CN1283388A - Effervescent table as agricultural chemical and its preparing process - Google Patents
Effervescent table as agricultural chemical and its preparing process Download PDFInfo
- Publication number
- CN1283388A CN1283388A CN 00107465 CN00107465A CN1283388A CN 1283388 A CN1283388 A CN 1283388A CN 00107465 CN00107465 CN 00107465 CN 00107465 A CN00107465 A CN 00107465A CN 1283388 A CN1283388 A CN 1283388A
- Authority
- CN
- China
- Prior art keywords
- agricultural chemical
- acid
- effervescent
- effervescent table
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003905 agrochemical Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims description 6
- 239000007938 effervescent tablet Substances 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 11
- 238000004078 waterproofing Methods 0.000 claims abstract description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 19
- 239000000575 pesticide Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 239000003826 tablet Substances 0.000 claims description 15
- 239000003814 drug Substances 0.000 claims description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 12
- -1 cyfloxylate Chemical compound 0.000 claims description 11
- 239000002917 insecticide Substances 0.000 claims description 11
- 239000005893 Diflubenzuron Substances 0.000 claims description 10
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 claims description 10
- 229940019503 diflubenzuron Drugs 0.000 claims description 10
- 239000007779 soft material Substances 0.000 claims description 10
- 239000002671 adjuvant Substances 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 150000003851 azoles Chemical class 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 5
- 235000011837 pasties Nutrition 0.000 claims description 5
- 239000005874 Bifenthrin Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 4
- 239000004009 herbicide Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- 239000005660 Abamectin Substances 0.000 claims description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 239000005648 plant growth regulator Substances 0.000 claims description 3
- 229940072033 potash Drugs 0.000 claims description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 3
- 235000015320 potassium carbonate Nutrition 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000013638 trimer Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 claims description 2
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims description 2
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 claims description 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 claims description 2
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 claims description 2
- ZRDUSMYWDRPZRM-UHFFFAOYSA-N 2-sec-butyl-4,6-dinitrophenyl 3-methylbut-2-enoate Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)C=C(C)C ZRDUSMYWDRPZRM-UHFFFAOYSA-N 0.000 claims description 2
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 claims description 2
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 claims description 2
- 241000894006 Bacteria Species 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 239000005746 Carboxin Substances 0.000 claims description 2
- 239000005974 Chlormequat Substances 0.000 claims description 2
- 239000005496 Chlorsulfuron Substances 0.000 claims description 2
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 239000005504 Dicamba Substances 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 2
- HMIBKHHNXANVHR-UHFFFAOYSA-N Fenothiocarb Chemical compound CN(C)C(=O)SCCCCOC1=CC=CC=C1 HMIBKHHNXANVHR-UHFFFAOYSA-N 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 229930191978 Gibberellin Natural products 0.000 claims description 2
- PFDCOZXELJAUTR-UHFFFAOYSA-N Inabenfide Chemical compound C=1C(Cl)=CC=C(NC(=O)C=2C=CN=CC=2)C=1C(O)C1=CC=CC=C1 PFDCOZXELJAUTR-UHFFFAOYSA-N 0.000 claims description 2
- FAIXYKHYOGVFKA-UHFFFAOYSA-N Kinetin Natural products N=1C=NC=2N=CNC=2C=1N(C)C1=CC=CO1 FAIXYKHYOGVFKA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005983 Maleic hydrazide Substances 0.000 claims description 2
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005584 Metsulfuron-methyl Substances 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005985 Paclobutrazol Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000005822 Propiconazole Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005939 Tefluthrin Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- QGXGSMKMRQNEAQ-UHFFFAOYSA-N [Na].C(CCCCCCC)OC(CCC(=O)O)=O Chemical compound [Na].C(CCCCCCC)OC(CCC(=O)O)=O QGXGSMKMRQNEAQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000642 acaricide Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 229960000250 adipic acid Drugs 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 claims description 2
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 claims description 2
- JUZXDNPBRPUIOR-UHFFFAOYSA-N chlormequat Chemical compound C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 claims description 2
- VJYIFXVZLXQVHO-UHFFFAOYSA-N chlorsulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VJYIFXVZLXQVHO-UHFFFAOYSA-N 0.000 claims description 2
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 2
- VAIZTNZGPYBOGF-CYBMUJFWSA-N fluazifop-P-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-CYBMUJFWSA-N 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 235000011087 fumaric acid Nutrition 0.000 claims description 2
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003448 gibberellin Substances 0.000 claims description 2
- 230000002363 herbicidal effect Effects 0.000 claims description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 2
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 claims description 2
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- QANMHLXAZMSUEX-UHFFFAOYSA-N kinetin Chemical compound N=1C=NC=2N=CNC=2C=1NCC1=CC=CO1 QANMHLXAZMSUEX-UHFFFAOYSA-N 0.000 claims description 2
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- 229920005610 lignin Polymers 0.000 claims description 2
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 2
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 claims description 2
- 229930182490 saponin Natural products 0.000 claims description 2
- 150000007949 saponins Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 claims description 2
- 238000004659 sterilization and disinfection Methods 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 claims description 2
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 claims description 2
- 229930192474 thiophene Natural products 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 claims description 2
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 2
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 claims description 2
- 238000009333 weeding Methods 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 2
- 238000007723 die pressing method Methods 0.000 abstract 1
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- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
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- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 239000005811 Myclobutanil Substances 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
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- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
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- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
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- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
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- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An effervescent tablet of agricultural chemical is prepared from raw agricultural chemical, acid source, CO2 source, water-proofing agent and assistant through preparing soft mixture and die pressing. Its advantages include small size and convenient transportation, storage and application.
Description
The present invention relates to the pesticide processing field, specifically the present invention relates to a kind of pesticides new formulation--effervescent table as agricultural chemical.
The formulations of pesticide commonly used have missible oil, pulvis, wetting powder, colloidal suspending agent etc., and pesticide species is many mostly becomes the commercially available agricultural chemical list marketing with these several dosage form.In these formulations of pesticide commonly used, missible oil is owing to contain organic solvent, thus inflammable, easy leakage, produce and transportation in must be strict with prevent fires, leakage-preventing; Pulvis, wetting powder easily lump in storage because granularity is very little, and the volume that accounts for is big, bring inconvenience to use; There is leakage problem too in colloidal suspending agent.The present invention intends working out a kind of pesticides new formulation, to overcome the deficiency of above preparation form.So effervescent table as agricultural chemical has just arisen at the historic moment.
The objective of the invention is to propose a kind of effervescent table as agricultural chemical and manufacture method thereof.
Below narrate main contents of the present invention:
Effervescent tablet of the present invention is made up of pesticide original medicine, acid source, carbon dioxide source, waterproofing agent, insecticides adjuvant, through certain process obtain can be in water disintegration and form the tablet of the suspension that can be used for spraying automatically.
Agricultural chemicals in the effervescent tablet of the present invention can be a desinsection, kill one or both compositions in mite, sterilization, weeding, the plant growth regulating.Wherein insecticide can be: the young urea that goes out, deinsectization azoles, diflubenzuron, UC 62644, Cyhalothrin, cyfloxylate, tefluthrin, bifenthrin, Avermectin, ivermectin; Miticide comprises: Cyhalothrin, Avermectin, bifenthrin, azacyclotin, binapacryl, fenbutatin oxide, fenothiocarb, plictran; Weed killer herbicide can be: metsulfuron-methyl, chlorsulfuron, tribenuron-methyl, triasulfuron, thiophene methyl, ethyl methyl, benzyl ethyl methyl, surely kill, clean, the quinclorac of fluazifop-p-butyl, Dicamba, the wealthy pleasure of gram, prowers, thiameturonmethyl, broad-leaved, fixed, the happy spirit of quinoline of fluorine grass; Bactericide can be the mould prestige of second, thiophanate, triazolone, alkene azoles alcohol, nitrile bacterium azoles, propiconazole, Flusilazole, carboxin; Plant growth regulator can be: heteroauxin, indolebutyric acid, kinetin, paclobutrazol, maleic hydrazide, alar-85, naa, chlormequat, Lodging-proof agent, inabenfide, ethrel, triacontanol, gibberellin.
The acid source material of effervescent tablet of the present invention is any one in citric acid, tartaric acid, fumaric acid, hexanedioic acid, malic acid, the water-soluble amino acids.
Carbon dioxide source material in the effervescent tablet of the present invention is a sodium carbonate, any one in the materials such as sodium bicarbonate, saleratus, potash, calcium carbonate.
Insecticides adjuvant in the effervescent tablet of the present invention, can be one or more mixtures in the following material, as draw back materials such as powder, saponin, lignin sulfonic acid salt material, alkyl sulfonates material, laruyl alcohol, alkylphenol polyoxyethylene succinic acid sodium sulfonate, dodecyl benzene sulfonate, succinic acid-monooctyl ester sodium sulfonate, nekal, sodium phosphate trimer, sodium silicate, Sodium Benzoate (potassium), stearate.
Waterproofing agent in the effervescent tablet of the present invention can be any one or a few mixture in the materials such as zeolite, silicic acid, white carbon black, talcum powder, bentonite, alundum (Al, silicon bath soil.
The processing technology of effervescent tablet of the present invention is divided three steps:
A. with the acid source material, carbon dioxide source material, waterproofing agent be dry respectively, pulverized 60 mesh sieves, mixes; With isopropyl alcohol or butanols or isobutanol with mixture furnishing pasty state; Under vacuum, remove adding alcohol, cross 20 mesh sieves, promptly get soft material.
B. soft material and pesticide original medicine, the insecticides adjuvant with the steps A gained mixes, and gets the disintegratable shot-like particle.
C. in tablet press machine, the disintegratable shot-like particle of step B gained is pressed into the tablet of suitable size, promptly get this effervescent table as agricultural chemical.
Each component optimum weight percentage in the effervescent tablet of the present invention is:
Pesticide original medicine 2～30%
Acid source 15～30%
Carbon dioxide source 15～20%
Waterproofing agent 5～20%
Insecticides adjuvant 5～50%
The present invention compares than prior art has following typical advantages:
1. have that production process safety, tablet volume are little, convenient transportation, advantage such as easy to use.The characteristics of effervescent tablet are with after forming the various raw materials compactings in flakes of this agent and since acid source and carbon dioxide source in water rapidly reaction generate carbonic acid gas, make this tablet can disintegration automatically in water, and become operable liquid or suspension.This formulation is applied to pharmaceutical preparation the earliest, the patient of particularly suitable children, the elderly and the solid pharmaceutical preparation of can not swallowing; Because of taking with the solution form, drug effect is rapid again, bioavilability height, and comparing with liquid preparation, its advantage be carry more convenient.This research has successfully also been made effervescent tablet with various agricultural chemicals on the basis of medical effervescent tablet.And before this, from domestic patent and practical application, also there is not pesticide species with this dosage form application, effervescent table as agricultural chemical of the present invention, overcome many shortcomings of agricultural chemicals common formulations such as missible oil, wetting powder, pulvis, colloidal suspending agent, and have that production process safety, tablet volume are little, convenient transportation, advantage such as easy to use.
2. employed insecticides adjuvant in the effervescent tablet of the present invention, suspending agent, wetting agent, emulsifier etc. have been comprised, so this effervescent tablet is in water after the disintegration, can form the soup that meets the pesticide standard requirement, this soup can be used for spraying, regulates with the disease of control in the agricultural production, worm, crop smothering and to growth and development of plant.
3. effervescent table as agricultural chemical of the present invention, owing to added the waterproofing agent of tool high dispersive performance, and make tablet be difficult for influencing the disintegration ability of tablet because of the moisture absorption.The pesticide original medicine that is suitable for being processed into effervescent tablet can be a solid, can be liquid also, but when pesticide original medicine is liquid, need with porous filler such as carbon black, alundum (Al etc. the former medicine of liquid to be adsorbed earlier, mix with other auxiliary material again, become effervescent tablet through compressing tablet.
4. consumption is little.When being liquid except that the pesticide original medicine when processing, the agricultural chemicals consumption under normal conditions that is processed into effervescent tablet should be not more than 500g/ha.
Below narrate embodiments of the invention:
Embodiment 1: take by weighing citric acid 25.0g, and potash 25.0g, dry respectively, and be crushed to 60 mesh sieves; Zeolite and each 6.0g of silicic acid of adding 400 mesh sieves mix the back and with an amount of isobutanol mixture are modulated into pasty state, remove isobutanol under vacuum, residue is crossed 20 mesh sieves, promptly makes soft material; Take by weighing lauryl sodium sulfate 10g, draw back powder 8g, Sodium Benzoate 15g, former medicine 5.0g of diflubenzuron (pure) and the soft material of gained fully mix, and compacting promptly gets 5% diflubenzuron effervescent tablet in flakes in tablet press machine.This diflubenzuron effervescent tablet disintegration automatically in water, and form uniform suspension is used to spray and can effectively prevents and treats Lepidoptera on the various crops, insects such as coleoptera.
Embodiment 2: take by weighing vinic acid 20.0g, sodium bicarbonate 20.0g, and dry respectively and be crushed to 60 mesh sieves; Add 10g respectively and cross the alundum (Al and the carbon black of 425 mesh sieves, fully mix, with an amount of isopropyl alcohol this mixture is modulated into pasty state again, remove isopropyl alcohol under vacuum, residue is crossed 20 mesh sieves, promptly makes soft material; Take by weighing dolomol 15g, sodium lignin sulfonate 15g, sodium silicate 15g, the former medicine 10g of benzene ethyl methyl (pure) after mixing with soft material, neutralizes in flakes through tablet press machine, promptly get 10% benzene ethyl methyl effervescent tablet, this effervescent tablet is in water after the disintegration, and the suspension of formation is suitable for spraying, to broad leaved weed and the rice field very high preventive effect of taking to the greenwood.
Embodiment 3: take by weighing malic acid 30g, saleratus 30g is dry respectively and be crushed to 60 mesh sieves; Took by weighing the swelling ± 10g of 400 mesh sieves, and mixed the back and be modulated into pasty state with isobutanol, isobutanol is removed in vacuum drying, promptly makes soft material; Soft material and 5g laruyl alcohol, 5g sodium phosphate trimer, 3g bulk myclobutanil (pure) and the former medicine of 7g thiophanate-methyl (pure) are fully mixed, get 10% formonitrile HCN effervescent tablet through the tablet press machine film-making.This tablet forms the suspension can be used for spraying after the disintegration in water, can effectively prevent and treat the disease such as scab, powdery mildew of crops such as apple, pears, cucumber and wheat powdery mildew, grape bunch and fruit black rot are also had good preventive effect.
EXPERIMENTAL EXAMPLE 1: with the preparation of the different dosage form of diflubenzuron to three age mythimna separata carried out toxicity test.Measure and adopt leaf dipping method, every kind of preparation is established 5-6 concentration, and every concentration is established 3 repetitions, and every reprocessing 20 cephalont are contrast with the clear water.Check 5 days and symptom or dead examination worm ratio occur.Ask the school preventive effect with the Abbort formula, obtain the virulence curve and the EC of each preparation with the probit value analytical method
50, the results are shown in Table 1.
Four kinds of diflubenzuron preparations of table 1 to 3 age mythimna separata virulence relatively
The result shows: the diflubenzuron effervescent tablet is higher than other three kinds of common dosage forms to the virulence of mythimna separata.
| Formulation | Virulence equation (y=) | ????EC 50(mg／L) |
| Effervescent tablet wetting powder colloidal suspending agent | ????6．0822+1．1799x ????5．9952+1．0962x ????5．3561+1．1782x | ????0．1210 ????0．1236 ????0．4986 |
| Missible oil | ????5．6832+0．8379x | ????0．1530 |
EXPERIMENTAL EXAMPLE 2: adopt pesticide wettable to measure the method for effective ingredient suspensibility, measured the suspensibility of diflubenzuron effervescent tablet, the suspensibility of diflubenzuron effervescent tablet of the present invention is 71.34%, satisfies the pesticidal preparations suspensibility greater than 60% requirement.
Claims (9)
1. effervescent table as agricultural chemical is characterized in that this effervescent table as agricultural chemical is made up of pesticide original medicine, acid source, carbon dioxide source, waterproofing agent, insecticides adjuvant.
2. effervescent table as agricultural chemical as claimed in claim 1 is characterized in that the optimum weight percentage of each component in this effervescent table as agricultural chemical is:
Pesticide original medicine 2～30%
Acid source 15～30%
Carbon dioxide source 15～20%
Waterproofing agent 5～20%
Insecticides adjuvant 5～50%
3. effervescent table as agricultural chemical as claimed in claim 1 is characterized in that agricultural chemicals can be various desinsections, kill one or more the material in mite, weeding, sterilization, the plant growth regulator.
4. effervescent table as agricultural chemical as claimed in claim 3, it is characterized in that insecticide can be go out that young urea, deinsectization azoles, diflubenzuron, UC 62644, desinsection are grand, among the Cyhalothrin, cyfloxylate, tefluthrin, bifenthrin, ivermectin one or more; Miticide is one or more among Cyhalothrin, Avermectin, bifenthrin, azacyclotin, binapacryl, fenbutatin oxide, fenothiocarb, the plictran; Weed killer herbicide can be metsulfuron-methyl, chlorsulfuron, tribenuron-methyl, triasulfuron, thiophene methyl, ethyl methyl, benzyl ethyl methyl, surely kill, among fixed, the happy spirit of quinoline of clean, the quinclorac of fluazifop-p-butyl, Dicamba, the wealthy pleasure of gram, prowers, thiameturonmethyl, broad-leaved, fluorine grass one or more; Bactericide can be one or more among the mould prestige of second, thiophanate, triazolone, alkene azoles alcohol, nitrile bacterium azoles, propiconazole, Flusilazole, the carboxin; Plant growth regulator can be: one or more among heteroauxin, indolebutyric acid, kinetin, paclobutrazol, maleic hydrazide, alar-85, naa, chlormequat, Lodging-proof agent, inabenfide, ethrel, triacontanol, the gibberellin.
5. effervescent table as agricultural chemical as claimed in claim 1 is characterized in that acid source used in this effervescent tablet is any one in citric acid, tartaric acid, fumaric acid, hexanedioic acid, malic acid, the water-soluble amino acids.
6. effervescent table as agricultural chemical according to claim 1, it is characterized in that carbon dioxide source can be in the materials such as sodium carbonate, sodium bicarbonate, potash, saleratus, calcium carbonate any one.
7. effervescent table as agricultural chemical according to claim 1 is characterized in that insecticides adjuvant can be one or more mixtures that draw back among powder, saponin, lignin, Sulfonates material, alkyl sulfonates material, laruyl alcohol, alkylphenol polyoxyethylene succinic acid sodium sulfonate, dodecyl benzene sulfonate, succinic acid-monooctyl ester sodium sulfonate, nekal, sodium phosphate trimer, sodium silicate, Sodium Benzoate (potassium), the stearate.
8. effervescent table as agricultural chemical according to claim 1 is characterized in that waterproofing agent can be any one or a few mixture among zeolite, silicic acid, white carbon black, talcum powder, bentonite, alundum (Al, the silicon bath soil.
9. the manufacture method of an effervescent table as agricultural chemical is characterized in that:
A. with the acid source material, carbon dioxide source material, waterproofing agent be dry respectively, pulverized 60 mesh sieves, mixes; With isopropyl alcohol or butanols or isobutanol with mixture furnishing pasty state; Under vacuum, remove adding alcohol, cross 20 mesh sieves, promptly get soft material;
B. soft material and pesticide original medicine, the insecticides adjuvant with the steps A gained mixes, and gets the disintegratable shot-like particle;
C. in tablet press machine, the disintegration shot-like particle of step B gained is pressed into the tablet of suitable size, promptly get this effervescent table as agricultural chemical.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00107465 CN1193664C (en) | 2000-05-17 | 2000-05-17 | Effervescent table as agricultural chemical and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00107465 CN1193664C (en) | 2000-05-17 | 2000-05-17 | Effervescent table as agricultural chemical and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1283388A true CN1283388A (en) | 2001-02-14 |
| CN1193664C CN1193664C (en) | 2005-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00107465 Expired - Fee Related CN1193664C (en) | 2000-05-17 | 2000-05-17 | Effervescent table as agricultural chemical and its preparing process |
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| Country | Link |
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| CN (1) | CN1193664C (en) |
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| CN101874491A (en) * | 2010-06-04 | 2010-11-03 | 江苏七洲绿色化工股份有限公司 | Effervescent tablet containing propiconazole and preparation method thereof |
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| CN110100816A (en) * | 2019-05-14 | 2019-08-09 | 允发化工（上海）有限公司 | A kind of gibberellic acid soluble tablets and preparation method thereof |
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