CN1297004A - 颜料制剂 - Google Patents
颜料制剂 Download PDFInfo
- Publication number
- CN1297004A CN1297004A CN00128542A CN00128542A CN1297004A CN 1297004 A CN1297004 A CN 1297004A CN 00128542 A CN00128542 A CN 00128542A CN 00128542 A CN00128542 A CN 00128542A CN 1297004 A CN1297004 A CN 1297004A
- Authority
- CN
- China
- Prior art keywords
- pigment
- pigment preparation
- dust
- solvent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000049 pigment Substances 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title claims abstract description 50
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 238000001704 evaporation Methods 0.000 claims abstract description 8
- 230000008020 evaporation Effects 0.000 claims abstract description 8
- 239000003791 organic solvent mixture Substances 0.000 claims abstract description 6
- 239000002932 luster Substances 0.000 claims description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- 239000000428 dust Substances 0.000 claims description 11
- 229910052618 mica group Inorganic materials 0.000 claims description 11
- 239000010445 mica Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- 150000002632 lipids Chemical class 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000011877 solvent mixture Substances 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 230000009974 thixotropic effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000011521 glass Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000012856 packing Methods 0.000 description 8
- 238000013019 agitation Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- -1 sericite Chemical compound 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 229920000027 Valéron Polymers 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229940094522 laponite Drugs 0.000 description 2
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- OYPYHLHPFMMLSO-UHFFFAOYSA-N C(CCCCC)CCO[Si](OCC)(OCC)CCCCCCCCCC Chemical compound C(CCCCC)CCO[Si](OCC)(OCC)CCCCCCCCCC OYPYHLHPFMMLSO-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- GDKNTQLYMFFORS-UHFFFAOYSA-N [Na].[Si](O)(O)(O)O.[Mg].[Li] Chemical compound [Na].[Si](O)(O)(O)O.[Mg].[Li] GDKNTQLYMFFORS-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical class CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- QSMIRPHGIZUKQF-UHFFFAOYSA-N decoxy-decyl-diethoxysilane Chemical compound CCCCCCCCCCO[Si](OCC)(OCC)CCCCCCCCCC QSMIRPHGIZUKQF-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229960004232 linoleic acid Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical class [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
-
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Abstract
本发明涉及一种无粉尘、含溶剂的均匀颜料制剂,该制剂包括≥70%(重量)的一种或多种有效颜料,0.1—30%(重量)具有蒸发值(EN)为10—100且表面张力(ST)≤35mN/m的有机溶剂或溶剂混合物,并任选0—5%(重量)的表面活性物质。
Description
本发明涉及无粉尘、含溶剂的均匀颜料制剂及其应用，特别是用于印刷油墨中。
工业过程中往往不使用呈干粉形式的颜料，因为这些粉尘关系到车间的安全，从而导致对它提高了要求。此外，将粉末掺入塑料、底基涂料体系等经常伴随颜料粉末的附聚。因此，即使可能也往往很难实现将颜料均匀地分配到相应的基质中。
采用无粉尘的颜料制剂代替颜料粉末。这些制剂是- 具有低含湿量自由流动的着色粉末，例如，可从DE-A-41 39 993得知，- 具有较高含湿量的着色粉末，通常，由于它们的易流动性稠度也称之为糊剂，- 涂以用量为5-20％(重量)的亚烷基二醇烷基醚的珠光光泽颜料，可从US 5,234,496得知。
在工业上，糊剂可以代替干的或潮湿的粉末，只要它们符合下列一般条件：- 易流动性稠度- 很低的膨胀性- 很高的颜料含量
该制剂的组分应该是这样的，即该制剂与特定涂料体系的其它组分是高度相容的，且在掺入时易于均匀地分散。
除了与涂料体系的其它组分具有良好的相容性之外，颜料制剂还必须具有高度的稳定性，即它们必须既不趋向于相分离，又不会改变其总组成。在基于片晶形状颜料的颜料制剂情况下，上述要求是特别重要的，因为由于它们的松散结构势必会引起相分离。例如，通过将由珠光光泽颜料组成的粉末、溶剂和水糊化而得到的含溶剂颜料制剂往往缺乏稳定性，各组分会相互分离且装填物的上部区域会变干。
含有过量挥发物例如低沸点有机溶剂的颜料制剂，通常有组成不稳定的缺点，这是由于该溶剂的挥发性所致。此外，由于珠光光泽颜料具有高表面张力因而难以用有机物质和溶剂润湿，由于这些颜料具有夹层结构因而尤其在表面上具有特别大量的孔隙，这些孔隙大部分也很难让液体物质接近(与常规的有机和无机的颜料比较)。
迄今，为用于涂料体系而开发的、颜料含量＞30(重量)和＜70％(重量)的含溶剂珠光光泽颜料制剂不完全符合上述要求，特别是由于它们趋向于剪切稠化。
因此，本发明的目的提供了一种含有至少70％(重量)有效(effect)颜料的自由流动颜料制剂。该制剂在贮存时具有高度稳定性，且具有与涂料体系的其它组分极好的相容性。
在印刷中特别关注的是，一旦施加了印刷油墨，必须非常迅速地释出其中所有的挥发性组分，以使干产物中没有可检测到的这些物质的气味(Robinson试验)。因此，务必确保蒸发值不超过某一上限。
已发现，采用本发明的颜料制剂可以达到上述目的。
因此，本发明提供了一种无粉尘、均匀的颜料制剂，该制剂包括- ≥70％(重量)的一种或多种有效颜料，- 0.1-30％(重量)具有蒸发值(EN)为10-100且表面张力(ST)≤35 mN/m的有机溶剂或溶剂混合物，并任选- 0-20％(重量)的表面活性物质。
本发明的制剂是一种取决于含湿量的自由流动粉末，该粉末特别适用于掺入印刷油墨。更具体而言，本发明的制剂可缩短将颜料搅拌进入印刷油墨所需的时间。此外，在将该制剂掺入水性印刷油墨体系时它可显著地减少起泡沫的问题。本发明的颜料制剂同样具有在着色的印刷油墨中更迅速达到“最终粘度”的效果。这样着色了的印刷油墨在贮存时是稳定的，而且特别易于再分散。
本发明的颜料制剂在贮存时同样是稳定的，且在贮存罐中不会分离或使组成变化。
本发明的颜料制剂的基本成分是有效颜料，例如珠光光泽颜料、干扰色颜料、多层颜料、片晶状的金属氧化物，例如Fe2O3、TiO2、SiO2、Al2O3、用一种或多种金属氧化物和/或金属硫化物涂覆了的、全息颜料、基于片晶状基质的功能颜料以及本领域中的技术人员熟知的所有珠光颜料。
使用有机溶剂或溶剂混合物，优选采用酯、酮、醇、矿物油或芳族溶剂，可对有效颜料，特别是在具有高孔隙率的颜料例如珠光光泽颜料的情况下提供极好的润湿作用。
所用的珠光光泽颜料是基于片晶状、透明或半透明基质的颜料，该基质是例如由片状硅酸盐例如天然或合成云母、滑石、绢云母、高岭土组成的、由玻璃或其它硅酸盐材料组成的、由玻璃或石墨组成的，并以单层或逐层的方式涂以单独的或混合的有色或无色金属氧化物，例如TiO2、低价钛氧化物、钛的氧氮化物、Fe2O3、Fe3O4、SnO2、Cr2O3、ZnO、CuO、NiO以及其它金属氧化物。珠光光泽颜料例如可从以下德国专利和专利申请得知：14 67 468、19 59 998、20 09 566、22 14 454、22 15 191、22 44 298、23 13 331、25 22 572、31 37 808、31 37 809、31 51 343、31 51 354、31 51 355、32 11 602、32 35 017和P 38 42330且可从市场上买到，例如可按Iriodin商标从Merck KGaA，Darmstadt，Germany买到。特别优选的颜料制剂含有TiO2/云母、Fe2O3/云母和/或TiO2/Fe2O3云母颜料。
还优选涂覆了TiO2-和/或Fe2O3-的SiO2或Al2O3片晶。可以将SiO2片晶涂以一种或多种金属氧化物，如WO 93/08237(湿法化学涂覆)或DE-A 196 14 637(CVD法)中所述。涂覆了的Al2O3片晶例如可从EP 0 763573得知。
本发明的颜料制剂可以含一种或多种有效颜料。通常，采用至少两种不同的有效颜料会提供特殊的颜色和光泽效果。
本发明的颜料制剂优选含有≥70％(重量)、特别是≥80％(重量)的有效颜料。非常特别优选的是有效颜料含量大于85％(重量)的颜料制剂。优选采用一种或多种珠光光泽颜料。重量百分数均以糊化了的颜料制剂为基准。
用于本发明颜料制剂的有机溶剂，特别是如果该颜料制剂是用于印刷和包装时，可包括酯类、醇类、二元醇和三元醇类、酮类、多元醇类、矿物油类和/或芳族溶剂类。
所述的溶剂具有的蒸发值为10-100，以确保较快速地干燥，特别是在高速印刷机上印刷时。所用溶剂或溶剂混合物的蒸发值(EN)优选为12-40，特别是15-30(乙醚=1)，以确保快速干燥并使印刷品的气味减到最少。该溶剂的表面张力应为≤35mN/m，特别是≤30mN/m。
除了蒸发值之外，该溶剂应优选具有介电常数≥4，优选≥6。所用的溶剂或溶剂混合物的粘度通常为≤20厘泊、优选为≤5厘泊。
符合所述物理参数条件的溶剂是例如4-甲基-2-戊醇(EN=66；ST=22.7)、2-丁醇(EN=15;ST=23.3)、2,6-二甲基-4-庚酮(EN=48;ST=22.6)、乙酸1-甲氧基-2-丙酯(EN=34;ST=27.6)、二甲苯(EN=17.3;ST=28.7)、Aromatic 100*(芳族溶剂混合物)可从例如Eastman(EN=41.7;ST=29.0)得到(根据1992年11月Eastman,M-167R的技术数据表)。
亚烷基二醇烷基醚，例如乙二醇单丁醚(EN=160)、二甘醇正丁醚(EN=37.50)、丙二醇正丁醚(EN=156)作为用于现有技术US 5,234,496中的溶剂具有过高的蒸发值，因此不适用于本发明的糊剂。
将0-5％(重量)、优选0.01-3％(重量)、特别优选0.05-1％(重量)的润温剂或表面活性物质包含在本发明的颜料制剂中通常是可取的。实用的润湿剂具体是包含疏水性侧链例如还可含其它官能团的烷基硅烷、不饱和或饱和脂肪酸或含氟表面活性剂的润温剂。特别优选式(CnH2n+1)Si(OCmH2m+1)3的硅烷化合物作为表面活性物质，式中，n为1-30而m为1-10。适宜的硅烷化合物是例如正己基癸基三乙氧基硅烷和正辛基癸基三乙氧基硅烷(Si 116和Si 118，分别来自Degussa Hüls AG，Frankfurt,FRG)以及相应的氟代烷基硅烷。
实用的表面活性物质还包括饱和和不饱和的脂肪酸，例如己酸、辛酸、癸酸、月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、油酸、亚油酸及其混合物。
实用的表面活性剂具有较长的烷基链，它可以是单或多氟化的，且具有亲水的或亲有机质的首基，例如聚氧乙烯基、羧基或砜基。它们具有阳离子、非离子或阴离子的结构。特别采用的含氟表面活性剂是以商品名FLUORAD FC430和FC431(3 M生产)和BorchigolFT448(Borchers，Düsseldorf，Germany生产)销售的含氟表面活性剂。
该颜料制剂优选包括硅烷、表面活性剂或脂肪酸。该表面活性剂还可以是硅烷、脂肪酸和/或表面活性剂的混合物。
实用的表面活性物质还包括片状硅酸盐、特别是来自蒙脱石系列例如蒙脱石/贝得石系列的片状硅酸盐。所提及的蒙脱石类，由于它们显著的溶胀性是特别值得注意的。这些产品可以在市场上买到，例如Laporte UK或Südchemie，RFG以商品名Optigel CG在市场上按laponite的商标销售的一种合成硅酸锂镁钠(类似于锂蒙脱石)、膨润土，或tixogel PE，一种亲有机质的疏水性蒙脱石。但是，蛭石和伊利石系列的云母类硅酸盐及云母本身(白云母、金云母、黑云母)也是适宜的。决定性的标准是该片晶状颗粒的稠度及其在喷雾干燥过程中被消化的性能。
为了表面改性，也可以使用上述片状硅酸盐和已改性的片状硅酸盐的混合物。优选采用呈活性形式的片状硅酸盐，即，将硅酸盐分散在水中，使其转化为溶胶，随后进行喷雾干燥。
本发明的颜料制剂可以在其制备过程中或之后，将另一些常规添加剂例如消泡剂、润湿剂、抗沉降剂、流动活性剂、或摇溶剂添加到其中。这些添加剂都是印刷工业中的常规助剂，且在本发明颜料制剂中的含量可以为0-10％(重量)。
本发明的颜料制剂可以通过将溶剂和任选的其它添加剂同时或相继添加到有效颜料或有效颜料混合物中，然后，将所得混合物在混合设备特别是Dispermat中匀化而简单地制备。优选将该颜料作为初始进料引入，然后用少量溶剂将其糊化。
本发明的制剂可用于印刷、涂料和油漆领域中的涂料体系。该制剂特别优选用于任何衬底材料，例如金属如铁、钢、铝、铜、青铜、黄铜以及金属箔的装饰和/或保护，而且还可用于玻璃的金属镀覆表面、陶瓷和混凝土，以及用于木材例如家具、粘土、纺织品、纸张、包装材料例如塑料容器、薄膜或纸板，或其它材料。
因此，本发明还提供了该颜料制剂在例如油漆、涂料、印刷油墨和塑料配方中的应用。
以下非限制性实施例将对本发明作详细说明。
实施例
实施例1
将540克Iriodin123(具有粒度为5-20微米的TiO2云母颜料，Merck KGaA,Germany生产)作为初始进料引入，然后，在搅拌下添加60克乙酸1-甲氧基-2-丙酯(EN=34,ST=27.6)。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例2
将1020克涂覆了Fe2O3、粒度为5-40微米的SiO2片晶(Merck KGaA，Germany生产)作为初始进料引入，然后，在搅拌下添加180克2,6-二甲基-4-庚酮(EN=48,ST=22.6)。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例3
将540克Iriodin123(具有粒度为5-20微米的TiO2云母颜料，Merck KGaA,Germany生产)作为初始进料引入，然后，在搅拌下添加30克乙酸1-甲氧基-2-丙酯和30克2,6-二甲基-4-庚酮的1∶1混合物。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例4
将270克XirallicCrystal Silver(具有粒度为10-30微米的涂覆了TiO2的Al2O3片晶，Merck KGaA,Germany生产)作为初始进料引入，然后，在搅拌下添加30克2,6-二甲基-4-庚酮。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例5
将Paliocrom L 2000(涂覆了氧化铁的铝，粒度为10-36微米，BASF,Germany生产)作为初始进料引入，然后，在搅拌下添加60克乙酸1-甲氧基-2-丙酯(EN=34,ST=27.6)。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例6
将540克Iriodin123(具有粒度为5-20微米的TiO2云母颜料，Merck KGaA,FRG生产)作为初始进料引入，然后，在搅拌下添加60克乙酸1-甲氧基-2-丙酯和12克LaponiteRDS(天然片状硅酸盐，Laporte生产)。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
实施例7
将540克Iriodin123(具有粒度为5-20微米的TiO2云母颜料，Merck KGaA,FRG生产)作为初始进料引入，然后，在搅拌下添加60克乙酸1-甲氧基-2-丙酯和5克Byk 307(硅氧烷表面活性剂)。将该混合物匀化，然后将潮湿、均匀的产物放出并将其装入密封的玻璃瓶中。
Claims (9)
1．无粉尘、均匀的颜料制剂，其特征在于它包括- ≥70％(重量)的一种或多种有效颜料- 0.1-30％(重量)具有蒸发值(EN)为10-100且表面张力(ST)≤35mN/m的有机溶剂或溶剂混合物并任选- 0-5％(重量)的表面活性物质。
2．根据权利要求1的无粉尘、均匀的颜料制剂，其特征在于该有效颜料是珠光光泽颜料。
3．根据权利要求1或2的无粉尘、均匀的颜料制剂，其特征在于该珠光光泽颜料是涂覆了TiO2-和/或Fe2O3-的云母片晶。
4．根据权利要求1-3中任一项的无粉尘、均匀的颜料制剂，其特征在于该有机溶剂或溶剂混合物是酮、酯、醇、二元醇或三元醇、多元醇、矿物油或芳族溶剂。
5．根据权利要求1-4中任一项的无粉尘、均匀的颜料制剂，其特征在于该溶剂是乙酸1-甲氧基-2-丙酯。
6．根据权利要求1-5中任一项的无粉尘、均匀的颜料制剂，其特征在于该表面活性物质是含氟表面活性剂、硅氧烷表面活性剂、硅烷、片状硅酸盐或脂肪酸。
7．根据权利要求1-6中任一项的无粉尘、均匀的颜料制剂，其特征在于它还包括再分散剂。
8．根据权利要求1-7中任一项的无粉尘、均匀的颜料制剂，其特征在于它可以包括消泡剂、润湿剂、抗沉降剂、催干剂、和/或摇溶剂作为追加的组分。
9．根据权利要求1的颜料制剂在印刷品、印刷油墨、液体着色剂和塑料中的应用。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19955477.3 | 1999-11-18 | ||
| DE1999155477 DE19955477A1 (de) | 1999-11-18 | 1999-11-18 | Pigmentpräparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1297004A true CN1297004A (zh) | 2001-05-30 |
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ID=7929471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00128542A Pending CN1297004A (zh) | 1999-11-18 | 2000-11-17 | 颜料制剂 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6648956B1 (zh) |
| EP (1) | EP1101806A3 (zh) |
| JP (1) | JP2001181550A (zh) |
| CN (1) | CN1297004A (zh) |
| DE (1) | DE19955477A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057456A (zh) * | 2009-12-15 | 2017-08-18 | 道达尔炼油与销售部 | 非芳族溶剂混合物及制备方法及用于印刷墨和清漆的用途 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI292773B (en) * | 2001-05-09 | 2008-01-21 | Merck Patent Gmbh | Effect pigments based on coated glass flakes |
| US20050255999A1 (en) * | 2004-05-11 | 2005-11-17 | Appleton Papers Inc. | Faux metallic imaging thermally responsive record material |
| DE102005019431A1 (de) * | 2005-04-25 | 2006-10-26 | Eckart Gmbh & Co. Kg | Pulverförmige Perlglanzzusammensetzung, Verfahren zu deren Herstellung und deren Verwendung |
| US8052269B2 (en) * | 2007-01-30 | 2011-11-08 | Hewlett-Packard Development Company, L.P. | Jettable inks with reduced frothing |
| DE102009037323A1 (de) * | 2009-08-14 | 2011-02-17 | Eckart Gmbh | Tintenstrahldrucktinte enthaltend Effektpigmente mit hohem Glanz |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3840381A (en) * | 1968-03-28 | 1974-10-08 | Nikon Kogen Kogyo Co Ltd | Titanium coated pigments |
| US4154622A (en) * | 1977-06-21 | 1979-05-15 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Granular pigment composition |
| US5116664A (en) * | 1988-02-09 | 1992-05-26 | Shiseido Company Ltd. | Titanium-mica composite material |
| DE4120921A1 (de) * | 1991-06-25 | 1993-01-07 | Merck Patent Gmbh | Oberflaechenmodifizierte plaettchenfoermige substrate mit verbessertem absetz- und aufruehrverhalten |
| US5234496A (en) * | 1991-07-30 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Mica based pigments coated with alkylene glycol alkyl ether |
| DE4137860A1 (de) * | 1991-11-16 | 1993-05-19 | Merck Patent Gmbh | Interferenzpigmente |
| DE4446456A1 (de) * | 1994-12-27 | 1996-07-04 | Merck Patent Gmbh | Pigmentzubereitung und deren Verwendung |
| DE19708167A1 (de) * | 1997-02-28 | 1998-09-03 | Merck Patent Gmbh | Pigmentpräparation |
| GB9704992D0 (en) * | 1997-03-11 | 1997-04-30 | Eastman Kodak Co | Ink composition |
| EP0931112B1 (de) * | 1997-05-23 | 2003-01-08 | MERCK PATENT GmbH | Metalloxidbeschichtete titandioxidplättchen |
| EP0905204B1 (de) * | 1997-09-26 | 2002-11-20 | MERCK PATENT GmbH | Oberflächenmodifizierte plättchenförmige Substrate |
| US6129784A (en) * | 1997-09-30 | 2000-10-10 | Shiseido Co., Ltd. | Color titanated mica pigment and coated-body using the same |
| DE19813394A1 (de) * | 1998-03-26 | 1999-09-30 | Merck Patent Gmbh | Pigmentpräparation |
| DE19847169A1 (de) * | 1998-10-14 | 2000-04-20 | Merck Patent Gmbh | Pigmentpräparation |
| DE10023286A1 (de) * | 2000-05-12 | 2001-11-15 | Merck Patent Gmbh | Pigmentpräparation mit modifizierten Kolophoniumharzen |
-
1999
- 1999-11-18 DE DE1999155477 patent/DE19955477A1/de not_active Withdrawn
-
2000
- 2000-11-07 EP EP20000124092 patent/EP1101806A3/de not_active Withdrawn
- 2000-11-17 CN CN00128542A patent/CN1297004A/zh active Pending
- 2000-11-17 JP JP2000350710A patent/JP2001181550A/ja active Pending
- 2000-11-20 US US09/715,049 patent/US6648956B1/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057456A (zh) * | 2009-12-15 | 2017-08-18 | 道达尔炼油与销售部 | 非芳族溶剂混合物及制备方法及用于印刷墨和清漆的用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6648956B1 (en) | 2003-11-18 |
| DE19955477A1 (de) | 2001-05-23 |
| EP1101806A2 (de) | 2001-05-23 |
| EP1101806A3 (de) | 2001-09-12 |
| JP2001181550A (ja) | 2001-07-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |