CN1327078A - Austenitic stainless steel excellent in precision blanking property - Google Patents

Abstract

A novel austenitic stainless steel comprising (C +1/2N) at most 0.060 mass%, Si at most 1.0 mass%, Mn at most 5 mass%, S at most 0.006 mass%, Cr in the range of 15 to 20 mass%, Ni in the range of 5 to 12 mass%, Cu at most 5 mass%, Mo in the range of 0 to 3.0 mass%, and Fe and impurities, provided that Md is defined by the following formula₃₀The value is controlled within-60 to-10. The hardness increase of the steel sheet after cold rolling is preferably 20% or more in vickers hardness. The metallographic structure of the steel sheet is preferably adjusted to a grain size of #8 to #11 in the final annealed state. Md₃₀=551－462(C+N)－9.2Si－29(Ni+Cu)－8.1Mn－13.7Cr－18.5Mo。

Description

The austenitic stainless steel of good accurate punching property

The present invention relates to the austenitic stainless steel of die-cut property (blankability), particularly good accurate punching property.

To various metal sheets, impose shearing as general steel plate, stainless steel plate and non-ferrous metal board with pressing machine, particularly die-cut, after this metal sheet can be made target shape by size effectively.But, the face poor dimensional precision of die-cut formation.Metal sheet may tilt on wide surface, and reduces at the plate thickness near die-cut face portion.

When manufacturing needs the high dimensional accuracy product and adopts clicking technique, be by aftertreatment, for example barreling is ground die-cut.This aftertreatment is additional process basically, reduces productivity.Therefore, adopted the accurate punching method for the product of making high dimensional accuracy.In this accurate punching method, with very little value specified gap, suppress forming ruptured surface, and suppress metal and flow into, produce when die-cut to reduce.

On the other hand, so far stainless steel be exposed to the corrosion or hot environment under use.Particularly the stainless steel of SUS304 representative is fit to this purposes.

The SUS304 austenitic stainless steel is a mechanically resistant material, so that the lost of life of accurate punching mould.The hard end of SUS304 austenitic stainless steel, also increase the ratio of the ruptured surface that reduces die-cut quality, also increases and.Even by the die-cut shear surface that forms high dimensional accuracy, tooling cost is also than the cost height of die-cut ordinary steel.Solve these shortcomings, the die-cut SUS304 austenitic stainless steel of available usual way grinds then and makes the product with die-cut of high dimensional accuracy.

The object of the invention is to provide the may command austenite to soften mutually and the austenitic stainless steel of stability, to improve the ratio of shearing, particularly suitable accurate punching.

The present invention proposes a kind of new austenitic stainless steel, its composition comprises: (C+1/2N)≤0.060 quality %, Si≤1.0 quality %, Mn≤5 quality %, S≤0.006 quality %, Cr are 15～20 quality %, and Ni is 5～12 quality %, Cu≤5 quality %, Mo are that 0～3.0 quality % and surplus are essentially Fe.The Md of the ratio of expression deformation induced martensite phase ₃₀Value is adjusted in-60～-10 scopes.This value is determined by following formula:

Md ₃₀＝551－462(C＋N)－9.2Si－29(Ni＋Cu)－8.1Mn－13.7Cr－18.5Mo

Making this austenitic stainless steel can be with comprising hot rolling, annealing, pickling, cold rolling and whole annealed ordinary process.The ratio that increases in Cold Rolled Strip hardness preferably is controlled at Vickers' hardness 20% or bigger value.Preferably control to the metallographic structure of grain fineness number (adjusting) in 8～11 scopes at whole as-annealed condition stainless steel with JIS G0551.

Fig. 1 is the synoptic diagram that the die-cut sample of explanation produced and checked the sloping portion position;

Fig. 2 is the formation of explanation shear surface on die-cut of product and the synoptic diagram of measuring the shear surface position;

Fig. 3 shows Md ₃₀The figure of value and shear surface proportionlity;

Fig. 4 is the figure that shows (C+1/2N) and shear surface proportionlity;

Fig. 5 is the figure of S content and shear surface proportionlity when being presented at gap ratio 2%;

Fig. 6 is the figure of S content and shear surface proportionlity when being presented at gap ratio 5%;

Fig. 7 is the figure that shows Vickers' hardness and shear surface proportionlity;

Fig. 8 is hardness ratio that increases and the figure that shears the inclination proportionlity that shows cold rolling generation;

Fig. 9 is the figure that shows grain fineness number and shear surface proportionlity;

Figure 10 shows grain fineness number and the figure that shears the inclination proportionlity.

The contriver discovers from the each side of the die-cut surface state relation that the material property of austenitic stainless steel and accurate punching form, and the ratio of deformation induced martensite (α ' phase) has remarkably influenced to shear surface and die-cut 's ratio.

Deformation induced martensite (α ' phase) compare harder with austenite (γ mutually) matrix and plasticity poor.Excessive generation deformation induced martensite (α ' phase) mean that plasticity reduces, and occurs breaking and reducing the shear surface ratio at die-cut too early.On the contrary, very little, die-cut austenitic stainless steel under γ phase plasticity difference causes occurring too early breaking and reducing the shear surface ratio at die-cut like this if produce deformation induced martensite (α ' phase).

The softening degree of austenitic stainless steel and strain-induced martensite (α ' mutually) are to ruptured surface Effect on Performance balance well, so that suppress to tilt to take place.Like this, die-cut dimensional precision improved, and the mould life-span prolongs.

It is as follows that the predetermined proportion amount of the austenitic stainless steel that provides contains various alloy ingredients:

(C+1/2N)≤0.060 quality %

C and N are the effective ingredients of adjusting the austenite phase stability.But excessive interpolation C makes austenite mutually owing to solution strengthening is hardened with N, and deformation induced martensite is hardened mutually.This sclerosis increases die-cut load and shortens the mould life-span.So the ratio of control (C+1/2N) is≤0.060 quality %.

Si≤1.0 quality %

Si is the alloying element that adds as reductor in the steel refining stage.Because solution strengthening, excessive interpolation Si hardens austenite mutually, and reduces stainless die-cut property.Therefore, the upper limit of silicone content is determined at 1.0 quality %.

Mn≤5 quality %

Mn is stable austenite phase and the effective alloying element that improves stainless die-cut property.This effect is along with the increase of Mn content is tangible.But, increase the nonmetallic impurity that solidity to corrosion and processibility is had harmful effect greater than the excessive interpolation Mn of 5 quality %.

S≤0.006 quality %

Along with the increase of S content, shear surface reduces with die-cut ratio.Element S is also to having harmful effect for the solidity to corrosion of the most important character of stainless steel.Therefore, the upper limit of S content is determined at 0.006 quality %.Particularly for the product that requires to have die-cut of high dimensional accuracy, S content preferably controls to 0.003 quality % or littler, to improve the ratio of shear surface.

Cr is 15～20 quality %

Cr content is necessary for 15 quality % or bigger, to guarantee stainless solidity to corrosion.But, make the stainless steel sclerosis greater than the excessive interpolation Cr of 20 quality %, and there is harmful effect in the mould life-span.

Ni is 5～12 quality %

Ni is the alloying element of stable austenite phase.Add 5 quality % or more the Ni of vast scale can obtain this effect.Along with the increase of Ni content also improves stainless die-cut property.But Ni is a noble element, increase the cost of steel, so the upper limit of Ni content is defined as 12 quality %.

Cu≤5 quality %

Cu improves die-cut property and the effective mutually alloying element of stable austenite.But, hot workability is had injurious effects greater than the excessive interpolation Cu of 5 quality %.

Mo is 0～3.0 weight %

Mo improves the effectively optional alloying element of solidity to corrosion.But, make stainless steel too hard greater than the excessive interpolation Mo of 3.0 quality %, the result reduces accurate punching property.

Md ₃₀Value (expression deformation induced martensite ratio) :-60～-10

The contriver finds the effect of deformation induced martensite (α ' phase) to shear surface and die-cut ratio by various test-results.Composition by austenitic stainless steel and content can calculate the ratio of deformation induced martensite (α ' mutually).Has the Md that is controlled in-60～-10 scopes at design austenite stainless steel constitution ₃₀Under the situation of value, described in following embodiment, the ratio of shear surface is higher, and forms die-cut of high dimensional accuracy.

The ratio that the hardness of austenitic stainless steel increases: Vickers' hardness 20% or bigger.

Compare with comprising the annealed sheet that seldom is shifted, owing to bring many displacements into during cold rolling, cold rolled stainless steel sheet is harder.When the hardenability of cold rolling generation during in Vickers' hardness ratio 20% or bigger adjustment, can suppress metal flow and flow to lower die-cut part, the result has reduced inclination.

Through type in the present invention: [(Vickers' hardness of cold-rolled steel sheet)-(Vickers' hardness of annealed sheet steel)]/(Vickers' hardness of annealed sheet steel) x100 (%) can determine the ratio that hardness increases.The ratio that hardness increases is necessary for 20% or bigger, with the inclination that suppresses to produce by the die-cut annealed sheet steel of tilting to of die-cut generation half or littler.But stone steel plate produces shear resistant when die-cut increases, and quickens the wearing and tearing of mould.Therefore, the upper limit of the ratio that hardness increases is preferably determined 150%, solves the effect that reduces the angular balance mould life-span.

Grain fineness number: #8～#11

Along with grain coarsening, stainless steel is softer, and shear surface and die-cut 's ratio is higher, but that die-cut steel plate tilts is serious.Therefore, coarse grain is unsuitable for and makes the product that requires die-cut dimensional precision and slickness.The condition of the austenitic stainless steel that provides on the other hand, is to be made of the minimum crystal grain of grain fineness number in #8～#11 scope in whole as-annealed condition metallographic structure.Compare with the common grain fineness number of #6～#8, this grain fineness number is bigger.By reducing interior energy, promptly under low relatively temperature or in the short relatively time, stainless steel annealing is obtained minimum crystal grain.Because such grain fineness number condition suppresses the existence of inclination, keeps the shear surface ratio in same level simultaneously.

Embodiment 1

To have each stainless steel melting, casting of composition shown in the table 1,1230 ℃ of soaking and be rolled into thickness 10mm.After this, at 1150 ℃ hot-rolled steel sheet was annealed 1 minute, pickling is cold rolled to thickness 5mm, in 1050 ℃ of annealing 1 minute and pickling again.

The austenitic stainless steel that uses among table 1 embodiment 1

Sample	Alloy ingredient (quality %)									Md 30	Remarks
												?????C	????Si	????Mn	???Ni	???Cr	???S	??Cu	??Mo	??N
	????1 ????2 ????3	????0.01 ????0.02 ????0.03	????0.5 ????0.6 ????0.5	????1.0 ????1.2 ????1.0	?10.75 ?8.21 ?8.32	?18.25 ?18.70 ?18.10	?0.001 ?0.003 ?0.002	?0.10 ?2.10 ?1.92	?0.08 ?0.07 ?0.07												?0.01 ?0.03 ?0.03	-37.1 -43.8 -35.6	The embodiment of the invention
????4										????0.04	????0.4	????1.0	?10.23	?17.16	?0.001	?0.10	?0.06	?0.05	-38.1	Comparative example
	????5 ????6 ????7	????0.02 ????0.01 ????0.02	????0.3 ????0.4 ????0.5	????1.7 ????1.0 ????0.8	?8.01 ?10.01 ?11.15	?17.10 ?18.26 ?18.42	?0.001 ?0.002 ?0.002	?3.21 ?0.08 ?0.08	?0.07 ?0.08 ?0.05												?0.01 ?0.01 ?0.02	-40.3 -14.3 -57.5	The embodiment of the invention
????8 ????9 ????10 ????11										????0.01 ????0.02 ????0.01 ????0.03	????0.4 ????0.6 ????0.5 ????0.6	????1.2 ????0.5 ????0.7 ????0.7	?11.20 ?11.82 ?9.83 ?8.21	?19.10 ?18.33 ?18.25 ?18.25	?0.001 ?0.001 ?0.001 ?0.001	?0.10 ?0.10 ?0.10 ?0.10	?0.08 ?0.08 ?0.08 ?0.08	?0.01 ?0.02 ?0.01 ?0.04	-62.5 -75.3 -8.0 15.0	Comparative example
	????12 ????13 ????14	????0.05 ????0.03 ????0.02	????0.5 ????0.6 ????0.6	????0.8 ????1.0 ????1.0	?8.81 ?10.27 ?9.89	?18.25 ?18.91 ?19.10	?0.001 ?0.004 ?0.006	?0.81 ?0.10 ?0.10	?0.08 ?0.09 ?0.07												?0.02 ?0.02 ?0.02	-22.9 -47.2 -33.8	The embodiment of the invention
????15 ????16										????0.01 ????0.03	????0.4 ????0.6	????0.8 ????0.6	?10.27 ?9.21	?18.91 ?19.10	?0.007 ?0.009	?0.08 ?0.08	?0.09 ?0.09	?0.02 ?0.02	-33.9 -15.2	Comparative example

Study the ratio of shear resistant, shear surface and die-cut ratio and gradient and thickness by following each annealed sheet steel of die-cut experimental examination, and the Rockwell hardness B that adjusts by JIS Z2240 measures Vickers' hardness like that.

Use the drift of external diameter 50mm and the mould of internal diameter 50.2mm or 50.5mm, the sample that will be cut out by each annealed sheet steel with 600mm/ minute die-cut speed is die-cut into disc with gap 0.1mm or 0.25mm (the gap ratio in the gap/THICKNESS CALCULATION of sample is respectively 2% or 5%).

With the contactless positioned sensor of laser type on 8 points, promptly as shown in Figure 1 along rolling direction, transverse direction with become each 2 each disk of point measurement (die-cut sample) of directions of 45 degree with rolling direction, to measure the gradient Z of each point.Obtain the mean value of observed value, and calculate the ratio of gradient and thickness by this mean value and the ratio of the thickness of sample.

At 8 points, promptly as shown in Figure 2 along rolling direction, transverse direction with become each 2 point of directions of 45 degree also to measure the thickness of the shear surface S of each disk (die-cut sample) with rolling direction.Ask the mean value of observed value, and calculate the ratio of shear surface by this mean value and the ratio of sample thickness.

Ratio and each sample Md of the shear surface that research forms than 2% die-cut each sample with the gap ₃₀The relation of value.The results are shown in Fig. 3.It should be noted that, at Md ₃₀Value can obtain the shear surface ratio in-60～-10 scope be 100% die-cut.But sample 4,15 and 16 Md ₃₀Value in-60～-10 scope, its die-cut exception poor, the ratio of shear surface is respectively 85%, 95%, 71%.

Just respectively has the Md in-60～-10 scopes ₃₀The relation of the sample 1～4 of value and 12 researchs (C+1/2N) and shear surface ratio.The results are shown in Fig. 4.It should be noted that it is die-cut less than the sample 1～3 and 12 of 0.06 quality % respectively to contain (C+1/2N), the ratio of shear surface is 100%.On the other hand, it is die-cut greater than the sample 4 of 0.06 quality % to contain (C+1/2N), and the ratio of shear surface is 85%.

With Md ₃₀Value is in-60～-10 scopes and to contain (C+1/2N) die-cut less than the sample 1～3 and 13～16 of 0.06 quality %, and the gap ratio is 2%.Study the ratio of shear surface of die-cut formation and the relation of each sample S content. the results are shown in Fig. 5.It should be noted that will to contain S die-cut less than the sample 1～3,13 and 14 of 0.006 quality %, the ratio of shear surface is 100%, and it is die-cut greater than the sample 15 and 16 of 0.006 quality % to contain S, and the ratio of shear surface is respectively 95% and 71%.

Even under the situation of die-cut same steel plate, the relation of S content and shear surface ratio also changes with the gap ratio.That is, when with gap ratio 2% die-cut sample 13 and 14, it is 100% that the die-cut mask of formation has the shear surface ratio.When with gap ratio 5% die-cut sample 13 and 14, as shown in Figure 6, the ratio of shear surface is reduced to 92% and 88% respectively.The result proves, die-cut have a big gap ratio steel plate that reduces the shear surface ratio, and control S content is effective less than 0.003 quality %.

Embodiment 2

The stainless steel melting that will have composition shown in the table 2, casting is arrived thickness 10mm in 1230 ℃ of hot rollings of initial temperature.After this, every hot-rolled steel sheet 1150 ℃ of annealing 1 minute, pickling, is cold rolled to interior thickness 5～8mm, in 1050 ℃ of annealing pickling again in 1 minute.Annealed sheet steel (A1, B1) with thickness 5mm provides some steel plates.Other interior thickness annealed sheet steels are further cold rolled to thickness 5mm, and provide with skin-pass rolling steel plate (A2-A6, B2, B3).

The austenitic stainless steel that uses among table 2 embodiment 2

The kind of steel	Alloy ingredient (quality %)									Md 30	Remarks
												???C	????Si	????Mn	???Ni	???Cr	???S	??Cu	??Mo	???N
	??A	?0.01	????0.5	????0.8	?10.43	?18.40	?0.001	?0.09	?0.07												??0.01	-27.8	The embodiment of the invention
??B										?0.06	????0.6	????0.6	?8.02	?18.21	?0.003	?0.08	?0.08	??0.04	8.6	Comparative example

Cut out sample by each annealing and smooth cold-rolled steel sheet, and sample is die-cut with gap ratio 2% under the condition identical with embodiment 1.Fig. 7 shows the Vickers' hardness of various samples and the relation of shear surface ratio.It should be noted that annealing or any of skin-pass rolling Sample A 1～A6 is die-cut, and the ratio of shear surface is 100%.On the other hand, the die-cut and corresponding sample B 1～B3 of SUS304, the ratio of shear surface is low, near 45%.

Calculate the gradient ratio of shearing according to (ratio of skin-pass rolling steel plate gradient and thickness)/(ratio of annealed sheet steel gradient and thickness), research skin-pass rolling hardness increases producing the influence of inclination.The results are shown in Fig. 8.It should be noted that, in the shearing inclination ratio of Vickers' hardness 20% or the arbitrary skin-pass rolling steel plate of bigger hardened A3-A6 less than 50%, i.e. half of the gradient that produces less than annealed sheet steel A1.On the other hand, the ratio that increases with hardness is in a ratio of about 70% less than shearing inclination ratio and the annealed sheet steel A1 of 20% hardened skin-pass rolling steel plate A2.This result prove 20% or bigger hardness to increase abundant reduction gradient be effective.

Each sample continuous cutting up to die change more, is studied the influence of steel plate materials performance to the mould life-span.Estimate the mould life-span up to die change more as the die-cut cycle.The results are shown in table 3.It should be noted that, with the category-B steel plate relatively, die-cut arbitrary category-A steel plate is longer up to the cycle of die change more.That is, the category-A steel plate is effective to prolonging the mould life-span.Should also be noted that the category-A steel plate compares mutually, the excessive increase of hardness is unfavorable for reducing the die-cut cycle.For example, steel plate A6 hardens greater than 150%, up to more some reduction of die-cut cycle of die change.

Table 3 steel plate materials performance is to the influence in mould life-span

Number	Up to die-cut cycle of die change more	Estimate	Remarks
				????A1	????302969	????◎	The embodiment of the invention
????A2	????323341	????◎
			????A3	????309629	????◎
????A4	????314211	????◎
			????A5	????354824	????◎
????A6	????248142	????○
			????B1	????103288	????×	Comparative example
????B2	????52783	????×
			????B3	????9879	????×

◎: A1 compares with steel plate, the identical or longer mould life-span

Zero: the mould life-span is lower than steel plate A1, but is better than steel plate B1

*: the mould noticeable wear

Embodiment 3

Thickness 10mm is cast and is rolled in stainless steel C, the D melting that will have composition shown in the table 4 under an initial temperature.After this, each hot-rolled steel sheet was annealed 1 minute at 1150 ℃, pickling, cold rolling one-tenth thickness 5mm annealed 1 minute down at 800～1100 ℃, and then pickling.

The austenitic stainless steel that uses among table 4 embodiment 3

Sample	Alloy ingredient (quality %)									Md 30	Remarks
												???C	??Si	?Mn	??Ni	??Cr	???S	??Cu	??Mo	??N
	?C	?0.02	?0.6	?0.7	?10.21	?18.71	?0.002	?0.08	?0.05												?0.02	-34.3	The embodiment of the invention
?D										?0.06	?0.6	?0.6	?8.02	?18.21	?0.003	?0.08	?0.08	?0.04	8.6	Comparative example

Each steel plate by the pickling of annealing back cuts out sample, and sample is die-cut with gap ratio 2% under the condition identical with embodiment 1.Calculate the ratio of the shear surface of die-cut sample, to study the relation of it and steel plate grain fineness number.The results are shown in Fig. 9.It should be noted that arbitrary C class steel plate of the present invention is die-cut, and the ratio of shear surface is 100%, no matter its grain fineness number.On the other hand, the D class steel plate of arbitrary corresponding SUS304 is die-cut, and the ratio of shear surface is low, near 45%.

Figure 10 illustrates the relation of shearing inclination ratio and grain fineness number.This concerns proof, shears the inclination ratio with the increase (being minimum metallographic structure) of grain fineness number and improves, no matter the kind of steel plate.About C class steel plate of the present invention, will respectively have the shearing inclination ratio of grain fineness number greater than the arbitrary steel plate of C3～C6 of #8, with grain fineness number less than steel plate C1, the C2 of #8 compare be reduced to half or littler.

Each sample continuous cutting up to die change more, is estimated according to the die-cut modulus of periodicity life-span.The results are shown in table 5.It should be noted that, compare arbitrary C class steel plate die-cutly with D class steel plate, can increase the cycle, promptly be applicable to prolong the mould life-span up to die change more.But, as pointed among the steel plate C6, increasing greater than #11 with grain fineness number, the die-cut cycle reduces slightly.This result proves that metallographic structure is too small and is unfavorable for the mould life-span.

The relation of table 5 mould life-span and steel plate materials performance

Number	Up to die-cut cycle of die change more	Estimate	Remarks
				????C1	????321962	????◎	The embodiment of the invention
????C2	????339672	????◎
			????C3	????321111	????◎
????C4	????342632	????◎
			????C5	????315522	????◎
????C6	????236981	????○
			????D1	????112011	????×	Comparative example
????D2	????49876	????×
			????D3	????5621	????×

◎: A1 compares with steel plate, the identical or longer mould life-span

Zero: the mould life-span is lower than steel plate A1, but is better than steel plate B1

*: the mould noticeable wear

Austenitic stainless steel provided by the invention can be die-cut into the product of high dimensional accuracy, because fabulous die-cut property, particularly accurate punching property.Even when with the die-cut steel plate of little gap ratio, shear surface and die-cut 's ratio can remain on high level, and does not have the inclination of essence to exist.With common austenitic stainless steel, as SUS304 relatively, this stainless steel plate also helps and prolongs the mould life-span.Therefore, can obtain the die-cut product of high dimensional accuracy by this austenite stainless steel plate that provides, and not increase manufacturing cost.

Claims (3)

1. new austenitic stainless steel, it has good accurate punching performance, comprises (C+1/2N)≤0.060 quality %, Si≤1.0 quality %, Mn≤5 quality %, S≤0.006 quality %, Cr are 15～20 weight %, and Ni is 5～12 quality %, Cu≤5 weight %, selectable Mo is that 0～3.0 quality % and surplus are Fe and unavoidable impurities, and condition is determined by following formula, represents the Md of the ratio of deformation induced martensite phase ₃₀Value is in-60～-10 scopes.

Md ₃₀＝551－462(C＋N)－9.2Si－29(Ni＋Cu)－8.1Mn－13.7Cr－18.5Mo

2. according to the austenitic stainless steel of claim 1,, harden 20% or bigger by Vickers' hardness by cold rolling after annealing and the pickling.

3. according to the austenitic stainless steel of claim 1, it has the minimum metallographic structure to #8～#10 of grain fineness number.

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