320775B (en) * 2010-09-07 2013-02-13 深圳市陆基建材技术有限公司 Seawater corrosion resisting mineral additive for concrete, and preparation method thereof
CN104628298B (en) * 2013-11-06 2016-08-10 郭太宗 Cement presses down alkali additive
CN103641355B (en) * 2013-12-10 2015-06-10 江苏苏博特新材料股份有限公司 Concrete sulfate corrosion-resistant selective crystallization inhibitor and preparation method thereof
CN105236799A (en) * 2015-09-01 2016-01-13 江苏百瑞吉新材料有限公司 General concrete composite additive agent
CN105837079B (en) * 2016-03-24 2017-04-26 广州市水电建设工程有限公司 Additive for sea sand concrete
CN111333366B (en) * 2020-03-31 2020-12-18 深圳市中兆荣新材料有限公司 Seawater-resistant reinforced concrete admixture and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107817A (en) * 1994-12-14 1995-09-06 华南理工大学 Method for preparing high impervious and anticorrosive concrete with ternary agent
CN1270150A (en) * 1999-04-14 2000-10-18 济南华迪有限责任公司 Composite additive for concrete
CN1406902A (en) * 2001-08-24 2003-04-02 沈阳运龙防水材料厂 High Performance organo-silicon waterproofing agent for mortar and concrete

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107817A (en) * 1994-12-14 1995-09-06 华南理工大学 Method for preparing high impervious and anticorrosive concrete with ternary agent
CN1270150A (en) * 1999-04-14 2000-10-18 济南华迪有限责任公司 Composite additive for concrete
CN1406902A (en) * 2001-08-24 2003-04-02 沈阳运龙防水材料厂 High Performance organo-silicon waterproofing agent for mortar and concrete

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