CN1293029A - Aerosol device of hair dressing composition containing at least one siloxane/acrylate copolymer - Google Patents
Aerosol device of hair dressing composition containing at least one siloxane/acrylate copolymer Download PDFInfo
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- CN1293029A CN1293029A CN00128742A CN00128742A CN1293029A CN 1293029 A CN1293029 A CN 1293029A CN 00128742 A CN00128742 A CN 00128742A CN 00128742 A CN00128742 A CN 00128742A CN 1293029 A CN1293029 A CN 1293029A
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- Prior art keywords
- group
- acid
- ester
- vinyl
- ethyl
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
To provide an aerosol device containing a hair-treating cosmetic composition containing at least one kind of a specific silicone/acrylate copolymer and provide a beautifying hair-treating method using the aerosol device, especially a method for fixing and/or keeping the hair style.
Description
The present invention relates to a kind of aerosol device, this device contains the hair dressing composition that comprises at least a specific siloxane/acrylate copolymer.The present invention also relates to a kind of hair caring method, particularly by using this aerosol device to fix and/or keep a kind of method of hair style.
In the hair-dressing article of the most widely used molding and/or maintenance hair style, what can mention is a kind of spray composite on cosmetics market, and it basic composition is: a kind of solution, normally a kind of alcohol or aqueous solution; And one or more materials, being generally fluoropolymer resin, the effect of this fluoropolymer resin is to form bonding between hair; Also be well-known shaping material, be mixed with various cosmetic adjuvant.This solution can add with propellant usually to be depressed in the aerosol device of packing into, or in the pump pressure quantifier bottle of packing into.
Shaping material generally is a styling polymer, promptly can water-soluble and alcoholic acid film forming polymer, for example particularly at United States Patent (USP) 3,929,735 and 3, polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl acetate co-polymer, vinylacetate/.beta.-methylacrylic acid copolymer and anion or the amphoteric acrylic resin described in 770,683.Although these materials brush hold together or combing after be easy to the effect that obtains finalizing the design, common making under the bright and clean condition of hair surface, the hair outward appearance is hardened, and feels coarse even is clamminess, and after the drying powder is arranged in addition.
These shortcomings are relevant with Several Parameters, and this can mention in the character of styling polymer or cementing property.In order to overcome these shortcomings, therefore may two parameters work in this respect, if there are not this two parameters, can reduce desirable typing effect.In order to improve the cosmetic properties of shaping material, ad hoc proposal is mixed different polymer.(WO94／12148，WO96／06592，US5，158，762)。
The applicant has been found that at present, by selecting suitable styling polymer and propellant gas, might overcome top listed variety of issue, particularly obtain a kind of good atomization quality, such as droplet size and diffusibility, gratifying cosmetic properties and few powder.
A theme of the present invention is a kind of aerosol device, this aerosol device is made up of the container that a kind of aerosol composition is housed, this aerosol composition comprises the liquid phase (or fluid) that contains at least a shaping material that is dissolved in suitable solvent on the one hand, also comprise propellant on the other hand, and the process for dispersing of said aerosol composition, it is characterized in that:
(ⅰ) shaping material is a kind of siloxane/acrylate copolymer, and this polymer is to be obtained through the polymerization of free radical medium in the presence of at least a silicone derivative (b) that comprises oxyalkylene group by at least a vinyl unsaturated monomer (a),
(ⅱ) be selected from dimethyl ether, C
3-C
4Hydrocarbon, dimethyl ether and C
3-C
5The mixture of hydrocarbon, C
3-C
4The mixture of hydrocarbon and
(ⅲ) when propellant has only dimethyl ether, contain the aerosol composition of 10% above water.
Another theme of the present invention relates to a kind of hair caring method, particularly fixes and/or keep a kind of method of hair style with aerosol device.
As the siloxane/acrylate copolymer of target of the present invention, in International Patent Application WO 99/04750, be described especially.The copolymer of the called after Luviflex Silk that preferred BASF sells.This polymer is the graft copolymer of acrylic acid tertiary butyl ester/methacrylic acid and silicone copolyol (copolyol).
Preferably, the corresponding general formula (I of monomer (a)
a) be:
Wherein:
-X is selected from OH, OM, OR
8, NH
2, NHR
8Or N (R
8)
2
-M is selected from Na
+, K
+, Mg
++, NH
4+, alkylammonium, dialkyl ammonium, trialkyl ammonium and tetra-allkylammonium a kind of cation;
-radicals R
8Can be identical or different, be selected from hydrogen, linearity or side chain C
1-C
40Alkyl group, monobasic or multi-hydroxy C
1-C
40Alkyl, optional one or more alkoxyls, amino or carboxylic acid group, hydroxylating polyethers or the N, N '-dimethyl aminoethyl, 2-hydroxyethyl, 2-methoxy ethyl, 2-ethoxyethyl group, hydroxypropyl, methoxy-propyl or ethoxycarbonyl propyl group of being substituted with.
-radicals R
7And R
6Be selected from group independent of each other, this group is selected from the C of hydrogen, linearity or side chain
1-C
8Alkyl group, methoxyl group, ethyoxyl, 2-hydroxyl-oxethyl, 2-methoxy ethoxy and 2-ethoxyethyl group group, or CN, COOH or COOM group.
Particularly, the monomer (a) in the general formula (Ia) is acrylic acid and its salt, ester or amide.Ester can be a derivant, and this derivant is derived from linear C
1-C
40The C of alkyl, branching
3-C
40Alkyl or C
3-C
40Carboxylic acid alcohol, the multi-group alcohol of containing 2-8 hydroxyl such as ethylene glycol, hexanediol, glycerol and 1,2,6-hexanetriol, amino alcohol, or alcohol ether such as pure and mild ethoxy ethanol of methoxy methyl or polyalkylene glycols.
Monomer (a) in the general formula (Ia) also can be selected from acrylic acid N, N '-dialkyl amino Arrcostab, methacrylate, acryloyl N-dialkyl amino alkylamine, methacryl N-dialkyl amino alkylamine, wherein amide group can not be substituted, carried out list replacement or N by N-alkyl or N-alkyl amino, and the N-dialkyl amido carries out two replacements; Alkyl or alkyl amino can be derived from linear C
1～C
40Or side chain C
3～C
40The carboxyl unit.
Monomer (a) in the spendable general formula (Ia) also can be replaced for example methacrylic acid that may mention, ethylacrylic acid and 3-alpha-cyanoacrylate by the chemical compound of derived from propylene acid or its salt, ester or amide.
Other specially suitable monomers (a) are C
1～C
40Vinyl and allyl ester, linear C
3～C
40Carboxylic acid or C
3～C
40Carboxyl naphthenic acid, vinyl or allyl halide, vinyl lactam, preferred vinyl ketopyrrolidine and caprolactam; Heterocyclic compound by vinyl or pi-allyl replacement, optimal ethylene yl pyridines, second alkene oxazolin and allyl pyridine, N-vinyl imidazole, diallylamine, vinylidene chloride, carbochain unsaturated compound, for example styrene or isoprene, and with 3-chloro-1,2 epoxy prapane (chloropropylene oxide) quaternised acrylic or methacrylic acid derivative.
Other monomers (a) that can mention at last are N-vinyl imidazole, diallylamine, 1,1-dichloroethylene, carbochain unsaturated compound such as styrene and isoprene, and with 3-chloro-1,2 epoxy prapane (chloropropylene oxide) quaternised acrylic or methacrylic acid derivative.
Most preferred monomer (a) is: acrylic acid, methacrylic acid and ethylacrylic acid; Acrylic acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Methacrylic acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Ethyl propylene acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Acrylic acid-2,3-dihydroxypropyl ester; Methacrylic acid 2,3-dihydroxypropyl ester; Acrylic acid-2-dihydroxy ethyl ester; The acrylic acid hydroxy-propyl ester; Methacrylic acid 2-hydroxyethyl ester; Ethylacrylic acid-2-hydroxyethyl ester; Acrylic acid-2-methoxy ethyl ester; Methacrylic acid-2-ethoxyethyl group ester; Ethylacrylic acid-2-ethoxyethyl group ester; Methacrylic acid hydroxyl propyl diester; Single acrylic acid glyceride; Monomethyl acrylic acid glyceride; Poly-(methyl) acrylic acid alkylidene diol ester; Unsaturated sulfonic acid; Acrylamide, Methacrylamide, ethyl acrylamide, N, N-DMAA, N-ethyl acrylamide, N-ethyl-methyl acrylamide, 1-vinyl-imidazoles, (methyl) acrylic acid N, N-dimethylamino ethyl ester, maleic acid, fumaric acid, maleic anhydride and its monoesters .beta.-methylacrylic acid, methylene-succinic acid, vinyl ethers, vinyl formamide, vinyl amine, vinylpyridine, vinyl imidazole, vinyl furan, styrene, styryl sulphonic acid ester and allyl alcohol and their mixture.
Monomer (a) also can comprise silicon or fluorine atom or other thio groups.Monomer (a) is if contain that acidic-group can partly be neutralized or all neutralizations, and N-process can realize before or after polyreaction, and purpose is to be adjusted at the level that dissolubility in the water or dispersion reach hope.The reagent that can be used for neutralization has inorganic base, for example sodium carbonate; With organic base such as amino alcohol, for example alkanolamine such as methyl hydramine, 2-amino-2-methyl-1-propanol or triethanolamine reach diamidogen as 2, the 6-diaminocaproic acid.
When monomer (a) when comprising basic nitrogen atom, also can be by quaternized.If they contain two ethylene double bonds at least, monomer (a) can partly be crosslinked.
Silicone derivative (b) particularly known dimethyl silicone copolyol or silicone surfactant chemical compound with the name of INCI nomenclature.That particularly point out is Abil with the Goldschmidt company of trademark naming
, Rh ne-Poulenc company Alkasil
, Genesee company the silicone copolyol copolymer
, Wacker company Besil
, OSI company Silwet
Or the Dow Corning190 of Dow Corning company
Preferred silicone derivative (b) has following general formula I:
In its formula of (I):
-R
2Be selected from CH
3Or following group:
-R
3Be selected from CH
3And radicals R
2-R
4Be selected from hydrogen, CH
3With following group:
-R
6Be a kind of C that can comprise amino, carboxyl or sulfonate ester group
1～C
40Organic group, if C=0, R
6It is the anion of mineral acid;
-radicals R
1Can be identical or different, be selected from C
1～C
20Aliphatic hydrocarbon, C
3～C
20Aliphatic or annular aliphatic hydrocarbon, and radicals R
5Corresponding general formula is as follows:
-n is 1～6 integer,
-X and Y are integers, and it makes the polysiloxane molecule amount is 300～30,000,
-a and b be 0～50 integer and
-c is 0 or 1
R
1Preferably certainly: methyl, ethyl, propyl group, butyl, isobutyl group, amyl group, isopentyl, hexyl, octyl group, decyl dodecyl and eicosyl; Cyclic aliphatic group, particularly cyclohexyl group; Aromatic group, particularly phenyl or naphthyl group; And fragrance and aliphatic group mixture, for example benzyl and phenethyl, and tolyl and xylyl.
Preferred R
4Group is that those contain general formula and are-(CO) C-R
6Group, R
6Be to contain 1～4 carbon atom alkyl, cycloalkyl or aryl, wherein can contain other groups such as NH on the carbon atom
2, COOH and/or SO
3The H group.
Preferred R
6Phosphate when group is c=0 or sulfate.
Silicone derivative (b) especially preferably has those derivants of following general formula:
The relative scale of derivant in copolymer (b) is 0.1wt%～50wt% normally, preferred 1wt%～20wt%.
Preferred copolymer is water miscible siloxane/acrylate copolymer, or the following copolymer of those water dispersibles: in volume ratio was water/alcohol mixture of 50/50, they can the dissolving ratio be more than above, the preferred 0.2g/l of 0.1g/l.Advantageously, the compositions among the present invention is a benchmark with relative weight percent, comprises 0.1～20% siloxane/acrylate copolymer and further preferred 0.5～10% this copolymer.Favourable aerosol device comprises 10～90% propellant, preferred 20～70% propellant.
According to first advantageous embodiment of apparatus of the present invention, propellant is a dimethyl ether, and the concentration range that in aerosol device, contains this propellant be 30～60% o'clock be favourable.
According to second advantageous embodiment of apparatus of the present invention, propellant is a kind of C
3～C
4Hydrocarbon, and the concentration range that in aerosol device, contains this propellant be 10～70% o'clock be favourable.This hydrocarbon is preferably from normal butane, propane, iso-butane and halogenated hydrocarbons, and their mixture.
According to the embodiment of the three-favour of apparatus of the present invention, propellant is a kind of dimethyl ether and C
3～C
5The mixture of hydrocarbon, and the proportion of methyl ether/hydrocarbon be 10: 90～90: 10 o'clock favourable.
Acceptable medium is preferably by acceptable solvent or water/solvent mixture in water or one or more cosmetics in the cosmetic.The preferred C of these solvents
1～C
4Alcohol, special preferred alcohol.
Convenient and suitable solvent contains the ethanol of 50 volume %, the ethanol of preferred at least 70 volume %.
Compositions among the present invention also comprises at least a additive, this additive is selected from anion, cation, nonionic and amphoteric surfactant, flavouring agent, sunscreen, antiseptic, protein, vitamin, the polymer except polymer of the present invention, particularly anion, amphion or nonionic styling polymer, vegetable oil, mineral oil or artificial oil and be usually used in other additives of cosmetic composition.
Need not illustrate that those skilled in the art can careful select to join any chemical compound in the present composition so that be not subjected to the closely-related advantageous property of compositions of the present invention or do not degenerate because of the adding of additive substantially.
The present composition is particularly suitable for doing as a kind of approved product and sends out or wet sending out.
The present composition can be used for skin, fingernail, lip, hair, eyebrow, eyelash.
To explain the present invention more comprehensively by means of detail description embodiment.
All percent is the relative weight percent with respect to composition total weight, and a.m. refers to activated material.
Embodiment:
Aerosol device among the present invention is prepared as follows.
Compositions A fluid: Luviflex Silk* 6%AMP qs 100% neutralization reaction ethanol qs 100g pressurization table: fluid 37%DME 43% pentane 20%
Compositions B fluid: Luviflex Silk* 4%Amphomer LV71 2%AMP qs 100% neutralization water 16% ethanol 78% pressurization table: fluid 65%DME 35%
These two kinds of compositionss are injected in the European respectively and tremble on the brown hair, in two kinds of situations, all have good cosmetic properties after the hair drying.
* the siloxane/acrylate copolymer (tert-butyl group acrylate/methacrylic acid/PDMS polyethers) sold of BASF
Claims (14)
1, the aerosol device of forming by the container that contains a kind of aerosol composition, this aerosol composition comprises the liquid phase (or fluid) that is dissolved at least a shaping material in the suitable solvent on the one hand, also comprise propellant on the other hand, and the process for dispersing of said aerosol composition
It is characterized in that:
(ⅰ) shaping material is a kind of siloxane/acrylate copolymer, this polymer be by at least a vinyl unsaturated monomer (a) in the presence of at least a silicone derivative (b) that comprises oxyalkylene group through the polymerization of free radical medium obtain and
(ⅱ) be selected from dimethyl ether, C
3-C
4Hydrocarbon, dimethyl ether and C
3-C
5The mixture of hydrocarbon, C
3-C
4The mixture of hydrocarbon and
(ⅲ) when propellant has only dimethyl ether, contain the aerosol composition of 10% above water.
2, the device in the claim 1 is characterized in that the general formula (I that monomer (a) is corresponding
a) be:
Wherein:
-X is selected from OH, OM, OR
8, NH
2, NHR
8Or N (R
8)
2
-M is selected from Na
+, K
+, Mg
++, NH
4+, alkylammonium, dialkyl ammonium, trialkyl ammonium and tetra-allkylammonium a kind of cation;
-radicals R
8Can be identical or different, be selected from hydrogen, linearity or side chain C
1-C
40Alkyl group, monobasic or multi-hydroxy C
1-C
40Alkyl group, optional one or more alkoxyls, amino or carboxylic acid group, hydroxylating polyethers, the N, N '-dimethyl aminoethyl, 2-hydroxyethyl, 2-methoxy ethyl, 2-ethoxyethyl group, hydroxypropyl, methoxy-propyl and ethoxycarbonyl propyl group of being substituted with;
-radicals R
7And R
6Be selected from incoherent each other group, this group comprises the C of hydrogen, linearity or side chain
1-C
8Alkyl group, methoxyl group, ethyoxyl, 2-hydroxyl-oxethyl, 2-methoxy ethoxy and 2-ethoxyethyl group group, and CN, COOH and COOM group.
3, the device in the claim 1 is characterized in that the corresponding general formula (I) of silicone derivative (b) is as follows:
In its formula of (I):
-R
2Be selected from CH
3Or following group:
-R
3Be selected from CH
3And radicals R
2
-R
4Be selected from hydrogen, CH
3With following group:
-R
6Be a kind of C that can comprise amino, carboxyl or sulfonate ester group
1～C
40Organic group, if c=0, R
6It is the anion of mineral acid;
-radicals R
1Can be identical or different, be selected from C
1～C
20Aliphatic hydrocarbon, C
3～C
20Aliphatic or annular aliphatic hydrocarbon, and radicals R
5Corresponding general formula is as follows:
-n is 1～6 integer,
-x and y are integers, and it makes polysiloxanes two molecular weight is 300～30,000,
-a and b be 0～50 integer and
-c is 0 or 1
4, the device in the claim 1 is characterized in that monomer (a) is selected from C
1～C
40Vinyl esters and allyl ester, linear C
3～C
40Carboxylic acid or C
3～C
40Carboxyl naphthenic acid, vinyl or allyl halide, vinyl lactam, preferred vinyl ketopyrrolidine and caprolactam; Heterocyclic compound by vinyl or pi-allyl replacement, optimal ethylene yl pyridines, second alkene oxazolin and allyl pyridine, N-vinyl imidazole, diallylamine, 1,1-dichloroethylene, carbon back unsaturated compound, for example styrene or isoprene, and the quaternised acrylic or methacrylic acid derivative of 3-chloro-1,2 epoxy prapane.
5, the device in the claim 1 is characterized in that monomer (a) is selected from acrylic acid, methacrylic acid and ethylacrylic acid; Acrylic acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Methacrylic acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Ethyl propylene acid methyl, ethyl, propyl group, normal-butyl, isobutyl group, the tert-butyl group, 2-ethylhexyl and decyl ester; Acrylic acid-2,3-dihydroxypropyl ester; Methacrylic acid 2,3-dihydroxypropyl ester; Acrylic acid-2-dihydroxy ethyl ester; The acrylic acid hydroxy-propyl ester; Methacrylic acid 2-hydroxyethyl ester; Ethylacrylic acid-2-hydroxyethyl ester; Acrylic acid-2-methoxy ethyl ester; Methacrylic acid-2-ethoxyethyl group ester; Ethylacrylic acid-2-ethoxyethyl group ester; Methacrylic acid hydroxyl propyl diester; Single acrylic acid glyceride; Monomethyl acrylic acid glyceride; Poly-(methyl) acrylic acid alkylidene diol ester; Unsaturated sulfonic acid; Acrylamide, Methacrylamide, ethyl acrylamide, N, N-DMAA, N-ethyl acrylamide, N-ethyl-methyl acrylamide, 1-vinyl-imidazoles, (methyl) acrylic acid N, N-dimethylamino ethyl ester, maleic acid, fumaric acid, maleic anhydride and its monoesters .beta.-methylacrylic acid, methylene-succinic acid, vinyl ethers, vinyl formamide, vinyl amine, vinylpyridine, vinyl imidazole, vinyl furan, styrene, styryl sulphonic acid ester and allyl alcohol and their mixture.
6, the device of arbitrary claim in the claim of front is characterized in that, silicone derivative (b) is selected from dimethyl siloxane polyol and silicone surfactant.
7, the device of arbitrary claim in the claim of front is characterized in that, based on relative weight percent, it comprises 0.1～20% siloxane/acrylate copolymer, reaches more preferably 0.5～10% this copolymer.
8, the device of arbitrary claim in the claim of front is characterized in that, propellant be dimethyl ether and the concentration range that in aerosol device, contains this propellant be 30～60% o'clock be favourable.
9, the device of arbitrary claim in the claim 1～7 is characterized in that, propellant is that the hydrocarbon of C3～C4 and concentration range that this propellant is present in the aerosol device are 10～70%.
10, the aerosol device of arbitrary claim in the claim 1～7 it is characterized in that propellant is the mixture of dimethyl ether and C3～C5 hydrocarbon, and dimethyl ether/hydrocarbon proportion is between 10: 90～90: 10.
11, the aerosol device of arbitrary claim in the claim of front, it is characterized in that, compositions also contains at least a additive, this additive is selected from anion, cation, nonionic and amphoteric surfactant, flavouring agent, sunscreen, antiseptic, protein, vitamin, the polymer except polymer of the present invention, particularly anion, amphion or nonionic styling polymer, vegetable oil, mineral oil or artificial oil.
12, the method that keeps hair style or molding hair style is characterized in that it has used the device of arbitrary claim in the claim 1～11.
13, the application of the device of arbitrary claim in production a kind of cosmetic product, particularly hair caring product in the claim 1～11.
14. the compositions of arbitrary claim is used for skin, fingernail, lip, hair, eyebrow and ciliary application in the claim 1～11.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9911595A FR2798588B1 (en) | 1999-09-16 | 1999-09-16 | AEROSOL DEVICE CONTAINING A HAIR COMPOSITION COMPRISING AT LEAST ONE SILICONE / ACRYLATE COPOLYMER |
| FR99/11595 | 1999-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1293029A true CN1293029A (en) | 2001-05-02 |
Family
ID=9549921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00128742A Pending CN1293029A (en) | 1999-09-16 | 2000-09-15 | Aerosol device of hair dressing composition containing at least one siloxane/acrylate copolymer |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1084699A1 (en) |
| JP (1) | JP2001097810A (en) |
| KR (1) | KR20010030417A (en) |
| CN (1) | CN1293029A (en) |
| AU (1) | AU748685B2 (en) |
| BR (1) | BR0004405A (en) |
| CA (1) | CA2319947A1 (en) |
| FR (1) | FR2798588B1 (en) |
| PL (1) | PL342560A1 (en) |
| RU (1) | RU2203102C2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2968544B1 (en) * | 2010-12-14 | 2013-01-11 | Oreal | PLANE DIFFUSION AEROSOL DEVICE FOR HAIR STAPPING |
| FR3017288B1 (en) * | 2014-02-10 | 2019-06-07 | Bbr | COSMETIC COMPOSITION SUITABLE FOR MODIFYING THE COLOR OF KERATIN FIBERS, IN PARTICULAR HAIR |
| CN112423731A (en) | 2018-07-17 | 2021-02-26 | 株式会社Lg化学 | Hair styling compositions and spray systems |
| CN110152177A (en) * | 2019-06-17 | 2019-08-23 | 沈昌 | A kind of anion cream and preparation method |
| KR20210003693A (en) | 2019-07-02 | 2021-01-12 | 주식회사 엘지생활건강 | Injection system of spray comprising hair styling composition |
| FR3109730B1 (en) * | 2020-04-30 | 2023-10-06 | Oreal | Aerosol device containing a composition comprising at least one silicone acrylic copolymer and at least one propellant |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5166276A (en) * | 1989-07-12 | 1992-11-24 | Mitsubishi Petrochemical Company Ltd. | Polymer for hair-care products |
| FR2735689B1 (en) * | 1995-06-21 | 1997-08-01 | Oreal | COMPOSITION COMPRISING A DISPERSION OF POLYMER PARTICLES IN A NON-AQUEOUS MEDIUM |
| DE59814329D1 (en) * | 1997-07-23 | 2009-02-05 | Basf Se | USE OF POLYSILOX-CONTAINING POLYMERS FOR COSMETIC FORMULATIONS |
| EP1207843A2 (en) | 1999-08-26 | 2002-05-29 | Basf Aktiengesellschaft | Cosmetic and/or pharmaceutical preparations with polymers containing polysiloxanes and the uses thereof |
-
1999
- 1999-09-16 FR FR9911595A patent/FR2798588B1/en not_active Expired - Fee Related
-
2000
- 2000-08-28 EP EP00402378A patent/EP1084699A1/en not_active Withdrawn
- 2000-09-05 AU AU56488/00A patent/AU748685B2/en not_active Ceased
- 2000-09-12 JP JP2000277132A patent/JP2001097810A/en active Pending
- 2000-09-14 CA CA002319947A patent/CA2319947A1/en not_active Abandoned
- 2000-09-15 PL PL00342560A patent/PL342560A1/en not_active Application Discontinuation
- 2000-09-15 CN CN00128742A patent/CN1293029A/en active Pending
- 2000-09-15 RU RU2000123754/14A patent/RU2203102C2/en not_active IP Right Cessation
- 2000-09-15 BR BR0004405-9A patent/BR0004405A/en not_active IP Right Cessation
- 2000-09-16 KR KR1020000054454A patent/KR20010030417A/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2319947A1 (en) | 2001-03-16 |
| BR0004405A (en) | 2001-04-10 |
| KR20010030417A (en) | 2001-04-16 |
| JP2001097810A (en) | 2001-04-10 |
| FR2798588A1 (en) | 2001-03-23 |
| PL342560A1 (en) | 2001-03-26 |
| AU5648800A (en) | 2001-03-22 |
| AU748685B2 (en) | 2002-06-13 |
| RU2203102C2 (en) | 2003-04-27 |
| EP1084699A1 (en) | 2001-03-21 |
| FR2798588B1 (en) | 2001-11-30 |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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