CN1271270A - Cleaning compositions - Google Patents

Abstract

A rinse-off liquid personal cleansing composition comprising surfactant and water wherein the composition comprises less than 8% of a first surfactant selected from a crystallizing anionic surfactant and greater than 3% of a second surfactant selected from non-crystalizing anionic surfactants, amphoteric surfactants, nonionic surfactants, zwitterionic surfactants, and mixtures thereof, and wherein the composition has a Mean Rinse Feel Value of 3.5 or less as measured by the Rinse Feel Panel Test. The personal cleansing compositions of the invention provide excellent rinse feels and skin mildness.

Description

Cleasing compositions

Affiliated field

The present invention relates to Cleasing compositions.Be specifically related to gentle personal cleaning compositions, said composition has improved rinsing sense and advantages of good skin sense quality and foam characteristics, be applicable to cleaning and conditioning skin and/or hair simultaneously, and for example can foam bath with preparation, bathe with product, skin cleaner, hands with, face with and forms such as body and function abluent, shampoo use.

Background technology

Gentle cosmetic composition should satisfy following some conditions, comprises spatter property, foaminess and to the mildness/low irritant/good usability of skin, hair and eye mucosa.Skin is by which floor cellularity, and this counts, and confluent monolayer cells coats and the protection subcutaneous tissue.Keratin and collagen fiber albumen constitute the skeleton of skin texture.The outermost layer of these cellular layers is called horny layer.Hair has the protective skin equally, is coated on the hair fiber outside, is called cuticula.Anion surfactant can infiltrate horny layer and cuticula, destroys the globality of film through degreasing, and buffer action and water retaining function can be lost.This influence to skin and hair overcoat can make the skin roughening, and can stimulate eye, and surfactant finally can be interacted with keratin and hair proteins, produces stimulation.Finally make surfactant cause immunoreation and produce stimulation.

Skin or hair should be leniently cleaned in ideal cosmetic cleansing agent, can not make the struetural lipid of hair and skin destroy and/or drying, and can not stimulate the eye mucosa or make skin tight after frequent the use.There are deficiency in great majority foaming soap, bath in this respect with product, shampoo and soap bar.

Known some synthetic surfactant is gentle.But the major defect of most gentle synthetic surfactant systems is: when preparation synthetic detergent system was used for hair washing or personal cleanliness, they had and are described as " sliding " or " non-retardance " rinse feel, and this is that some consumer dislikes.On the other hand, adopt certain surfactant such as potassium laurate can reach suitable rinse feel, but can lose clinical skin mildness.These 2 facts make that the selection to suitable surfactant need reach a kind of delicate balance in the process for preparation that reaches rinsing and mildness effect.

Therefore just need some can produce " retardance " rinse feel, the personal cleaning compositions that has simultaneously good skin mildness again, in addition, these compositionss also have the good quality production characteristic, the dermal sensation characteristic during as foaming, cleaning, stability, thickening, rheological characteristic and use.

The known personal cleaning compositions that has certain poly ﹠ Alpha ,-olefin oil to be used for skin and hair.WO97/09031, US-A-5441730, WO 94/27574, EP-A-0692244, among WO 96/32092 and the WO 96/06596 relevant for the reference material that in personal cleanliness's composition formula, uses this class oil.Also the silicone oil of known hydrophobically modified also is used for personal cleaning compositions, discloses embodiment in JP 05-310540.

Surprisingly, people just find to have the rinsing sense of " retardance " up to now, the personal cleaning compositions that has simultaneously good gentle characteristic again is by with so-called " retardance " and " non-retardance " surfactant and some water-insoluble oil, suitably combines and obtains as some poly ﹠ Alpha ,-olefin oil or the improved silicone oil of hydrophobic.

The rinsing sense of " retardance " is considered to relevant with the increase of moist skin coefficient of friction, but is not to be subjected to theoretic restriction.It is believed that a very important mechanism of action of such oil is their deposition capability and the ability that changes the skin surface energy, even skin surface is more hydrophobic.In rinse cycle, moisture film is considered to the lubricant of skin, and along with the hydrophobicity increase on surface, moisture film is destroyed and dried in the surface.Therefore at first attenuation of moisture film is replaced then, allows the direct contact between some surfaces simultaneously.These two kinds of variations all can increase friction and produce the rinsing sense of " retardance ".

General introduction of the present invention

According to the invention provides the personal cleaning compositions that floats type, wherein contain water and surfactant, wherein compositions comprises the first surface activating agent that is less than 8% weight and greater than the second surface activating agent of 3% weight, the first surface activating agent is selected from the crystallization anion surfactant, the second surface activating agent is selected from noncrystalline anion surfactant, amphoteric surfactant, non-ionic surface active agent and zwitterionic surfactant and composition thereof, wherein the average rinse feel value of compositions is 3.5 or lower, and this value is recorded by rinse feel panel test method.

Compositions of the present invention is improved rinse feel, and is very gentle to skin simultaneously.

Herein all concentration and ratio all are based on the weight of Cleasing compositions, unless specify in addition.The chain length of surfactant also is based on the weight average chain length, unless specify in addition.

Detailed description of the present invention

Liquid cleansing composition herein contains water and comprises the surfactant of crystal surface activating agent and noncrystalline surfactant.Said composition has 3.5 or lower average rinse feel value, and this value is recorded by following rinse feel panel test method.Compositions preferably has 3.25 or lower average rinse feel value, and more preferably 3.0 or lower.In preferred embodiments, the average rinse feel value of compositions is 3.5 to 1.0.

Term used herein " rinse feel " means, the dermal sensation in the rinsing foaming process after using the Cleasing compositions cleaning skin.The rinse feel type that compositions of the present invention produces can use following term description, as " retardance " rinse feel, and " class is saponaceous " rinse feel, " not cunning " or " not stick-slip " rinse feel." retardance " like this, " class is saponaceous ", " not sliding " or " not stick-slip " rinse feel can be felt by the frictional force that increases between hands and skin in the rinsing foaming process.

Term used herein " water-insoluble " is about oil used herein, and it is a kind of other adjuvant and other composition as described herein of at room temperature need not adding, and promptly is insoluble to the material of distilled water substantially.Surfactant

Basis of the present invention is one or more surfactants.The present composition comprises and is lower than 8%, preferably be lower than the first surface activating agent of 6% weight, with second surface activating agent greater than 3% weight, the first surface activating agent is selected from the crystallization anion surfactant, and the second surface activating agent is selected from noncrystalline anion surfactant, amphoteric surfactant, non-ionic surface active agent and zwitterionic surfactant and composition thereof.

The term here " crystallization anion surfactant " refers to such anion surfactant, and promptly its monovalent salt (as sodium, potassium or ammonium salt) can produce precipitation in the presence of calcium ion.In addition, the term here " crystal surface activating agent " is meant such surfactant, promptly can produce precipitation under following situation and become turbid solution by the solution of substantial transparent, this situation is meant by about 1: 1 to about 2: 1 surfactant: the mol ratio of calcium is with the Ca of 3.56mmol ²⁺Ion (20 ° of d water hardness, temperature is with 10% surfactant solution) progressively dilutes 10% this surfactant solution (temperature of this surfactant is its temperature that is the substantially transparent shape (30-50 a ℃, preferred about 30 ℃)).This effect also is considered to have departed from the perfect condition of the surface tension curve of surfactant.The crystallization anion surfactant produces " retardance " rinsing sense on skin.The term here " noncrystalline anion surfactant " refers to such anion surfactant, and it can not present the behavior of above-mentioned crystal surface activating agent, does not promptly produce precipitation in the presence of calcium ion." noncrystalline " anion surfactant generally produces " stick-slip " rinsing sense on skin.

The surfactant that is applicable to the present composition generally has the oleophylic chain length of about C6 to about C22.Though bound by theory not, type, length and the distribution of surfactant oleophylic chain can influence the precipitation behavior of surfactant.For example use greater than 90% single chain length and the longer chain length of use and can strengthen calcium sensitivity and strengthen surfactant " retardance " character.On the other hand, adopt the wide distribution of chain length branching and/or short and/or chain length can hinder " stick-slip " character that precipitates and increase surfactant.

Said composition comprises and is lower than 8%, preferably is lower than 6%, and preferred 0% to about 5%, 1% first surface activating agent especially to about 5% weight, and it is selected from " crystalline " or " retardance " anion surfactant.

Here the suitable anion surfactant of Ding Yi " crystalline " or " retardance " type comprises alkyl sulfate, methyl-acyl taurine salt, acylglycine salt, N-acyl glutamate, acyl isethinate, alkyl sulfo succinate, alkyl phosphate, acyl sarcosinates and acylaspartic acid salt, linear alkylbenzene sulfonate (LAS), soap and alpha-alkene sulfonate and composition thereof.

Here preferred " crystalline " anion surfactant of Shi Yonging comprises the N-acyl glutamate, as lauroyl and myristoyl glutamate, Glu; Acyl isethinate is as lauroyl and myristoyl isethionate; And alkyl phosphate, as lauroyl and myristoyl phosphate ester.

Said composition comprises greater than 3%, be preferably greater than 5%, preferred about 5% to about 30%, especially about 5% second surface activating agent to about 20% weight, it is selected from " crystalline " or " non-retardance " surfactant, amphoteric surfactant, nonionic surfactant and zwitterionic surfactant, and composition thereof.

Here the suitable surfactant of Ding Yi " amorphous " or " non-retardance " type comprises ethoxylated alkyl sulfates, alkyl ethoxy carboxylate, alkyl glyceryl ether sulfonate, alkyl ethoxy sulfosuccinate, α-alpha-sulfonated fatty acid, their salt and/or ester, ethoxylated alkyl phosphate ester, ethoxylated alkyl glycerol ether sulfonate, alkane sulfonate, alkoxyl amidosulfonic acid salt and composition thereof.

Here preferred " amorphous " surfactant is an ethoxylated alkyl sulfates, as lauryl ether-3 ammonium sulfate.

The total content of anion surfactant is preferably about 5% to about 20%, especially about 5% to about 15% weight in the present composition.

Other surfactant that is suitable for that is used for said composition comprises the water soluble surfactant active, and it comprises non-ionic, amphoteric and/or zwitterionic surfactant.Here Ding Yi the water solublity relevant with surfactant is meant that molecular weight is lower than about 20,000 surfactant, and surfactant wherein at room temperature when soluble in water, can form transparent isotropic aqueous solution with 0.2%w/w.The surfactant that is applicable to the present composition has the oleophylic chain length of about C6 to about C22 usually.The gross weight of surfactant is preferably about 2% to about 40%, and more preferably from about 3% to about 20% weight, and preferred about 5% to about 15% weight.Compositions preferably comprises the mixture of anion surfactant and amphion and/or amphoteric surfactant.The weight ratio of anion surfactant and amphion and/or amphoteric surfactant is about 1: 10 to about 10: 1, preferred about 1: 5 to about 5: 1, and more preferably from about 1: 3 to about 3: 1.The compositions that in the scope of the invention other is suitable for comprises the mixture of anionic, zwitterionic and/or amphoteric surfactant and one or more non-ionic surface active agents.

The present composition can comprise about 0.1-20% (weight), is more preferably 0.1-10% (weight), especially preferably is about the water soluble nonionic surfactant of 1-8% (weight).This class surfactant comprises sucrose polyfatty acid esters surfactant, C ₁₀-C ₁₈Alkyl poly glucoside, and the polyhydroxy fatty acid amide surfactants shown in following general formula (III):

Preferred N-alkyl, N-alkoxyl or N-aryloxy group, polyhydroxy fatty acid amide surfactants are R in the formula (III) ₈Be C ₅-C ₃₁Alkyl, preferred C ₆-C ₁₉Alkyl comprises straight or branched alkyl and alkenyl, or their mixture, and R ₉Be generally H, C ₁-C ₈Alkyl or hydroxyalkyl, preferable methyl or formula-R ¹-O-R ²Shown group, wherein R ¹Be C ₂-C ₈Alkyl comprises straight chain, side chain and cyclic group (comprising aryl), and is preferably C ₂-C ₄Alkylidene, R ²Be C ₁-C ₈Straight chain, side chain and cyclic hydrocarbon radical comprise aryl and oxygen-containing hydrocarbon base, preferably C ₁-C ₄Alkyl, particularly methyl or phenyl.Z ₂It is the polyhydroxy alkyl structure division that comprises the straight-chain alkyl that contains 2 (when adopting glyceraldehyde) or 3 (when adopting other reducing sugar) hydroxyls at least, perhaps their alkoxyl derivatives (preferred ethoxylated derivative or propoxylated derivative), wherein hydroxyl directly links to each other with hydrocarbyl chain.Z ₂Preferably react (ammination) derived from reducing sugar, most preferably Z through reductive amination ₂It is sugar alcohol base (glycityl) part.The reducing sugar that is suitable for comprises glucose, fructose, maltose, lactose, galactose, mannose, and xylose, and glyceraldehyde.Except that each above-mentioned sugar, also can adopt following raw material, as high glucose corn syrup, high-fructose corn syrup and high malt sugar corn syrup.Can obtain being used for Z by these syrup ₂The saccharic composition mixture.Be understood that and do not get rid of the raw material that other is suitable for.Z ₂Be preferably selected from CH ₂-(CHOH) _n-CH ₂OH, CH (CH ₂OH)-(CHOH) _N-1-CH ₂OH, CH ₂(CHOH) ₂(CHOR ') CHOH)-CH ₂OH, wherein n is the integer of 1-5, comprises end value, and R ' is H or cyclic monosaccharides or ring polysaccharide, and their alkyl derivative.According to described, sugar alcohol base most preferably, wherein n is 4, especially-CH ₂-(CHOH) ₄-CH ₂OH.

Most preferred polyhydroxy fatty acid amide is suc as formula R ₈(CO) N (CH ₃) CH ₂(CHOH) ₄CH ₂Shown in the OH, R wherein ₈Be C ₆-C ₁₉Straight chained alkyl or alkenyl.In the following formula chemical compound, R ₈-CO-N＜for example can be coconut oleoyl amine, stearmide, oleamide, lauramide, myristamide, decyl amide, caprylamide, palmitamide, Adeps Bovis seu Bubali amide etc.

The exemplary embodiment that is applicable to the nonionic surfactant of the present composition includes primary amine, as coconut oleoyl amine (the Adagen 160D that Witco produces ^(TM)) and alkanolamide, as coconut oleoyl amine MEA (the Empilan CME that Albright and Wilson produces ^(TM)), PEG-3 coconut oleoyl amine, coconut oleoyl amine DEA (the Empilan CDE that Albright and Wilson produces ^(TM)), lauramide MEA (the Empilan LME that Albright and Wilson produces ^(TM)), lauramide MIPA, lauramide DEA, and their mixture.

The amphoteric surfactant of Shi Yonging includes the ammonium salt derivatives of (a) structural formula for [V] in this article:

R in the formula ₁Be C ₅-C ₂₂Alkyl or alkenyl, R ₂Be CH ₂CH ₂OH or CH ₂CO ₂M, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, R ₃Be CH ₂CH ₂OH or H; (b) the amino-alkane hydrochlorate of formula (VI):

R ₁NH (CH ₂) _nCO ₂The iminodiacetic alkanoate of M formula (VII)

R ₁N[(CH ₂) _mCO ₂M] ₂And the imino group multichain alkyl salt of formula (VIII) Wherein n, m, p and q are the numbers of 1-4, and R ₁Be independently from each other above-mentioned group with M; And (c) their mixture.

Suitable (a) class amphoteric surfactant comprises the chemical compound of formula V, wherein R ₁Be C ₁₁H ₂₃The commercially available prod of suitable (a) class amphoteric surfactant is Miranol and Empigen.

According to the CTFA nomenclature principle, the material that is suitable among the present invention comprises cocos nucifera oil acyl both sexes carboxyl propionate, cocos nucifera oil acyl both sexes carboxyl propanoic acid, cocos nucifera oil acyl both sexes acetate, cocos nucifera oil acyl both sexes diacetin (perhaps being called cocos nucifera oil acyl both sexes carboxyl glycinate), lauroyl both sexes sodium acetate (being also referred to as lauroyl both sexes carboxyl Glycine sodium).Concrete commercial product comprises the material that those are sold with following trade name: Ampholak 7TX (many propyl group of carboxyl methyl Adeps Bovis seu Bubali amine sodium), Empigen CDL 60 and CDR 60 (Albright ﹠amp; Wilson), Miranol H2M Conc.Miranol C2M Conc.N.P., Miranol C2M Conc.O.P., Miranol C2M SF, Miranol CM Special, MiranolUltra L32 and C32 (Rhone-Poulenc); Alkateric 2CIB (AlkarilChemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, MonatericCSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); And Schercotic MS-2 (Scher Chemicals).

Certainly, the commercially available amphoteric surfactant of some these types is with the form preparation of the electric neutrality complex of following material with sell, for example, perhaps have anion sulfate or sulfosalt surfactant, especially those Sulfated C with the hydroxide counter ion counterionsl gegenions ₈-C ₁₈Alcohol, C ₈-C ₁₈The alcohol of ethoxylation or C ₈-C ₁₈The surfactant of acyl glyceride type.Yet, consider the compositions of preferably essentially no (not ethoxylation) Sulfated pure surfactant from mildness and product stability aspect.Also should note: in this article, the concentration of amphoteric surfactant and weight ratio are based on the surfactant of non-complexed forms formula, generally arbitrary anionic surfactant counter ion counterionsl gegenions are taken as the part for total anionic surfactant content.

The example of the preferred amphoteric surfactant of type (b) comprise by Berol Nobel with the many trimethylenes of N-alkyl that trade name Ampholak X07 and Ampholak 7CX sell many-salt of carboxymethyl amine and salt thereof, especially tri ethanol ammonium salt and N-lauryl-Beta-alanine and N-lauryl-imino group-dipropionic acid.Sell such material with trade name Deriphat (by Henkel) and Mirataine (by Rhone-Poulenc).

The compositions of this paper also can comprise about 0.1% to about 20%, more preferably about 0.1% to about 10%, especially is about 1% to about 8% zwitterionic surfactant.

The water solublity beet alkali surface activator that is suitable for being included in the compositions of the present invention comprises formula R ₅R ₆R ₇N ⁺(CH ₂) _nCO ₂The amido betaines of the alkyl betaine of M and following formula (IX):

R wherein ₅Be C ₅-C ₂₂Alkyl or alkenyl, R ₆And R ₇Be C independently ₁-C ₃Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and n, m be the number of 1-4 separately.Preferred betanin comprises cocos nucifera oil acylamino-propyl-dimethyl carboxymethyl betaine (with trade name Tego betanin available from THGoldschmidt), and lauryl acylamino-propyl-dimethyl carboxymethyl betaine is (with trade name EmpigenBR available from Alright ﹠amp; Wilson and with trade name Tego betanin L10S available from THGoldschmidt).

The water solublity sulfobetaines surfactant that is suitable for being included in the compositions of the present invention comprises the alkylamidoalkyl sulfobetaines with following formula;

R wherein ₁Be C ₇-C ₂₂Alkyl or alkenyl, R ₂And R ₃Be C independently ₁-C ₃Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and m and n are the numbers of 1-4.The suitable this paper's of being used for is cocamidopropyl propyl hydroxy sulfobetaines, and it is available from Rhone-Poulenc with trade name Mirataine CBS.

The water-soluble amine oxides surfactant that is suitable for being included in the compositions of the present invention comprises alkyl amine oxide R ₅R ₆R ₇NO and acylamino-amine oxide with following formula:

R wherein ₅Be C ₁₁-C ₂₂Alkyl or alkenyl, R ₆And R ₇Be C independently ₁-C ₃Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and m is the number of 1-4.Preferred amine oxide comprises cocos nucifera oil acylamino-propyl group amine oxide, lauryl dimethyl amine oxide and myristyl dimethyl amine oxide.Non-essential component

In addition, compositions herein can also contain a variety of non-essential components.The non-limiting instance of this class component is as described below.

Preferred material has in order to provide especially that preferred material is a water-insoluble oil in the compositions of " retardance " rinse feel.The water-insoluble oil that is suitable in personal cleaning compositions of the present invention comprises (a) highly branched poly alpha olefin, and its structural formula is as follows:

R in the formula ¹Be H or C ₁-C ₂₀Alkyl, R ⁴Be C ₁-C ₂₀Alkyl, R ²Be H or C ₁-C ₂₀, R ³Be C ₅-C ₂₀, n is 0 to 3 integer, and m is 1 to 1000 integer, and its number-average molecular weight is about 1000 to about 25,000, preferably about 2000 to about 6000, more preferably about 2500 to about 4000.The preferred poly alpha olefin viscosity of (a) used herein class for about 300cst to about 50, it is about 12 that 000cst, preferably about 1000cst arrive, 000cst, more preferably about 1000cst arrives about 4000cst, this viscosity is to record under 40 ℃ with ASTM D-445 method.(a) class oil also can have unsaturation to a certain degree, but preferably saturated.

The example of this class oil includes poly decene oil, as Mobil Chemical Company (P.O.Box3140, Edison, New Jersey 08818, USA) the poly decene oil of Chu Pining, its commodity are called Puresyn 100.

Other water-insoluble oil of Shi Yonging comprises those (b) class oil in this article, and they are the poly alpha olefins with following structural formula:

R in the formula ¹Be H or C ₁-C ₄Alkyl, R ⁴Be C ₁-C ₄Alkyl, R ²Be H or C ₁-C ₄Alkyl or C ₂-C ₄Thiazolinyl, R ³Be H or C ₁-C ₄Alkyl or C ₂-C ₄Thiazolinyl, n is 0 to 3 integer, m is 1 to 1000 integer, its number-average molecular weight is about 600 to about 1,000, preferably about 750 to about 1000, particularly preferably is about 800 to about 1000.Preferably to about 50, in the scope of 000cst, it is about 10 that preferably about 1000cst arrives at about 500cst for the basic material viscosity of (b) class branching alkane (alkene), 000cst, and this viscosity is to record at 40 ℃ with ASTM D-445 method.(b) class oil can be undersaturated also can be saturated.

The basic material of (b) class alkane (alkene) of Shi Yonging is a butylene in this article, isoprene, terpenes, the polymer of styrene or isobutene., the preferably polymer of butylene or isobutene..

(b) example of class alkane (alkene) base oil includes polybutene oil, as the polybutene oil of the commodity of Amoco product Indopol 40 by name and Indopol 100, and the polyisobutylene oil of the Parapol 950 of the Permethyl 104A of Presperse Inc. product and Exxon Chemical Inc. product.

In addition, the hydrophobically modified polysiloxanes that has following structural formula in addition that is suitable in this article: R is C in the formula ₁-C ₄Alkyl or phenyl, R ' is C ₁-C ₂₀Alkyl or phenyl, z is 5 to 21, the scope of x number average value is about 20 to about 400, the scope of y number average value is about 0 to about 10, the scope of x+y is 30 to 400.Its x value of preferable material is 40 to 200, preferably 60 to 100, and the value of y is 0 to 5, preferably 0, x and y's and be 60 to 100.Alkylidene chain z can be a straight or branched.In addition, the polysiloxanes skeleton of the polysiloxanes of hydrophobically modified can have the branching of less degree, thereby produces resin (as MDQ or MDT resin).

The example of this class oil includes following hydrophobically modified polysiloxanes: the commodity that GE Silicones produces SF 1632 (C by name ₁₆-C ₁₈The alkyl methyl polysiloxanes) polysiloxanes, and octyl group and decyl methyl polysiloxane.

The mixture of above-mentioned water-insoluble oil also is suitable in this article.

Consider from the angle that produces improved rinsing sense for compositions, particularly preferably be highly branched (a) class poly alpha olefin, its number-average molecular weight is about 2500 to about 4000, viscosity arrives about 2000cst (ASTMD-445 for about 100cst, 45 ℃), the poly alpha olefin of the commodity Puresyn 100 by name that produces as Mobil.

In preferred embodiments, the number average bead diameter of used in this article water-insoluble oil arrives in about 500 microns scope about 1, preferably about 5 to about 200 microns, more preferably about 5 to 50 microns, particularly preferably is about 5 to 20 microns.

For compositions herein, preferably, it can not only produce the rinsing sense of " retardance " when cleaning on skin, and in the sensation that produces " not sticking " or " inadhesion ".Therefore, preferably use the water-insoluble oil that can be considered to " not sticking ".The viscosity degree of water-insoluble oil can record with the tacktech method of testing, and this method is described in detail as follows.

In preferred specific embodiments, the viscous index of water-insoluble oil used herein be Viscasil 5M (dimethyl polysiloxane) 120% or lower, this viscous index records with tacktech method of testing as described below.More preferably the viscous index of water-insoluble oil be Viscasil5M (dimethyl polysiloxane) 110% or lower.The viscous index that particularly preferably is water-insoluble oil be Viscasil 5M (dimethyl polysiloxane) 100% or lower, particularly 1% to 100%.The tacktech method of testing

Described herein tacktech method of testing is from basic viscous elasticity development.This viscosity basic theories can be summed up as the form of Stefan equation, and what the Stefan equation was described is that the disk that two liquid that approached by one deck " squeeze film " connect is separated the resistance that is run into.This method also is used for other viscosity estimation is required much skill in the field, as marking ink.Reference material about basic viscous elasticity can be referring to Phillips, J.C. and Chaing, the article of A.C. " the low speed viscosity of fluid and ink is measured ", J.Applied Polymer Science, 1995,58,881-895.

Two radiuses are the disk of r, are h by thickness, and viscosity is that the liquid film of η links to each other, and be t the action time that they are separated, and the Stefan equation of the reduced form of calculating maximum force F is as follows: $F=\frac{3.\mathrm{\π}.\mathrm{\η}{r}^4}{8.t.h^2}......\left(1\right)$

Equation separates with speed ν when two surfaces as can be seen thus, and isolating active force becomes:

F＝k.η.ν?????????????????(2)

If wherein h and r immobilize in series of experiments, then k is a constant.

The basis of the relative tack that mensuration that Here it is is oily.

Employed instrument is Instron 4301 tension testers, and 10N is housed on the crosshead that moves, and to load box and diameter be 10 millimeters smooth steel disk.Fixed lower disk also is smooth steel disk, and it has the rubber spring (56 Newton/millimeter) of a flexibility and is fixed on horizontal device on the instrument base.Same disk and spring are assemblied in the cover contrast test.Two disks are close to and make it parallel with horizontal device.A given fixed thickness, the contact force that can calculate every kind of oil from equation is:

F＝0.0726η???????????????????(3)

Wherein η is an oil viscosity, and unit is handkerchief second, and F is a contact force, and unit is newton.Machine is set when pressure and is stopped during for F.Nearly three oil drippings place tries to get to the heart of a matter, under the disk on top.Two disks are close to, kept required power 1 minute.Draw speed is set at 1 mm/min, and maximum power is registered as the observed result of viscosity.Two disks are close together again, collect three times observed result.In order to control isolating observed result, the value of the ratio of the scope/meansigma methods of three observed results should be less than 10%.If not so, then to regather three groups of observed results.In every group of contrast test, three kinds of reference oil samples all will be arranged, they are Indopol H100, Viscasil 5M (dimethyl polysiloxane) and SF 1000.Three oil samples have the viscosity of certain limit, and these data are used to measure other oily relative tack, and the repeatability of evaluation methodology.In each test, the ratio of maximum, force all represents to become the percent to the value of Viscasil 5M (dimethyl polysiloxane) concerning a kind of oil, and this promptly is a viscous index.After these data were correctly set up, their expectation coefficient of variation was lower than 15%.Measure the main difference of one group of oil sample with the unidirectional ANOVA of the logarithmic transformation of force data.The 1. extruding force conditions of measuring viscosity as a result

Oil sample	Viscosity handkerchief second (25 ℃)	Extruding force (newton, 1 minute)
			?Puresyn?100 1	????????2.90	?????0.23
?Puresyn?40 1	????????0.77	?????0.06
			?Indopol?H100 2	????????21.0	?????1.52
?Indopol?H40 2	????????8.4	?????0.61
			SF 1000 (dimethyl polysiloxane) 3	????????1.1	?????0.08
Viscasil 5M (dimethyl polysiloxane) 3	????????5.34	?????0.39
			?Permethyl?104A 4	????????21.0	?????1.52
The decyl methyl polysiloxane 3	????????0.98	?????0.07
			The octyl group methyl polysiloxane 3	????????0.632	?????0.05

2. the average separating force under the separating rate of 1mm/min

Oil sample	Average separating force (newton)	Relative Viscasil 5M 3The viscous index of (dimethyl polysiloxane)
			?Puresyn?100 1	?????2.44	?????84.4
?Puresyn?40 1	?????1.11	?????38.4
			?Indopol?H100 2	?????5.93	?????205.2
?Indopol?H40 2	?????4.04	?????139.8
			SF 1000 (dimethyl polysiloxane) 3	?????1.34	?????46.4
Viscasil 5M (dimethyl polysiloxane) 3	?????2.89	?????100.0
			?Permethyl?104A 4	?????6.48	?????224.2
The decyl methyl polysiloxane 3	?????1.18	?????40.8
			The octyl group methyl polysiloxane 3	?????0.90	?????31.1

In statistical analysis, the viscosity of every kind of oil all is (95%) that there were significant differences.3. the repeatability of the viscous index of five groups of independent trialss

Oil sample	Relative Viscasil 5M 3The average viscous index of (dimethyl polysiloxane)	Coefficient of variation	The 95% fiducial limit lower limit upper limit
					?Indopol?H100 2	?????217.2	????13.1	??204.5	????229.9
SF 1000 (dimethyl polysiloxane) 3	?????49.8	????7.1	??38.5	????61.1

1.Mobil?Chemical?Co.(P.O.Box?314O，Edison，New?Jersey?08818，

USA) poly alpha olefin of Chu Pining

2.Amoco?Chemcial?Co.(200?East?Randolph?Drive，Chicago，Illinois

60601-7125 USA) produces

3.GE Silicones produces

4.Presperse the polyisobutylene that Inc. produces

Consider that from the angle that reduces viscosity particularly preferably be above-mentioned (a) class poly alpha olefin, its structural formula is as follows:

R in the formula ¹Be H or C ₁-C ₂₀Alkyl, R ⁴Be C ₁-C ₂₀Alkyl, R ²Be H or C ₁-C ₂₀, R ³Be C ₅-C ₂₀, n is 0 to 3 integer, m is 1 to 1000 integer, its number-average molecular weight is about 2500 to about 4000, and its viscosity is about 1, and 000cst is to about 2,000cst, this viscosity is to record under 40 ℃ with the ASTMD-445 method, is called the poly alpha olefin of Puresyn 100 as the commodity of Mobil product.

Preferably, the weight percentage of water-insoluble oil is about 0.1% to about 20%, more preferably about 0.5% to about 10% in the compositions herein, particularly preferably is about 1% to about 5%.

Another water-insoluble skin/hair-care component that is used for the composition, foam of this paper is liquid polyol carboxylate.

The preferred in this article polyol ester that uses is the liquid or liquable polyol carboxylate of non-occlusive.These polyol esters are derived by polynary alcohol radical or polyol moiety and one or more carboxylic acid group or carboxylic moiety.That is to say that these esters comprise a part of being come by polyol derivative and one or more part of being come by carboxylic acid derivatives.These carboxylates also can be by carboxylic acid derivatives.Also these carboxylates can be described as liquid polyol fatty acid ester, because for the personnel in this technical field, these two terms of carboxylic acid and fatty acid can exchange.

The preferred liquid polyol polyester of Shi Yonging contains some polyhydric alcohol, particularly sugar or sugar alcohol in the present invention, and they are by at least 4 fatty acid group esterifications.Therefore, the raw material of polyhydric alcohol must have at least 4 can esterified hydroxyl.The example of preferred polyhydric alcohols has sugar, comprises monosaccharide, disaccharide and sugar alcohol.The example that contains the monosaccharide of 4 hydroxyls has xylose and arabinose, and by the xylose that contains 5 hydroxyls, promptly xylitol is derived and next sugar alcohol.Monosaccharide, erythrose are not suitable for the present invention, because it only contains 3 hydroxyls, but are derived and next sugar alcohol by erythrose, and promptly erithritol contains 4 hydroxyls, therefore can use.The monosaccharide that contains 5 hydroxyls that is suitable for is galactose, fructose and sorbose.Derive and the next sugar alcohol that contains 6-OH by the hydrolyzate of sucrose and glucose and sorbose, be suitable for too as Sorbitol.Operable disaccharide examples of polyhydric alcohols comprises maltose, lactose and sucrose, and they all contain 8 hydroxyls.

For being used for preparing the polyester that uses in the present invention, preferred polyhydric alcohols is selected from erithritol, xylitol, Sorbitol, dextrose plus saccharose.Particularly preferably be sucrose.

Have at least the polyhydric alcohol raw material of 4 hydroxyls to have at least 4-OH to be contained about 8 fatty acid esterifications to about 22 carbon atoms.That the embodiment of these fatty acids has is sad, capric acid, lauric acid, myristic acid, myristoleic acid, Palmic acid, palmitoleic acid, stearic acid, oleic acid, castor oil acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, Ara, behenic acid and erucic acid.Fatty acid can be derived by natural or synthetic fatty acid; They can be saturated or unsaturated, comprise position isomer and geometric isomer.But for the liquid polyester that can preferably be used, what enter into that the intramolecular fatty acid of polyester should have 50% weight at least is undersaturated.Particularly preferably be oleic acid and linoleic acid, and their mixture.

The polyol fatty acid polyesters that can use in the present invention contain 4 fatty acid ester group at least.Though all by fatty acid esterification, preferably containing in the polyester, all hydroxyls that do not need polyhydric alcohol are no more than 2 nonesterified hydroxyls.Most preferably, all hydroxyls of polyhydric alcohol are all by fatty acid esterification basically, and promptly polyol moiety is basically by complete esterification.The fatty acid of esterification polyol molecule can be identical or blended, but as noted above like that, must have the unsaturated acids ester group of quite a lot of quantity to exist and make it keep liquid.

For above-mentioned viewpoint is described, by sucrose-fatty three esters, it is inapplicable in this article to be because it does not contain needed 4 fatty acid ester group.Sucrose four fatty acid esters are suitable for, but are not to be preferred, because it has the nonesterified hydroxyl more than 2.Sucrose six fatty acid esters are exactly preferred, because it has no more than 2 nonesterified hydroxyl.Very preferably all hydroxyls are all by fatty acid esterification in the chemical compound, and these chemical compounds comprise liquid sucrose eight substituted fatty acid esters.

It below is the limiting examples that is applicable to concrete polyol fatty acid polyesters of the present invention, these fatty acid poleysters contain at least 4 fatty acid ester group: glucose four oleates, the glucose tetra-ester of soy(a)-bean oil fatty acid (unsaturated), mannose four esters that mix soy(a)-bean oil fatty acid, oleic galactose four esters, linoleic arabinose four esters, xylose four linoleates, galactose five oleates, Sorbitol four oleates, Sorbitol six esters of unsaturated soy(a)-bean oil fatty acid, xylitol five oleates, sucrose four oleates, sucrose five oleates, sucrose six oleates, sucrose seven oleates, sucrose eight oleates, and their mixture.

Just as noted above like that, particularly preferred polyol fatty acid ester is that wherein fatty acid contains about 14 to about 18 carbon atoms.

The preferred in this article preferred liquid polyol polyester that uses, its complete fusing point is lower than about 30 ℃, preferably is lower than about 27.5 ℃, more preferably is lower than about 25 ℃.The complete fusing point here is to record (DSC) with differential scanning calorimetry.

The polyol fatty acid polyesters of Shi Yonging can be by a variety of method preparations in this article, and these methods are known for the personnel in the present technique field.These methods comprise: under the situation of using various catalyst, and the transesterification of polyhydric alcohol and fatty acid methyl ester, ethyl ester or fatty glyceride; The acylation of polyhydric alcohol and fat acyl chloride; The acylation of polyhydric alcohol and fatty acid anhydride; And the acylation of polyhydric alcohol and fatty acid itself.See U.S.Patent No.2,831,854; Authorized the U.S.Patent No.4 of Jandacek, 005,196 on January 25th, 1977; The polymerizing cationically conditioner

Selectively comprise the polymerizing cationically conditioner according to compositions of the present invention.In according to compositions of the present invention, the polymerizing cationically conditioner is valuable for required skin sense attribute is provided.The polymerization skin conditioning agent preferably exists to the content of about 5% (weight) with about 0.01%, and more preferably about 0.01% to about 3%, especially is about 0.01% to about 2%.

Suitable polymers is high molecular weight material (the quality mean molecule quantity that is recorded by for example light scattering is generally about 2,000 to about 5,000,000, is preferably about 5,000 to about 3,000,000, more preferably about 100,000 to about 1,000,000).

Represent other polymer of level to comprise cation guar gum, cationic polysaccharide; Derive from the cationic homopolymer and the copolymer of acrylic acid and/or methacrylic acid; The cationic cellulose resin; Quaternized hydroxyethyl cellulose ethers; Dimethyl diallyl ammonium chloride and acrylamide are or/and acrylic acid cation copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; The copolymer of amino-ethyl dimethylaminoethyl acrylate methyl ester and acrylamide, the copolymer of dimethyl diallyl ammonium chloride and acrylamide, acrylic acid/dimethyl diallyl ammonium chloride/acrylamide copolymer, the quaternized vinyl pyrrolidone acrylates or the methacrylic acid salt copolymer of amino alcohol, the copolymer of vinyl pyrrolidone and dimethylaminoethyl Methacrylamide, vinyl pyrrolidone/vinyl imidazole methochloride copolymer and polyalkylene and ethyoxyl polyalkyleneimine; Quaternised polysiloxanes, terpolymer of acrylic acid, Methacrylamide oxypropyl trimethyl ammonium chloride and acrylic acid methyl ester. and composition thereof.

Explanation by way of example, the cationic polymer that is suitable for this paper comprises cation guar gum, for example with the commercially available Hydroxyproyl Trimethyl ammonium guar gum of trade name Jaguar C-14-S (RTM) and Jaguar C-17 (RTM) and Jaguar C-16 (RTM) ((d.s. is about 0.11 to about 0.22) (comprising also that except that the cation group of above explanation d.s. is the hydroxypropyl substituent group of 0.8-1.1), and with trade name Ucare Polymer JR-30M, JR-400, LR400, Catanal (RTM) and the commercially available quaternised hydroxyethyl cellulose ethers of Celquat.Other suitable cation polymer is the homopolymer (commercially available with trade name Merquat 100) of dimethyl two allyl ammonium chloride, the copolymer of amino-ethyl methacrylate dimethyl ester and acrylamide, the copolymer of dimethyl diallyl ammonium chloride and acrylamide (commercially available) with trade name Merquat 550 and Merquat S, acrylic acid/dimethyl diallyl ammonium chloride/acrylamide copolymer (commercially available) with trade name Merquat 3330 and Merquat 3331, acrylic acid, the terpolymer of Methacrylamide oxypropyl trimethyl ammonium chloride and acrylic acid methyl ester. (selling) with trade name Merquat 2001, (for example polyquaternary ammonium salt 11 for the quaternised vinyl pyrrolidone acrylate of amino alcohol or methacrylate ester copolymer (Gafquat is commercially available with trade name), 23 and the 28 (quaternised copolymer-Gafquat 755N of vinyl pyrrolidone and amino-ethyl methacrylate dimethyl ester, and the quaternized copolymer-HS 100 of vinyl pyrrolidone and dimethyl aminoethyl methacrylate amide)), vinyl pyrrolidone/vinyl imidazole methochloride copolymer is (with trade name Luviquat FC370, polyquaternary ammonium salt 2 is commercially available), and polyalkyleneimine (as polyethylene imine based and ethoxylation polyethylene imine based).

Compositions of the present invention also preferably comprises about 0.1% oil or the deutero-nonionic surfactant of its mixture to about 20% (weight), is preferably about 1% to about 15%, more preferably about 2% to about 10%.In according to compositions of the present invention, oily deutero-nonionic surfactant is in use with skin sense benefit aspect is provided is valuable after using.The oily deutero-nonionic surfactant that is suitable for this paper comprises the deutero-emollient of the water miscible plant and animal triglyceride of insertion polyglycol chain wherein (as have), the mono and di-glycerides of ethoxylation, the butter derivant of the lanoline of polyethoxylated and ethoxylation.Other the oily deutero-nonionic surfactant of a priority that is used for this paper has general formula (XII): Wherein n is about 5 to about 200, is preferably about 20 to about 100, more preferably about 30 to about 85, and wherein R comprises aliphatic group, and its average carbon atom number is about 5-20, is preferably about 7-18.

The oil ﹠ fat of the suitable ethoxylation of this classification comprises glyceryl cocoate, caproin, caprylin, tallow fatty acid glyceride, tripalmitin, tristerin, glyceryl laurate ester, olein, castor oil acid glyceride and derives from triglyceride, as the glycerin fatty family ester of Petiolus Trachycarpi oil, almond oil and Semen Maydis oil, be preferably the polyethyleneglycol derivative of tallow fatty acid glyceride and glyceryl cocoate.

The suitable oily deutero-nonionic surfactant of this classification is can be by Croda Inc. (New York, the U.S.) their the Crovol series material that obtains, as Crovol EP40 (PEG 20 Oenothera glyceride), Crovol EP70 (PEG 60 Oenothera glyceride), Crovol A-40 (PEG 20 Semen Armeniacae Amarum glyceride), Crovol A-70 (PEG 60 Semen Armeniacae Amarum glyceride), Crovol M-40 (PEG 20 corn glyceride), Crovol M-70 (PEG 60 corn glyceride), Crovol PK-40 (PEG 12 Petiolus Trachycarpis nuclear glyceride) and Crovol PK-70 (PEG 45 Petiolus Trachycarpis nuclear glyceride), and their Solan series material is (as Solan E, and the Aqualose L-20 (PEG 24 lanolin alcohols) and the Aqualose W15 (PEG 15 lanolin alcohols) that can obtain by Westbrook Lanolin the lanoline of E50 and X polyethoxylated).This level other more suitably surfactant be surfactant by the Varonic LI series of commercially available they of Sherex chemical company (Dublin, Ohio, the U.S.), and by the Rewoderm series of surfactants of commercially available they of Rewo.These surfactants comprise, Varonic LI 48 (Polyethylene Glycol (n=80) tallow fatty acid glyceride for example, perhaps be referred to as PEG 80 tallow fatty acid glyceride), Varonic LI 2 (PEG 28 tallow fatty acid glyceride), Varonic LI 420 (PEG 200 tallow fatty acid glyceride) and Varonic LI63 and 67 (PEG 30 and PEG 80 glyceryl cocoate), Rewoderm LI5-20 (PEG-200 cetylate), Rewoderm 80 (the PEG-200 cetylate that the PEG-7 glyceryl cocoate is arranged) and Rewoderm LIS-75 (the PEG-200 cetylate that the PEG-7 glyceryl cocoate is arranged) and composition thereof.The PEG derivant that to be suitable for other oily deutero-emollient herein be corn, American Avocado Tree and babassu oil, and Softigen 767 (PEG (6) caprylic/capric glyceride).

The surfactant that also is suitable for this paper is nonionic surfactant and the derivant thereof that derives from the mixed plant fat that extracts from the fruit of Butyrospermum (ButyrospermumKarkii Kotschy).Known this plant fat that is called Adeps Bovis seu Bubali resin in must arrive widely and use, its using method is varied as be used for making soap and as cold cream, this plant fat is sold by Sederma (78610 Le Perray En Yvelines, France).Specially suitable is by (the Columbos of Karlshamn chemical company, the Ohio, the U.S.) derivant of the ethoxylation of the Adeps Bovis seu Bubali resin that provides with Lipex series chemical drugs, as Lipex 102 E-75 and Lipex 102 E-3 (list of the ethoxylation of Adeps Bovis seu Bubali resin-, two-glyceride), and by Croda Inc. (New York, the U.S.) derivant of the ethoxylation of the Adeps Bovis seu Bubali resin that provides with their Crovol series material is as CrovolSB-70 (list of the ethoxylation of Adeps Bovis seu Bubali resin-, two-glyceride).Similarly, the ethoxylated derivative of Fructus Mangifera Indicae, cocoa and East India Sapotaceae vegetable butter can be used for according to compositions of the present invention.Though these surfactants are classified as the nonionic surfactant of ethoxylation, much less still keep the vegetable oil or the fat of a certain proportion of not ethoxylation.

Other suitable oily deutero-nonionic surfactant comprises almond oil, Oleum Arachidis hypogaeae semen, Testa oryzae oil, wheat germ oil, Semen Lini oil, simmondsia oil, the oil of Fructus Pruni pit, Semen Juglandis, palm nut, pistachio pit, til seed, Semen Brassicae campestris, cade oil, Semen Maydis oil, Semen Persicae oil, seed of Papaver somniferum L. powder, Oleum Pini, Oleum Ricini, soybean oil, American Avocado Tree oil, safflower oil, Oleum Cocois, hazelnut oil, olive oil, the ethoxylated derivative of Oleum Vitis viniferae and sunflower seed oil.

With regard to best mildness and skin sense characteristic aspect, the oily deutero-nonionic surfactant that most preferably is used for this paper is Lipex 102-3 (RTM) (the PEG-3 ethoxylated derivative of Adeps Bovis seu Bubali resin) and Softigen767 (RTM) (PEG-6 caprylic/capric glyceride).

The present composition can comprise lipophilic emulsifier as the skin care activity composition.The lipophile skin care activity composition that is suitable for comprises the anion food emulsifier, wherein contains and the mutually blended bisgallic acid of monoglyceride (as succinylation monoglyceride, the stearic alcohol ester of citric acid list, stearic acid monoglyceride, diacetyl tartrate and their mixture).

These compositionss also can contain auxiliary nonionic or anionic thickening polymer component, particularly molecular weight are higher than about 20,000 water-soluble, polymeric material." water-soluble polymer " means under 25 ℃ of this materials that concentration is in water at 1% o'clock, be to form transparent solution substantially, and this material can increase the viscosity of water.The example that can satisfy the water-soluble polymer of the auxiliary thickening component of conduct in this compositions in addition is hydroxy ethyl cellulose, hydroxy propyl cellulose, HYDROXY PROPYL METHYLCELLULOSE, Polyethylene Glycol, polyacrylamide, polyacrylic acid, polyvinyl alcohol (example comprises the PVA 217 that Japanese KuraryChemical Co. produces), polyvinyl pyrrolidone K-120, glucosan are as D﹠amp; The secretions of the thick Dextran of 2P level purification that OChemicals produces, carboxy methyl cellulose, plant, as arabic gum, ghatti gum and Tragacanth, Sargassum extract is as sodium alginate, propylene glycol alginate and carrageenin sodium.Concerning compositions of the present invention, preferred supplementary thickener is a natural polysaccharide.The example of these materials has guar gum, locust bean gum and xanthan gum.The preferred material that is suitable in this article is that molecular weight is about 700,000 hydroxy ethyl cellulose in addition.Hydrotropic solvent

Also can not necessarily comprise hydrotropic solvent in the present composition.Be applicable to that hydrotropic solvent of the present invention is well known in the art, comprise sodium xylene sulfonate, ammonium xylene sulfonate, cumene sodium sulfonate, short-chain alkyl sulfate, and their mixture.The content of hydrotropic solvent is about 0.01-5% (weight) in the present composition, preferably is about 0.1-4% (weight), more preferably 0.5-3% (weight).Aforesaid hydrotropic solvent is meant it is added in undiluted water soluble surfactant active's system and can improves the viscosity of product and the composition of rheological properties.

Except above-mentioned water-insoluble oil, the present composition also can comprise insoluble spice or cosmetic oil or wax or its mixture, and content is about 10% for being no more than, and preferably is no more than about 3% weight, wherein from 25 ℃ product substrate insoluble angle say that these oil or wax are insoluble.

Be applicable to that insoluble cosmetic oil of the present invention and wax are selected from: the water-insoluble polysiloxanes, comprising non-volatile poly-alkyl and poly-aryl siloxanes glue and fluid, volatile cyclic polydimethylsiloxane, poly-alkoxylation polysiloxanes, through amino and quaternised modified polysiloxanes, rigidity cross linking polysiloxane and through enhanced polysiloxanes, and their mixture, C ₈-C ₃₀The C of fatty acid ₁-C ₂₄Ester is as isopropyl myristate, myristyl myristate and castor oil acid cetyl, benzoic C ₈-C ₃₀Ester, Cera Flava, saturated and unsaturated fatty alcohol such as behenyl alcohol, hydro carbons such as mineral oil, vaseline, squalane and Squalene, fatty acid esters of sorbitan is (referring to US-A-3988255, Seiden, on October 26th, 1976 authorized), lanoline and oily lanolin derivative, vegetable and animals oils triglyceride such as almond oil, Oleum Arachidis hypogaeae semen, wheat germ oil, bran coat oil, Semen Lini oil, simmondsia oil, and Semen Armeniacae Amarum, Semen Juglandis, palm kernel, the pistachio fruit, til seed, the oil of Semen Brassicae campestris, cade oil, Semen Maydis oil, peach kernel oil, seed of Papaver somniferum L. powder, Oleum Pini, Oleum Ricini, soybean oil, American Avocado Tree oil, safflower oil, Oleum Cocois, acorn nut oil, olive oil, Oleum Vitis viniferae and Oleum Helianthi, and the C of dimeric dibasic acid and trimer acid ₁-C ₂₄Ester is as diacid diisopropyl ester, malic acid diisopstearate, diacid diisopstearate and three sour three isostearates.

(Brookfield DV II, 1 rev/min of rotating speed adopt CP41 or CP52 rotor to the viscosity of final composition, 25 ℃, net phase) preferably be at least about 500 centipoises, be more preferably the 1000-50000 centipoise, especially be about the 1000-30000 centipoise, more particularly about 1000-15000 centipoise.

Also can not necessarily contain other hair that dissolves in Cleasing compositions substrate or skin moisturizing agent in this Cleasing compositions.The preferred content of this humidizer is about 0.5-20% (weight).In preferred embodiments, humidizer is selected from the natural amino acid whose chemical compound that is present in the necessity in the keratodermatitis, and the non-occlusive composition and their chemical compound of the non-polyhydric alcohol of water solublity.

Some preferred example to non-occlusive humidizer has: squalane, carboxylic acid ketopyrrolidine sodium, D-panthenol, lactic acid, L-proline, guanidine, ketopyrrolidine, hydrolyzed protein and other protein derived from collagen, Lu Yun gel, acetamide MEA and lactamide MEA, and their mixture.

Compositions herein also can contain one or more suspending agents.The suspending agent of Shi Yonging comprises the mixture of any long acyl derivant or this class material in this article.Comprise 16 the glycol esters of having an appointment to the fatty acid of about 22 carbon atoms.Stearic acid second diester preferably, monostearate and distearate can, contain the distearate that is lower than about 7% monostearate but particularly preferably be.Other available suspending agent has the alkanolamide of fatty acid, contains about 16 to 22 carbon atoms, preferably contains about 16 to 18 carbon atoms.Preferred alkanolamide is a stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide stearate.

Other suspending agent that is suitable for also has alkyl (C ₁₆-C ₂₂) dimethyl oxidation amine, the trihydroxy stearin of the commodity Thixcin (RTM) by name that produces as the oxide of stearyl dimethylamino and Rheox.

The content of suspending agent preferably about 0.5% to about 5%, preferably about 0.5% to about 3%.Suspending agent helps to make water-insoluble oil to suspend and makes product that pearly-lustre be arranged.The mixture of suspending agent also is applicable to compositions of the present invention.

According to also containing opacifier or pearling agent in the compositions of the present invention.The content of these materials can be about 0.01% to about 5%, preferably about 0.2% to about 1.3% weight.

Opacifier/the pearling agent that is applicable to the present composition comprises: titanium dioxide TiO ₂EUPERLAN 810 (RTM); TEGO-PEARL (RTM); Long-chain (C ₁₆-C ₂₂) acyl derivative, contain the glycol or the macrogol ester of the fatty acid of 16-22 carbon atom according to appointment, wherein contain 7 ethylene oxide units at most; The fatty acid alkanol amides that contains 16-22 carbon atom, preferred 16-18 carbon atom approximately, as stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide, and alkyl (C ₁₆-C ₂₂) dimethyl oxidation amine, as stearyl dimethyl amine oxide.

In preferred composition, opacifier/pearling agent is crystalloid.In particularly preferred compositions, opacifier/pearling agent is that granularity is about the 0.05-0.45 micron, preferably is about the granular polystyrene dispersion of 0.17-0.3 micron, for the angle of best rheological properties and shear shinning performance, and preferred such dispersion.Particularly preferably be copolymer in cinnamic acrylic ester and available from the OPACFIER 680 (RTM) of Morton International.

The content that can be used for other nonessential composition of majority of Cleasing compositions is about 0.1-2% (weight) respectively.This constituents comprises protein and polypeptide, and their derivant; Water solublity or soluble antiseptic, as methyl ester, ethyl ester, propyl ester and the butyl ester of DMDM allantoin, Germall 115, hydroxy benzoic acid, EDTA, Euxyl (RTM) K400, natural antiseptic agent such as benzyl alcohol, potassium sorbate and bisabolol; Sodium benzoate and 2-phenyl phenol; Other humidizer such as hyaluronic acid, chitin and starch-grafted sodium polyacrylate, as available from CelanessSuperabsorbent Materials (Portsmith, VA, Sanwet USA) (RTM) IM-1000, IM-1500 and IM-2500, and can be referring to US-A-4076663; Solvent; The antibacterial that is suitable for, as Oxeco (phenoxy group isopropyl alcohol), trichlorine carbanilide (TCC) and triclosan, and low temperature phase modifier such as ammonium ion source (for example, NH ₄Cl); Viscosity modifier such as magnesium sulfate and other electrolyte; Coloring agent; The Muscovitum of titanium dioxide and coated by titanium dioxide; Essence and essence solubilizing agent; And zeolite such as Valfour BV400 and derivant thereof, and Ca ⁺/ Mg ²⁺Sequestering agent such as multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphate, amino polyphosphate, EDTA etc., water softener such as sodium citrate and insoluble granule such as zinc stearate and calcine Silicon stone.The content of water preferably accounts for the 20-99.89% (weight) of the present composition, preferably is about 40-90% (weight), more preferably is at least about 75% (weight).

The pH of compositions preferably is about 3-10,5-9 more preferably from about, particularly about 5-8, and 5-7 most preferably from about.

Compositions of the present invention can be used for the occasion of a lot of skins and hair-care, uses gel, bath foam, shampoo and similar compositions as bathing.

Compositions of the present invention can be smeared with hands, perhaps preferably smears with individual implement, pounces on as foam.The suitable individual implement that uses with compositions of the present invention comprises those disclosed apparatus in following patent documentation, and these patent documentations are referred to herein as a reference: JIUYUE in 1992 were authorized the US-A-5 of Campagnoli, 144,744 on the 8th; Authorize the US-A-3 of Barnhouse, 343,196; Authorize the WO95/26671 of P﹠G; Authorize the WO95/00116 of P﹠G; Authorize the WO95/26670 of P﹠G;

Following non-restrictive example has illustrated according to compositions of the present invention.

	???I/％	???II/％	??III/％	??IV/％	???V/％
						The lauryl ether of close limit-3 sodium sulfate (Genopol ZRONR) 1	???-	????-	????-	????-	????-
Lauryl ether-3 ammonium sulfate (Empicol EAC/TP) 2	???8.4	????8.4	????15	????15	????15
						Ammonium lauryl sulfate (Empicol AL30) 2	???-	????-	????-	????5	????2.0
Lauro ampho acetate (Empigen CDL60P) 2	???3.6	????3.6	????10	????-	????5.0
						Sodium lauroyl sarcosine (Hamposyl L30) 3	???0.5	????0.5	????-	????-	????-
Dodecanamide propyl betanin (Empigen BR) 2	???-	????-	????-	????-	????-
						Coconut oleoyl amine MEA (Empilan CME) 2	???-	????-	????1.0	????1.0	????1.0
Distearyl acid second diester	???2.0	????2.0	????2.0	????2.0	????2.0
						Trihydroxy stearin (Thixcin) 4	???-	????-	????-	????-	????-
Lauric acid	???-	????-	????-	????-	????-
						??Dobanol?23 5	???0.4	????0.4	????-	????-	????-
Water-insoluble oil 6	???2.0	????10.0	????6.0	????4.0	????2.0
						Water-insoluble oil 8	???0.0	????10.0	????0.0	????4.0	????0.0
Spice	???0.5	????0.5	????1.0	????1.0	????1.5
						??EDTA	???0.11	????0.11	????0.11	????0.11	????0.11
Benzoate	???0.25	????0.25	????0.25	????0.25	????0.25
						DMDM Hydantoin	???0.138	????0.138	????0.138	????0.138	????0.138
Sodium chloride	???0.5	????0.5	????0.5	????0.5	????0.5
						Citric acid	???0.7	????0.7	????1.5	????0.4	????1.0
Viscasil D5M (dimethyl polysiloxane) 7	???-	????-	????-	????-	????-
						Water	Add to 100

	??VI/％	??VII/％	??VIII/％	????IX/％	???X/％
						The lauryl ether of close limit-3 sodium sulfate (Genopol ZRONR) 1	???-	????-	????10.0	????-	???-
Lauryl ether-3 ammonium sulfate (Empicol EAC/TP) 2	???15.0	????8.5	????-	????6.0	???10.0
						Ammonium lauryl sulfate (Empicol AL30) 2	???5.0	????2.0	????-	????-	???-
Lauro ampho acetate (Empigen CDL60P) 2	???2.0	????4.0	????-	????3.0	???-
						Sodium lauroyl sarcosine (Hamposyl L30) 3	???-	????-	????-	????1.5	???-
Dodecanamide propyl betanin (Empigen BR) 2	???-	????-	????5.0	????-	???4.0
						Coconut oleoyl amine MEA (Empilan CME) 2	???1.0	????-	????1.0	????1.0	???1.0
Diglycol stearate	???2.0	????2.0	????2.0	????2.0	???2.0
						Trihydroxy stearin (Thixcin) 4	???-	????-	????-	????-	???-
Lauric acid	???-	????-	????-	????-	???-
						Dobanol?23 5	???-	????-	????-	????0.2	???-
Water-insoluble oil 6	???8.0	????4.0	????2.0	????4.0	???4.0
						Spice	???0.5	????0.5	????1.0	????0.5	???1.0
EDTA	???0.11	????0.11	????0.11	????0.11	???0.11
						Benzoate	???0.25	????0.25	????0.25	????0.25	???0.25
DMDM Hydantoin	???0.138	????0.138	????0.138	????0.138	???0.138
						Sodium chloride	???0.5	????0.5	????0.5	????0.5	???0.5
Citric acid	???0.5	????0.8	????0.2	????0.6	???0.3
						Viscasil D5M (dimethyl polysiloxane) 7	???-	????-	????-	????-	???-
Water	Add to 100

	??XI/％	??XII/％	??XIII/％	??XIV/％	??XV/％
						The lauryl ether of close limit-3 sodium sulfate (Genopol ZRONR) 1	???-	????-	????-	????-	????-
Lauryl ether-3 ammonium sulfate (Empicol EAC/TP) 2	???8.4	????10.0	????10.0	????8.0	????15.0
						Ammonium lauryl sulfate (Empicol AL30) 2	???-	????-	????2.0	????-	????5.0
Lauro ampho acetate (Empigen CDL60P) 2	???3.6	????5.0	????5.0	????3.6	????-
						Sodium lauroyl sarcosine (Hamposyl L30) 3	???0.5	????0.5	????-	????0.5	????-
Dodecanamide propyl betanin (Empigen BR) 2	???-	????-	????-	????-	????-
						Coconut oleoyl amine MEA (Empilan CME) 2	???-	????-	????-	????-	????1.0
Diglycol stearate	???-	????-	????-	????2.0	????2.0
						Trihydroxy stearin (Thixcin) 4	???1.5	????1.5	????1.5	????-	????-
Lauric acid	???1.5	????-	????-	????-	????-
						Dobanol?23 5	???-	????1.5	????1.5	????0.4	????-
Water-insoluble oil 6	???4.0	????10.0	????4.0	????4.0	????4.0
						Spice	???1.5	????0.5	????1.0	????0.5	????1.0
EDTA	???0.11	????0.11	????0.11	????0.11	????0.11
						Benzoate	???0.25	????0.25	????0.25	????0.25	????0.25
DMDM Hydantoin	???0.138	????0.138	????0.138	????0.138	????0.138
						Sodium chloride	???0.5	????0.5	????0.5	????0.5	????0.5
Citric acid	???0.7	????0.7	????0.7	????0.7	????0.7
						Viscasil D5M (dimethyl polysiloxane) 7	???-	????-	????-	????1.0	????0.5
Water	Add to 100

1.Hoechst product 2.Albright ﹠amp; Wilson product 3.Hampshire Chemicals product 4.Rheox product 5.Shell Chemicals product 6. water-insoluble oil in each embodiment can be Indopol 40 and the Indopol 100 that Amoco Chemicals produces, the Puresyn 100 that Mobil Chemicel Co. produces, the Permethyl 104A that Presperse produces, the SF1632 that GE Silicones produces, octyl group methyl polysiloxane or decyl methyl polysiloxane 7.GE Silicones product production method

Be the preparation compositions, at first prepare the premix of a surfactant and suspending agent.This premix should contain the surfactant that is no more than composition total weight 15%.This process is mixed by surfactant (except the sarcosinate), a certain proportion of water, antiseptic powder and pH regulator agent are stirred gently.When stir adding aliphatic alcohol/fatty acid, suspending agent and sodium chloride, with this mixture heated to 90 ℃.

Mixture kept high temperature 5 minutes to 1 hour before cooling, with heat exchanger mixture is cooled to about 30 to 40 ℃ with the speed of a control, so that suspending agent crystallizes out.

Before water-insoluble oil, remaining surfactant, liquid preservative and spice join in the premix, remaining water is added this premix then.This part of the method is at room temperature to carry out, and stirring lightly and making the drop size is 5 to 20 microns.

These products have excellent rinse feel and mildness and at storage, batching and the good rheological characteristic in use aspect also have favorable effects, comprise greater skin conditioning efficacy, skin moisturizing effect, good product stability, cleaning and foaming effect.The rinse feel panel test

In order to measure the effect of water-soluble oil, carried out panel test as described below to the rinse feel of the present composition.

This test needs one 8 people's panel of expert, and they are through special training and the qualified panel test that carries out rinse feel.Instrument

It is as follows that this tests required instrument: intervalometer, 2 milliliters of syringes, thermometer, ballot single (every group member 2), 2 20 liters of plastic containers with cover, 1 tank with 2 draining board zones, tank is received a water hardness system and is changed hardness, and the flow velocity of water is 1600-1800 milliliter/30 second.(should control and write down the temperature and the hardness of water) group member's training

Train every group member can recognize 0 grade, 4 grades and 8 grades of three kinds of different moist skins sensations-as described below.0 grade (extremely retardance)

Ivory (RTM) soap bar is used for 0 grade.Hardness of water is 16gpg, and water temperature is 36 ± 1 ℃.5 seconds were drenched in forearm inboard and both hands.Soap bar is rotated on palm with finger on hand at one, make the soap bar foaming, all be that soap bar is rotated a whole circle at every turn.The foam that produces is spread upon the inboard of forearm with the pressure of moderate, in 10 seconds internal friction 10 times (1 time rub=from the wrist to the ancon again to wrist).Foam was stopped for 30 seconds on forearm, and with product from washing off on hand.With mobile water rinse forearm, in 30 seconds of rinsing, current begin from ancon.Pat from ancon arm with slight pressure after 30 seconds, and guarantee that this process is to begin to finish under the place at current to wrist.The sensation of this rinsing is just represented 0 grade.4 grades (slight stick-slip and slight retardance)

Zest White Water Fresh (RTM) soap synthetic detergent (U.S.'s product) is used for 4 grades.Hardness of water is 16gpg, and water temperature is 36 ± 1 ℃.5 seconds were drenched in forearm inboard and both hands.Soap bar was being foamed for 6 seconds on hand, all was that soap bar is rotated a whole circle at every turn.The foam that produces is spread upon the inboard of forearm with the pressure of moderate, in 10 seconds internal friction 10 times (1 time rub=from the wrist to the ancon again to wrist).Foam was stopped for 30 seconds on forearm, and with product from washing off on hand.With mobile water rinse forearm, in 10 seconds of rinsing, current begin from ancon.Pat from ancon arm with slight pressure after 10 seconds, and guarantee that this process is to begin to finish under the place at current to wrist.The sensation of this rinsing is just represented 4 grades.8 grades (extremely stick-slip)

Oil of Olay (RTM) humidification body lotion (U.S.'s product) is used for 8 grades.Hardness of water is 3gpg, and water temperature is 36 ± 1 ℃.5 seconds were drenched in forearm inboard and both hands.1.7 milliliters products are spread upon on the both hands that drench.Make product on hand with the mode of the circular motion palm that rubs, 6 seconds internal friction rotate 6 circles and make its foaming, all be to rotate a whole circle at every turn.The foam that produces is spread upon the inboard of forearm with the pressure of moderate, in 10 seconds internal friction 10 times (1 time rub=from the wrist to the ancon again to wrist).Foam was stopped for 30 seconds on forearm, and with product from washing off on hand.With mobile water rinse forearm, and pat from ancon arm with slight pressure immediately, and guarantee that this process is to begin to finish under the place at current to wrist.The sensation of this rinsing is just represented 8 grades.Group member's qualification

For making the rinse feel panel test qualified, the group member must successfully carry out following qualification test.

5 seconds were drenched in forearm inboard and both hands.Every kind of product to be fractionated is spread upon on the both hands that drench for each 1.7 milliliters, and make product on hand with the mode of the circular motion palm that rubs, 6 seconds internal friction rotate 6 circles and make its foaming (at every turn all being to rotate a whole circle).The foam that produces is spread upon the inboard of forearm with the pressure of moderate, in 10 seconds internal friction 10 times (1 time rub=from the wrist to the ancon again to wrist).Foam was stopped for 30 seconds on forearm.And with product from washing off on hand.With the mobile water rinse forearm that begins from ancon, 15 seconds of rinsing.To feel to estimate to moist skin at following time point during this period: 3 seconds, 9 seconds and 15 seconds.Finish this process by the forearm inboard of patting gently from the ancon to the wrist, pat three times and under the position that current begin, pat with slight pressure.Stopped later rinsing in 15 seconds, each moist skin feeling evaluation be marked on the following ballot list:

Extremely the slight moderate height of the slight retardance of height moderate extremely blocks/the slight stick-slip stick-slip stick-slip stick-slip stick-slip 012345678 of Jerkey retardance retardance retardance

Every group member hides the order evaluation to 2 groups of samples with known qualified group member result.Every kind of product is all tested 2 times to determine its accuracy.If the group member does not correctly mark the grade of product for twice in one takes turns, they just must reappraise to this, up to obtaining correct result.But if their a kind of product has the grade that does not correctly mark product for 4 times, they just must train (part I) again.If the grade that they mark is incorrect, can not inform the grade that they expect, only to tell them to block very much or stick-slip too.

Every group member must have 3 hours at least at interval every kind of product test.

All results all must qualified group member result ± 1 grade (seeing the following form).If the group member can make correct evaluation twice to every kind of product in one takes turns, they are exactly qualified.The 1st group of product: be applicable to that normal LUX to dry skin takes a shower in white (Taiwan) and the contrast of Taiwan Olay humidification body lotion.The 2nd group: Taiwan Olay humidification body lotion and the contrast of U.S. Olay humidification body lotion.Qualified products grade to hard water (16gpg)

Product	3 seconds grade	9 seconds grade	15 seconds grade
				LUX	????4.0	????3.0	????2.0
Taiwan Olay humidification body lotion	????6.0	????5.0	????4.0
				U.S. Olay humidification body lotion	????7.5	????7.0	????6.0

Qualified products grade to soft water (3gpg): the 1st group: Safaguard body lotion (China) and the 2nd group of the natural humidizer of BIORE (Japan) contrast: be applicable to normal LUX shower frost (Taiwan) and the contrast of U.S. Olay humidification body lotion to dry skin.Hardness is the grade of qualified products in the water of 3gpg

Product	3 seconds grade	9 seconds grade	15 seconds grade
				Safaguard body lotion (China)	????6.5±1.0	????6.0±1.0	????5.0±1.0
The natural humidizer of BIORE	????6.0±1.0	????5.0±1.0	????3.5±1.0
				LUX takes a shower white	????6.0±1.0	????3.5±1.0	????2.0±1.0
U.S. Olay humidification body lotion	????7.0±1.0	????6.0±1.0	????5.5±1.0

Testing evaluation

Can clean two arms at any time, every arm is all washed once.Every group member can assess one group of above test every day, but between every group of test 3 hours interval will be arranged.In preceding 24 hours of test or test period can not on forearm, smear humidizer.

Following process is all from left arm.5 seconds were drenched in forearm inboard and both hands.1.7 milliliters of products to be fractionated are coated on the both hands that drench.With the pressure of moderate 6 seconds inherences of product are rubbed on hand and to produce foam (rotating a whole circle each second) for 6 times.With the pressure of moderate the foam that produces is spread upon the forearm inboard and be coated with 10 seconds (from the wrist to the ancon again to wrist).Foam was stopped for 30 seconds on forearm.With product from rinsing on hand., current begin stream from ancon in 15 seconds of forearm rinsing with mobile water.To feel to estimate to moist skin at following time point during this period: 3 seconds, 9 seconds and 15 seconds.Finish this process by the forearm inboard of patting gently from the ancon to the wrist, pat three times and under the position that current flow through, pat with slight pressure.Stopped later rinsing in 15 seconds, each moist skin feeling evaluation is marked on the following ballot list: EXPERIMENTAL DESIGN

Pass through 8 detection bodies with incomplete Latin-square battle array design at random, two into treatment sites of each detection bodies come 8 kinds of products are compared.Calculate

Should use the statistical package (as Statgraphics Plus, 2.1 editions) that can carry out variance analysis to calculate.This analysis should be carried out on 90% significance level, and as dependent variable, product, group member and test position are the factor with the time point of assessing.To 8 detection bodies, on 90% significance level, this design has 80% ability to show the difference of 0.71 grade.Rinse feel group test result

With the test of aforesaid rinse feel group several compositionss according to the present invention are tested.Also several Comparative composition are tested in addition.The prescription of every kind of product and rinsing value are as shown in the table.Test product I-IX is according to compositions of the present invention.

Component	????I/％	????II/％	????III/％	????IV/％	????V/％	????VI/％
							Zetesol AP (Empicol EAC/TP 1)	????8.4	????8.4	????8.4	????8.4	????8.4	????8.4
Lauroyl both sexes sodium acetate (Empigen CDL60P 1)	????3.6	????3.6	????3.6	????3.6	????3.6	????3.6
							Sodium lauroyl sarcosine (Hamposyl L30 2)	????0.5	????0.5	????0.5	????0.5	????0.5	????0.5
Diglycol stearate 3	????2	????2	????2	????2	????2	????2
							(Puresyn 100 for poly alpha olefin 4)	????2	????4	????0	????0	????0	????0
Polybutene (Indopol H40 5)	????0	????0	????2	????0	????0	????0
							Polybutene (Indopol H100 5)	????0	????0	????0	????2	????0	????0
C 16-C 18Alkyl methyl polysiloxanes (SF1632 6)	????0	????0	????0	????0	????2	????0
							Polyisobutylene (Permethyl 104A 7)	????0	????0	????0	????0	????0	????2
EDTA four sodium	????0.11	????0.11	????0.11	????0.11	????0.11	????0.11
							DMDM Hydantoin	????0.138	????0.138	????0.138	????0.138	????0.138	????0.138
Sodium benzoate	????0.25	????0.25	????0.25	????0.25	????0.25	????0.25
							Citric acid	????0.7	????0.7	????0.7	????0.7	????0.7	????0.7
Spice	????0.5	????0.5	????0.5	????0.5	????0.5	????0.5
							Sodium chloride	????0.5	????0.5	????1.4	????0.5	????1.4	????1
(Dobanol 23 for Pareth 1213 alcohol 8)	????0.4	????0.4	????0.4	????0.4	????0.4	????0.4
							Deionized water	Add to 100
Average rinse feel value	???3.38	????2.80	????1.0	????1.0	????3.25	????1.25

Component	??VII/％	??VIII/％	????IX/％
				Zetesol AP (Empicol EAC/TP 1)	????8.4	????8.4	????8.4
Lauroyl both sexes sodium acetate (Empigen CDL60P 1)	????3.6	????3.6	????3.6
				Sodium lauroyl sarcosine (Hamposyl L30 2)	????0.5	????0.5	????0.5
Diglycol stearate 3	????2	????2	????2
				The decyl methyl polysiloxane 6	????0	????4	????0
The octyl group methyl polysiloxane 6	????4	????0	????0
				Puresyn?100 4	????0	????0	????4
JR30M 9	????0	????0	????0.1
				EDTA four sodium	????0.11	????0.11	????0.11
DMDM Hydantoin	????0.138	????0.138	????0.138
				Sodium benzoate	????0.25	????0.25	????0.25
Citric acid	????0.7	????0.7	????0.7
				Spice	????0.5	????0.5	????0.5
Sodium chloride	????0.5	????0.5	????0.5
				(Dobanol 23 for Pareth 1213 alcohol 8)	????0.4	????0.4	????0.4
Deionized water	Add to 100
				Average rinse feel value	????2.8	????2.96	????3.25

For comparing, following product is tested:

Component	????X/％	????XI/％	????XII/％
				Zetesol AP (Empicol EAC/TP 1)	????8.4	????8.4	????8.4
Lauroyl both sexes sodium acetate (Empigen CDL60P 1)	????3.6	????3.6	????3.6
				Sodium lauroyl sarcosine (Hamposyl L30 2)	????0.5	????0.5	????0.5
Diglycol stearate 3	????2	????2	????2
				Viscasil?5M 6(dimethyl polysiloxane)	????2	????0	????0
Puresyn?40 4	????0	????4	????0
				EDTA four sodium	????0.11	????0.11	????0.11
DMDM Hydantoin	????0.138	????0.138	????0.138
				Sodium benzoate	????0.25	????0.25	????0.25
Citric acid	????0.7	????0.7	????0.7
				Spice	????0.5	????0.5	????0.5
Sodium chloride	????0.5	????0.5	????0.5
				(Dobanol 23 for Pareth 1213 alcohol 8)	????0.4	????0.4	????0.4
Average rinse feel value	????3.94	????3.63	????4.2

To above all results, its standard units of the error of the mean are 0.25 to 0.27.1.Albright ﹠amp; Wilson product 2.Hampshire Chemicals product 3.Saci product 4.Mobil Chemical Co. product 5.Amoco Chemical Co. product 6.GE Silicones product 7.Presperse Inc. product 8.Shell Chemicals product 9.Amercol produces

Claims (24)

1. liquid personal cleansing composition that floats type, wherein contain surfactant and water, wherein compositions comprises the first surface activating agent that is less than 8% weight and greater than the second surface activating agent of 3% weight, the first surface activating agent is selected from the crystallization anion surfactant, the second surface activating agent is selected from noncrystalline anion surfactant, amphoteric surfactant, non-ionic surface active agent and zwitterionic surfactant and composition thereof, wherein the average rinse feel value of compositions is 3.5 or lower, and this value is recorded by rinse feel panel test method.

2. according to the personal cleaning compositions of claim 1, wherein the average rinse feel value of compositions is 3.25 or lower.

3. according to the personal cleaning compositions of claim 1 or 2, wherein the average rinse feel value of compositions is 3.0 or lower.

4. according to each personal cleaning compositions of claim 1 to 3, it comprises the crystalline anion surfactant that is lower than 6% weight.

5. according to each personal cleaning compositions of claim 1 to 4, wherein the crystallization anion surfactant is selected from alkyl sulfate, methyl-acyl taurine salt, fat acidyl glycine salt, N-acyl glutamate, acyl isethinate, alkyl sulfo succinate, alkyl phosphate, acyl sarcosinates, soap, alpha-alkene sulfonate, linear alkylbenzene sulfonate (LAS) and acylaspartic acid salt and composition thereof.

6. according to each personal cleaning compositions of claim 1 to 5, wherein noncrystalline anion surfactant is selected from ethoxylated alkyl sulfates, alkyl ethoxy carboxylate, alkyl glyceryl ether sulfonate, alkyl ethoxy sulfosuccinate, α-alpha-sulfonated fatty acid, their salt and/or ester, ethoxylated alkyl phosphate ester, ethoxylated alkyl glycerol ether sulfonate, alkane sulfonate, alkoxyl amidosulfonic acid salt and composition thereof.

7. according to each personal cleaning compositions of claim 1 to 6, wherein also contain and have an appointment 0.5%, preferred about 1% water-insoluble oil to about 10% weight to about 20% weight.

8. according to the personal cleaning compositions of claim 7, wherein water-insoluble oil is selected from the polysiloxanes of hydrocarbon-type oil and hydrophobically modified, and their mixture.

9. according to the personal cleaning compositions of claim 7 or 8, wherein the viscous index with respect to Viscasil 5M (dimethyl polysiloxane) of water-insoluble oil is 120% or lower, and this viscous index is measured with the tacktech assay method.

10. according to each personal cleaning compositions in the claim 7 to 9, wherein the viscous index with respect to Viscasil 5M (dimethyl polysiloxane) of water-insoluble oil is 110% or lower, and this viscous index is measured with the tacktech assay method.

11. according to each personal cleaning compositions in the claim 7 to 10, wherein the viscous index with respect to Viscasil 5M (dimethyl polysiloxane) of water-insoluble oil is 100% or lower, this viscous index is measured with the tacktech assay method.

12. each personal cleaning compositions in 11 according to Claim 8, hydrocarbon-type oil wherein is selected from the highly branched poly alpha olefin of (a) class, and its structural formula is as follows: R in the formula ¹Be H or C ₁-C ₂₀Alkyl, R ⁴Be C ₁-C ₂₀Alkyl, R ²Be H or C ₁-C ₂₀, R ³Be C ₅-C ₂₀, n is 0 to 3 integer, and m is 1 to 1000 integer, and its number-average molecular weight is about 1000 to about 25,000.

13. according to the personal cleaning compositions of claim 12, the number-average molecular weight of (a) class poly alpha olefin wherein is about 2000 to about 6000, more preferably about 2500 to about 4000.

14. personal cleaning compositions according to claim 12 or 13, the viscosity of (a) class poly alpha olefin wherein arrives about 50 for about 300cst, 000cst, preferably about 1000cst is to about 12,000cst, more preferably about 1000cst is to about 4000cst, and this viscosity is to record with ASTM D-445 method down at 40 ℃.

15. according to the personal cleaning compositions of claim 11, hydrocarbon-type oil wherein is selected from (b) class poly alpha olefin, its structural formula is as follows: R in the formula ¹Be H or C ₁-C ₄Alkyl, R ⁴Be C ₁-C ₄Alkyl, R ²Be H or C ₁-C ₄Alkyl or C ₂-C ₄Thiazolinyl, R ³Be H or C ₁-C ₄Alkyl or C ₂-C ₄Thiazolinyl, n is 0 to 3 integer, m is 1 to 1000 integer, its number-average molecular weight is about 600 to about 1,000.

16. according to the personal cleaning compositions of claim 15, to about 50, in the scope of 000cst, it is about 10 that preferably about 1000cst arrives at about 500cst for (b) class hydro carbons oil viscosity wherein, 000cst, and this viscosity is to record under 40 ℃ with ASTM D-445 method.

17. according to the personal cleaning compositions of claim 15 or 16, (b) class hydrocarbon-type oil wherein is polybutene or polyisobutylene.

18. according to the personal cleaning compositions of claim 11, hydrophobically modified polysiloxanes wherein is selected from the polysiloxanes with following structural formula: R is C in the formula ₁-C ₄Alkyl or phenyl, R ' is C ₁-C ₂₀Alkyl or phenyl, z is 5 to 21, the scope of x number average value is about 20 to 400, and is preferred 40 to 200, the scope of y number average value is about 0 to about 10, the scope of x+y is 30 to 400, preferred 30 to 100.

19. according to each personal cleaning compositions in the claim 1 to 18, wherein noncrystalline anion surfactant is an ethoxylated alkyl sulfates.

20. according to each personal cleaning compositions in the claim 1 to 19, compositions wherein is not contain soap basically.

21. according to each personal cleaning compositions in the claim 1 to 20, soluble amphoteric surfactant wherein is selected from: structural formula is the ammonium salt derivatives of [V]:

R in the formula ₁Be C ₅-C ₂₂Alkyl or alkenyl, R ₂Be CH ₂CH ₂OH or CH ₂CO ₂M, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, R ₃Be CH ₂CH ₂OH or H.

22. according to each personal cleaning compositions in the claim 1 to 21, it is R that zwitterionic surfactant wherein is selected from structural formula ₅R ₆R ₇N ⁺(CH ₂) _nCO ₂The alkyl betaine of M and structural formula are the amido betaine of (IX): R in the formula ₅Be C ₅-C ₂₂Alkyl or alkenyl, R ₆And R ₇Be respectively C ₁-C ₃Alkyl, M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, n, m are respectively 1 to 4 numerals.

23. according to each personal cleaning compositions in the claim 1 to 22, said composition also contains the cation type polymer skin conditioning agent of 0.01% to 5% weight of having an appointment, this skin conditioning agent is selected from cation guar gum, cationic polysaccharide, derive by acrylic acid and methacrylic acid and to come cationic homopolymer and copolymer, cationic celluosic resin, quaternised hydroxyethyl cellulose ethers, dimethyl diallyl ammonium chloride and acrylamide and/or acrylic acid cation copolymer, the cationic homopolymer of dimethyl diallyl ammonium chloride, the copolymer of amino-ethyl dimethylaminoethyl acrylate methyl ester and acrylamide, the copolymer of acrylic acid/dimethyl diallyl ammonium chloride/acrylamide, the copolymer of quaternised vinyl pyrrolidone acrylates or methacrylate and amino alcohol, the quaternised copolymer of vinyl pyrrolidone and dimethyl aminoethyl Methacrylamide, the copolymer of vinyl pyrrolidone/vinyl imidazole methochloride and polyalkylene and ethyoxyl polyalkyleneimine, quaternised polysiloxanes, acrylic acid, the ter-polymers of Methacrylamide oxypropyl trimethyl ammonium chloride and acrylic acid methyl ester., and their mixture.

24. according to each personal cleaning compositions in the claim 7 to 22, the number average bead diameter of water-insoluble oil wherein is about 1 micron to about 500 microns, preferably about 5 microns to about 200 microns, particularly preferably is about 5 microns to about 50 microns.