CN1297680A - Insect growth regulator - Google Patents
Insect growth regulator Download PDFInfo
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- CN1297680A CN1297680A CN 99125100 CN99125100A CN1297680A CN 1297680 A CN1297680 A CN 1297680A CN 99125100 CN99125100 CN 99125100 CN 99125100 A CN99125100 A CN 99125100A CN 1297680 A CN1297680 A CN 1297680A
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- growth regulator
- insect growth
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Abstract
The insect growth regulator is prepared by using cyromazine, as one insect growth regulator, as well as buprofezin, imidacloprid, nicotine and abmetin as effective components and adding proper amount of surfactant, dispersant, wetter and other additive. It has the features of high efficiency, wide insecticidal spectrum, fast effect, fast degradation, no residue, small use amount and low cost. It is suitable for use in crop to prevent and control plant hopper, mite, cabbage butterfly, cabbage caterpillar, etc., and it may be also used as additive for domestic animals to prevent and eliminate larvas of fly and mosquito in droppings of domestic animals. It has no negative effect on crop, domestic animal and environment.
Description
The invention belongs to chemical pesticide, relate to a kind of insect growth regulator, IGR composition, relating in particular to a kind of is the composition of active ingredient with Buprofezin, Imidacloprid, nicotine, Avermectin respectively with triazines insect growth regulator, IGR fly eradication amine.
Disease in the agricultural production, worm, grass, mouse four big harm are still threatening vast farmland at present; and the production and the development of agricultural chemicals at present; strictness has been subjected to environment and ecological restriction; for environment and the agricultural sustainable development of protecting the mankind to depend on for existence; exploitation is efficient, the environmental protection type agricultural chemical of low toxicity, low using dosage, nuisanceless, easy degraded, noresidue, has become the new problem of pesticide industry.
The triazines insect growth regulator, IGR is inhaled conduction in having, this medicament can make dipteral insect and larva distortion take place or sprout wings not cause death entirely on form, especially Americal rice leaf miner is had special efficacy.This medicament is applicable to that vegetables, fruit, crop etc. prevent and kill off the fly class of diving, Diptera pest.But because the shortcoming that fly eradication amine list agent insecticidal spectrum is narrow, drug effect is single, cost is high has been brought inconvenience in the middle of producing use.
The purpose of this invention is to provide a kind of complex preparation that contains fly eradication amine, enlarged the insecticidal spectrum of former fly eradication amine, and dosage capable of reducing using, reduce cost, to satisfy market demand.
Insect growth regulator, IGR composition of the present invention is to be active ingredient with Buprofezin, Imidacloprid, nicotine, Avermectin respectively with triazines insect growth regulator, IGR fly eradication amine, and adds Compound Machining such as an amount of surfactant, diffusant, wetting agent and form.
Insect growth regulator, IGR composition of the present invention, contain:
A. triazines insect growth regulator, IGR fly eradication amine, chemical name: N-cyclopropyl-1,2,3-triazine-2,4, the 6-triamine is characterized in that also containing in the said composition one of following four kinds of materials:
B. Buprofezin, chemical name: 2-spy-1-fourth imido grpup-3-isopropyl-5-phenyl-3,4,5,6-tetrahydrochysene-2H-1,3,5-thiadiazine-4-ketone
C. Imidacloprid, chemical name: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine
D. nicotine, chemical name: (S)-3-(1-methyl-2-pyrrolidinyl) pyridine
E. Avermectin has another name called shepherd's purse mite element;
Their content in composite formula is (ratio of weight and number):
A. fly eradication amine: 0.1-100 part
B. Buprofezin: 1-100 part
C. Imidacloprid: 0.1-100 part
D. nicotine: 0.01-50 part
E. Avermectin: 0.01-50 part
Also contain surfactant, diffusant, wetting agent and solid in the composition of the present invention
The body filler, their content in composite formula is (ratio of weight and number):
Surfactant: 1-10 part
Wetting agent: 0.1-5 part
Diffusant: 1-10 part
Solid packing: 1-50 part
Surfactant is one or more in alpha-alkene sulfonate, higher alcohol sulfate, APEO, polyoxyethylene oleate, polyoxyethylene oleoyl ether, PEP-101, polyoxyethylene fatty acid ester, the Arlacel-80.
Diffusant is one or more in sodium lignin sulfonate, lauryl sodium sulfate, benzyl naphthalene sodium sulfonate, novalgin, the sodium metnylene bis-naphthalene sulfonate.
Wetting agent is one or more in alkyl phosphoric acid sodium, alkyl butyric acid sulfonate, lauryl sodium sulfate, dodecyl sodium sulfate, neopelex, the disconnected thing of polyoxyethylene polyoxypropylene embedding.
Solid packing is one or more in kaolin, talcum powder, potter's clay, diatomite, bentonite, the silica.
The production method of complex composition of the present invention is: earlier with active component and surfactant, wetting agent, diffusant and filler, fully mix in proportion, be crushed to 44 μ m then, obtain bulky powder shape preparation, be packaged into product then.
Preparation of the present invention can be wetting powder, granule, fine granule, suspension emulsion or missible oil, water-dispersion type granula, tablet, and wherein active component content is that 50% wetting powder is best.
Its application method of preparation of the present invention is: crops adopt basic leaf to handle spray-on process; Fowl, animal are adopted the body surface spray-on process.
Complex composition of the present invention has following beneficial effect:
1. enlarged insecticidal spectrum:
Fly eradication amine list agent insecticidal spectrum is narrow, as the present invention carry out composite after, insecticidal spectrum greatly enlarges:
1), fly eradication amine+Buprofezin
This complex preparation has special efficacy to diptera, coleoptera, Semiptera, Delphacidae, Cicadellidae, is applicable to insects such as preventing and kill off lice section, Pseudococcidae, rice fulgorid, value a red-spotted lizard on the crops such as paddy rice, potato, citrus, cotton.
2), fly eradication amine+Imidacloprid
Inhale the selectivity insect growth regulator, IGR in this complex preparation belongs to, can destroy the nervous centralis normal conduction of insect and cause neural paralysis death.Be applicable to crops such as corn, wheat, paddy rice, cotton, beet, fruit tree, insects such as plant hopper, thrips, snout moth's larva, aphid.
3), fly eradication amine+nicotine
This complex preparation can be widely used on the crops such as vegetables, tealeaves, fruit, watermelon, strawberry, prevents and kill off various insects such as pickles pretty young woman, cabbage caterpillar, aphid, two spotted spider mite, cotton bollworm, Americal rice leaf miner, belongs to environment friendly agricultural nuisanceless, noresidue.
4), fly eradication amine+Avermectin
This complex preparation can be widely used in tobacco, vegetables, broad bean, cotton, ornamental plants etc., can prevent and treat cotton bollworm, oriental tobacco budworm, cabbage caterpillar, pickles pretty young woman, beet pretty young woman at night, leaf mining pretty young woman, liriomyza bryoniae, aphid, wood louse, tetranychid.Also can be used for domestic animal, pet, ox, sheep appearance and colony house, insects such as fly, mosquito, flea are prevented and kill off in spraying, and are as safe as a house to the people, animal environment.
2. using dosage reduces: than single agent, using dosage can reduce about 1/3.
3. cost reduces: than single agent, cost can reduce about 30%.
4. insecticidal effect is remarkable:
With fly eradication amine carry out composite after, the more single agent of insecticidal effect improves a lot, and specifically sees Table one～table four.
Below be embodiments of the invention.
Embodiment 1:
Each composition weight umber is:
1 part of fly eradication amine
2 parts of Buprofezins
1 part of sodium lignin sulfonate
2 parts in polyoxyethylene oleoyl ether
0.8 part of lauryl sodium sulfate
10 parts of silica
25 parts in diatomite
44 μ m are fully mixed, are crushed to above component in proportion, be packaged into product then.
Embodiment 2:
2 parts of fly eradication amine
3 parts of Imidacloprids
1 part of sodium lignin sulfonate
5 parts of Arlacel-80s
2 parts of neopelexes
10 parts of bentonites
10 parts of embodiment 3 of potter's clay:
2 parts of fly eradication amine
3 parts in nicotine
3 parts of novalgins
10 parts of OPEOs
5 parts in butyl phosphoric acid sodium
10 parts of kaolin
5 parts of silica
Embodiment 4:
10 parts of fly eradication amine
1 part of Avermectin
8 parts of alpha-butylene sodium sulfonates
6 parts of sodium metnylene bis-naphthalene sulfonates
3 parts of the disconnected things of polyoxyethylene polyoxypropylene embedding
5 parts of talcum powder
5 parts in diatomite
Table one
Cyromazine+buprofezin control rice grub effectiveness unit that is mixed: Wenzhou District of Zhejiang Province aggie on July 13rd, 98
| Test is processed | Every 667m2Dosage (gai) | Radix before the dispenser (only/100 clumps) | Behind the medicine planthopper is proofreaied and correct preventive effect (%) | Radix before the dispenser (head/100 clump) | Behind the medicine leaf-roller is proofreaied and correct preventive effect (%) | |||||||
| 1 day | 3 days | 5 days | 8 days | 12 days | 21 days | 31 days | 5 days | Relatively protect leaf | ||||
| 50% goes out pounces on WP | 4 | 9226.7 | 84.6aA | 93.0aA | 91.8aA | 84.4aA | 97.7aA | 97.1 | 94.4 | 93.3 | 92.4 | 72.4 |
| 50% goes out pounces on WP | 4.5 | 10500 | 89.9aA | 95.3bA | 94.4aA | 92.6aA | 98.6aA | 98.1 | 97.2 | 126.7 | 94.4 | 69.5 |
| 50% goes out pounces on WP | 5 | 10686.7 | 91.2aA | 96.5bA | 96.1aA | 95.2aA | 98.9aA | 99.0 | 98.1 | 116.7 | 96.4 | 71.4 |
| Buprofezin | 5 | 11246.7 | 44.56B | 70.0cB | 80.3aA | 80.4aA | 95.1aA | 83.1 | 88.3 | 123.3 | 93.2 | 72.4 |
| Blank | 10073.3 | 15260 | 17433.3 | 15046.7 | 8633.3 | 5753.3 | 2090 | 3626.7 | 126.7 | 300 | 350 | |
Annotate: same letter represents that the difference on P=0.05,0.01 level is not remarkable in the table.
Table two
The 50% pyrrole WP control pear tree pear sucker effectiveness unit of going out: the high Mi County in Shandong fruit tree field on May 20th, 98
| (effective ingredient doubly) processed in test | Investigation strain number | The investigation number of sheets | Radix before the medicine | Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | Behind the medicine 14 days | ||||||||
| Preventive effect % | Significance test | Preventive effect % | Significance test | Preventive effect % | Significance test | Preventive effect % | Significance test | ||||||||
| 0.05 | 0.01 | 0.05 | 0.01 | 0.05 | 0.01 | 0.05 | 0.01 | ||||||||
| The 50% pyrrole WP4g/667m that goes out2 | 8 | 400 | 470 | 92.4 | a | AB | 91.5 | abc | AB | 94.9 | a | A | 86.8 | abc | AB |
| The 50% pyrrole WP4.5g/667m that goes out2 | 8 | 400 | 352 | 94.0 | a | AB | 95.7 | a | AB | 96.8 | a | A | 92.2 | ab | AB |
| The 50% pyrrole WP5g/667m that goes out2 | 8 | 400 | 506 | 93.6 | a | A | 95.1 | a | A | 98.0 | a | A | 96.3 | a | A |
| 300 times of 10% Imidacloprids | 8 | 400 | 410 | 89.4 | a b | AB | 86.5 | bc | AB | 92.6 | a | AB | 77.5 | bc | AB |
| Blank | 8 | 400 | 385 | - | - | - | - | - | - | - | - | - | - | - | - |
Table three
The 50% nicotine WP control broccoli cabbage caterpillar field control effectiveness test unit of going out: Taizhou City of Zhejiang Province plant protection unit on April 30th, 98
| (effective ingredient g/ mu) is processed in test | Insect population number (head) before anti- | Anti-rear 1 day | Anti-rear 3 days | Anti-rear 5 days | ||||||
| Borer population (head) alive | Insect population decline rate (%) | Preventive effect (%) | Borer population (head) alive | Insect population decline rate (%) | Preventive effect (%) | Borer population (head) alive | Insect population decline rate (%) | Preventive effect (%) | ||
| 50% cigarette 4.5 that goes out | 23.25 | 2.2 | 89.3 | 89.3 | 2 | 91.4 | 92 | 3 | 87.1 | 89.22 |
| 50% nicotine 5 that goes out | 31.75 | 2.7 | 92.3 | 92.3 | 1.8 | 94.33 | 94.7 | 2 | 93.7 | 94.74 |
| 50% nicotine 6 that goes out | 35.75 | 2 | 94.4 | 94.4 | 0 | 100 | 100 | 1.5 | 95.8 | 96.5 |
| 10% nicotine 6 | 22.5 | 3 | 86.39 | 86.39 | 2.5 | 88.75 | 89.44 | 6.25 | 72.34 | 76.88 |
| Blank | 29.00 | 29.00 | 0 | 30.50 | -6.56 | 34.00 | -19.65 | |||
Digital averaging is four repetition mean values in the table
Table four
The 50% indoor sheep hurdle of the A Wei WP control liriomyza bryoniae test report unit of going out: Kuitun city plant on July 4th, 98
| Test is processed | Extension rate (doubly) | Processed rear 2 days | Processed rear 5 days | Processed rear 10 days | ||||||
| Total borer population (head) | Borer population (head) alive | The death rate (%) | Total borer population (head) | Borer population (head) alive | The death rate (%) | Total borer population (head) | Borer population (head) alive | The death rate (%) | ||
| The 50% A Wei WP that goes out | 1500 times | 114 | 10 | 91.2 | 143 | 7 | 95.1 | 145 | 5 | 96.6 |
| 50% A Wei that goes out | 1000 times | 126 | 8 | 93.7 | 138 | 5 | 96.4 | 150 | 3 | 98 |
| 50% cyromazine | 1000 times | 109 | 12 | 89 | 125 | 10 | 92 | 130 | 15 | 88.76 |
| Blank | The spray clear water | 94 | 87 | 7.3 | 115 | 97 | 15.7 | 128 | 100 | 21.9 |
Claims (7)
1. insect growth regulator, IGR composition, contain:
A. triazines insect growth regulator, IGR fly eradication amine, chemical name: N-cyclopropyl-1,2,3-triazine-2,4, the 6-triamine is characterized in that also containing in the said composition one of following four kinds of materials:
B. Buprofezin, chemical name: 2-spy-1-fourth imido grpup-3-isopropyl-5-phenyl-3,4,5,6-tetrahydrochysene-2H-1,3,5-thiadiazine-4-ketone
C. Imidacloprid, chemical name: 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine
D. nicotine, chemical name: (S)-3-(1-methyl-2-pyrrolidinyl) pyridine
E. Avermectin has another name called shepherd's purse mite element;
Their content in composite formula is (ratio of weight and number):
A. fly eradication amine: 0.1-100 part
B. Buprofezin: 1-100 part
C. Imidacloprid: 0.1-100 part
D. nicotine: 0.01-50 part
E. Avermectin: 0.01-50 part
2. composition as claimed in claim 1, it is characterized in that also containing in the said composition surfactant, diffusant, wetting agent and solid packing, their content in composite formula is (ratio of weight and number): surfactant: 1-10 part wetting agent: 0.1-5 part diffusant: 1-10 part solid packing: 1-50 part.
3. composition as claimed in claim 2 is characterized in that surfactant is one or more in alpha-alkene sulfonate, higher alcohol sulfate, APEO, polyoxyethylene oleate, polyoxyethylene oleoyl ether, PEP-101, polyoxyethylene fatty acid ester, the Arlacel-80.
4. composition as claimed in claim 2 is characterized in that diffusant is one or more in lauryl sodium sulfate, benzyl naphthalene sodium sulfonate, novalgin, the sodium metnylene bis-naphthalene sulfonate.
5. composition as claimed in claim 2 is characterized in that wetting agent is one or more in alkyl phosphoric acid sodium, alkyl butyric acid sulfonate, lauryl sodium sulfate, dodecyl sodium sulfate, neopelex, the disconnected thing of polyoxyethylene polyoxypropylene embedding.
6. composition as claimed in claim 2 is characterized in that solid packing is one or more in kaolin, talcum powder, potter's clay, diatomite, bentonite, the silica.
7. composition as claimed in claim 2 is characterized in that said composition is wetting powder, granule, fine granule, suspension emulsion or missible oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99125100 CN1297680A (en) | 1999-11-29 | 1999-11-29 | Insect growth regulator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99125100 CN1297680A (en) | 1999-11-29 | 1999-11-29 | Insect growth regulator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1297680A true CN1297680A (en) | 2001-06-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99125100 Pending CN1297680A (en) | 1999-11-29 | 1999-11-29 | Insect growth regulator |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1297680A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007052256A2 (en) * | 2005-11-01 | 2007-05-10 | Makhteshim Chemical Works Ltd. | Pesticidal compositions and method for their preparation |
| EP1545542A4 (en) * | 2002-08-29 | 2009-04-22 | Piedmont Pharmaceuticals Llc | Methods for the control of insect pests |
| CN102283238A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Insecticidal composition containing imidacloprid and cyromazine |
| CN102405917A (en) * | 2011-11-29 | 2012-04-11 | 宁波蓝鼎电子科技有限公司 | Insecticidal composition |
| CN103416430A (en) * | 2012-05-24 | 2013-12-04 | 陕西汤普森生物科技有限公司 | Pesticide composition |
| CN106342868A (en) * | 2016-08-31 | 2017-01-25 | 吴齐仟 | Chemical prevention and control method of melanagromyza sojae of edible podded peas |
| WO2019005700A1 (en) * | 2017-06-26 | 2019-01-03 | Merial, Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
-
1999
- 1999-11-29 CN CN 99125100 patent/CN1297680A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1545542A4 (en) * | 2002-08-29 | 2009-04-22 | Piedmont Pharmaceuticals Llc | Methods for the control of insect pests |
| WO2007052256A2 (en) * | 2005-11-01 | 2007-05-10 | Makhteshim Chemical Works Ltd. | Pesticidal compositions and method for their preparation |
| WO2007052256A3 (en) * | 2005-11-01 | 2009-04-09 | Makhteshim Chem Works Ltd | Pesticidal compositions and method for their preparation |
| CN102283238A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Insecticidal composition containing imidacloprid and cyromazine |
| CN102405917A (en) * | 2011-11-29 | 2012-04-11 | 宁波蓝鼎电子科技有限公司 | Insecticidal composition |
| CN103416430A (en) * | 2012-05-24 | 2013-12-04 | 陕西汤普森生物科技有限公司 | Pesticide composition |
| CN103416430B (en) * | 2012-05-24 | 2016-01-13 | 陕西汤普森生物科技有限公司 | A kind of composition pesticide |
| CN106342868A (en) * | 2016-08-31 | 2017-01-25 | 吴齐仟 | Chemical prevention and control method of melanagromyza sojae of edible podded peas |
| WO2019005700A1 (en) * | 2017-06-26 | 2019-01-03 | Merial, Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
| US11147273B2 (en) | 2017-06-26 | 2021-10-19 | Boehringer Ingelheim Animal Health USA Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
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