CN1289751C - Wear-resistant and highly elastic racket string structure and its manufacturing method - Google Patents
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- CN1289751C CN1289751C CN 01120246 CN01120246A CN1289751C CN 1289751 C CN1289751 C CN 1289751C CN 01120246 CN01120246 CN 01120246 CN 01120246 A CN01120246 A CN 01120246A CN 1289751 C CN1289751 C CN 1289751C
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- 238000004519 manufacturing process Methods 0.000 title abstract description 12
- 229920001778 nylon Polymers 0.000 claims abstract description 56
- 239000004677 Nylon Substances 0.000 claims abstract description 52
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 11
- 229920000577 Nylon 6/66 Polymers 0.000 claims abstract description 11
- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 43
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- -1 poly amido formate Chemical compound 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- 239000010410 layer Substances 0.000 description 38
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 28
- 239000011247 coating layer Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000005253 cladding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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Abstract
Description
技术领域
本发明是关于一种耐磨的高弹性球拍线构造及其制法,它利用熔融的TPE混合于尼龙单丝各线束间,使得TPE可在均匀且被稳定控制的状态下存在于蕊线的各尼龙单丝间,再于其上依次包覆TPU与尼龙混合层、TPE与尼龙混合层、TPU层等三道包覆层,形成球拍线体的结构,确保该球拍线具有更加稳定的耐磨性及弹性,并提供最佳的产业利用性与实用价值。The present invention relates to a wear-resistant and high-elastic racket string structure and its manufacturing method. It utilizes molten TPE to be mixed between the strands of nylon monofilament, so that TPE can exist in the center of the string in a uniform and stably controlled state. Between each nylon monofilament, three coating layers, such as TPU and nylon mixed layer, TPE and nylon mixed layer, and TPU layer, are sequentially coated on it to form the structure of the racket string body, ensuring that the racket string has a more stable durability. Abrasive and elastic, and provide the best industrial utilization and practical value.
背景技术 Background technique
一般而言,判断球拍品质的良窳,除球拍杆体本身以外,更着重于球拍线的耐磨性及弹性表现,这也关系到球拍线的使用寿命及击球效能;因此,目前所有球拍线体的生产制作过程当中,多需将蕊线经过热塑性塑胶含浸程序,并藉由热塑性塑胶本身具有较佳弹力的特性,增加球拍线的弹性,以期达到人们的要求。Generally speaking, to judge the quality of a racket, in addition to the racket shaft itself, more emphasis is placed on the wear resistance and elastic performance of the racket string, which is also related to the service life of the racket string and the hitting performance; therefore, all current racket strings During the production process of the racket body, it is often necessary to impregnate the core thread with thermoplastic plastic, and the thermoplastic plastic itself has better elastic properties to increase the elasticity of the racket string, in order to meet people's requirements.
然而,此种利用含浸将热塑性塑胶与蕊线结合的方式,具有使用上的盲点,因为该方式并无法确切控制蕊线含浸可塑性塑胶的含浸量及其分布状况,故常造成可塑性塑胶分布不均匀,且工艺及品质不稳定,不合格率亦相对居高不下。换言之,其在一般球拍线特别重视的耐磨性、弹性等物理特性表现上,无法达到预期的效果;相关人员深受这一瓶颈困扰,故有突破及改良的必要,以期望其品质更臻完美。However, this method of using impregnation to combine thermoplastic plastic with core wire has a blind spot in use, because this method cannot accurately control the impregnation amount and distribution of plastic plastic impregnated into core wire, so it often results in uneven distribution of plastic plastic. Moreover, the process and quality are unstable, and the failure rate is relatively high. In other words, it can’t achieve the expected results in terms of physical properties such as wear resistance and elasticity, which are particularly important for general racket strings; relevant personnel are deeply troubled by this bottleneck, so there is a need for breakthroughs and improvements in order to expect its quality to be better. Perfect.
为此,本发明者凭借着个人长期对于各种耐磨的高弹性球拍线构造及其制法的研究及融会贯通的构思,发明出一种利用熔融的TPE混合于尼龙单丝各线束间,使得TPE可在均匀且被稳定控制的状态下存在于蕊线的各尼龙单丝间,再于其上依次包覆TPU与尼龙混合层、TPE与尼龙混合层、TPU层等三道包覆层,形成球拍线体的结构,确保该球拍线具有更加稳定的耐磨性及弹性,以达最佳的产业利用性与实用性。For this reason, the inventor of the present invention relies on his long-term research on the structure of various wear-resistant high-elastic racket strings and their production methods and the idea of comprehension, and invented a method that uses molten TPE to be mixed between the wire bundles of nylon monofilaments, so that TPE can exist between the nylon monofilaments of the core thread in a uniform and stable state, and then cover it with three coating layers such as TPU and nylon mixed layer, TPE and nylon mixed layer, and TPU layer in sequence. The structure of the racket string body is formed to ensure that the racket string has more stable wear resistance and elasticity, so as to achieve the best industrial utilization and practicality.
发明内容Contents of invention
因此,本发明的主要目的是提供一种耐磨的高弹性球拍线构造及其制法,其主要是通过将熔融的TPE加压融合于若干尼龙单丝的线束间,使得TPE可在均匀且被稳定控制的状态下存在于蕊线的各尼龙单丝间;这样,可确保蕊线紧密结合,同时提供更稳定的弹性。Therefore, the main purpose of the present invention is to provide a wear-resistant high-elastic racket string structure and its manufacturing method, which is mainly through the fusion of molten TPE between a number of nylon monofilament strands under pressure, so that the TPE can be uniform and It exists between the nylon monofilaments of the core thread in a stable and controlled state; in this way, it can ensure that the core thread is tightly combined and provides more stable elasticity.
本发明的另一目的是提供一种耐磨的高弹性球拍线构造及其制法,其是在蕊线外依次包覆一TPU与尼龙混合层、一TPE与尼龙混合物层及一TPU层,并借助第一包覆层中的TPU具有可增加球拍线耐磨耗的特性,使该TPU与尼龙混合层能增加包覆的界面强力,同时通过第二包覆层TPE与尼龙混合物层受力后具有较佳的弹性回复率及回复速率、最外层的TPU层具有稳定与较佳的磨耗性,而使利用该方法所制成的球拍线同时具有稳定的耐磨性及弹性,从而可广泛运用于各种球拍。Another object of the present invention is to provide a wear-resistant and high-elastic racket string structure and its manufacturing method, which is to sequentially coat a TPU and nylon mixed layer, a TPE and nylon mixed layer and a TPU layer on the outside of the core wire, And with the help of the TPU in the first coating layer, which can increase the wear resistance of the racket string, the TPU and nylon mixed layer can increase the interface strength of the coating, and at the same time, the force is applied through the second coating layer TPE and nylon mixture layer Afterwards, it has better elastic recovery rate and recovery rate, and the outermost TPU layer has stability and better abrasion resistance, so that the racket string made by this method has stable abrasion resistance and elasticity at the same time, so that it can Widely used in various rackets.
本发明的目的通过下述方法和结构得以实现:The object of the present invention is achieved by following method and structure:
一种耐磨的高弹性球拍线的制法,其中该球拍线的线体是利用如下的方法制成:将若干尼龙6或尼龙6/66共聚体单丝相互缠绕,并将热塑性弹性体TPE熔融混合于各尼龙6或尼龙6/66共聚体单丝之间而形成一心蕊结构,再于外部依次包覆一热塑性聚胺基甲酸酯TPU与尼龙聚合物形成的第一包覆层、一TPE与尼龙混合物形成的第二包覆层及一TPU层。A method for making a wear-resistant and highly elastic racket string, wherein the string body of the racket string is made by the following method: intertwining several nylon 6 or nylon 6/66 copolymer monofilaments, and thermoplastic elastomer TPE Melt and mix between nylon 6 or nylon 6/66 copolymer monofilaments to form a core structure, and then cover the outside with a first coating layer formed by thermoplastic polyurethane TPU and nylon polymer, A second covering layer formed of a mixture of TPE and nylon and a TPU layer.
一种耐磨的高弹性球拍线的结构,该球拍线包括如下结构:由若干尼龙6或尼龙6/66共聚体单丝相互缠绕并将热塑性弹性体TPE熔融混合于各尼龙6或尼龙6/66共聚体单丝之间而形成的心蕊结构;所述心蕊结构的外部所依次包覆的一热塑性聚胺基甲酸酯TPU与尼龙聚合物形成的第一包覆层、一TPE与尼龙混合物形成的第二包覆层及一TPU层。A wear-resistant and highly elastic racket string structure, the racket string includes the following structure: a number of nylon 6 or nylon 6/66 copolymer monofilaments are intertwined and thermoplastic elastomer TPE is melt-mixed with each nylon 6 or nylon 6/66 The core structure formed between 66 copolymer monofilaments; the outside of the core structure is coated in turn with a thermoplastic polyurethane TPU and a first coating layer formed by nylon polymer, a TPE and A second cover layer of nylon blend and a TPU layer.
为了进一步说明本发明能,以下列举一较佳实施例,并配合图示、图号,将本发明的构成内容及其所达到的效果详细说明如下:In order to further illustrate the performance of the present invention, a preferred embodiment is enumerated below, and in conjunction with the drawings and figure numbers, the composition of the present invention and the effects achieved are described in detail as follows:
附图说明Description of drawings
图1是本发明球拍线的组成构造图;Fig. 1 is the constituent structural diagram of racket string of the present invention;
图2是本发明球拍线的制作流程简图;Fig. 2 is a schematic diagram of the production process of the racket string of the present invention;
图3是本发明球拍线的制作流程方块图。Fig. 3 is a block diagram of the manufacturing process of the racket string of the present invention.
图中:In the picture:
(A) 线体(A) Line body
(10) 心蕊(10) heart core
(11) TPE(11) TPE
(12) 尼龙单丝(12) Nylon monofilament
(20) TPU与尼龙混合物层(20) TPU and nylon blend layer
(30) TPE与尼龙混合物层(30) TPE and nylon mixture layer
(31) 尼龙单丝(31) Nylon monofilament
(32) TPE(32) TPE
(40) TPU层(40) TPU layer
(50) 成型设备(50) molding equipment
(51)(52) 放线台(51)(52) Pay-off table
(511) 线轴(511) Spools
(53)(54) 集束器(53)(54) Cluster
(55) 烘箱(55) Oven
(56)(57) 包覆装置(56)(57) Coating device
(58) 收线台(58) Take-up table
具体实施方式 Detailed ways
请参阅图1所示,它是本发明球拍线的组成构造图,本发明的球拍线体(A)主要是由TPE(热塑性弹性体)(11)熔融于若干尼龙6或尼龙6/66共聚体尼龙单丝(12)间所形成的一心蕊(10),于外部依次包覆(coating)一TPU(热塑性聚胺基甲酸酯)与尼龙混合物层(20)、一TPE与尼龙混合物层(30)及一TPE层(40)所组成;其中,该心蕊(10)是由若干尼龙单丝(12)以正向相互缠绕后,再将熔融的TPE(11)予以加压融合于各尼龙6或尼龙6/66共聚体尼龙单丝(12)间所形成,从而紧密结合成一体结构;这样,使其可在均匀及被控制的状态下存在于心蕊(10)蕊线的各尼龙单丝(12)间,从而能获得稳定的弹性功效;其次,该心蕊(10)蕊线外围包覆的TPU与尼龙混合物层(20),是充分利用TPU本身的物理特性,以增加其耐磨耗性能,而整体的混合层相对线体而言,是可增加其包覆的界面强力;另外,该包覆第一层的TPU与尼龙混合物层(20)外围是再包覆一层与心蕊(10)相同的TPE与尼龙混合物层(30),其不同在于该尼龙单丝(31)是以反向互相缠绕后,再将熔融的TPE(32)予以加压融合于各尼龙单丝(32)间所形成,以增加该球拍线体(A)的结构紧密性及其受力后的弹性回复率及回复速率;又在包覆第二层的TPE与尼龙混合物(30)流程后需经过一烘箱(OVEN)的烘干固化,并待其固化成型后于外围再包覆一TPU层(40),藉此TPU层(40)可增加该球拍线体A的耐磨耗性。Please refer to shown in Fig. 1, it is the constituent structure drawing of racket string of the present invention, and racket string body (A) of the present invention is mainly made of TPE (thermoplastic elastomer) (11) melted in some nylon 6 or nylon 6/66 copolymerization A core (10) formed between body nylon monofilaments (12) is coated (coating) a TPU (thermoplastic polyurethane) and nylon mixture layer (20), a TPE and nylon mixture layer on the outside in sequence (30) and a TPE layer (40); wherein, the core (10) is made of a number of nylon monofilaments (12) that are intertwined with each other in the forward direction, and then the melted TPE (11) is pressurized and fused in Formed between each nylon 6 or nylon 6/66 copolymer nylon monofilament (12), thereby tightly combined into an integral structure; like this, it can exist in the center of the core (10) core line under a uniform and controlled state. Between each nylon monofilament (12), thereby can obtain stable elastic effect; Secondly, the TPU and nylon mixture layer (20) that this heart core (10) core wire periphery coats, is to make full use of the physical characteristic of TPU itself, with Increase its wear resistance, and the overall mixed layer can increase the interface strength of its coating relative to the wire body; in addition, the outer periphery of the TPU and nylon mixture layer (20) that covers the first layer is recoated One layer of the same TPE and nylon mixture layer (30) as the core (10), the difference is that the nylon monofilament (31) is twisted in opposite directions, and then the melted TPE (32) is pressurized and fused Formed between each nylon monofilament (32), to increase the structural tightness of the racket string (A) and its elastic recovery rate and recovery rate after being stressed; and in the second layer of TPE and nylon mixture ( 30) After the process, it needs to be dried and cured in an oven (OVEN), and after it is cured and formed, a TPU layer (40) is coated on the periphery, so that the TPU layer (40) can increase the durability of the racket string A. Abrasive.
请参阅图2所示,它是本发明球拍线的制作流程简图,其设有一成型设备(50),其是包括两道放线台(51)(52)、两道集束器(53)(54)、一烘箱(55)、两包覆装置(56)(57)及一收线台(58);成型时,先分别将尼龙6或尼龙6/66共聚体的尼龙单丝(12)由放线台(50)上的线轴(511)一齐释放出来(请配合参阅图3所示),并在正向相互缠绕后于集束器(53)收束形成一线体结构,再利用熔融TPE(11)加压熔合于各尼龙单丝(12)间形成一束线作为心蕊(10),再将制成的心蕊(10)经过第一包覆装置(56),使其外部得以包覆一TPU与尼龙混合物层(20),之后再将其通过第二道放线台(52)及集束器(54),使其外部再以反向缠绕一尼龙单丝(31)层,再以TPE(32)熔合于各尼龙单丝(31)间而形成TPE与尼龙混合物层(30)的第二包覆层,待其包覆完成后,将其通过一烘箱(55)予以烘干固化,再经过最后一道包覆装置(57),使其包覆一TPU层(40)后,即可完成球拍线体心的成型流程,再通过收线台(58)将其卷收完成。Please refer to shown in Fig. 2, it is the production process schematic diagram of racket string of the present invention, and it is provided with a molding equipment (50), and it is to comprise two roads pay-off table (51) (52), two road bundler (53) (54), a baking oven (55), two cladding devices (56) (57) and a take-up table (58); during molding, the nylon monofilament (12 ) are released together from the spools (511) on the pay-off table (50) (please refer to Figure 3 for details), and after they are intertwined in the forward direction, they are bundled in the bundler (53) to form a wire structure, and then melted TPE (11) is pressurized and fused between each nylon monofilament (12) to form a bundle of wires as the core (10), and then the core (10) is passed through the first coating device (56) to make its outer surface A TPU and nylon mixture layer (20) can be coated, and then it is passed through the second pay-off table (52) and the bundler (54), so that the outside is wound with a nylon monofilament (31) layer in reverse , and then TPE (32) is fused between each nylon monofilament (31) to form the second coating layer of TPE and nylon mixture layer (30). After the coating is completed, it is passed through an oven (55). Dry and solidify, and then go through the last coating device (57) to make it coated with a TPU layer (40), then the molding process of the racket string body center can be completed, and then it is wound up by the wire take-up table (58) Finish.
综上所述,本发明耐磨的高弹性球拍线构造及其制法,是一种利用熔融的TPE混合于尼龙单丝各线束间,使得TPE在均匀且被稳定控制的状态下存在于蕊线的各尼龙单丝间,再于其上依次包覆TPU与尼龙混合层、TPE与尼龙混合层、TPU层等三道包覆层,从而形成球拍线体的方法及其结构,它可确保该球拍线具有更加稳定的耐磨性及弹性,以符合产业实用性及成本效益,且其构成结构又未曾见诸于书刊或公开使用。To sum up, the wear-resistant and high-elastic racket string structure and its manufacturing method of the present invention are a kind of use of melted TPE mixed between the wire bundles of nylon monofilament, so that the TPE exists in the core in a uniform and stable state. Between the nylon monofilaments of the string, three coating layers, such as TPU and nylon mixed layer, TPE and nylon mixed layer, and TPU layer, are sequentially coated on it to form the method and structure of the racket string body, which can ensure The racket string has more stable wear resistance and elasticity to meet industrial practicability and cost-effectiveness, and its structure has never been seen in books or public use.
需要指出的是,以上所述乃是本发明的具体实施例及所运用的技术原理,若依本发明的构想所作的改变,其所产生的功能作用仍未超出说明书及图式所涵盖的精神时,均应在本发明的范围内。It should be pointed out that the above descriptions are the specific embodiments of the present invention and the technical principles used. If changes are made according to the concept of the present invention, the functions produced will not exceed the spirit covered by the description and drawings. should be within the scope of the present invention.
Claims (8)
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CN101205649B (en) * | 2006-12-18 | 2011-04-20 | 耀亿工业股份有限公司 | Racquet string extrusion molding manufacturing method and products thereof |
FR2934958B1 (en) * | 2008-08-12 | 2012-11-09 | Babolat Vs | ROPE FOR RACKETS, IN PARTICULAR FOR TENNIS RACKETS |
CN102711558B (en) * | 2009-12-31 | 2017-06-23 | 伊利诺斯工具制品有限公司 | Carry support surface |
JP5593005B1 (en) * | 2013-04-19 | 2014-09-17 | 株式会社ゴーセン | Racket string and manufacturing method thereof |
CN106366410A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | High-shock-absorptivity high-durability badminton net line and preparation method thereof |
CN106317868A (en) * | 2016-08-30 | 2017-01-11 | 安徽翰文运动用品股份有限公司 | String for badminton racket |
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