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CN1298858A - Process for synthesizing aldehyde from olefine, CO and hydrogen - Google Patents

Process for synthesizing aldehyde from olefine, CO and hydrogen Download PDF

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Publication number
CN1298858A
CN1298858A CN00128279A CN00128279A CN1298858A CN 1298858 A CN1298858 A CN 1298858A CN 00128279 A CN00128279 A CN 00128279A CN 00128279 A CN00128279 A CN 00128279A CN 1298858 A CN1298858 A CN 1298858A
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reaction
rhodium
ammonium
pressure
ammonium salt
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CN1123557C (en
Inventor
贺德华
刘金尧
朱起明
刘晔
陈瑜
庞东成
王同恩
尹斗源
孙昌奎
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Tsinghua University
Lotte Daesan Petrochemical Corp
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Tsinghua University
Hyundai Petrochemical Co Ltd
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Priority to KR10-2001-0006755A priority patent/KR100436594B1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/822—Rhodium

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  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

本发明涉及一种从烯烃、一氧化碳和氢气合成醛的方法,首先在反应釜中,加入铑化合物、无机铵盐和烯烃。反应釜密闭后置于加热炉中,用CO∶H2=1∶1的合成气置换反应釜中的空气后,在同样的气氛中、在一定的温度和压力下,反应一段时间,冷却后经减压蒸馏即得到产物醛。本发明的方法,可以在温和的条件下,高效率地从烯烃、一氧化碳和氢气合成醛,并且产物与催化剂分离后回收的铑－无机铵盐催化体系可以循环使用。The invention relates to a method for synthesizing aldehydes from olefins, carbon monoxide and hydrogen. First, rhodium compounds, inorganic ammonium salts and olefins are added into a reaction kettle. The reaction kettle is sealed and placed in a heating furnace. After replacing the air in the reaction kettle with CO:H 2 =1:1 synthesis gas, react for a period of time in the same atmosphere at a certain temperature and pressure, and after cooling The product aldehyde can be obtained by distillation under reduced pressure. The method of the present invention can efficiently synthesize aldehydes from olefins, carbon monoxide and hydrogen under mild conditions, and the rhodium-inorganic ammonium salt catalytic system recovered after the product is separated from the catalyst can be recycled.

Description

Method from the synthetic aldehyde of alkene, carbon monoxide and hydrogen
The present invention relates in the presence of rhodium catalyst, synthesize the method for aldehyde, relate to the Speciality Petrochemicals field from alkene, carbon monoxide and hydrogen.
Aldehyde is important organic chemicals, and wherein the higher alcohols that obtain through hydrogenation of high-carbon aldehyde except that as tensio-active agent, the oil dope, are used to prepare softening agent in large quantities.On industrial production, most aldehyde can be made by the hydroformylation process.Since fritz rowland at the end of the thirties (O.Roelen) has been invented hydroformylation catalyst; hydroformylation catalyst and reaction process thereof a large amount of R and D have been carried out both at home and abroad; existing multiple catalyst system and technological process are applied to suitability for industrialized production, mainly contain the cobalt carbonyl catalyst and the rhodium phosphine catalyst of cobalt carbonyl catalyst, tertiary phosphine modification.As the modification cobalt method (cobalt phosphine catalyst, US Pat.3239566) of shell (Shell) company, connection carbon (UCC) company and Mitsubishi change into the rhodium-tertiary phosphine method (US Pat.3527809, US Pat.4247486, US Pat.5105018) of company.On activity, rhodium catalytic system will be higher than cobalt catalyst far away.Though the rhodium catalyst of triphenylphosphine modification is applied to have excellent catalytic performance in the hydroformylation of low carbon number (carbon atom quantity＜4) alkene; but in high carbon number alkene is especially branched in the hydroformylation reaction of alkene; rhodium-triphenylphosphine catalyzer fails to demonstrate good performance (speed of response is slower, and transformation efficiency and yield are all lower).
At alkene in the side chain of high carbon number, the new catalyst system that United States Patent (USP) is invented a kind of rhodium/triphenylphosphine oxide No. 4528403, and be applied to the hydroformylation process of mixed octene.Though this method is under 130 ℃, 200 normal atmosphere, 4 hours reaction conditions, the yield of the higher aldehyde C-9 mixture that can obtain, stablize rhodium catalyst but in carrying out the isolating still-process of catalyzer and product, will add triphenylphosphine in addition, and must after peroxidation, just can recycle with the rhodium catalyst that contains triphenylphosphine after product separates.Therefore still to exist processing step many for this method, severe reaction conditions (200 normal atmosphere), problem such as unfavorable economically.
The objective of the invention is to propose a kind of have industrial application value, with rhodium and inorganic ammonium salt (ammonium salt of periodictable group vib metal oxygen-containing acid) be catalyst system, by the method for the synthetic aldehyde of alkene, carbon monoxide and hydrogen, to produce important organic chemicals aldehyde.Use the ammonium salt of a kind of metal (being selected from periodictable group vib element) oxygen acid and the catalyst system that a kind of rhodium compound is formed, under the condition of gentleness, synthesize aldehyde from alkene, carbon monoxide and hydrogen expeditiously, and the rhodium that reclaims after product and the catalyst separating-inorganic ammonium salt catalyst system can recycle.
The method from the synthetic aldehyde of alkene, carbon monoxide and hydrogen that the present invention proposes comprises following each step:
(1) in reactor, adds rhodium compound (as dimerization acetic acid rhodium, 16 carbonyls, six rhodiums), inorganic ammonium salt (ammonium salt of periodictable group vib metal oxygen-containing acid is as ammonium dichromate, ammonium chromate, ammonium molybdate and ammonium tungstate) and alkene.The ratio of inorganic ammonium salt and rhodium compound is in ratio (atomic ratio) N: the Rh=5 of Rh in N in the ammonium salt and the rhodium compound: 1～35: 1; The ratio of alkene and rhodium compound is 1.0 * 10 -3～1.0mg rhodium metal/1mL alkene.
(2) reactor is airtight is placed in the process furnace, with synthetic gas (CO: H 2=1: 1) behind the air in the replacement reaction kettle, under normal pressure, reactor is heated to temperature of reaction (60～160 ℃).
(3) under given temperature of reaction (60～160 ℃), charge into synthetic gas (CO: H to reactor 2=1: 1) to reaction pressure (6～12MPa).Under temperature of reaction and reaction pressure, under agitation reacted 2～6 hours.In reaction process, Lian Xu supplies the Give synthetic gas and keeps reaction pressure stable.
(4) after reaction finishes, reactor is taken out from process furnace, be cooled to room temperature after, reacting kettle inner pressure is let out to normal pressure.Open kettle cover, take out the reaction solution that contains product aldehyde.Reaction solution is carried out underpressure distillation, obtain product aldehyde.
In order to recycle Noble Metal Rhodium, to save production cost, after reaction process finished, after product aldehyde distilled, catalyst residue was at the bottom of still kettle, catalyst recovery and be added to the circulating reaction that carries out catalyzer in the reactor.
Below the present invention is further illustrated.
Rhodium is the activity of such catalysts component in the present invention.By add rhodium compound and above-mentioned ammonium salt and carbon monoxide, hydrogen and alkene in reactor, hydroformylation catalyst can generate in reaction process " original position ".
The compound of rhodium can be the inorganic salt of rhodium or the organic compound of rhodium, as rhodium chloride, rhodium nitrate, dimerization acetic acid rhodium, 16 carbonyls, six rhodiums, ten dicarbapentaborane, four rhodiums, Rh (C 5H 7O 2) 3, RhCl (PPh 3) 3, [ClRh (CO) 2] 2, Rh (CO) 2(C 5H 7O 2), Rh (CO) (PPh 3) (C 5H 7O 2), RhCl (CO) (PPh 3) 2And HRh (CO) (PPh 3) 3Deng.
The inorganic ammonium salt that uses among the present invention, (W) ammonium salt of oxygen acid is as ammonium dichromate, ammonium chromate, ammonium molybdate and ammonium tungstate for Cr, Mo for periodic table of elements group vib metal.
The alkene that the present invention uses is that carbonatoms is 6～14 aliphatics alkene, and its general expression is R 1R 2-C=C-R 3R 4, R wherein 1, R 2, R 3, R 4Be straight or branched alkyl or hydrogen atom.Particularly, as hexene, heptene, octene, nonene, decene, hendecene, laurylene, tridecylene and tetradecene.Above-mentioned alkene as raw material can be single isomer, also can be the various mixture of isomers of same carbonatoms alkene.
The synthetic gas that the present invention uses is carbon monoxide (CO) and hydrogen (H 2) gas mixture, CO/H 2Ratio be 1/2～2/1, be preferably CO/H 2=1/1.
By the above-mentioned reaction that method of the present invention is carried out, the usage quantity of catalyzer Rh is 1.0 * 10 -3～1.0mg rhodium (metal)/1mL alkene is preferably 1.0 * 10 -2～0.1mg rhodium (metal)/1mL alkene.
By the above-mentioned reaction that method of the present invention is carried out, the consumption of inorganic ammonium salt (vib metal oxygen acid ammonium salt) is in N atomicity in the ammonium salt, and the ratio of N and Rh is generally 2/1～40/1, is preferably 5/1～35/1.
Carry out above-mentioned reaction by method of the present invention, under heating, carry out.Temperature of reaction is generally 40～200 ℃.Be higher than ceiling temperature, the more and catalyzer of by product easily decomposes and loses activity, and is lower than lower limit temperature, and then speed of response is too slow, and preferable reaction temperature is 60～160 ℃.
Carry out above-mentioned reaction by the inventive method, carry out adding to depress.The pressure of synthetic gas is generally 4～16MPa, is preferably 6～12MPa.In reaction process, supply with synthetic gas continuously and keep the synthetic gas pressure-stabilisation.
By the above-mentioned reaction that the inventive method is carried out, in autoclave, carry out, raw material olefin can continuously feeding, and also intermittently (disposable) is reinforced.When reacting with intermittent mode, the reaction times was generally 1～8 hour, was preferably 2～5 hours.
Carry out above-mentioned reaction by the present invention, can use solvent as required, also can not use solvent.The solvent that uses has: ether solvent such as glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dme, tetraethyleneglycol dimethyl ether, 1,4-dioxane, tetrahydrofuran (THF) etc.; Alcoholic solvent is as methyl alcohol, ethanol, propyl alcohol, butanols etc.; Aliphatic saturated hydrocarbon and alicyclic hydrocarbon type solvent such as hexane, heptane, octane, nonane, decane, undecane, dodecane, tridecane, hexanaphthene etc.; Aromatic hydrocarbon solvent such as benzene,toluene,xylene etc.
With embodiment the present invention is made specific description below.
Embodiment 1
At internal volume is in the stainless steel autoclave of 50ml, adds 1.6mg dimerization acetic acid rhodium (containing 0.73mg metal Rh) (molecular formula: [Rh (CH 3COO) 2] 2, Belgian ACROS Chemicals company product), 4.5mg ammonium dichromate (molecular formula: (NH 4) 2Cr 2O 7, Tianjin chemical reagent three factory's products), 8ml (5.720g) 1-octene (molecular formula: C 8H 16, Belgian ACROS Chemicals company product).Behind the closed reactor, charge into synthetic gas (CO/H to reactor 2=1/1) to 3MPa, pressure release is to normal pressure again, and three times with the air in the replacement reaction kettle so repeatedly.Reacting by heating still to 80 ℃ under normal pressure fills synthetic gas (CO/H again in reactor 2=1/1) to 8MPa, 80 ℃, stir under reaction 2.5 hours, supply with synthetic gas in the reaction process continuously and keep pressure-stabilisation in 8MPa.After reaction finishes, stop synthetic gas and supply with, reactor is cooled to room temperature and the still internal pressure is reduced to normal pressure, reaction solution is taken out carry out underpressure distillation again, obtain the product aldehyde C-9.The results are shown in table 1.
Embodiment 2
Remove with 7.4mg ammonium molybdate (molecular formula: (NH 4) 6Mo 7O 244H 2O, Beijing 57601 chemical plant products) replace outside the ammonium dichromate among the embodiment 1, other is operated with embodiment 1.Reaction result is listed in table 1.
Embodiment 3
Remove with 11.6 mg ammonium tungstate (molecular formula: (NH 4) 5[H 7(WO 4) 6] H 2O, Shanghai reagent two factory's products) replace outside the ammonium dichromate among the embodiment 1, other is operated with embodiment 1.Reaction result is listed in table 1.
Embodiment 4
Except that temperature of reaction is 140 ℃, other is operated with embodiment 1.Reaction result is listed in table 1.
Embodiment 5
Except that temperature of reaction is 140 ℃, other is operated with embodiment 2.Reaction result is listed in table 1.
Comparative example 1
Except that without the ammonium dichromate, other is operated with embodiment 1.Reaction result is listed in table 1.
Comparative example 2
Except that without the ammonium dichromate, other is operated with embodiment 4.Reaction result is listed in table 1.
Embodiment 6
At internal volume is in the stainless steel autoclave of 100ml, adds 5.8mg dimerization acetic acid rhodium (containing 2.7mg metal Rh), 23.2mg ammonium dichromate, 30ml (21.450g) mixed octene (molecular formula: C 8H L6, Hyundai petroleum chemistry company provides, and contains 20% positive octene, 50% methyl heptene, 30% dimethyl hexene, purity 99%).Behind the closed reactor, charge into synthetic gas (CO/H to reactor 2=1/1) to 3MPa, pressure release is to normal pressure again, and three times with the air in the replacement reaction kettle so repeatedly.Reacting by heating still to 140 ℃ under normal pressure fills synthetic gas (CO/H again in reactor 2=1/1) to 8MPa, reaction is 2.5 hours under 140 ℃ of stirrings, supplies with synthetic gas in the reaction process continuously and keeps pressure-stabilisation in 8MPa.After reaction finishes, stop synthetic gas and supply with, reactor is cooled to room temperature and the still internal pressure is reduced to normal pressure, again reaction solution is taken out, carry out underpressure distillation, obtain the product aldehyde C-9.The results are shown in table 2.
Embodiment 7
Except that the ammonium dichromate that replaces with the 37.8mg ammonium molybdate among the embodiment 6, other is operated with embodiment 6.Reaction result is listed in table 2.
Embodiment 8
Except that the ammonium dichromate that replaces with the 269.6mg ammonium tungstate among the embodiment 6, other is operated with embodiment 6.Reaction result is listed in table 2.
Embodiment 9
Remove with 13.8mg ammonium chromate (molecular formula: (NH 4) 2CrO 4, Shanghai chemical reagent two factory's products) replace outside the ammonium dichromate among the embodiment 6, other is operated with embodiment 6.Reaction result is listed in table 2.
Embodiment 10
Except that the ammonium dichromate consumption was 39.7mg, other was operated with embodiment 6.Reaction result is listed in table 2.
Embodiment 11
Except that the ammonium dichromate consumption was 99.3mg, other was operated with embodiment 6.Reaction result is listed in table 2.
Comparative example 3
Except that without the ammonium dichromate, other is operated with embodiment 6.Reaction result is listed in table 2.
Comparative example 4
Remove with 316.6mg triphenylphosphine (molecular formula: (C 6H 5) 3P, Beijing Chemical Plant's product) replace outside the ammonium dichromate among the embodiment 6, other is operated with embodiment 6.Reaction result is listed in table 2.
Comparative example 5
Except that (the molecular formula: (C of seeing with the oxidation of 335.8mg triphenyl 6H 5) 3PO, Beijing Chemical Plant's product) replace outside the ammonium dichromate among the embodiment 6, other is operated with embodiment 6.Reaction result is listed in table 2.
Embodiment 12
Remove with 8 ml (5.720g) 2,4,4-trimethylammonium-2-amylene (molecular formula: C 8H 16, Belgian ACROS Chemicals company product) replace outside the 1-octene among the embodiment 4, other is operated with embodiment 4.Reaction result is listed in table 3.
Embodiment 13
Remove with 8ml (5.720g) 2,4, outside the 1-octene among 4-trimethylammonium-2-amylene replacement embodiment 5, other is operated with embodiment 5.Reaction result is listed in table 3.
Embodiment 14
Remove with 8ml (6.000g) 1-laurylene (molecular formula: C 12H 24, Belgian ACROS Chemicals company product) and replace 1-octene and dimerization acetic acid rhodium ([Rh (CH among the embodiment 2 3COO) 2] 2) usage quantity is 1.1mg, ammonium molybdate ((NH 4) 6Mo 7O 244H 2O) usage quantity is outside the 5.1mg, and other is operated with embodiment 2.Reaction result is listed in table 3.
Comparative example 6
Except that without the ammonium dichromate, other is operated with embodiment 12.Reaction result is listed in table 3.
Comparative example 7
Except that the ammonium dichromate that replaces with the 9.5mg triphenylphosphine among the embodiment 12, other is operated with embodiment 12.Reaction result is listed in table 3.
Comparative example 8
Except that without the ammonium molybdate, other is operated with embodiment 14.Reaction result is listed in table 3.
Comparative example 9
Except that the ammonium molybdate that replaces with the 6.6mg triphenylphosphine among the embodiment 14, other is operated with embodiment 14.Reaction result is listed in table 3.
Embodiment 15
All operations is with embodiment 7, and reaction result is listed in table 4.(reaction solution that embodiment 15 obtains is used for the underpressure distillation of following embodiment 16, and the catalyzer of recovery is used further to reaction.)
Embodiment 16
The reaction solution that embodiment 15 is obtained places the 100mL distilling flask to carry out underpressure distillation, and the tower top temperature of control distillation earlier is that temperature is that 80～90 ℃ and vacuum tightness are 20～30mmHg at the bottom of 40～45 ℃, still, unreacted raw material olefin from cat head distillation recovery; Control distillation tower top temperature is that temperature is that 110～120 ℃ and vacuum tightness are 5～10mmHg at the bottom of 65～70 ℃, still again, and product aldehyde is reclaimed from the cat head distillation.The catalyst recovery in (distilling flask) at the bottom of the still and be added in the autoclave, except not adding in addition dimerization acetic acid rhodium and the ammonium molybdate, other are operated with embodiment 7.Reaction result is listed in table 4.
Embodiment 17
The reaction solution that embodiment 16 is obtained carries out underpressure distillation (method is with embodiment 16), and the catalyzer of recovery is added in the autoclave, and except not adding in addition dimerization acetic acid rhodium and the ammonium molybdate, other are operated with embodiment 7.Reaction result is listed in table 4.
Table 1
The reaction example Rhodium compound (mg) Inorganic ammonium salt ( The ammonium rhodium compares N Alkene (g) Temperature (℃) Pressure (MPa) Time (2.5) Conversion of olefines (%) Aldehyde yield (%)
Embodiment 1 ?Rh-ac (1.6) Cr-2 (4.5) 7/1 ?1-C8 (5.720) 80 ?8.0 ?2.5 ?82 ?81
Embodiment 2 ?Rh-ac (1.6) Mo (7.4) 7/1 ?1-C8 (5.720) 80 ?8.0 ?2.5 ?65 ?65
Embodiment 3 ?Rh-ac (1.6) W (11.6) 7/1 ?1-C8 (5.720) 80 ?8.0 ?2.5 ?62 ?62
Embodiment 4 ?Rh-ac (1.6) Cr-2 (4.5) 7/1 ?1-C8 (5.720) 140 ?8.0 ?2.5 ?92 ?92
Embodiment 5 Rh-ac (1.6) Mo (7.4) 7/1 ?1-C8 (5.720) 140 ?8.0 ?2?5 ?91 ?90
Comparative example 1 ?Rh-ac (1.6) Do not have ?- 1-C8 (5.720) 80 ?8.0 ?2.5 ?58 ?58
Comparative example 2 ?Rh-ac (1.6) Do not have ?- 1-C8 (5.720) 140 ?8.0 ?2.5 ?87 ?87
Rhodium compound Rh-ac: dimerization acetic acid rhodium ([Rh (CH 3COO) 2] 2);
Inorganic ammonium Cr-2: ammonium dichromate ((NH 4) 2Cr 2O 7);
Inorganic ammonium Mo: ammonium molybdate ((NH 4) 6Mo 7O 244H 2O);
Inorganic ammonium W: ammonium tungstate ((NH 4) 5[H 7(WO 4) 6] H 2O);
The 1-C8:1-octene;
Table 2
The reaction example Rhodium compound (mg) Inorganic ammonium salt part (mg) Ammonium rhodium ratio Alkene (g) Temperature (℃) Pressure (MPa) Time (2.5) Alkene changes (%) Aldehyde yield (%)
Embodiment 6 ?Rh-ac (5.8) Cr-2 (23.2) 7/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?67 ?66
Embodiment 7 ?Rh-ac (5.8) Mo (37.8) 7/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?63 ?62
Embodiment 8 ?Rh-ac (5.8) W (269.6) 7/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?65 ?63
Embodiment 9 ?Rh-ac (5.8) Cr-1 (13.8) 7/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?59 ?57
Embodiment 10 ?Rh-ac (5.8) Cr-2 (39.7) 12/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?61 ?60
Embodiment 11 ?Rh-ac (5.8) Cr-2 (99.3) 30/1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?61 ?60
Comparative example 3 ?Rh-ac (5.8) Do not have ?- m-C8 (21.450) 140 ?8.0 ?2.5 ?51 ?50
Comparative example 4 ?Rh-ac (5.8) (C 6H 5) 3P (316.6) ?- m-C8 (21.450) 140 ?8.0 ?2.5 ?52 ?50
Comparative example 5 ?Rh-ac (5.8) (C 6H 5) 3PO (335.8) ?- m-C8 (21.450) 140 ?8.0 ?2.5 ?65 ?64
Rhodium compound Rh-ac: dimerization acetic acid rhodium ([Rh (CH 3COO) 2] 2);
Inorganic ammonium Cr-2: ammonium dichromate ((NH 4) 2Cr 2O 7);
Inorganic ammonium Mo: ammonium molybdate ((NH 4) 6Mo 7O 244H 2O);
Inorganic ammonium W: ammonium tungstate ((NH 4) 5[H 7(WO 4) 6] H 2O);
Inorganic ammonium Cr-1: ammonium chromate ((NH 4) 2CrO 4);
M-C8: mixed octene
Table 3
The reaction example Rhodium compound (mg) Inorganic ammonium salt or phosphine part (mg) The ammonium rhodium compares N/Rh Alkene (g) Temperature (℃) Pressure (MPa) Time (2.5) Olefin conversion (%) Aldehyde yield (%)
Embodiment 12 ?Rh-ac (1.6) Cr-2 (4.5) 7/1 ?in-C8 (5.720) 140 ?8.0 ?2.5 ?44 ?43
Embodiment 13 ?Rh-ac (1.6) Mo (7.4) 7/1 ?in-C8 (5.720) 140 ?8.0 ?2.5 ?33 ?33
Embodiment 14 ?Rh-ac (1.1) Mo (5.1) 7/1 ?1-C12 (6.000) 80 ?8.0 ?2.5 ?62 ?61
Comparative example 6 ?Rh-ac (1.6) Do not have 7/1 ?in-C8 (5.720) 140 ?8.0 ?2.5 ?30 ?29
Comparative example 7 ?Rh-ac (1.6) (C 6H 5) 3P (9.5) ?- in-C8 (5.720) 140 ?8.0 ?2.5 ?4 ?4
Comparative example 8 ?Rh-ac (1.1) Do not have ?- 1-C12 (6.000) 80 ?8?0 ?2.5 ?42 ?41
Comparative example 9 ?Rh-ac (1.1) (C 6H 5) 3P(6?6) ?- 1-C12 (6.000) 80 ?8.0 ?2.5 ?51 ?43
Rhodium compound Rh-ac: dimerization acetic acid rhodium ([Rh (CH 3COO) 2] 2);
Inorganic ammonium Cr-2: ammonium dichromate ((NH 4) 2Cr 2O 7);
Inorganic ammonium Mo: ammonium molybdate ((NH 4) 6Mo 7O 244H 2O);
In-C8:2,4,4-trimethylammonium-2-amylene
The 1-C12:1-laurylene
Table 4
The reaction example Rhodium compound (mg) Inorganic ammonium salt (mg) Cycle index Alkene (g) Temperature (℃) Pressure (MPa) Time (2.5) Olefin conversion (%) Aldehyde yield (%)
Embodiment 15 ?Rh-ac (5.8) Mo (37.8) 0 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?59 ?57
Embodiment 16 ?- ?- ?1 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?56 ?53
Embodiment 17 ?- ?- ?2 ?m-C8 (21.450) 140 ?8.0 ?2.5 ?61 ?55
Rhodium compound Rh-ac: dimerization acetic acid rhodium ([Rh (CH 3COO) 2] 2);
Inorganic ammonium Mo: ammonium molybdate ((NH 4) 6Mo 7O 244H 2O);
M-C8: mixed octene

Claims (4)

1、一种从烯烃、一氧化碳和氢气合成醛的方法，其特征在于，该方法包括以下各步骤：1. A method for synthesizing aldehydes from olefins, carbon monoxide and hydrogen, characterized in that the method comprises the following steps: (1)在反应釜中，加入铑化合物、无机铵盐和烯烃，其中无机铵盐与铑化合物的比例为：按铵盐中的N与铑化合物中的Rh的原子比N∶Rh=7～30∶1；烯烃与铑化合物的比例为1.0×10-3～1.0mg铑金属/1mL烯烃；(1) In the reactor, add rhodium compound, inorganic ammonium salt and olefin, wherein the ratio of inorganic ammonium salt and rhodium compound is: press the atomic ratio of N in the ammonium salt and Rh in the rhodium compound N: Rh=7～ 30:1; the ratio of olefin to rhodium compound is 1.0×10 -3 ~1.0mg rhodium metal/1mL olefin; (2)反应釜密闭后置于加热炉中，用CO∶H2=1∶1的合成气置换反应釜中的空气后，在常压下将反应釜加热至反应温度60～160℃；(2) The reaction kettle is sealed and placed in a heating furnace, and the air in the reaction kettle is replaced with CO:H 2 =1:1 synthesis gas, and the reaction kettle is heated to a reaction temperature of 60-160°C under normal pressure; (3)在60～160℃的反应温度下，向反应釜充入CO∶H2=1∶1的合成气至反应压力为6～12MPa，在反应温度和反应压力下、搅拌反应2～6小时，在反应过程中，连续供給合成气并维持反应压力稳定；(3) At a reaction temperature of 60-160°C, fill the reaction vessel with CO:H 2 =1:1 synthesis gas until the reaction pressure is 6-12 MPa, and stir the reaction for 2-6 hours at the reaction temperature and reaction pressure. Hours, during the reaction, continuously supply synthesis gas and keep the reaction pressure stable; (4)反应结束后，使反应釜冷却至室温，压力泄至常压，将反应液进行减压蒸馏，即得到本发明的产物醛。(4) After the reaction finishes, the reactor is cooled to room temperature, the pressure is released to normal pressure, and the reaction solution is subjected to vacuum distillation to obtain the product aldehyde of the present invention. 2、如权利要求1所述的方法，其特征在于，其中所述的铑化合物为二聚醋酸铑。2. The method of claim 1, wherein said rhodium compound is rhodium diacetate. 3、如权利要求1所述的方法，其特征在于，其中所述的无机铵盐为重铬酸铵、铬酸铵、钼酸铵和钨酸铵。3. The method according to claim 1, wherein said inorganic ammonium salt is ammonium dichromate, ammonium chromate, ammonium molybdate and ammonium tungstate. 4、如权利要求1所述的方法，其特征在于，其中所述的烯烃为含8-12个碳原子、一般式为R1R2-C=C-R3R4的烯烃，其中R1，R2，R3，R4为直链或支链烷基或氢原子。4. The method according to claim 1, wherein said olefin is an olefin containing 8-12 carbon atoms and having a general formula of R 1 R 2 -C=CR 3 R 4 , wherein R 1 , R 2 , R 3 , and R 4 are linear or branched alkyl groups or hydrogen atoms.
CN00128279A 2000-12-15 2000-12-15 Process for synthesizing aldehyde from olefine, CO and hydrogen Expired - Fee Related CN1123557C (en)

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CN114539090A (en) * 2020-11-24 2022-05-27 中国科学院大连化学物理研究所 Method for preparing primary amide by heterogeneous catalysis of inorganic ammonium salt and olefin
CN114920643A (en) * 2022-04-27 2022-08-19 华东师范大学 Method for preparing 4-acetoxy butyraldehyde from allyl acetate

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KR102771291B1 (en) 2020-07-30 2025-02-24 주식회사 엘지화학 Hydroformylation process
CN115007180A (en) * 2022-06-21 2022-09-06 烟台大学 A kind of highly dispersed rhodium catalyst for olefin hydroformylation reaction, its preparation method and use

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CN114539090A (en) * 2020-11-24 2022-05-27 中国科学院大连化学物理研究所 Method for preparing primary amide by heterogeneous catalysis of inorganic ammonium salt and olefin
CN114539090B (en) * 2020-11-24 2023-08-22 中国科学院大连化学物理研究所 Method for preparing primary amide by heterogeneous catalysis of inorganic ammonium salt and olefin
CN114920643A (en) * 2022-04-27 2022-08-19 华东师范大学 Method for preparing 4-acetoxy butyraldehyde from allyl acetate

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