CN1315132A - Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide - Google Patents
Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide Download PDFInfo
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- CN1315132A CN1315132A CN 00112179 CN00112179A CN1315132A CN 1315132 A CN1315132 A CN 1315132A CN 00112179 CN00112179 CN 00112179 CN 00112179 A CN00112179 A CN 00112179A CN 1315132 A CN1315132 A CN 1315132A
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- agent
- acetamiprid
- microemulsion
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- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000002917 insecticide Substances 0.000 title claims abstract description 9
- 230000003115 biocidal effect Effects 0.000 title 1
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 25
- 239000005875 Acetamiprid Substances 0.000 claims description 25
- 239000004530 micro-emulsion Substances 0.000 claims description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 230000003750 conditioning effect Effects 0.000 claims description 7
- 239000003120 macrolide antibiotic agent Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 150000003222 pyridines Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 230000000740 bleeding effect Effects 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 229920006184 cellulose methylcellulose Polymers 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- 229940068968 polysorbate 80 Drugs 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 239000005660 Abamectin Substances 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 239000000575 pesticide Substances 0.000 abstract description 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract 1
- 229950008167 abamectin Drugs 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 6
- 230000001988 toxicity Effects 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 241000500437 Plutella xylostella Species 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940041033 macrolides Drugs 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- -1 with homogeneous Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A composition of hexadecamacrolide antibiotic-type miticiding insecticides and pyridine-type pesticides is disclosed, and features that it contains abamectin (0.05-2.5%) and acetamipid (0.05-10%). Its advantages include broad spectrum, low dosage and cost, solving the problem of pest's resistance to drug, and high synergistic action to lepidopterous pests.
Description
The present invention relates to the composition of a kind of ten former powder of hexa-atomic macrolides agricultural chemicals (cream) and the former powder of pyridine farm chemical.It has obvious synergistic effect.Add pesticides new formulation---the microemulsion that becomes ultra-fine grain diameter, stable storage with emulsifier, dispersant, proportion conditioning agent, thickener, bleeding agent, antifreezing agent and water through the homogeneous dispersible formulation.
Now have missible oil, microemulsion and the wetting powder of the single agent of acetamiprid (Avermectin); Wetting powder, microemulsion and the missible oil of the agent of Acetamiprid list.Its shortcoming is: the agent of acetamiprid list is the biological species insecticidal/acaricidal agent, and Insecticiding-miticiding quick-acting is poor, and is poor slightly to Semiptera insect preventive effect in addition; The agent of Acetamiprid list is to Semiptera insect special efficacy, doublely controls Lepidoptera, wing order insect slightly.
The objective of the invention is to avoid above-mentioned weak point of the prior art and a kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides are provided, insecticidal spectrum is enlarged; And in the content range that the present invention comprises, Lepidoptera insects such as (diamond-back moth, cotton bollworms) there is the notable synergistic effect; Thoroughly solved the resistance problem of single agent to some insect; Reduce the independent usage amount of two single agent, reduced the mu cost.
Purpose of the present invention can reach by following measure:
A kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides is characterized in that said composition contains 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid.
Purpose of the present invention can also reach by following measure:
A kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides, it is characterized in that the microemulsion that said composition is made contains: 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid, 12-20% (m/m) emulsifier is OX901, OX902, OX903, DNP-18,500
#, 1600
#, 2000
#In three kinds of compositions, 2-5% (m/m) dispersant is a kind of in NNO, OX2000, sodium lignin sulfonate, calcium lignosulfonate, the penetrant t, 1-5% (m/m) bleeding agent is two kinds in azone, polysorbate 80, the penetrant t, 2-6% (m/m) proportion conditioning agent, 1-5% (m/m) thickener, the water of 1-5% (m/m) antifreezing agent and equivalent;
Emulsifier adopts OX903,500
#, 2000
#Three kinds of compositions are best;
It is best that dispersant adopts OX2000;
The used proportion conditioning agent of microemulsion is one of following kind: isopropyl alcohol, propane diols, urea, cyclohexanone, ethylenediamine, ethylene glycol;
The used thickener of microemulsion is two kinds of following kind: polyvinyl alcohol, CMC, xanthans, bentonite, white carbon;
The used antifreezing agent of microemulsion is one of following kind: ethylene glycol, polyethylene glycol, glycerine;
Microemulsion is to adopt homogeneous blender high degree of dispersion production technology and make;
Said composition also can be made into emulsifiable concentrate, missible oil, wetting powder.
The present invention has following advantage compared to existing technology:
The present invention has adopted microemulsion, emulsifiable concentrate thoroughly to solve problem of environmental pollution.By Toxicity Determination, determined the rational proportion of two effective ingredients, carried out the industrialness production test, product toxicity is measured, and has finished the present invention.It is the good agent for killing mite and pest of various crop such as control vegetables, fruit, melon beans, fruit tree, flowers, cotton, tobacco leaf, tea tree, accomplishes the end in view.
Microemulsion technical target of the product of the present invention is:
Project indicator acetamiprid content, % (m/m) 0.05-2.5 Acetamiprid content, the cold storage qualified stability in % (m/m) 0.05-10PH value 5-9 heat storage stability (54 ± 2 ℃, 14 days) %＜5
The microemulsion outward appearance is blueing optical transparency or outer transparency liquid, through 54 ± 2 ℃ of heat storages in 14 days, effective ingredient resolution ratio＜5%.
Toxicity Determination result:
After measured, two kinds of effective ingredients are in content range of the present invention, and composition has obvious synergistic function than two kinds of single agent.Subjects is lepidopterous diamond-back moth and cotton bollworm.
The measurement result of toxicity test and best proportioning sees Table 1, as can be seen from Table 1, acetamiprid and Acetamiprid by different proportionings composite after, diamond-back moth all there are to a certain degree addition or synergistic effect, wherein acetamiprid and Acetamiprid in proportion 0.2: 1.3 composite after, co-toxicity coefficient reaches 190.4, has significant synergies.
Acetamiprid is the GABA acceptor to the action target of insect, and Acetamiprid is the Ach acceptor to the action target of insect, and they have different mechanism of action, do not have cross resistance, therefore with they by best proportioning composite after, can improve control efficiency, the development of delaying drug resistance to diamond-back moth.
| Medicament | ?LD 50(μ g/ head) | The actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient CTC |
| Avermectin | 0.0500 | ????592.8 | ||
| Acetamiprid | 0.2964 | ????100 | ||
| Together+pyridine (0.1: 1.4) | 0.2081 | ????142.4 | ????132.8 | ????107.2 |
| Together+pyridine (0.2: 1.3) | 0.0939 | ????315.6 | ????165.7 | ????190.4 |
| Together+pyridine (0.3: 1.2) | 0.1169 | ????253.5 | ????198.5 | ????127.7 |
Embodiment 1:
Get 1.10 kilograms in the former powder of 92% acetamiprid, 3.15 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903+2000
#(1: 0.1-10: 0.1-10) 18 kilograms, 3.5 kilograms of dispersant OX2000,4 kilograms of proportion conditioning agent propane diols, 2 kilograms of thickener xanthans+polyvinyl alcohol, 4 kilograms of penetrant azone+penetrant ts, 6 kilograms of antifreeze glycols, 58.25 kilograms in water, with homogeneous, dispersion, test package are promptly formed microemulsion.
Annotate: OX series is Liaoyang, Liaoning Province gram difficult to understand chemicals Co., Ltd trade name.
Embodiment 2:
Get 23 kilograms of 4.3% acetamiprid cream, 3 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903+2000
#(1: 0.1-10: 0.1-10) 19 kilograms, 3.8 kilograms of dispersant OX2000,4 kilograms of proportion conditioning agent propane diols, 2 kilograms of thickener xanthans, 4 kilograms of penetrant azone+penetrant ts, 6 kilograms of antifreeze glycols, 35.2 kilograms in water is promptly made emulsifiable concentrate (aqueous emulsion) product through homogeneous dispersion, test package.
Embodiment 3:
Get 28 kilograms of 4.3% acetamiprid cream, 3.8 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903 (1: 0.1-10) 15 kilograms, 3 kilograms of antifreeze glycols, homogeneous disperses promptly to get the missible oil product.
Embodiment 4:
Get 1.5 kilograms in the former powder of 92% acetamiprid, 3.8 kilograms of 93% Acetamiprids, emulsifier 500
#+ OX903 (1: 0.1-10) 5 kilograms, dispersant NNO10 kilogram, 2 kilograms of white carbons, but mix, pulverize and promptly get the wet-milling product.
Claims (9)
1, a kind of ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides is characterized in that said composition contains 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid.
2, according to claim 1 ten hexa-atomic macrolide antibiotics agent for killing mite and pest and pyridines insecticides, it is characterized in that the microemulsion that said composition is made contains: 0.05-2.5% (m/m) acetamiprid and 0.05-10% (m/m) Acetamiprid, 12-20% (m/m) emulsifier is OX901, OX902, OX903, DNP-18,500#, 1600
#, 2000
#In three kinds of compositions, 2-5% (m/m) dispersant is a kind of in NNO, OX2000, sodium lignin sulfonate, calcium lignosulfonate, the penetrant t, 1-5% (m/m) bleeding agent is two kinds in azone, polysorbate 80, the penetrant t, 2-6% (m/m) proportion conditioning agent, 1-5% (m/m) thickener, the water of 1-5% (m/m) antifreezing agent and equivalent.
3, composition according to claim 2 is characterized in that emulsifier adopts OX903,500
#, 2000
#Three kinds of compositions are best.
4, composition according to claim 2 is characterized in that dispersant adopts OX2000 for best.
5, composition according to claim 2 is characterized in that the used proportion conditioning agent of microemulsion is one of following kind: isopropyl alcohol, propane diols, urea, cyclohexanone, ethylenediamine, ethylene glycol.
6, composition according to claim 2 is characterized in that the used thickener of microemulsion is two kinds of following kind: polyvinyl alcohol, CMC, xanthans, bentonite, white carbon.
7, composition according to claim 2 is characterized in that the used antifreezing agent of microemulsion is one of following kind: ethylene glycol, polyethylene glycol, glycerine.
8, composition according to claim 2 is characterized in that microemulsion is to adopt homogeneous blender high degree of dispersion production technology and make.
9, composition according to claim 1 is characterized in that said composition also can be made into emulsifiable concentrate, missible oil, wetting powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00112179 CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00112179 CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1315132A true CN1315132A (en) | 2001-10-03 |
Family
ID=4582061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00112179 Pending CN1315132A (en) | 2000-03-28 | 2000-03-28 | Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1315132A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100588320C (en) * | 2008-03-14 | 2010-02-10 | 中国农业科学院郑州果树研究所 | Acetamiprid and pirimicarb pesticide composition for controlling apple cotton aphid and yellow aphid |
| WO2010092031A3 (en) * | 2009-02-11 | 2011-05-05 | Basf Se | Pesticidal mixtures |
| WO2010092028A3 (en) * | 2009-02-11 | 2011-07-14 | Basf Se | Pesticidal mixtures |
| CN106305714A (en) * | 2016-07-28 | 2017-01-11 | 尹正平 | Fruit fly attractant concentrated solution and matched fruit fly attractant thereof |
| CN107027800A (en) * | 2017-05-26 | 2017-08-11 | 河北威远生化农药有限公司 | A kind of Pesticidal combination containing avermectin B2a |
-
2000
- 2000-03-28 CN CN 00112179 patent/CN1315132A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100588320C (en) * | 2008-03-14 | 2010-02-10 | 中国农业科学院郑州果树研究所 | Acetamiprid and pirimicarb pesticide composition for controlling apple cotton aphid and yellow aphid |
| WO2010092031A3 (en) * | 2009-02-11 | 2011-05-05 | Basf Se | Pesticidal mixtures |
| WO2010092028A3 (en) * | 2009-02-11 | 2011-07-14 | Basf Se | Pesticidal mixtures |
| CN106305714A (en) * | 2016-07-28 | 2017-01-11 | 尹正平 | Fruit fly attractant concentrated solution and matched fruit fly attractant thereof |
| CN107027800A (en) * | 2017-05-26 | 2017-08-11 | 河北威远生化农药有限公司 | A kind of Pesticidal combination containing avermectin B2a |
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