CN1310215A - Black ink for ink jet printer to produce water insoluble and light resistant print and its preparation - Google Patents
Black ink for ink jet printer to produce water insoluble and light resistant print and its preparation Download PDFInfo
- Publication number
- CN1310215A CN1310215A CN 01107567 CN01107567A CN1310215A CN 1310215 A CN1310215 A CN 1310215A CN 01107567 CN01107567 CN 01107567 CN 01107567 A CN01107567 A CN 01107567A CN 1310215 A CN1310215 A CN 1310215A
- Authority
- CN
- China
- Prior art keywords
- ink
- jet printer
- preparation
- water insoluble
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 11
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004202 carbamide Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- -1 polyoxyethylene Polymers 0.000 claims description 10
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 abstract 1
- 239000004147 Sorbitan trioleate Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229960000391 sorbitan trioleate Drugs 0.000 abstract 1
- 235000019337 sorbitan trioleate Nutrition 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 24
- 230000006750 UV protection Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
本发明涉及一种字迹不溶于水、耐光照的喷墨打印机用黑墨水及其制备方法。该黑墨水按下列组分及其重量百分比用量范围配料:60～70%的去离子水、5.5～12.5%的聚乙二醇、3.0～10.0%的直接黑、2.0～10.0%的聚丙烯酸、0.5～2.5%的烷基酚聚氧乙烯醚、0.5～2.0%的失水山梨醇三油酸酯、0.5～1.5%的对苯二酚、0.5～1.5%的尿素、5.0～10.0%的氨水、经充分搅拌,过滤后得产品。本黑墨水固化成膜迅速,字迹不被水溶解,耐光照、耐热等,符合打印机各项参数要求。The invention relates to a black ink for an ink-jet printer whose writing is insoluble in water and resistant to light and a preparation method thereof. The black ink is prepared according to the following components and their dosage ranges by weight: 60-70% deionized water, 5.5-12.5% polyethylene glycol, 3.0-10.0% direct black, 2.0-10.0% polyacrylic acid, 0.5-2.5% alkylphenol polyoxyethylene ether, 0.5-2.0% sorbitan trioleate, 0.5-1.5% hydroquinone, 0.5-1.5% urea, 5.0-10.0% ammonia water , After fully stirring and filtering, the product was obtained. This black ink solidifies quickly to form a film, and the handwriting is not dissolved by water. It is resistant to light and heat, etc., and meets the requirements of various parameters of the printer.
Description
The present invention relates to fine chemistry industry, be meant that specifically a kind of writing is water insoluble, the ink-jet printer of fast light photograph India ink and preparation method thereof.
The ink-jet printer of being sold ink in the market, comprise printer special-purpose inks such as internationally famous brand Canon, Hewlett-Packard and EPSON, be and print the water-soluble product of back writing, and aqueous ink is not ejected on the paper writing not by water-soluble ink by ink-jet printer.
The objective of the invention is to overcome the deficiencies in the prior art part, provide a kind of and be ejected into the rapid film-forming of India ink writing on the paper by ink-jet printer, water insoluble, ultraviolet resistance irradiation, heat-stable ink-jet printer are with India ink and preparation method thereof.
The objective of the invention is to realize by following measure:
The ink-jet printer of the water insoluble fast light photograph of a kind of writing preparation method of India ink, it comprises following processing step and condition thereof:
Step 1: get the raw materials ready
Prepare burden by following component and weight percent amount ranges thereof:
1, deionized water 60～70%
2, polyoxyethylene glycol 5.5～12.5%
3, directly black (L-3BQ) 3.0～10.0%
4, polyacrylic acid 2.0～10.0%
5, alkylphenol polyoxyethylene 0.5～2.5%
6, Witconol AL 69-66 0.5～2.0%
7, Resorcinol 0.5～1.5%
8, urea 0.5～1.5%
9, ammoniacal liquor 5.0～10.0%
Step 2: stir
The order of one batching sequence number 1～8 is dosed in the reactor that is stirring successively set by step, and continuously stirring;
Step 3: heat treated
Be heated to 75～85 ℃ by 50 ℃ temperature rise rate per hour, and under this temperature constant temperature at least 2 hours, naturally cool to below 50 ℃ after, add the ammoniacal liquor of sequence number 9 again;
Step 4: filter
At least filter secondary through filtering element (cartridge) less than the strainer of 2m μ density, the ink-jet printer India ink, can be stored in the encloses container to be packed dispatching from the factory.
The present invention compares with ink with the ink-jet printer of selling in the market has following advantage:
1, the invention solves a difficult problem of the prior art, after using this ink for ink-jet print to print, the writing that is printed is water insoluble, ultraviolet resistance irradiation, heat-resisting, and the energy prolonged preservation is colour-fast, no matter the type fount size is equally clear, can forever preserve as archives material.
2, to compare cost lower for product of the present invention and international advanced brand, is a kind of value added product of higher pair that has, and in addition, along with popularizing of computer, the printer ink water consumption also increases thereupon, so product of the present invention has fabulous market outlook.
3, the India ink of the present invention's preparation can meet every technical performance index of various brand printers fully, and shower nozzle had the good moisture preserving function, ink has good flowing property, the fine ink droplet of ink-jet ejection has infiltration function rapidly to paper, meets the requirement of permanent archives material with China ink fully.The product of present embodiment is on probation on famous brand printers such as EPSON, obtains satisfied effect, proves famous brand printers such as the compatible EPSON of this ink energy.
The present invention is further illustrated by following embodiment:
Embodiment 1
The ink-jet printer of the water insoluble fast light photograph of a kind of writing preparation method of India ink, it comprises following processing step and condition thereof:
Step 1: get the raw materials ready
Prepare burden by following component and weight percent consumption thereof:
1, deionized water 69.5%
2, polyoxyethylene glycol 10%
3, directly black (L-3BQ) 5.0%
4, polyacrylic acid 6.0%
5, alkylphenol polyoxyethylene 1.8%
6, Witconol AL 69-66 1.2%
7, Resorcinol 0.5%
8, urea 0.5%
9, ammoniacal liquor 5.5%
Step 2: stir
The order of one batching sequence number 1～8 is dosed in the reactor that is stirring successively set by step, and continuously stirring;
Step 3: heat treated
Be heated to 75 ℃ by 50 ℃ temperature rise rate per hour, and under this temperature constant temperature 3 hours, naturally cool to 50 ℃ after, add the ammoniacal liquor of sequence number 9 again;
Step 4: filter
Through the strainer filtration secondary of filtering element (cartridge) less than 2m μ density, get the ink-jet printer India ink, can be stored in the encloses container to be packed dispatching from the factory.
Embodiment 2
The ink-jet printer of the water insoluble fast light photograph of a kind of writing preparation method of India ink, it comprises following processing step and condition thereof:
Step 1: get the raw materials ready
Prepare burden by following component and weight percent amount ranges thereof:
1, deionized water 65.7%
2, polyoxyethylene glycol 12%
3, directly black (L-3BQ) 9.0%
4, polyacrylic acid 2.5%
5, alkylphenol polyoxyethylene 0.5%
6, Witconol AL 69-66 0.8%
7, Resorcinol 0.5%
8, urea 1.0%
9, ammoniacal liquor 8.0%
Step 2: stir
One batching is dosed in the reactor that is stirring successively by the order of sequence number 1～8 set by step, and continuously stirring;
Step 3: heat treated
Be heated to 85 ℃ by 50 ℃ temperature rise rate per hour, and under this temperature constant temperature 2 hours, naturally cool to 40 ℃ after, add the ammoniacal liquor of sequence number 9 again;
Step 4: filter
Through the strainer filtration secondary of filtering element (cartridge) less than 2m μ density, get the ink-jet printer India ink, can be stored in the encloses container to be packed dispatching from the factory.
Embodiment 3
The ink-jet printer of the water insoluble fast light photograph of a kind of writing preparation method of India ink, it comprises following processing step and condition thereof:
Press following component and weight percent amount ranges thereof:
Batching:
1, deionized water 64%
2, polyoxyethylene glycol 7.0%
3, directly black (L-3BQ) 3.5%
4, polyacrylic acid 10.0%
5, alkylphenol polyoxyethylene 2.0%
6, Witconol AL 69-66 1.5%
7, Resorcinol 1.5%
8, urea 0.5%
9, ammoniacal liquor 10.0%
Step 2: stir
The order of one batching sequence number 1～8 is dosed in the reactor that is stirring successively set by step, and continuously stirring;
Step 3: heat treated
Be heated to 80 ℃ by 50 ℃ temperature rise rate per hour, and under this temperature constant temperature 2.5 hours, naturally cool to room temperature after, add the ammoniacal liquor of sequence number 9 again;
Step 4: filter
Through the strainer filtration secondary of filtering element (cartridge) less than 2m μ density, get the ink-jet printer India ink, can be stored in the encloses container to be packed dispatching from the factory.
Claims (2)
1, the ink-jet printer of the water insoluble fast light photograph of a kind of writing preparation method of India ink, it comprises following processing step and condition thereof:
Step 1: get the raw materials ready
Prepare burden by following component and weight percent amount ranges thereof:
(1) deionized water 60～70%
(2) polyoxyethylene glycol 5.5～12.5%
(3) directly black (L-3BQ) 3.0～10.0%
(4) polyacrylic acid 2.0～10.0%
(5) alkylphenol polyoxyethylene 0.5～2.5%
(6) Witconol AL 69-66 0.5～2.0%
(7) Resorcinol 0.5～1.5%
(8) urea 0.5～1.5%
(9) ammoniacal liquor 5.0～10.0%
Step 2: stir
The order of one batching sequence number (1)～(8) is dosed in the reactor that is stirring successively set by step, and continuously stirring;
Step 3: heat treated
Be heated to 75～85 ℃ by 50 ℃ temperature rise rate per hour, and under this temperature constant temperature at least 2 hours, naturally cool to below 50 ℃ after, add the ammoniacal liquor of sequence number (9) again;
Step 4: filter
At least filter secondary through filtering element (cartridge) less than the strainer of 2m μ density, the ink-jet printer India ink, can be stored in the encloses container to be packed dispatching from the factory.
2, the ink-jet printer India ink of the water insoluble fast light photograph of the resulting writing of preparation method according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011075678A CN1142224C (en) | 2001-02-23 | 2001-02-23 | Black ink for ink jet printer to produce water insoluble and light resistant print and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011075678A CN1142224C (en) | 2001-02-23 | 2001-02-23 | Black ink for ink jet printer to produce water insoluble and light resistant print and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1310215A true CN1310215A (en) | 2001-08-29 |
| CN1142224C CN1142224C (en) | 2004-03-17 |
Family
ID=4656487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011075678A Expired - Fee Related CN1142224C (en) | 2001-02-23 | 2001-02-23 | Black ink for ink jet printer to produce water insoluble and light resistant print and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1142224C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004052647A2 (en) * | 2002-12-11 | 2004-06-24 | Creo Il. Ltd. | Lithographic printing precursor and method of making a printing plate by ink jet imaging |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2850966B1 (en) | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | PROCESS FOR PRODUCING DINITRIL COMPOUNDS |
| FR2854891B1 (en) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | PROCESS FOR PREPARING DINITRILES |
| EP1948591A1 (en) | 2005-10-18 | 2008-07-30 | INVISTA Technologies S.à.r.l. | Process of making 3-aminopentanenitrile |
| CA2644961A1 (en) | 2006-03-17 | 2007-09-27 | Invista Technologies S.A.R.L. | Method for the purification of triorganophosphites by treatment with a basic additive |
| US7919646B2 (en) | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| WO2008157218A1 (en) | 2007-06-13 | 2008-12-24 | Invista Technologies S.A.R.L. | Process for improving adiponitrile quality |
| EP2229354B1 (en) | 2008-01-15 | 2013-03-20 | Invista Technologies S.à.r.l. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
| CN101918356B (en) | 2008-01-15 | 2013-09-25 | 因温斯特技术公司 | Hydrocyanation of pentenenitriles |
| JP5619753B2 (en) | 2008-10-14 | 2014-11-05 | インヴィスタテクノロジーズ エスアエルエル | Process for producing 2-secondary-alkyl-4,5-di- (linear-alkyl) phenols |
| KR20120047251A (en) | 2009-08-07 | 2012-05-11 | 인비스타 테크놀러지스 에스.에이.알.엘. | Hydrogenation and esterification to form diesters |
-
2001
- 2001-02-23 CN CNB011075678A patent/CN1142224C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004052647A2 (en) * | 2002-12-11 | 2004-06-24 | Creo Il. Ltd. | Lithographic printing precursor and method of making a printing plate by ink jet imaging |
| WO2004052647A3 (en) * | 2002-12-11 | 2004-12-29 | Creo Il Ltd | Lithographic printing precursor and method of making a printing plate by ink jet imaging |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1142224C (en) | 2004-03-17 |
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| C14 | Grant of patent or utility model | ||
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