CN1306050A - Organosilicon modified acrylic paint for external wall and its preparing process - Google Patents
Organosilicon modified acrylic paint for external wall and its preparing process Download PDFInfo
- Publication number
- CN1306050A CN1306050A CN 99112498 CN99112498A CN1306050A CN 1306050 A CN1306050 A CN 1306050A CN 99112498 CN99112498 CN 99112498 CN 99112498 A CN99112498 A CN 99112498A CN 1306050 A CN1306050 A CN 1306050A
- Authority
- CN
- China
- Prior art keywords
- defoamer
- organosilicon
- modified acrylic
- water
- external wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000003973 paint Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title description 4
- 239000000178 monomer Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000012153 distilled water Substances 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- -1 disperser Substances 0.000 claims abstract description 4
- 239000013530 defoamer Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 15
- 239000004816 latex Substances 0.000 claims description 15
- 229920000126 latex Polymers 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 7
- 150000001282 organosilanes Chemical class 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004922 lacquer Substances 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 238000005304 joining Methods 0.000 claims description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 15
- 230000002159 abnormal effect Effects 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000006253 efflorescence Methods 0.000 description 3
- 206010037844 rash Diseases 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
An organosilicon modified acrylic paint for external surface of wall is prepared through solution polymerization reaction of organosilicon monomer, acrylate monomer, acrylic acid, emulsifier, trigger and distilled water, and mixing the resultant high-molecular polymer with water, defoaming agent, anticorrosion agent, disperser, filler and thickening agent. Its advantages are high weatherability, hardness, adhesion and surface hydrophobicity, gay lustre, long service life and no environmental pollution.
Description
The present invention relates to this technical field of coating, particularly a kind of organosilicon modified acrylic paint for external wall and preparation method.
At present, the most frequently used building coating of China can be divided into oil paint and water-borne coatings two big series.Oil paint contains objectionable constituent such as formaldehyde, organic solvent, benzene series thing and heavy metal, and organic solvent is inflammable, not only bring inconvenience, and evaporate in the air and can cause environmental pollution and waste of material, thereby also easily efflorescence, variable color of product, coming off influences decorative effect to construction.Though water-borne coatings can be protected environment, save energy, at present the coating quality of throwing on the domestic market is poor, of low grade, mainly shows: gloss is low, poor adhesive force, not water-fastly wash, self-cleaning is poor, fugitive color.
It is that 97105779.6 patent relates to silicon Acrylote paint and preparation method thereof that an application number is arranged.This coating is made up of ACRYLIC EMULSION, silicone resin, filler, film coalescence aid, thickening material, water-resisting agent, dispersion agent, defoamer, sanitas and water.The main drawback of this coating is that weathering resistance is still strong inadequately.
The objective of the invention is at above-mentioned the deficiencies in the prior art part, provide a kind of produce and use in do not have environment-friendly type coating of high-weatherability that " three wastes " discharge, high adhesive force, high hydrophobicity, long service life and preparation method thereof.
The present invention is achieved through the following technical solutions: this coating is to be main film forming matter with organosilicon crylic acid latex, adds filler, dispersion agent, defoamer, sanitas, thickening material, water and makes.Proportioning between each composition is: organosilicon crylic acid latex 30-38, filler 30-35, dispersion agent 0.5-1, defoamer 0.1-0.2, sanitas 0.1-0.3, thickening material 1-2, water 30-35.The composition of organosilicon crylic acid latex (weight %) is the high molecular polymer that is made by solution polymerization by organosilane monomer 5-8, acrylate monomer 8.6-10, adding vinylformic acid 1-6, initiator 0.6-1.6, emulsifying agent 3-5, distilled water 70-80.
The compound method of this coating is: prepare burden by the said components proportioning, in reactor, add distilled water and be heated to the 85-90 degree, splash into organosilane monomer, acrylate monomer, vinylformic acid and initiator, emulsifying agent, dropwised in 2-3 hour, be incubated 1 hour again, cool to the 30-40 degree, regulate pH value to 6-9 discharging and promptly make organosilicon crylic acid latex.In joining the lacquer cylinder, add entry, add defoamer, sanitas, dispersion agent while stirring, mix the back and add filler, continue to be stirred to evenly, regulate pH value to 7.5-8.5, with shredder grind to fineness less than after 40 microns, under stirring at low speed, add organosilicon crylic acid latex, defoamer, adjust to proper viscosity with thickening material at last and get final product.
The present invention compared with prior art has following advantage: the main film forming matter organosilicon crylic acid latex of this coating is the high molecular polymer that is made by solution polymerization by organosilane monomer, acrylate monomer, adding vinylformic acid, initiator, emulsifying agent, distilled water.This coating has high-weatherability, and is all splendid on gloss, hardness, adhesion strength, surface hydrophobicity, long service life, and do not have " three wastes " discharging in the production use.
Embodiments of the invention are described in detail in detail below: a kind of organosilicon modified acrylic paint for external wall, its component (weight %) contains: organosilicon crylic acid latex 30-38, filler 30-35, dispersion agent 0.5-1, defoamer 0.1-0.2, sanitas 0,1-0,3, thickening material 1-2, water 30-35.The composition of organosilicon crylic acid latex (weight %) is the high molecular polymer that is made by solution polymerization by organosilane monomer 5-8, acrylate monomer 8.6-10, adding vinylformic acid 1-6, initiator 0.6-1.6, emulsifying agent 3-5, distilled water 70-80.Filler is made up of titanium dioxide, mica powder and water-ground limestone or kaolin, and the proportioning between them (weight %) is titanium dioxide 40-50, mica powder 10-15, water-ground limestone or kaolin 35-45.The method for preparing organosilicon modified acrylic paint for external wall, be in reactor, to add distilled water to be heated to the 85-90 degree, splash into organosilane monomer, acrylate monomer, vinylformic acid and initiator, emulsifying agent, dropwised in 2-3 hour, be incubated 1 hour again, cool to the 30-40 degree, regulate pH value to 6-9 discharging and promptly make organosilicon crylic acid latex.Add entry in the cylinder, add defoamer, sanitas, dispersion agent while stirring joining lacquer, mix the back and add filler, continue to be stirred to evenly, regulate pH value to 7.5-8.5, with shredder grind to fineness less than after 40 microns, under stirring at low speed, add organosilicon crylic acid latex, defoamer, adjust to proper viscosity with thickening material at last and get final product.Use for the first time the amount of defoamer as using 60-70%, the second time of defoamer total amount the 30-40% of the amount of defoamer as total amount.For the first time using the effect of defoamer is to make this coating non-foaming in process of production, and using defoamer for the second time is to make this coating in use non-foaming.Organosilicon crylic acid latex is the main film forming matter of this coating, organosilicon has higher thermotolerance, hydrophobic nature, lower temperature resistance, vinylformic acid is through after organic-silicon-modified, and the copolymer emulsion of generation has characteristics such as high-weatherability, high gloss, high rigidity, high-adhesion, surface hydrophobicity be fabulous.Colors such as this coating is the multiple color of furnishing as required, can select Rutile type Titanium Dioxide for use as white, and is red, yellow, green are selected red iron oxide, iron oxide green, iron oxide yellow etc. for use.
This coating is through the detection of national agent authorized, and every performance index have have all met or exceeded the standard-required of GB/T9755-1995 acceptable end product.See Table:
| Project name | Index request | Assay |
| Color and outward appearance | Appearance of film is normal | Appearance of film meets the aberration scope |
| Solids content | More than or equal to 45% | More than or equal to 50% |
| Opacifying power | Be less than or equal to 250 the gram/square metre | Be less than or equal to gram/square metre |
| Water tolerance (96h) | It is no abnormal to film | It is no abnormal to film |
| At condition in container | Mix the no lump in back and be uniform state | No lump is uniform state |
| Contrast ratio (white and light color) | More than or equal to 0.90 | More than or equal to 0.93 |
| Alkali resistance (48h) | It is no abnormal to film | No abnormal |
| Brushing resistance (1000 times) | It is no abnormal to film | No abnormal |
| Artificial ageing resistance (250h) | Efflorescence I level variable color II level | Efflorescence I level variable color I level |
Claims (4)
1, a kind of organosilicon-modified acrylic rustproof lacquer is characterized in that its component (weight %) contains: organosilicon crylic acid latex 30-38, filler 30-35, dispersion agent 0.5-1, defoamer 0.1-0.2, sanitas 0,1-0,3, thickening material 1-2, water 30-35.The composition of organosilicon crylic acid latex (weight %) is the high molecular polymer that is made by solution polymerization by organosilane monomer 5-8, acrylate monomer 8.6-10, adding vinylformic acid 1-6, emulsifying agent 3-5, initiator 0.6-1.6, distilled water 70-80.
2, organosilicon modified acrylic paint for external wall according to claim 1, it is characterized in that filler is made up of titanium dioxide, mica powder and water-ground limestone or kaolin, the proportioning between them (weight %) is titanium dioxide 40-50, mica powder 10-15, water-ground limestone or kaolin 35-45.
3, a kind of preparation method who prepares the described organosilicon modified acrylic paint for external wall of claim 1, it is characterized in that in reactor, adding distilled water and be heated to the 85-90 degree, splash into organosilane monomer, acrylate monomer, vinylformic acid and initiator, emulsifying agent, dropwised in 2-3 hour, be incubated 1 hour again, cool to the 30-40 degree, regulate pH value to 6-9 discharging and promptly make organosilicon crylic acid latex.In joining the lacquer cylinder, add entry, add defoamer, sanitas, dispersion agent while stirring, mix the back and add filler, continue to be stirred to evenly, regulate pH value to 7.5-8.5, with shredder grind to fineness less than after 40 microns, under stirring at low speed, add organosilicon crylic acid latex, defoamer, adjust to proper viscosity with thickening material at last and get final product.
4, the preparation method of organosilicon modified acrylic paint for external wall according to claim 3 is characterized in that using for the first time the amount of defoamer as using 60-70%, the second time of defoamer total amount the 30-40% of the amount of defoamer as total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112498 CN1131287C (en) | 1999-10-22 | 1999-10-22 | Organosilicon modified acrylic paint for external wall and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99112498 CN1131287C (en) | 1999-10-22 | 1999-10-22 | Organosilicon modified acrylic paint for external wall and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1306050A true CN1306050A (en) | 2001-08-01 |
| CN1131287C CN1131287C (en) | 2003-12-17 |
Family
ID=5275798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99112498 Expired - Fee Related CN1131287C (en) | 1999-10-22 | 1999-10-22 | Organosilicon modified acrylic paint for external wall and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1131287C (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304504C (en) * | 2003-02-16 | 2007-03-14 | 李清波 | Water-soluble metal baking coatings |
| CN1324099C (en) * | 2004-07-05 | 2007-07-04 | 常州市福莱姆汽车涂料有限公司 | Self-crosslinked aqueous traffic paint and method for using same |
| CN100345874C (en) * | 2005-02-28 | 2007-10-31 | 仪征多科特水性化学品有限责任公司 | Organosilicon modified acrylate emulsion for ambient temperature crosslinked aqueous paint and method for preparing same |
| CN100371402C (en) * | 2006-10-16 | 2008-02-27 | 陈东东 | Infrared resistant coating and preparation process |
| CN101812263A (en) * | 2010-04-16 | 2010-08-25 | 杭州美多乐化工有限公司 | Waterborne weather-resistant self-cleaning type silicone acrylic latex paint and production method thereof |
| CN101864235A (en) * | 2010-07-08 | 2010-10-20 | 内蒙古兴泰建筑有限责任公司 | Method for preparing exterior wall coating |
| CN101024748B (en) * | 2006-02-23 | 2010-11-24 | 富思特制漆（北京）有限公司 | Base paint for protection of cultural relics and preparation method thereof |
| CN102466324A (en) * | 2010-11-19 | 2012-05-23 | 北京佳盛世纪科技有限公司 | Organic silicon modified acrylate copolymer stainless steel composite inner container for water heater |
| CN103360890A (en) * | 2013-06-27 | 2013-10-23 | 中科院广州化学有限公司 | Organic-inorganic hybrid coating containing modified (methyl) acrylic ester copolymer emulsion |
| CN103938811A (en) * | 2014-03-22 | 2014-07-23 | 烟台斯坦普精工建设有限公司 | Photovoltaic awning system and manufacturing method thereof |
| CN104151980A (en) * | 2014-08-18 | 2014-11-19 | 安徽省思维新型建材有限公司 | Aqueous coating used in buildings |
| CN104194549A (en) * | 2014-08-18 | 2014-12-10 | 安徽省思维新型建材有限公司 | Water-base paint used for indoor woodware |
| CN104194437A (en) * | 2014-08-18 | 2014-12-10 | 安徽省思维新型建材有限公司 | Water-based paint for coating automobile frame |
| CN104250502A (en) * | 2014-09-19 | 2014-12-31 | 苏州云舒新材料科技有限公司 | Exterior wall protecting coating and preparation method thereof |
| CN104927534A (en) * | 2015-05-26 | 2015-09-23 | 江苏高科物流科技股份有限公司 | Building external wall insulation coating and preparation method thereof |
| CN105199522A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Weather-resistant heat-isolation outer wall emulsion paint |
| CN105199521A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Hydrophobic silica aerogel modified acrylate emulsion coating |
| CN106928800A (en) * | 2017-03-28 | 2017-07-07 | 常州大学 | A kind of preparation method of purify air interior wall aqueous latex paint |
| CN106977666A (en) * | 2017-04-27 | 2017-07-25 | 重庆三峡油漆股份有限公司 | Coating NC Nitroncellulose substitute and preparation method thereof |
| CN111363434A (en) * | 2020-04-16 | 2020-07-03 | 山东七维新材料有限公司 | Single-component modified acrylic coating and preparation method thereof |
| CN113861743A (en) * | 2021-12-03 | 2021-12-31 | 北京沃坦新能源科技有限公司 | Low-cost radiation refrigeration coating and preparation method and application thereof |
-
1999
- 1999-10-22 CN CN 99112498 patent/CN1131287C/en not_active Expired - Fee Related
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304504C (en) * | 2003-02-16 | 2007-03-14 | 李清波 | Water-soluble metal baking coatings |
| CN1324099C (en) * | 2004-07-05 | 2007-07-04 | 常州市福莱姆汽车涂料有限公司 | Self-crosslinked aqueous traffic paint and method for using same |
| CN100345874C (en) * | 2005-02-28 | 2007-10-31 | 仪征多科特水性化学品有限责任公司 | Organosilicon modified acrylate emulsion for ambient temperature crosslinked aqueous paint and method for preparing same |
| CN101024748B (en) * | 2006-02-23 | 2010-11-24 | 富思特制漆（北京）有限公司 | Base paint for protection of cultural relics and preparation method thereof |
| CN100371402C (en) * | 2006-10-16 | 2008-02-27 | 陈东东 | Infrared resistant coating and preparation process |
| CN101812263A (en) * | 2010-04-16 | 2010-08-25 | 杭州美多乐化工有限公司 | Waterborne weather-resistant self-cleaning type silicone acrylic latex paint and production method thereof |
| CN101864235A (en) * | 2010-07-08 | 2010-10-20 | 内蒙古兴泰建筑有限责任公司 | Method for preparing exterior wall coating |
| CN101864235B (en) * | 2010-07-08 | 2012-07-18 | 内蒙古兴泰建筑有限责任公司 | Method for preparing exterior wall coating |
| CN102466324A (en) * | 2010-11-19 | 2012-05-23 | 北京佳盛世纪科技有限公司 | Organic silicon modified acrylate copolymer stainless steel composite inner container for water heater |
| CN103360890A (en) * | 2013-06-27 | 2013-10-23 | 中科院广州化学有限公司 | Organic-inorganic hybrid coating containing modified (methyl) acrylic ester copolymer emulsion |
| CN103360890B (en) * | 2013-06-27 | 2015-09-23 | 中科院广州化学有限公司 | Containing the organic inorganic hybridized paint of modification (methyl) acrylate polymer emulsion |
| CN103938811A (en) * | 2014-03-22 | 2014-07-23 | 烟台斯坦普精工建设有限公司 | Photovoltaic awning system and manufacturing method thereof |
| CN103938811B (en) * | 2014-03-22 | 2017-02-01 | 烟台斯坦普精工建设有限公司 | Photovoltaic awning system and manufacturing method thereof |
| CN104194549A (en) * | 2014-08-18 | 2014-12-10 | 安徽省思维新型建材有限公司 | Water-base paint used for indoor woodware |
| CN104194437A (en) * | 2014-08-18 | 2014-12-10 | 安徽省思维新型建材有限公司 | Water-based paint for coating automobile frame |
| CN104151980A (en) * | 2014-08-18 | 2014-11-19 | 安徽省思维新型建材有限公司 | Aqueous coating used in buildings |
| CN104250502A (en) * | 2014-09-19 | 2014-12-31 | 苏州云舒新材料科技有限公司 | Exterior wall protecting coating and preparation method thereof |
| CN104927534A (en) * | 2015-05-26 | 2015-09-23 | 江苏高科物流科技股份有限公司 | Building external wall insulation coating and preparation method thereof |
| CN105199522A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Weather-resistant heat-isolation outer wall emulsion paint |
| CN105199521A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Hydrophobic silica aerogel modified acrylate emulsion coating |
| CN106928800A (en) * | 2017-03-28 | 2017-07-07 | 常州大学 | A kind of preparation method of purify air interior wall aqueous latex paint |
| CN106977666A (en) * | 2017-04-27 | 2017-07-25 | 重庆三峡油漆股份有限公司 | Coating NC Nitroncellulose substitute and preparation method thereof |
| CN111363434A (en) * | 2020-04-16 | 2020-07-03 | 山东七维新材料有限公司 | Single-component modified acrylic coating and preparation method thereof |
| CN113861743A (en) * | 2021-12-03 | 2021-12-31 | 北京沃坦新能源科技有限公司 | Low-cost radiation refrigeration coating and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1131287C (en) | 2003-12-17 |
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