CN1235994C - Water curable water paint composition - Google Patents
Water curable water paint composition Download PDFInfo
- Publication number
- CN1235994C CN1235994C CNB021035628A CN02103562A CN1235994C CN 1235994 C CN1235994 C CN 1235994C CN B021035628 A CNB021035628 A CN B021035628A CN 02103562 A CN02103562 A CN 02103562A CN 1235994 C CN1235994 C CN 1235994C
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- China
- Prior art keywords
- water
- pigment
- resin
- paint composition
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 239000003973 paint Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000000049 pigment Substances 0.000 claims abstract description 41
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract 2
- 239000000839 emulsion Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 13
- 229920000178 Acrylic resin Polymers 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 239000002893 slag Substances 0.000 claims description 9
- 239000010881 fly ash Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910021487 silica fume Inorganic materials 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002956 ash Substances 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 abstract description 7
- 239000004567 concrete Substances 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 10
- 230000002159 abnormal effect Effects 0.000 description 9
- 239000008199 coating composition Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000009775 high-speed stirring Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- 239000004902 Softening Agent Substances 0.000 description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000000454 talc Substances 0.000 description 5
- 235000012222 talc Nutrition 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000920 calcium hydroxide Substances 0.000 description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010440 gypsum Substances 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011083 cement mortar Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical class CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 238000009156 water cure Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Provided is a hydraulic, water-soluble paint composition having excellent adhesion to concrete surface and excellent acid resistance. The water-soluble paint composition comprises 10-60 parts by weight of synthetic resin, 20-50 parts by weight of hydraulic extender pigment, 1-15 parts by weight of color pigment, 1-15 parts by weight of additives such as an antifoaming agent, a dispersing agent, and a plasticizer, and 5-20 parts by weight of water.
Description
Invention field
The present invention relates to a kind of water curable water paint composition.
Prior art
In this manual, the water solidity is meant in water himself solidified character.In general, in the coating, thinner is called water-borne coatings (water soluble paint) by what water constituted, thinner is called oil paint (oil paint) by what organic solvent constituted.
As the color spreading agent of water-borne coatings, use vinyl acetate between to for plastic system, styrene butadiene system or acrylic resin as water-dispersed resin, to wherein adding various additives such as pigment extender and dispersion agent or stablizer, defoamer etc., can be made into water-borne coatings.This coating is many to be used as buildings inside and outside paint application.
When forming coating, to improve the power of covering and tinting strength or electrical insulating property and be used to make the easier Achromatic color pigment of adjusting of coating thickness to be called pigment extender (extender pigment) with tinting pigment, pigment extender mainly uses silica sand, kaolin, Wingdale (CaCO in the past
3), talcum, barite (BaSO
4), aluminum oxide (Al
2O
3) etc.
Now, paint application as the buildings inside and outside, the various water-borne coatingss and the aqueous waterproofing paint of KSM5310, KSM5320 specification satisfied in use, but its form is pigment extender and various additive such as mixed calcium carbonate or talcum in the ACRYLIC EMULSION resin substantially, because being designed to exsiccant films and is attached on the cement mortar face with physical force, therefore, shortcoming is that various rerum naturas such as weathering resistance and binding property are than oil paint difference.Therefore, in this area, be necessary to develop binding property and the good water-borne coatings of weather resisteant with the cement mortar face.
Invent problem to be solved
The object of the present invention is to provide a kind of and binding property and all good water curable water paint composition of weather resisteant concrete surface.
The present inventor pours into main strength in the performance history of the water-borne coatings that at cost low and rerum natura is better than original goods and finds, if make by oneself in the future iron industrial waste a kind of, system iron blast furnace slag (slag) micropowder that shows the water outlet solidity under certain condition, silica fume (silica fume), flyash (fly ash), volcanic ash etc. contain the pigment extender of the inanimate matter powder of active silica (being also referred to as soluble silica) as water-borne coatings, the calcium hydroxide generation chemical reaction of they and concrete surface then, thereby obtain adhesion strength and the good water curable water paint of weather resistance, so far finish the present invention.
Solve the means of problem
To achieve the above object, the invention provides a kind of water curable water paint composition, it is in water-dispersed resin, use the system iron blast furnace slag powder show the water outlet solidity under certain condition, flyash, silica fume, volcanic ash etc. as pigment extender, and constitute to wherein mixing tinting pigment and additive.
The scheme that carries out an invention
Among the present invention, water-dispersed resin is meant the resin that is emulsion state in such the be dispersed in aqueous solution of vinyl acetate resin or acrylic resin.Above-mentioned water-dispersed resin is vinyl acetate resin, styrene butadiene resin, acrylic resin or water-soluble urethane resin.
Usually, in the water-borne coatings, use water-based emulsions such as Emulsion acrylic resin or vinyl acetate resin emulsion as color spreading agent, wherein, also be mixed with various additives and tinting pigment except adding as the lime carbonate of pigment extender or the talcum etc.In the employed raw material, far-reaching to the rerum natura of dry coating is many resin and pigment extender of consumption when making water-borne coatings.
The drying mode of aqueous emulsion paint is seasoning, compare with pressure curing oil paint or seasoning type oil paint, shortcoming is poor properties such as weather resistance and adhesion strength, improve fully this shortcoming commercially available adding the curable aqueous coating of solidifying agent exist the high problem of manufacturing cost.
The present invention replaces pigment extender in the past to constitute the aqueous emulsion paint composition by the pigment extender (hereinafter referred to as water solidity pigment extender) that use has this solidified character in water of pigment, provides a kind of thus and binding property and the also good water-based paint compositions of weathering resistance concrete surface.
(be also referred to as soluble silica (Soluble SiO as containing active silica in the at high temperature processed silicon compound such as volcanic ash, flyash (fly ash), silica fume
2)), this active silica has the characteristic that combines the formation calcium silicate having high strength in water with calcium hydroxide.
The solidification process of cement is known to be calcium component in the cement and water reaction, forms calcium hydroxide [Ca (OH)
2] fine gel, this calcium hydroxide gel and silicic acid component (SiO
2) combination, on one side aggegation form Calucium Silicate powder (3CaOSiO on one side
2) reticulated structure, be high strength.
Therefore, coating composition of the present invention is coated with when installing on the concrete surface, the pigment extender generation Chemical bond of using among calcium hydroxide in the concrete and the present invention, form Calucium Silicate powder and curing, therefore, coating composition of the present invention can improve the binding property with concrete surface, simultaneously, pigment extender self has the characteristic of water solidity, can infer thus and can improve weather resistance and weathering resistance.
Silica fume is the waste gas control of dust that will produce when making silicon alloy such as silicon or ferro-silicon and a kind of by product that obtains is with amorphous silica (SiO
2) be the ultramicron of particle diameter below 1 μ m of main component.
Below, specifically describe the present invention with embodiment.The present invention is not subjected to the qualification of these embodiment.
Coating is made
Employed pigment in the coating is mixed with dispersion agent and defoamer, and high-speed stirring (2000rpm, 1 hour) is mixed various additives and water-dispersed resin emulsion after it is disperseed, and stirring at low speed (500rpm, 1 hour) is then made the coating of following composition.
(embodiment 1)
1) TiO
2(pigment) 28kg
2) water 12kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1.5kg
6) silicon defoaming agent (silicone oil) 0.2kg
7) system iron blast furnace slag powder 15.8kg
8) softening agent (Eastman Chemical company product, trade(brand)name Texanol) 0.5kg
9)NH
4OH 0.25kg
10) gypsum (CaSO
42H
2O) 1kg
11) Emulsion acrylic resin 40kg
With above-mentioned 1)～10) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed (500rpm, 1 hour) makes its uniform mixing, makes coating composition 100kg of the present invention.
(comparative example 1)
1) TiO
2(pigment) 28kg
2) water 12kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1.5kg
6) silicon defoaming agent (silicone oil) 0.2kg
7) lime carbonate (powder) 16.8kg
8) softening agent (Eastman Chemical company product, trade(brand)name Texanol) 0.5kg
9)NH
4OH 0.25kg
10) Emulsion acrylic resin 40kg
With above-mentioned 1)～9) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed makes its uniform mixing, makes coating composition 100kg of the present invention.
(embodiment 2)
1) TiO
2(pigment) 5kg
2) water 20kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1.5kg
6) silicon defoaming agent (silicone oil) 0.2kg
7) system iron blast furnace slag powder 37.8kg
8) talcum 18kg
9) softening agent (Eastman Chemical company product, trade(brand)name Texanol) 0.5kg
10)NH
4OH 0.25kg
11) gypsum (CaSO
42H
2O) 1kg
12) Emulsion acrylic resin 15kg
With above-mentioned 1)～11) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed makes its uniform mixing, makes coating composition 100kg.
(comparative example 2)
1) TiO
2(pigment) 5kg
2) water 20kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1.5kg
6) silicon defoaming agent (silicone oil) 0.2kg
7) lime carbonate (CaCO
3) 38.8kg
8) talcum 18kg
9) softening agent (Eastman Chemical company product, trade(brand)name Texanol) 0.5kg
10)NH
4OH 0.25kg
11) Emulsion acrylic resin 15kg
With above-mentioned 1)～10) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed makes its uniform mixing, makes coating composition 100kg.
(embodiment 3)
1) TiO
2(pigment) 1kg
2) water 12kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1kg
6) defoamer (U.S. HS.Chem corporate system, trade(brand)name EDW) 0.5kg
7) system iron blast furnace slag powder 23kg
8) flyash 11kg
9) cyanine green (pigment) 0.4kg
10) iron oxide yellow (pigment) 0.24kg
11) yellow ultramarine (trade(brand)name DE Huang) 0.36kg
12)NH
4OH 0.25kg
13) gypsum (CaSO
42H
2O) 1kg
14) Emulsion acrylic resin 48.5kg
With above-mentioned 1)～13) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed makes its uniform mixing, makes coating composition 100kg.
(comparative example 3)
1) TiO
2(pigment) 1kg
2) water 12kg
3) tackifier (union carbide corporation system, trade(brand)name QP 52000) 0.15kg
4) dispersion agent (Rohm ﹠amp; The Hass corporate system, trade(brand)name Orotan 1288) 0.6kg
5) ethylene glycol 1kg
6) silicon defoaming agent (silicone oil) 0.5kg
7) lime carbonate (CaCO
3) 35kg
8) cyanine green (pigment) 0.4kg
9) iron oxide yellow (pigment) 0.24kg
10) yellow ultramarine (trade(brand)name DE Huang) 0.36kg
11)NH
4OH 0.25kg
12) Emulsion acrylic resin 48.5kg
With above-mentioned 1)～11) mixture high-speed stirring (2000rpm, 1 hour) it is disperseed after, to wherein adding ACRYLIC EMULSION, stirring at low speed makes its uniform mixing, makes coating composition 100kg.
The Emulsion acrylic resin that uses in the foregoing description and the comparative example is to make the following compositions copolymerization and the acrylic resin multipolymer that obtains is scattered among the water 50 weight % and makes.
-methyl methacrylate: 12 weight %
-vinyl cyanide: 5 weight %
-Butyl Acrylate Monomer: 27 weight %
-six ethyl propenoates [ethyl hexaocrylate]: 5 weight %
-vinylformic acid: 0.5 weight %
Shown in the foregoing description and comparative example, among the present invention except the inanimate matter powder that will contain active silica uses as pigment extender, the technology that can also utilize all to implement in this area.
The tackifier that use among the present invention (viscosity increasing agent), dispersion agent, silicon defoaming agent, softening agent pigment and ACRYLIC EMULSION etc. are all used in this area, and the proportion of composing of each constituent also is known in the water-borne coatings field.
The slag powder that uses in the embodiment of the invention is to be obtained by the coal material of coal power generation field by-product.
The water curable water paint of making in the foregoing description makes water solidity pigment extender replace original pigment extender, to the gypsum (CaSO that wherein adds as water cure promotor
42H
2O), can in the storage process of coating, not induce reaction thus and curing reaction takes place when the bottom with strong basicity composition such as cement mortar contacts, thereby produce the firm sticking power in bottom surface.Its result will obtain good the filming of long durability.
Can confirm that from the result of table 1 use of water solidity pigment extender makes the sticking power and the acid resistance of filming become good.
Table 1
| Embodiment 1 | Comparative example 1 | Embodiment 2 | Comparative example 2 | Embodiment 3 | Comparative example 3 | Test method | |
| Sticking power (Kgf/cm 2) | 13.5 | 7.3 | 11.5 | 6.2 | 15.4 | 8.0 | KSF-4715 |
| Acid resistance | No abnormal | Protuberance | No abnormal | Protuberance | No abnormal | Protuberance | KSM-5000 |
| Alkali resistance | No abnormal | No abnormal | No abnormal | No abnormal | No abnormal | No abnormal | KSM-5000 |
The effect of invention
Effect of the present invention is, by will iron blast furnace slag powder processed, the industrial wastes such as flyash, silica cigarette ash are as the extender pigment of water paint, can make all good water paint of cohesive and weatherability.
Claims (3)
1. water curable water paint composition, this water-based paint compositions is made of water-dispersed resin emulsion 10～60 weight parts, water solidity pigment extender 20～50 weight parts, tinting pigment 1～15 weight part, defoamer, dispersion agent and plasticiser additive 1～5 weight part and water 5～20 weight parts that contain active silica.
2. the water curable water paint composition described in the claim 1, wherein, above-mentioned water solidity pigment extender is system iron blast furnace slag powder, flyash, silica fume or volcanic ash.
3. the water curable water paint composition described in the claim 1, wherein, above-mentioned water-dispersed resin is vinyl acetate resin, styrene butadiene resin, acrylic resin or water-soluble urethane resin.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR80450/2001 | 2001-12-18 | ||
| KR10-2001-0080450A KR100453631B1 (en) | 2001-12-18 | 2001-12-18 | Composition of hydraulic setting water soluble paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1427049A CN1427049A (en) | 2003-07-02 |
| CN1235994C true CN1235994C (en) | 2006-01-11 |
Family
ID=19717157
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021035628A Expired - Fee Related CN1235994C (en) | 2001-12-18 | 2002-02-07 | Water curable water paint composition |
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| KR (1) | KR100453631B1 (en) |
| CN (1) | CN1235994C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100634909B1 (en) | 2005-03-24 | 2006-10-16 | 정시영 | Bridge waterproof composition of bridge or concrete structure and bridge waterproof method using the same |
| KR100827296B1 (en) * | 2007-10-08 | 2008-05-06 | 공주대학교 산학협력단 | Breathable Waterproof Coating with Nano Calcium Carbonate |
| KR100888826B1 (en) | 2007-11-07 | 2009-03-17 | 지에스건설 주식회사 | Silica fume coating method for manufacturing high strength concrete |
| CN102408873B (en) * | 2011-11-10 | 2014-07-30 | 亓伟 | Powder and paint for inhibiting road from freezing and preparation methods thereof |
| CN102719122B (en) * | 2012-07-03 | 2015-02-04 | 株式会社艾姆&艾姆 | Coating made of coal ashes |
| CN103666264A (en) * | 2012-09-24 | 2014-03-26 | 肖怀龙 | Wall sealant |
| CN102936441B (en) * | 2012-11-12 | 2015-08-12 | 啄木鸟漆业集团有限公司 | A kind of Anion alkali-resistant primer |
| CN104592815B (en) * | 2014-12-26 | 2017-11-21 | 三棵树涂料股份有限公司 | Alkali-resistant primer and preparation method thereof |
| CN105295498B (en) * | 2015-10-23 | 2017-09-15 | 盐城永悦新材料有限公司 | A kind of preparation method of vessel slag modified aqueous paint dispersant |
| CN105819741A (en) * | 2016-03-17 | 2016-08-03 | 李金平 | Humidity adjusting inner wall paint |
| KR101963940B1 (en) * | 2016-12-02 | 2019-08-01 | 한국페인트(주) | Eco―friendly antifouling paint composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0565427A (en) * | 1991-06-12 | 1993-03-19 | Dainippon Ink & Chem Inc | Cement-based coating composition |
| JPH0827400A (en) * | 1994-07-20 | 1996-01-30 | Nippon Cement Co Ltd | Coating material composition |
| KR19980043623A (en) * | 1996-12-04 | 1998-09-05 | 우덕창 | Composition of Ultra High Strength Hydraulic Materials |
| KR19990073370A (en) * | 1999-07-06 | 1999-10-05 | 박홍욱 | Water born inorganic coating material with power type and inorganic coating material for finishing |
-
2001
- 2001-12-18 KR KR10-2001-0080450A patent/KR100453631B1/en not_active IP Right Cessation
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| KR100453631B1 (en) | 2004-10-20 |
| KR20030050067A (en) | 2003-06-25 |
| CN1427049A (en) | 2003-07-02 |
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