CN1282499C - Method of preparing amorphous silica-alumina using carbonization - Google Patents
Method of preparing amorphous silica-alumina using carbonization Download PDFInfo
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- CN1282499C CN1282499C CN 03133986 CN03133986A CN1282499C CN 1282499 C CN1282499 C CN 1282499C CN 03133986 CN03133986 CN 03133986 CN 03133986 A CN03133986 A CN 03133986A CN 1282499 C CN1282499 C CN 1282499C
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Abstract
The present invention discloses a preparation method for amorphous silaceous aluminum. A part of a sodium silicate solution is added to a sodium aluminate solution. Then, CO2 gas is led into the solution. After leading for a certain time, the rest sodium silicate solution is added, wherein in the process, the reaction temperature is controlled between 10 and 40 DEG C. The CO2 gas stops leading under the condition that the pH value of the system is from 8 to 11. The amorphous silaceous aluminium is obtained through stabilization, filtration, washing and desiccation. The preparation method has the advantages of simple technological process, low cost and no pollution. The obtained amorphous silaceous aluminium has the advantages of proper specific surface area, proper pore volume, proper acidity and sufficient silicon oxide, and can be used as a carrier component for catalytic cracking, hydrocracking and hydrotreating catalysts.
Description
Technical field
The present invention relates to a kind of preparation method of amorphous aluminum silicide, particularly a kind of method for preparing amorphous aluminum silicide with carbon dioxide neutralisation (being carbonizatin method).
Background technology
Amorphous aluminum silicide has certain pore structure and specific area, thereby can be used as catalyst carrier and adsorbent in oil refining and petrochemical industry.As the amorphous aluminum silicide of catalyst carrier, requiring itself must have bigger specific surface and pore volume, and with the dispersion of assurance catalyst activity component, and as carrier of cracking, amorphous aluminum silicide also must have certain lytic activity (promptly acid).
Along with developing rapidly of petrochemical industry, the demand of amorphous aluminum silicide is constantly increased, but, use NH mostly with the amorphous aluminum silicide of prior art for preparing
4OH, this contains the waste water of ammonia, nitrogen with generation, environment is produced pollute.In recent years, the environmental protection index of countries in the world improves constantly, and produces the environmental issue that amorphous silicon aluminium produced and is on the rise.Therefore, the good and free of contamination amorphous aluminum silicide of nature of production just becomes more and more important.
CN 1015638B has introduced a kind of low-voltage hydrogenation denitrification catalyst of fraction oil of petroleum, and wherein used carrier is the amorphous aluminum silicide that adopts Carbonization Preparation.Raw material is sodium metaaluminate and carbon dioxide, adds minor amount of silicon, SiO
2Content only accounts for 2% in carrier.The specific surface and the pore volume of this amorphous aluminum silicide are lower, can not provide higher metal dispersity for active component, and acidity is also lower, is not suitable for use in carrier of cracking.
GB2166971 discloses a kind of preparation method of amorphous aluminum silicide.Its preparation method is that composite alkali aluminum salt and silicate form mixed liquor about pH12, reacts preparation silica-alumina supports, its product specific surface 277m afterwards with aluminum sulfate
2/ g, pore volume 0.31mL/g contain SiO
235wt%, its shortcoming is that pore volume and specific surface are low, as the sial of supported catalyst, can not provide higher metal dispersity for active component.
CN1210755A discloses a kind of amorphous aluminum silicide and preparation method thereof, its silica content 10～50wt%, specific surface 350～600m
2/ g, pore volume 0.8～1.5mL/g, infrared acidity 0.25～0.55mmol/g, its preparation process is NH
4OH and aluminic acid form aluminium oxide analysing silicon hydrochlorate afterwards earlier, and this contains ammonia, nitrogen waste water, contaminated environment with generation.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above method, a kind of preparation method of amorphous aluminum silicide is provided.This method preparation technology is simple, cost is low, pollution-free.The amorphous aluminum silicide of gained has suitable specific surface, pore volume, proper acidic, and have the silica of q.s.
The preparation method of amorphous aluminum silicide of the present invention comprises the steps:
A, prepare sodium aluminate solution and silicon-containing compound solution respectively;
B, in sodium aluminate solution, add part silicon-containing compound solution, then feed concentration be 20v%～60v% (be preferably 30v%～50v%), flow is 2～8Nm
3The CO of/h
2After the gas 3～15 minutes, add remaining silicon-containing compound solution, make silicon oxide-containing 8wt%～50wt% in the final amorphous aluminum silicide product; Wherein the reaction temperature of this process is controlled at 10～40 ℃, is preferably 15～35 ℃, stops to feed CO
2The condition of gas is 8～11 for the pH value of this system;
C, under the control temperature and pH value of step b, said mixture ventilates and to stablize 10～30 minutes;
D, the solidliquid mixture of step c gained is filtered, filter cake washing, drying, amorphous aluminum silicide.
Among the step a, described silicon-containing compound is a sodium metasilicate; The concentration of the sodium aluminate solution of being prepared is 15～55g Al
2O
3/ L is preferably 15～35g Al
2O
3/ L, the concentration of silicon-containing compound solution is 50～200gSiO
2/ L is preferably 50～150g SiO
2/ L.
Adding part silicon-containing compound solution described in the step b, the addition of promptly described silicon-containing compound solution is the 5wt%～98wt% of the total addition of silicon-containing compound solution, is preferably 5wt%～50wt%.
Sodium aluminate solution, silicon-containing compound solution and CO among the step b
2The addition sequence of gas has following several situation: (1) adds the part silicon-containing compound in sodium aluminate after, feed CO
2Gas, the pH value of mixture reaches between 8～11, stops to feed CO
2Gas, and then in mixture, add residue silicon-containing compound solution; (2) in sodium aluminate, behind the adding part silicon-containing compound, feed CO
2Gas after a period of time, leads to CO on one side again
2Gas adds residue silicon-containing compound solution on one side, when the pH of mixture value reaches between 8～11, stops to feed CO
2Gas.
With the dope filtration of step c gained and be washed till neutrality, then 80～150 ℃ of dryings 2～12 hours with 50～90 ℃ of deionized waters.
Adopt the character of amorphous aluminum silicide of method of the present invention preparation as follows: silicon oxide-containing 8wt%～50wt%, specific surface are 300～550m
2/ g, preferably 300～500m
2/ g, pore volume are 0.7～1.5mL/g, 0.7～1.2mL/g preferably, and the pore volume of bore dia＞4nm accounts for the 80v%～95v% of total pore volume, and infrared acidity is 0.32～0.50mmol/g.
The acid difference of amorphous aluminum silicide causes the difference of cracking function, the present invention can prepare different acid amorphous aluminum silicides by the ratio that changes silica content and front and back adding silica, can also prepare the amorphous aluminum silicide of macropore, Large ratio surface in silica content variation scope greatly.
The present invention is to be the method for the active amorphous aluminum silicide of feedstock production with sodium aluminate, silicon-containing compound and carbon dioxide.This method is particularly suitable for adopting the producer of sintering process explained hereafter aluminium oxide, with product sodium aluminate solution in the middle of it and by-product CO
2Gas is that raw material is produced amorphous aluminum silicide, the Na that is produced
2CO
3Mother liquor can be circulated to sintering process so that part Na to be provided
2CO
3, form closed cycle, and do not produce contaminated wastewater.
Main feature of the present invention is as follows:
1, the present invention adopts sodium aluminate solution cheaply, becomes glue under change pH values, control easily, and technology is simple.
2, the present invention adds the silicon source side just, can produce amorphous aluminum silicide of different nature by adjusting silica content and secondary adding proportion of silica.
3, in the amorphous aluminum silicide preparation process, directly by CO
2Stir with wind, do not need electric power to stir, energy consumption is low.
4, production process does not have the discharging that contains ammonia, nitrogen waste water, no environmental protection pollution problem.
The amorphous aluminum silicide that the inventive method makes is applicable to the catalyst that PETROLEUM PROCESSING is required, can be used as the carrier component of catalytic cracking, hydrocracking and hydrotreating catalyst, also can be used as the carrier component of olefin oligomerization catalyst.
The specific embodiment
Further describe the present invention below by example:
Example 1
It is 200g Al that solid sodium aluminate is mixed with concentration
2O
3The dense sodium aluminate solution of/L, being diluted to concentration again is 20g Al
2O
3/ L sodium aluminate working solution is got and is contained SiO
2The sodium silicate solution of 28wt%, being diluted to concentration again is 100g SiO
2/ L sodium metasilicate working solution.Get 10L sodium aluminate working solution and place in the glue jar, add 0.3L sodium metasilicate working solution then, 24 ℃ of control reaction temperatures, the feeding flow is 6Nm
3/ h, concentration are the CO of 50v%
2Gas stops logical CO when the pH value reaches 9.0
2, add 0.6L sodium metasilicate working solution, ventilate then and stablized 10 minutes, dope filtration also is washed till neutrality with 75 ℃ of deionized waters.120 ℃ of dryings 8 hours, crushing screening got amorphous aluminum silicide product G L-1.
Example 2
Sodium aluminate working solution concentration 25g Al
2O
3/ L, sodium metasilicate working solution concentration 100g SiO
2/ L gets 10L sodium aluminate working solution and places in the glue jar, adds 0.5L sodium metasilicate working solution then, 20 ℃ of control reaction temperatures, and the feeding flow is 4Nm
3/ h, concentration are the CO of 35v%
2Gas fed after 5 minutes, added 0.6L sodium metasilicate working solution while ventilate, and stopped when pH value reaches 9.5, ventilated then and stablized 15 minutes, and the dope filtration drying is with example 1, amorphous aluminum silicide product G L-2.
Example 3
Sodium aluminate working solution concentration 30g Al
2O
3/ L, sodium metasilicate working solution concentration 150g SiO
2/ L gets 10L sodium aluminate working solution and places in the glue jar, adds 0.20L sodium metasilicate working solution then, 30 ℃ of control reaction temperatures, and the feeding flow is 7Nm
3/ h, concentration are the CO of 44v%
2Gas fed after 4 minutes, added 0.05L sodium metasilicate working solution again, stopped when pH value reaches 10.0, ventilated then and stablized 20 minutes, and the dope filtration drying is with example 1, amorphous aluminum silicide product G L-3.
Example 4
Sodium aluminate working solution concentration 15g Al
2O
3/ L, sodium metasilicate working solution concentration 50g SiO
2/ L gets 10L sodium aluminate working solution and places in the glue jar, adds 1L sodium metasilicate working solution then, 18 ℃ of control reaction temperatures, and the feeding flow is 4Nm
3/ h, concentration are the CO of 40v%
2Gas fed after 5 minutes, added 2L sodium metasilicate working solution while ventilate, and stopped when pH value reaches 9.5, ventilated then and stablized 20 minutes, and the dope filtration drying is with example 1, amorphous aluminum silicide product G L-4.
Example 5
Sodium aluminate working solution concentration 25g Al
2O
3/ L, sodium metasilicate working solution concentration 50g SiO
2/ L gets 10L sodium aluminate working solution and places in the glue jar, adds 0.4L sodium metasilicate working solution then, 21 ℃ of control reaction temperatures, and the feeding flow is 5Nm
3/ h, concentration are the CO of 40v%
2Gas fed after 4 minutes, added 0.4L sodium metasilicate working solution again, stopped when pH value reaches 9.0, ventilated then and stablized 20 minutes, and the dope filtration drying is with example 1, amorphous aluminum silicide product G L-5.
Comparative example 1
Sodium aluminate working solution concentration 25g Al
2O
3/ L, sodium metasilicate working solution concentration 100g SiO
2/ L gets 10L sodium aluminate working solution and places in the glue jar, adds 1.1L sodium metasilicate working solution then, 20 ℃ of control reaction temperatures, and the feeding flow is 5Nm
3/ h, concentration are the CO of 40v%
2Gas stops to feed CO when pH value reaches 9.0
2, ventilating then and stablized 15 minutes, dope filtration also is washed till neutrality with 75 ℃ of deionized waters.120 ℃ of dryings 8 hours, crushing screening got reference amorphous products GL-6.
Character by embodiment 1～5 and comparative example 1 prepared amorphous aluminum silicide product sees Table 1.
Table 1 amorphous aluminum silicide product property
| Production code member | GL-1 | GL-2 | GL-3 | GL-4 | GL-5 | GL-6 | The reference amorphous aluminum silicide |
| Specific surface, m 2/g | 430 | 470 | 480 | 350 | 480 | 270 | 220 |
| Pore volume, mL/g | 0.84 | 0.99 | 1.20 | 0.75 | 1.07 | 0.59 | 0.55 |
| The pore volume of aperture＞4nm accounts for total pore volume, v% | 88 | 90 | 92 | 80 | 90 | 70 | - |
| SiO 2，wt％ | 30 | 30 | 10 | 50 | 20 | 30 | 30 |
| Infrared acidity, mmol/g | 0.44 | 0.47 | 0.32 | 0.55 | 0.40 | 0.40 | 0.36 |
The reference amorphous aluminum silicide is the industrial products of Fushun Petrochemical Company catalyst plant.This product employing aluminium chloride, sodium metasilicate and ammoniacal liquor are neutralized into the preparation of glue method.
Claims (10)
1, a kind of preparation method of amorphous aluminum silicide comprises the steps:
A, prepare sodium aluminate solution and silicon-containing compound solution respectively;
B, add silicon-containing compound solution in sodium aluminate solution, the addition of described silicon-containing compound solution is the 5wt%～98wt% of the total addition of silicon-containing compound solution, is that 20v%～60v%, flow are 2～8Nm feeding concentration then
3The CO of/h
2After the gas 3～15 minutes, add residue silicon-containing compound solution, make silicon oxide-containing 8wt%～50wt% in the final amorphous aluminum silicide product; Wherein the reaction temperature of this process is controlled at 10～40 ℃, stops to feed CO
2The condition of gas is 8～11 for the pH value of this system;
C, under the control temperature and pH value of step b, said mixture was stablized 10～30 minutes;
D, the solidliquid mixture of step c gained is filtered, filter cake washing, drying, amorphous aluminum silicide;
Wherein among the step a, described silicon-containing compound is a sodium metasilicate; The concentration of the sodium aluminate solution of preparation is 15～55g Al
2O
3/ L, the concentration of silicon-containing compound solution is 50～200g SiO
2/ L.
2, preparation method according to claim 1 is characterized in that the concentration of the sodium aluminate solution prepared among the step a is 15～30g Al
2O
3/ L, the concentration of silicon-containing compound solution is 5～150g SiO
2/ L.
3, preparation method according to claim 1, the addition that it is characterized in that silicon-containing compound solution described in the step b is the 5wt%～80wt% of the total addition of silicon-containing compound solution.
4, preparation method according to claim 1, the addition that it is characterized in that silicon-containing compound solution described in the step b is the 20wt%～80wt% of the total addition of silicon-containing compound solution.
5, preparation method according to claim 1, the addition that it is characterized in that the described silicon-containing compound solution of step b is the 20wt%～50wt% of the total addition of silicon-containing compound solution.
6, preparation method according to claim 1, the addition that it is characterized in that the described silicon-containing compound solution of step b is 1/3～50wt% of the total addition of silicon-containing compound solution.
7, preparation method according to claim 1 is characterized in that the CO that feeds among the step b
2The concentration of gas is 30v%～50v%.
8, preparation method according to claim 1 is characterized in that the control reaction temperature is 15～35 ℃ among the step b.
9, preparation method according to claim 1, when it is characterized in that adding part silicon-containing compound solution earlier among the step b, sodium aluminate solution, silicon-containing compound solution and CO
2The addition sequence of gas has following two kinds of situations: (1) adds the part silicon-containing compound in sodium aluminate after, feed CO
2Gas, the pH value of mixture reaches between 8～11, stops to feed CO
2Gas, and then in mixture, add residue silicon-containing compound solution; (2) in sodium aluminate, behind the adding part silicon-containing compound, feed CO
2Gas after a period of time, leads to CO on one side again
2Gas adds remaining silicon-containing compound solution on one side, when the pH of mixture value reaches between 8～11, stops to feed CO
2Gas.
10, preparation method according to claim 1 is characterized in that the washing described in the steps d is will become the slurries behind the glue to be washed till neutrality with 50～90 ℃ of deionized waters, and described drying is 80～150 ℃ of dryings 2～12 hours.
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