CN1232867A - Phosphate-free washing powder and its preparation - Google Patents
Phosphate-free washing powder and its preparation Download PDFInfo
- Publication number
- CN1232867A CN1232867A CN 99106152 CN99106152A CN1232867A CN 1232867 A CN1232867 A CN 1232867A CN 99106152 CN99106152 CN 99106152 CN 99106152 A CN99106152 A CN 99106152A CN 1232867 A CN1232867 A CN 1232867A
- Authority
- CN
- China
- Prior art keywords
- sodium
- stir
- essence
- carboxymethyl cellulose
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 7
- 238000005406 washing Methods 0.000 title abstract description 15
- 239000000843 powder Substances 0.000 title abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 18
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 fatty acid alkyl alcohol amide Chemical class 0.000 claims abstract description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 9
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 8
- 238000011010 flushing procedure Methods 0.000 claims description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 8
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 8
- 239000003599 detergent Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 108091005804 Peptidases Proteins 0.000 abstract 1
- 229920002675 Polyoxyl Polymers 0.000 abstract 1
- 239000004365 Protease Substances 0.000 abstract 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 229940092714 benzenesulfonic acid Drugs 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 235000019794 sodium silicate Nutrition 0.000 abstract 1
- BRPNNYXZQLLLSN-UHFFFAOYSA-N sodium;dodecane Chemical compound [Na+].CCCCCCCCCCC[CH2-] BRPNNYXZQLLLSN-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical group [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 4
- 241000195493 Cryptophyta Species 0.000 description 2
- 208000003251 Pruritus Diseases 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000192700 Cyanobacteria Species 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 206010012442 Dermatitis contact Diseases 0.000 description 1
- 206010012444 Dermatitis diaper Diseases 0.000 description 1
- 208000003105 Diaper Rash Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010033554 Palmoplantar keratoderma Diseases 0.000 description 1
- 206010039796 Seborrhoeic keratosis Diseases 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003653 coastal water Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 208000010247 contact dermatitis Diseases 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000035618 desquamation Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 201000008743 palmoplantar keratosis Diseases 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- 201000003385 seborrheic keratosis Diseases 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The phosphate-free washing powder is prepared by mixing homogeneously the material components including: dodecyl sodium bensosulfonate, sodium carbonate, carboxymethyl cellulose, sodium sulfate, sodium silicate, benzene sulfonic acid, fluorescent whitening agent, alkali protease, essence, dodecyl alcohol sodium sulfate, fatty acid alkyl alcohol amide and dodecyl alcohol polyoxyl ether. The product deterges fast at normal temperature and has antiseptic effect.
Description
The invention belongs to a kind of washing composition, be specifically related to a kind of non-phosphide detergent and preparation method thereof.
Washing composition major part on the domestic market is phosphorous at present, and phosphorous washing powder not only destroys water quality but also contain carcinogens.
According to " Chinese Women's Weekly ", show what one's be at foreign board washing powder, show off detersive power how strong the time with the advertisement picture of taking the people by force, but coincidentally covered material facts, nearly all exactly joint washing powder all has phosphorus.The present washing powder of China is produced total amount per year about 2,000,000 tons, calculate with average 15% phosphate content, have every year 300000 tons of P contained compounds to be discharged in the surface water approximately, and the phosphorus of 1 gram just can make algal grown 100 grams, the authoritative department investigation shows, because of phosphorous too much, China lake nearly all is in the eutrophication state at present, Chaohu---one of outstanding five bright big freshwater lakes, because phosphorus content exceeds standard 3.4 times, cause algae to cover with full lake, smoked people smells as of rotten fish every summer; Dian Chi---the famous scenic spot of once yearning for for domestic and foreign tourists, because uncontrolled discharging phosphorus, lake water surpasses national 5 class surface water water quality standard, can't drink again; " Chi Hu "---a kind ofly occur in the coastal waters, because of the discoloured water phenomenon that phosphorus causes the explosive breeding of red planktonic organism, only 1992, China just took place 50.In the middle of the prolific algae, have a kind of blue-green algae can produce toxin, drinking this water can be carcinogenic.Obviously,, destroy water quality, produce grave danger for Chinese environmental quality because a large amount of phosphorous washess enter rivers,lakes and seas.
Owing to of the direct stimulation of high phosphorus washing powder, make many housewifves when laundry, produce the sensation of calcination pain, and make people's itch more than after the clothes of airing is put on after washing simultaneously skin.Have the expert to write articles and say: jade refers to that white wrist may be more and more far away from modern female.The trend that the tetter of a kind of being called as " domestic sort of eczema " is significantly increased.The clinician claims to ask among the doctor women most likely.Palm desquamation, blister, itch, breach is the frequently-occurring disease among the crowd, refers to seborrheic keratosis medically being called the palm, in the annual average 100,000 person-times outpatient of Guangzhou preventing and treating skin diseases institute, is no less than therefore prescription on individual diagnosis among 5% the patient.The doctor thinks that long trend is relevant with a large amount of uses of synthetic detergent in the urban life on the pilosity of this illness.Synthetic detergent also is that dermopathic stimulus is seen in feels such as contact dermatitis, infant diaper rash, palmoplantar keratoderma simultaneously.
Purpose of the present invention is exactly the deficiency that exists at above-mentioned prior art, and a kind of non-phosphide detergent and preparation method thereof is provided.
Purpose of the present invention can realize by following measure:
1, a kind of non-phosphide detergent, it is to be made by the following weight proportion raw material:
Sodium dodecylbenzene sulfonate 15-40 part
Yellow soda ash 40-80 part carboxymethyl cellulose 1-10 part
Sodium sulfate 120-180 part bubble flower alkali 110-140 part
Phenylsulfonic acid 4-35 part fluorescence white flushing agent 0.5-1 part
Sumizyme MP 0.5-4 part essence 0.3-0.5
Sodium lauryl sulfate 0-8 part fatty acid alkyl alcohol amide 0-5 part
Ethoxylated dodecyl alcohol 0-3 part.
2, the preparation method of described non-phosphide detergent:
1. place a container to stir in sodium sulfate, yellow soda ash;
2. place another container to stir Phenylsulfonic acid, fatty acid alkyl alcohol amide, ethoxylated dodecyl alcohol, carboxymethyl cellulose;
3. the material that above-mentioned steps is prepared is incorporated into together and stirs;
4. place a container to stir Sodium dodecylbenzene sulfonate, bubble flower alkali, fluorescence white flushing agent, Sumizyme MP, essence and sodium lauryl sulfate;
12 kinds of raw material mixing and stirring that 5. at last all stirred.
Advantage of the present invention:
(1) soil removability is strong than other kind under same consumption, and the oily dirt effect of especially removing underwear class neck, sleeve position is splendid.
(2) decontamination speed is fast, under the custom consumption, clothing need only be immersed in the water about 10 minutes, and the dirt of keypoint part just can come off voluntarily.
(3) in normal-temperature water, use, very convenient.
(4) low bubble, very easily rinsing.
(5) wash the back clothing glossy, soft, comfortable.
(6) without phosphorus, comply with the development trend of international articles for washing.
(7) adopt special technology to add essence and make that to wash back clothing fragrance pleasant.
(8) non-stimulated to skin, environmentally safe.
Be described in further detail below by embodiment:
Embodiment one:
Closely questioning board washing powder in a kind of the closely questioning is to be made by following materials of weight proportions:
Sodium dodecylbenzene sulfonate 32g yellow soda ash 76g
Carboxymethyl cellulose 1g sodium sulfate 141g
Bubble flower alkali 125g Phenylsulfonic acid 5g
Fluorescence white flushing agent 0.6g Sumizyme MP 0.5g
Essence 0.3g
Embodiment two:
Closely questioning board washing powder in a kind of the closely questioning is to be made by the following weight proportion raw material:
Sodium dodecylbenzene sulfonate 23g yellow soda ash 58.5g
Carboxymethyl cellulose 5g sodium sulfate 150g
Bubble flower alkali 130g Phenylsulfonic acid 25g
Fluorescence white flushing agent 0.6g Sumizyme MP 3.5g
Essence 0.4g sodium lauryl sulfate 4g
Fatty acid alkyl alcohol amide 3g ethoxylated dodecyl alcohol 1g.
Embodiment three:
Sodium dodecylbenzene sulfonate 23g yellow soda ash 60g
Carboxymethyl cellulose 5g sodium sulfate 143g
Bubble flower alkali 130g Phenylsulfonic acid 28g
Fluorescence white flushing agent 0.6g Sumizyme MP 0.5g
Essence 0.4g sodium lauryl sulfate 6g
Fatty acid alkyl alcohol amide 3.5g ethoxylated dodecyl alcohol 1g.
The preparation method of said washing powder is the same among three kinds of embodiment:
1. place a container to stir in sodium sulfate, yellow soda ash;
2. place a container to stir Phenylsulfonic acid, fatty acid alkyl alcohol amide, ethoxylated dodecyl alcohol, carboxymethyl cellulose;
3. the material that above-mentioned steps is prepared is incorporated into together and stirs;
4. place a container to stir Sodium dodecylbenzene sulfonate, bubble flower alkali, fluorescence white flushing agent, Sumizyme MP, essence and sodium lauryl sulfate;
5. 12 kinds of raw material mixing and stirring that at last all stirred washing powder.
Wherein do not add following three kinds of raw materials among the embodiment one:
Sodium lauryl sulfate, fatty acid alkyl alcohol amide and ethoxylated dodecyl alcohol.
Claims (5)
1, a kind of non-phosphide detergent is characterized in that it is to be made by the following weight proportion raw material:
Sodium dodecylbenzene sulfonate 15-40 part
Yellow soda ash 40-80 part carboxymethyl cellulose 1-10 part
Sodium sulfate 120-180 part bubble flower alkali 110-140 part
Phenylsulfonic acid 4-35 part fluorescence white flushing agent 0.5-1 part
Sumizyme MP 0.5-4 part essence 0.3-0.5
Sodium lauryl sulfate 0-8 part fatty acid alkyl alcohol amide 0-5 part
Ethoxylated dodecyl alcohol 0-3 part.
2, the preparation method of non-phosphide detergent according to claim 1 is characterized in that:
1. place a container to stir in sodium sulfate, yellow soda ash;
2. place another container to stir Phenylsulfonic acid, fatty acid alkyl alcohol amide, ethoxylated dodecyl alcohol, carboxymethyl cellulose;
3. the material that above-mentioned steps is prepared is incorporated into together and stirs;
4. place a container to stir Sodium dodecylbenzene sulfonate, bubble flower alkali, fluorescence white flushing agent, Sumizyme MP, essence and sodium lauryl sulfate;
12 kinds of raw material mixing and stirring that 5. at last all stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99106152 CN1232867A (en) | 1999-04-29 | 1999-04-29 | Phosphate-free washing powder and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99106152 CN1232867A (en) | 1999-04-29 | 1999-04-29 | Phosphate-free washing powder and its preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1232867A true CN1232867A (en) | 1999-10-27 |
Family
ID=5272282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99106152 Pending CN1232867A (en) | 1999-04-29 | 1999-04-29 | Phosphate-free washing powder and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1232867A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6995023B2 (en) | 2000-08-24 | 2006-02-07 | Bio-Rad Laboratories, Inc. | Labeling proteins with dyes that are insoluble or only sparingly soluble in water |
| CN101029281B (en) * | 2007-03-11 | 2010-12-15 | 李泽潜 | Cleaner |
| CN103113996A (en) * | 2013-01-24 | 2013-05-22 | 江苏创新日化科技有限公司 | Phosphate-free washing powder and production method thereof |
| CN105368607A (en) * | 2015-12-11 | 2016-03-02 | 天津璞誉环保科技开发有限公司 | Environment-friendly cleaning agent |
| CN105419977A (en) * | 2015-12-11 | 2016-03-23 | 天津璞誉环保科技开发有限公司 | Non-phosphate cleaning agent |
| CN111040892A (en) * | 2019-12-30 | 2020-04-21 | 北京绿伞化学股份有限公司 | Low-active low-alkalinity washing powder and preparation method thereof |
-
1999
- 1999-04-29 CN CN 99106152 patent/CN1232867A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6995023B2 (en) | 2000-08-24 | 2006-02-07 | Bio-Rad Laboratories, Inc. | Labeling proteins with dyes that are insoluble or only sparingly soluble in water |
| US7435603B2 (en) | 2000-08-24 | 2008-10-14 | Bio-Rad Laboratories, Inc. | Labeling proteins with dyes that are insoluble or only sparingly soluble in water |
| CN101029281B (en) * | 2007-03-11 | 2010-12-15 | 李泽潜 | Cleaner |
| CN103113996A (en) * | 2013-01-24 | 2013-05-22 | 江苏创新日化科技有限公司 | Phosphate-free washing powder and production method thereof |
| CN105368607A (en) * | 2015-12-11 | 2016-03-02 | 天津璞誉环保科技开发有限公司 | Environment-friendly cleaning agent |
| CN105419977A (en) * | 2015-12-11 | 2016-03-23 | 天津璞誉环保科技开发有限公司 | Non-phosphate cleaning agent |
| CN111040892A (en) * | 2019-12-30 | 2020-04-21 | 北京绿伞化学股份有限公司 | Low-active low-alkalinity washing powder and preparation method thereof |
| CN111040892B (en) * | 2019-12-30 | 2021-04-30 | 北京绿伞化学股份有限公司 | Low-active low-alkalinity washing powder and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1262264C (en) | Massage bathing salt | |
| CN1552836A (en) | Nanometer antibacterial non-phosphate washing powder | |
| CN1182786A (en) | Liquid detergent for cleaning thick dirty | |
| CN101061991A (en) | Solid bath salt and the preparing method thereof | |
| CN1232867A (en) | Phosphate-free washing powder and its preparation | |
| JP4773997B2 (en) | Fermented Makuwa Multipurpose Detergent and Method for Producing the Same | |
| CN107446732A (en) | A kind of submissive whitening laundry soap composition and preparation method thereof | |
| CN103773617A (en) | Special scrubbing solution for footgear and preparation method thereof | |
| CN1263937A (en) | Skin-protecting phosphorus-free washing powder | |
| CN103122279A (en) | Non-phosphorus low-foaming washing powder preparation method | |
| CN101240293B (en) | Bran extract and cleansing composition comprising bran extract and preparation method thereof | |
| KR102638591B1 (en) | Manufacturing method of eco-friendly kitchen detergent containing natural substances | |
| CN101514314B (en) | Transparent neutral laundry detergent containing high-concentration chelating agent and preparation method thereof | |
| CN1106253A (en) | Artificial tooth cleaning agent | |
| CN1827760A (en) | Gentle soap with saponin and its making method | |
| CN1168917A (en) | Activated sepiolite composite and method for preparing same | |
| CN102485877A (en) | Special underwear washing agent | |
| CN1919994A (en) | Green broad spectrum soap powder | |
| CN1112828A (en) | Face care cream containing extract of Chinese soft shelled turtle and snail | |
| KR20040108375A (en) | manufacture process of black mud powder is contain soap | |
| CN1208760A (en) | No environmental pollution synthetic detergent | |
| CN101045893A (en) | Negative ion washing powder | |
| CN1425387A (en) | Hydrolytic extrating method for medicinal component of pilose antler | |
| CN1153206A (en) | Composition and preparation method of widely used detergent | |
| CN1019986C (en) | Concentrated high-efficiency phosphate-free bactericidal detergent and its production process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |