CN119656089B - Oil-control fluffy shampoo composition and preparation method thereof - Google Patents
Oil-control fluffy shampoo composition and preparation method thereofInfo
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- CN119656089B CN119656089B CN202411856302.9A CN202411856302A CN119656089B CN 119656089 B CN119656089 B CN 119656089B CN 202411856302 A CN202411856302 A CN 202411856302A CN 119656089 B CN119656089 B CN 119656089B
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Abstract
本发明涉及化妆品技术领域，具体涉及一种控油蓬松洗发组合物及制备方法，所述控油蓬松洗发组合物，含有活性成分、锌盐、辛酰甘氨酸、二(氢化牛脂基)邻苯二甲酸酰胺、聚季铵盐、保湿剂、赋脂剂、B族维生素、表面活性剂和含水载体。该组合物通过科学配比多种活性成分，旨在从根本上改善头皮微生态环境，降低头皮刺激性，改善头皮健康，同时调节头皮水油平衡，促进头皮新陈代谢，从而达到控油蓬松的效果。This invention relates to the field of cosmetic technology, specifically to an oil-controlling and volumizing shampoo composition and its preparation method. The oil-controlling and volumizing shampoo composition contains active ingredients, zinc salt, capryloyl glycine, di(hydrogenated tallow-based) phthalamide, polyquaternium salt, moisturizer, emollient, B vitamins, surfactant, and an aqueous carrier. This composition, through a scientifically proportioned blend of multiple active ingredients, aims to fundamentally improve the scalp's microecological environment, reduce scalp irritation, improve scalp health, regulate the scalp's oil-water balance, and promote scalp metabolism, thereby achieving the effect of oil control and volumizing.
Description
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to an oil-control fluffy shampoo composition and a preparation method thereof.
Background
Scalp greasiness and hair collapse are hair care problems faced by many people. These problems are often caused by a number of factors such as disrupted scalp ecological balance, unbalanced oil secretion, and scalp cell dysfunction. Excessive grease secretion not only affects the beauty of the hair, but also can cause scalp itching, desquamation and other problems. Therefore, it is important to develop a shampoo composition which is effective in controlling oil and imparting a fluffy feel to the hair.
At present, the oil control hair washing products on the market are various in variety, but the effects are different. Some products may remove scalp grease by adding an effective cleanser, but long term use may break the natural barrier of the scalp, resulting in dry, sensitive scalp. Other products may use natural ingredients such as plant extracts to regulate scalp oil secretion, but the oil control effect and the bulking effect are often not ideal.
In view of the above, the invention aims to provide a novel oil-control fluffy shampoo composition and a preparation method thereof, so as to overcome the defects of the existing products.
Disclosure of Invention
The invention aims to provide an oil-control fluffy shampoo composition and a preparation method thereof, and aims to radically improve the micro-ecological environment of scalp, reduce the irritation of scalp, improve the health of scalp, and simultaneously regulate the water-oil balance of scalp and promote the metabolism of scalp by scientifically proportioning various active ingredients, so that the oil-control fluffy effect is achieved.
The oil-controlling fluffy shampoo composition comprises, by mass, 0.1% -11% of active ingredients, 0.15% -1.0% of zinc salts, 0.1% -1.0% of caprylylglycine, 0.1% -0.6% of bis (hydrogenated tallow) phthalic acid amide, 0.1% -1.6% of polyquaternary ammonium salts, 0.21% -3.2% of humectants, 0.1% -2.0% of fat-forming agents, 0.1% -1.0% of B vitamins, 10% -30% of surfactants, and the balance of water-containing carriers, wherein the water-containing carriers comprise sodium hydroxide.
Preferably, the active ingredients comprise white willow bark extract, camellia seed extract, aloe vera extract and bamboo leaf extract.
Preferably, the mass ratio of the salix alba (SalixalbaL.) bark extract, the camellia seed (Camellia oleifera Abel) extract, the Aloe vera (Aloe vera L.) extract and the Bamboo leaf (Bambusa leave) extract is (0.05-2.0): (0.1-5.0): (0.05-2.0): (0.05-2.0).
The inventor finds that the oil control and fluffiness effects and scalp health improvement effects of the shampoo composition can be improved by selecting white willow bark extract, camellia seed extract, aloe vera extract and bamboo leaf extract as active ingredients. This is probably because the four plant extracts have synergistic effect, and the phenolic compounds and flavonoid compounds in the white willow bark extract and the bamboo leaf extract have anti-inflammatory and antibacterial effects, so that scalp inflammation and bacterial growth are reduced, and a healthy microenvironment is created for the scalp. The camellia seed extract is rich in antioxidant components such as tea polyphenol and vitamin E, can nourish scalp, protect scalp cells from free radical damage, and can relieve scalp discomfort together with polysaccharide, amino acid and other components in the aloe vera extract, provide necessary nutrition and enhance scalp barrier function. The four plant extracts are compounded, so that not only can the secretion of scalp grease be reduced more effectively and the hair is enabled to be more fresh and fluffy, but also the scalp inflammation and bacterial infection can be reduced, the scalp health condition can be improved, the scalp barrier function can be enhanced, and the damage of external stimulus to the scalp can be reduced. In order to fully exert the beneficial effects of these several plant extracts, it is necessary to ensure that as much as possible of the active ingredient in the plant extract is present.
The preparation method of the four plant extracts is consistent, taking white willow bark extract as an example, the preparation method comprises the steps of cleaning white willow bark, drying, crushing, sieving with a 200-400-mesh sieve, adding water to adjust the water content to 45% -55% to obtain a fermentation substrate, adding a starter, culturing at 40-45 ℃ until the pH value is 4-4.5, taking out, dehydrating, drying to obtain a fermented product, mixing the fermented product with 90% -95% ethanol solution uniformly, performing supercritical extraction, and recovering ethanol to obtain the active ingredient.
Preferably, the starter comprises lactobacillus bulgaricus, streptococcus thermophilus, bacillus subtilis and lactobacillus casei.
The Lactobacillus bulgaricus strain is CICC 25031, the Streptococcus thermophilus strain is CICC 6038, the Bacillus subtilis strain is ATCC6633, and the Lactobacillus casei strain is CICC 20241.
Preferably, the lactobacillus bulgaricus is used for 10 6-107 CFU/g of fermentation substrate, the streptococcus thermophilus is used for 10 7-108 CFU/g of fermentation substrate, the bacillus subtilis is used for 10 7-108 CFU/g of fermentation substrate, and the lactobacillus casei is used for 10 5-106 CFU/g of fermentation substrate.
Preferably, the mass ratio of the fermentation product to the 90% -95% ethanol solution is 1 (30-40).
Preferably, the supercritical extraction is carried out under the conditions that the carbon dioxide consumption is 2-4 times of that of 90% -95% ethanol solution, the pressure is 30-40 MPa, the temperature is 35-45 ℃ and the time is 1-2 hours.
The inventor finds that when the active ingredients are prepared, the fermentation technology is matched with the supercritical extraction technology, so that the oil control and fluffing effects of the shampoo composition can be further improved, and meanwhile, the safety and the stability of the shampoo composition can be ensured. This is probably because the fermentation treatment of the plants is performed by four kinds of fermenting agents, lactobacillus bulgaricus and streptococcus thermophilus can cooperatively produce lactic acid, the pH value of the system is reduced, the generation of beneficial metabolites is promoted, bacillus subtilis can decompose complex organic matters to release nutrients, and lactobacillus casei is helpful for improving the flavor and the texture of the fermented product. The cooperation of the four fermenting agents not only accelerates the fermentation process, but also enriches the diversity and the biological activity of the fermentation products, and brings more comprehensive health benefits to the final products. The supercritical extraction treatment is carried out after fermentation, and the supercritical extraction can effectively separate and enrich target components due to the characteristics of high efficiency and environmental protection, and meanwhile, the problem of residues possibly caused by traditional solvent extraction is avoided. The combination of fermentation and supercritical extraction not only gives play to the advantages of the fermentation process in bioconversion and flavor formation, but also utilizes the high efficiency and purity of supercritical extraction, and under the synergistic effect of the two, the obtained active ingredient has higher purity and stronger biological activity, effectively retains various active substances and nutritional ingredients in the raw materials, and improves the overall quality and functional value of the product. The preparation method not only optimizes the extraction efficiency of the active ingredients, but also ensures the safety and stability of the final product, and provides powerful support for developing efficient and natural healthy products.
The zinc salt comprises 0.05 to 0.1 percent of zinc chloride, 0.05 to 0.7 percent of zinc pyrrolidone carboxylate and 0.05 to 0.2 percent of zinc gluconate according to the mass percentage of the oil-control fluffy shampoo composition.
The inventor finds that the oil control effect of the shampoo composition can be greatly improved by selecting zinc salt and octanoylglycine with specific components and combining natural active ingredients. This is probably due to the significant synergy between the several components. Zinc chloride, zinc pyrrolidone carboxylate and zinc gluconate serve as zinc salts, zinc ions can penetrate into skin, oil secretion is balanced, sebum production is reduced, and meanwhile, the zinc chloride, zinc pyrrolidone carboxylate and zinc gluconate have a certain anti-inflammatory effect, and are beneficial to alleviating skin problems caused by excessive oil. Octanoyl glycine is used as a mild and effective skin conditioner, has good antibacterial and fat-inhibiting properties, can further inhibit the growth of bacteria on the surface of the skin, and reduces excessive secretion of grease caused by bacterial activities. When the zinc salt and the natural active ingredient are compounded for use, the zinc salt controls grease secretion from the source, the octanoylglycine inhibits bacterial activity, and reduces the cause of excessive grease secretion, and the natural active ingredient provides lasting support for the oil control effect by regulating the skin state and enhancing the skin health. The compound not only improves the oil control efficiency, but also ensures the mildness and safety of the product, and meets the requirements of modern consumers on high efficiency, safety, health and skin care.
The humectant comprises 0.1-2.0% of sorbitol, 0.1-1.0% of trimethylglycine and 0.01-0.2% of arginine according to the mass percentage of the oil-control fluffy shampoo composition.
The fat-reducing agent comprises 0.05 to 1.0 percent of C12-13 alcohol lactate and 0.05 to 1.0 percent of oleamide propyl PG-dimethyl ammonium chloride phosphate according to the mass percentage of the oil-control fluffy shampoo composition.
Preferably, the acid value of the C12-13 alcohol lactate is 0.5-0.7mgKOH/g, the ester content is 70% -90%, and more preferably, the acid value of the C12-13 alcohol lactate is 0.6mgKOH/g, and the ester content is 75% -85%.
In some preferred embodiments, the C12-13 alcohol lactate is purchased from Jining Malus chemical Co., ltd.
Preferably, the pH value of the oleamide propyl PG-dimethyl ammonium chloride phosphate is 6.5-7.5, the HLB value is 17-19, and the solid content is more than or equal to 30%.
In some preferred embodiments, the oleamide propyl PG-dimethyl ammonium chloride phosphate is purchased from Shanghai Sedan Biotech Co.
The inventor finds that the scalp can be effectively moistened by selecting a specific humectant and a specific fat-imparting agent for compounding, and the problem of excessive sebum secretion caused by dry skin is remarkably reduced. This is probably because sorbitol, trimethylglycine and arginine are used as moisturizers, which not only can form a thin and durable moisturizing film on the surface of the scalp to effectively lock moisture and prevent scalp dryness, but also provide necessary moisture for the scalp, and maintain water-oil balance by adjusting the microenvironment of the scalp, thereby avoiding abnormal activity of sebaceous glands caused by water deficiency and reducing excessive secretion of sebum. And C12-13 alcohol lactate and oleamide propyl PG-dimethyl ammonium chloride phosphate are used as lipid excipients, so that the moisturizing degree and the protective force of the scalp are further improved by supplementing and strengthening the natural lipid layer of the scalp. They can form a soft and smooth lipid barrier, reduce evaporation of scalp moisture, and increase softness and smoothness of scalp, so that scalp is kept healthy and moist. The moisturizing effect not only relieves the dry feel of the scalp, but also indirectly reduces excessive sebum secretion caused by dry stimulation. Besides the effects of directly moistening and controlling oil, the compound use of the moisturizing agent and the fat-adding agent can also enhance the barrier function of the scalp, improve the resistance of the scalp to external stimulus, reduce the generation of dandruff and promote the health of the scalp. Meanwhile, the components have good skin compatibility and safety, can care the scalp mildly, and reduce sensitive or inflammatory reactions caused by chemical component stimulation.
The B vitamins comprise 50.01-0.8% of vitamin B and 30.01-0.5% of vitamin B according to the mass percentage of the oil-control fluffy shampoo composition.
The poly-quaternary ammonium salt comprises, by mass, 100.01% -0.6% of poly-quaternary ammonium salt and 70.05% -1.0% of poly-quaternary ammonium salt.
Preferably, the volatile matter of the polyquaternium-10 is less than or equal to 6 percent, the ash content is less than or equal to 3 percent, and the viscosity of the polyquaternium-10 in the water solution at normal temperature is 300-500cps when the mass concentration of the polyquaternium-10 is 2 percent.
In some preferred embodiments, the polyquaternium-10 is purchased from Shanghai Meilin Biochemical technologies Co.
Preferably, the viscosity of the polyquaternium-7 at normal temperature is 8000-15000cps, and the pH value of the polyquaternium-7 in the aqueous solution is 5-8 when the mass concentration of the polyquaternium-7 is 1%.
In some preferred embodiments, the polyquaternium-7 is purchased from Starfish environmental protection technology Inc. of Yunfloating city.
The inventors found that the use of di (hydrogenated tallow) phthalic acid amide and specific polyquaternium salts can form an elastic film on the hair surface, enhance hair elasticity and improve hair fullness. Di (hydrogenated tallow) phthalic acid amide is a cationic surfactant with good skin-friendly and wetting properties, and can form a film on the hair surface, which can not only reduce friction between hairs, but also lock water, so that the hairs are softer and smoother. The polyquaternium-10 and polyquaternium-7 are compounded to have excellent conditioning and softening effects, and can be adsorbed on the surface of the hair with negative charges to form a uniform protective film, so that the elasticity and toughness of the hair can be enhanced, and the damage of the external environment to the hair can be prevented. When the di (hydrogenated tallow) phthalic acid amide is compounded with the polyquaternium-10 and the polyquaternium-7 for use, the di (hydrogenated tallow) phthalic acid amide and the polyquaternium-7 have a synergistic effect, and the film formed by the di (hydrogenated tallow) phthalic acid amide can provide a stable substrate for the polyquaternium so as to enable the polyquaternium to be better attached to the surface of hair, and the polyquaternium further enhances the stability and uniformity of the film through the cationic property of the polyquaternium so that the film is firmer and durable. In addition, the compound can also reduce the grease secretion of the scalp, improve the microenvironment of the scalp, reduce the generation of dandruff, and increase the flexibility and glossiness of the hair, so that the hair is easier to be treated and shaped, has good skin compatibility and safety, can gently care the scalp and the hair, and reduces the sensitive or inflammatory reaction caused by the stimulation of chemical components.
The surfactant comprises 5.0% -20.0% of sodium laureth sulfate, 0.5% -5.0% of cocamidopropyl betaine, 0.5% -3.0% of disodium cocoyl amphodiacetate and 0.5% -3.0% of cocamide MEA (MEA) according to the mass percentage of the oil-control fluffy shampoo composition.
Preferably, the active matter content in the sodium laureth sulfate is more than or equal to 70%, the non-sulfated matter content is less than or equal to 2.5%, and the sodium sulfate content is less than or equal to 1.5%.
Preferably, the content of active substances in the cocamidopropyl betaine is 29% -31%, the content of free amine is less than or equal to 0.1%, and the solid content is more than or equal to 35%.
In some preferred embodiments, the sodium laureth sulfate and cocamidopropyl betaine are both available from Guangzhou co-letter chemical Co.
Preferably, the active matter content of the cocoyl disodium diacetate is 28% -32%, and the pH value of the cocoyl disodium diacetate in the aqueous solution is 4-8 when the mass concentration of the cocoyl disodium diacetate in the aqueous solution is 10%.
Preferably, the content of active substances in the cocoamide MEA is 85% -88%, and the content of free amine is less than or equal to 6%.
In some preferred embodiments, the disodium cocoyl amphodiacetate and cocamide MEA are available from Guangdong oil technologies Inc.
The water-containing carrier comprises, by mass, 0.1% -0.5% of sodium benzoate, 0.1% -1.0% of phenoxyethanol, 0.05% -0.2% of EDTA disodium, 0.1% -2.0% of sodium chloride, 0.05% -1.2% of essence, 0.01% -0.4% of sodium hydroxide and the balance of water.
The essence is not particularly limited, and includes, but is not limited to, rose essence, magnolia essence, sweet orange essence, vanilla essence, peppermint essence, and the like.
Preferably, the mass ratio of the octanoylglycine to the sodium hydroxide is 3 (1.0-1.2).
The preparation method of the oil-control fluffy shampoo composition comprises the following steps:
s1, adding octanoylglycine and sodium hydroxide into water accounting for 3-7% of the total mass of the water, stirring and neutralizing until the water is completely and uniformly dissolved to obtain a pre-prepared solution;
s2, stirring the rest water and the polyquaternium-10 until the water and the polyquaternium-10 are completely dissolved and transparent;
S3, adding a surfactant into the product obtained in the step S2, heating to 75-85 ℃, and stirring until the surfactant is completely dissolved;
s4, adding di (hydrogenated tallow) phthalic acid amide, zinc salt, humectant and fat-forming agent into the product obtained in the step S3, preserving heat at 75-85 ℃ and stirring for 25-35 min, and then cooling to below 45 ℃;
And S5, adding the pre-prepared solution, the active ingredient, the polyquaternium-7, the B vitamins and the rest components into the product obtained in the step S4, uniformly stirring, and standing to obtain the oil-control fluffy shampoo composition.
In some preferred schemes, the mass ratio of the octanoylglycine to the sodium hydroxide needs to be precisely controlled, and meanwhile, in the process of preparing the shampoo composition, partial water needs to be firstly taken and uniformly mixed with the octanoylglycine and the sodium hydroxide for standby. This is probably because octanoylglycine as a weak acidic amino acid derivative, and sodium hydroxide having a strong basicity can precisely control the pH of the shampoo composition by adjusting the mass ratio, which is directly related to the cleansing effect of the shampoo composition, the oil-controlling and bulking effects of the shampoo composition, the mildness to the scalp, and the health care of the hair. The reasonable pH value can not only optimize the performance of the shampoo composition, but also ensure the safety of the shampoo composition and avoid damage to scalp and hair caused by excessively strong alkalinity. Meanwhile, partial water, octanoylglycine and sodium hydroxide are firstly taken and uniformly mixed, so that the solubility and the dispersibility of the components in water can be improved, and incomplete dissolution or overhigh local concentration caused by direct addition into the whole formula can be prevented. In addition, the reaction rate of sodium hydroxide and octanoylglycine in the aqueous solution can be effectively controlled, and adverse reaction is avoided, so that the high quality, stability and safety of the shampoo composition are ensured.
Compared with the prior art, the invention has the advantages that:
1. The invention aims to fundamentally improve the micro-ecological environment of the scalp, reduce the irritation of the scalp, improve the health of the scalp, regulate the water-oil balance of the scalp and promote the metabolism of the scalp by scientifically proportioning a plurality of active ingredients, thereby achieving the effect of controlling the oil and fluffiness.
2. According to the invention, the white willow bark extract, the camellia seed extract, the aloe vera extract and the bamboo leaf extract are selected as active ingredients, so that the oil control and fluffiness effects and the scalp health improvement effects of the shampoo can be improved, meanwhile, the active ingredients are prepared by adopting a fermentation technology and a supercritical extraction technology, the oil control and fluffiness effects of the shampoo can be further improved, and meanwhile, the safety and stability of the shampoo can be ensured.
3. The invention selects zinc salt and octanoylglycine with specific components, and combines natural active ingredients, thereby greatly improving the oil control effect of the shampoo.
4. The invention adopts the specific humectant and the specific fat-imparting agent to compound, can effectively moisten the scalp, and remarkably reduces the problem of excessive sebum secretion caused by dry skin.
5. The invention selects the di (hydrogenated tallow) phthalic acid amide and the specific polyquaternium, which can form an elastic film on the surface of hair, improve the hair elasticity and improve the hair fullness.
6. According to the invention, by controlling the mass ratio of the octanoylglycine to the sodium hydroxide, and simultaneously taking part of water and uniformly mixing the water with the part of water for later use in the process of preparing the shampoo, the pH value of the shampoo can be accurately regulated, so that the cleaning effect of the shampoo, the oil control and bulking effects of the shampoo, the mildness of the shampoo to hair and the health care of hair are improved.
Detailed Description
The following description of the technical solutions in the embodiments of the present invention will be clear and complete, and it is obvious that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The raw materials used in the invention are all commercially available, and the invention is specific:
The Lactobacillus bulgaricus strain is CICC 25031, the Streptococcus thermophilus strain is CICC 6038, the Bacillus subtilis strain is ATCC6633, and the Lactobacillus casei strain is CICC 20241.
The acid value of the C12-13 alcohol lactate is 0.6mgKOH/g, the ester content is 75% -85%, and the C12-13 alcohol lactate is purchased from Jining Malus spectabilis chemical industry Co.
The pH value of the oleamide propyl PG-dimethyl ammonium chloride phosphate is 6.5-7.5, the HLB value is 17-19, the solid content is more than or equal to 30 percent, and the oleamide propyl PG-dimethyl ammonium chloride phosphate is purchased from Shanghai Seisakusho Biotech Co.
The volatile matter of the polyquaternium-10 is less than or equal to 6 percent, ash content is less than or equal to 3 percent, and the viscosity of the polyquaternium-10 in the water solution at normal temperature is 300-500cps when the mass concentration of the polyquaternium-10 is 2 percent, and the polyquaternium-10 is purchased from Shanghai Michelia Biochemical technology Co.
The viscosity of the polyquaternium-7 at normal temperature is 8000-15000cps, the pH value of the polyquaternium-7 in aqueous solution is 5-8 when the mass concentration of the polyquaternium-7 is 1%, and the polyquaternium-7 is purchased from Starfish environmental protection technology Co.
The active matter content in laureth sodium sulfate is more than or equal to 70%, the non-sulfated matter content is less than or equal to 2.5%, the sodium sulfate content is less than or equal to 1.5%, the active matter content in cocamidopropyl betaine is 29% -31%, the free amine content is less than or equal to 0.1%, and the solid content is more than or equal to 35%, which are all purchased from Guangzhou co-letter chemical industry Co-Ltd.
The content of active substances in the cocoyl disodium diacetate is 28% -32%, the pH value of the cocoyl disodium diacetate in the aqueous solution is 4-8 when the mass concentration of the cocoyl disodium diacetate is 10%, the content of active substances in cocoamide MEA is 85% -88%, the content of free amine is less than or equal to 6%, and the cocoyl disodium diacetate is purchased from Guangdong oil technology Co.
Bis (hydrogenated tallow) phthalic acid amide, CAS number 127733-92-0.
Example 1
The embodiment provides an oil-control fluffy shampoo composition which is prepared from the following raw materials, by mass, 6% of active ingredients, 0.68% of zinc salt, 0.6% of octanoylglycine, 0.3% of di (hydrogenated tallow) phthalic acid amide, 0.8% of poly quaternary ammonium salt, 1.6% of humectant, 1.0% of fat-forming agent, 0.7% of B vitamins, 20% of surfactant and the balance of water-containing carrier.
The active ingredients are white willow bark extract, camellia seed extract, aloe vera extract and bamboo leaf extract, and the mass ratio is 1:3:1:1.
The preparation method of the four plant extracts is consistent, taking white willow bark extract as an example, and comprises the steps of cleaning white willow bark, drying, crushing, sieving with a 300-mesh sieve, adding water to adjust the water content to 50% to obtain a fermentation substrate, adding a starter, culturing at 42 ℃ until the pH is 4.5, taking out, dehydrating, drying to obtain a fermented product, mixing the fermented product with 92% ethanol solution uniformly, performing supercritical extraction, and recovering ethanol to obtain the active ingredient white willow bark extract.
The starter is lactobacillus bulgaricus, streptococcus thermophilus, bacillus subtilis and lactobacillus casei, wherein the dosage of the lactobacillus bulgaricus is 10 6 CFU/g fermentation substrate, the dosage of the streptococcus thermophilus is 10 7 CFU/g fermentation substrate, the dosage of the bacillus subtilis is 10 8 CFU/g fermentation substrate, and the dosage of the lactobacillus casei is 10 6 CFU/g fermentation substrate.
The mass ratio of the fermented product to the 92% ethanol solution is 1:35.
The supercritical extraction condition is that the carbon dioxide consumption is 3 times of 92% ethanol solution, the pressure is 35MPa, the temperature is 40 ℃ and the time is 1.5h.
The zinc salt comprises 0.08% of zinc chloride, 0.5% of zinc pyrrolidone carboxylate and 0.1% of zinc gluconate according to the mass percentage of the oil-control fluffy shampoo composition;
The humectant comprises 1% of sorbitol, 0.5% of trimethylglycine and 0.1% of arginine;
The fatting agent is 0.5% of C12-13 alcohol lactate and 0.5% of oleamide propyl PG-dimethyl ammonium chloride phosphate;
the vitamin B is 50.4% of vitamin B and 30.3% of vitamin B;
The polyquaternary ammonium salt is 100.3 percent of polyquaternary ammonium salt and 70.5 percent of polyquaternary ammonium salt;
The surfactant is 14.0% of sodium laureth sulfate, 3.0% of cocamidopropyl betaine, 1.5% of disodium cocoyl amphodiacetate and 1.5% of cocamide MEA;
The water-containing carrier comprises 0.2% of sodium benzoate, 0.5% of phenoxyethanol, 0.1% of EDTA disodium, 1.0% of sodium chloride, 0.5% of essence and 0.2% of sodium hydroxide, and the balance of water.
The essence is rose essence.
The preparation method of the oil-control fluffy shampoo composition comprises the following steps:
S1, adding octanoylglycine and sodium hydroxide into water accounting for 5% of the total mass of the water, and stirring at a rotating speed of 400r/min for 20min to obtain a pre-prepared solution;
S2, stirring the rest water and the polyquaternium-10 for 20min at the rotating speed of 400 r/min;
S3, adding a surfactant into the product obtained in the step S2, heating to 80 ℃, and stirring for 30min at a rotating speed of 600 r/min;
S4, adding di (hydrogenated tallow) phthalic acid amide, zinc salt, humectant and fat-forming agent into the product obtained in the step S3, preserving heat, stirring at 400r/min for 30min at 80 ℃, and then cooling to below 45 ℃;
S5, adding the pre-prepared solution, the active ingredient, the polyquaternium-7, the B vitamins and the rest components into the product obtained in the step S4, stirring for 30min at the rotating speed of 400r/min, and standing to obtain the oil-control fluffy shampoo composition.
Example 2
The difference between the embodiment and the embodiment 1 is that the mass ratio of the white willow bark extract to the camellia seed extract to the aloe vera extract to the bamboo leaf extract is 2:5:1:2.
Example 3
The difference between the embodiment and the embodiment 1 is that the oil-control fluffy shampoo composition is prepared from the following raw materials, by mass, 8% of active ingredient, 0.68% of zinc salt, 0.6% of caprylylglycine, 0.6% of di (hydrogenated tallow) phthalic acid amide, 0.8% of polyquaternium, 1.6% of humectant, 1.0% of fatting agent, 0.7% of B vitamins, 20% of surfactant and the balance of water-containing carrier to 100%.
Comparative example 1
The comparison example is different from the example 1 in that the oil-control fluffy shampoo composition is prepared from, by mass, 0.68% of zinc salt, 0.6% of caprylylglycine, 0.3% of di (hydrogenated tallow) phthalic acid amide, 0.8% of polyquaternium, 1.6% of humectant, 1.0% of fat-forming agent, 0.7% of B vitamins, 20% of surfactant and the balance of water-containing carrier.
Comparative example 2
The difference between the comparative example and the example 1 is that the active ingredients are camellia seed extract, aloe vera extract and bamboo leaf extract, and the mass ratio is 3:1:1.
Comparative example 3
The comparison example is different from the example 1 in that the preparation method of the four plant extracts is the same, taking white willow bark extract as an example, the preparation method comprises the steps of cleaning white willow bark, drying, crushing, sieving with a 300-mesh sieve, reflux-extracting with 70% ethanol water solution for 3 times, each time for 1.5 hours, filtering, combining the extracts, concentrating and drying to obtain the active ingredient, wherein the mass ratio of the crushed plant to the 70% ethanol water solution is 1:30.
Comparative example 4
The difference between this comparative example and example 1 is that the starter is Streptococcus thermophilus, bacillus subtilis, lactobacillus casei. The dosage of streptococcus thermophilus is 10 7 CFU/g fermentation substrate, the dosage of bacillus subtilis is 10 8 CFU/g fermentation substrate, and the dosage of lactobacillus casei is 10 6 CFU/g fermentation substrate.
Comparative example 5
The comparison example is different from the example 1 in that the oil-control fluffy shampoo composition is prepared from the following raw materials, by mass, 6% of active ingredient, 0.6% of octanoylglycine, 0.3% of di (hydrogenated tallow) phthalic acid amide, 0.8% of polyquaternium, 1.6% of humectant, 1.0% of fat-forming agent, 0.7% of B vitamins, 20% of surfactant and the balance of water-containing carrier.
Comparative example 6
The difference between this comparative example and example 1 is that the humectant is sorbitol.
Comparative example 7
This comparative example differs from example 1 in that the fatting agent is a C12-13 alcohol lactate.
Comparative example 8
The comparison example is different from the example 1 in that the oil-control fluffy shampoo composition is prepared from the following raw materials, by mass, 6% of active ingredient, 0.68% of zinc salt, 0.6% of octanoylglycine, 0.8% of polyquaternium, 1.6% of humectant, 1.0% of fat-forming agent, 0.7% of vitamin B, 20% of surfactant and the balance of water-containing carrier.
Comparative example 9
The difference between the comparative example and the example 1 is that the water-containing carrier is sodium benzoate 0.2%, phenoxyethanol 0.5%, EDTA disodium 0.1%, sodium chloride 1.0%, essence 0.5%, sodium hydroxide 0.4% and the balance being water according to the mass percentage of the oil-control fluffy shampoo composition.
Comparative example 10
The comparison example is different from the example 1 in that the preparation method of the oil-control fluffy shampoo composition comprises the following steps:
s1, stirring water and polyquaternium-10 for 20min at a rotating speed of 400 r/min;
S2, adding a surfactant into the product obtained in the step S1, heating to 80 ℃, and stirring for 30min at a rotating speed of 600 r/min;
S3, adding di (hydrogenated tallow) phthalic acid amide, zinc salt, humectant and fat-forming agent into the product obtained in the step S2, preserving heat, stirring at 400r/min for 30min at 80 ℃, and then cooling to below 45 ℃;
s4, adding the pre-prepared solution, the active ingredient, the polyquaternium-7, the B vitamins and the rest components into the product obtained in the step S3, stirring for 30min at the rotating speed of 400r/min, and standing to obtain the oil-control fluffy shampoo composition.
Performance testing
The oil control effect of the shampoo is judged by testing the activity inhibition rate of the shampoo on the 5 alpha-reductase by referring to the method in the patent CN 117482002A, and the higher the activity inhibition rate of the shampoo on the 5 alpha-reductase is, the stronger the oil control effect is. The volume change of the hair before and after the shampoo is tested by referring to the method in the patent CN 116807953A to judge the fluffing effect, and the higher the volume change rate is, the better the fluffing effect is. The consumer use evaluation is carried out by referring to the method in the patent CN 116807953A, the fluffiness fraction and the oil control fraction are both 1-10, the higher the fraction is, the better the effect is, the higher the fluffiness is, the better the oil control is, 10 consumers are per sample, the test time is two weeks, the hair washing frequency is at least 3 days according to the personal condition, and the highest fraction and the lowest fraction are removed for average value. The results are shown in Table 1.
Table 1 measurement results
According to statistics, the oil-control fluffy shampoo composition prepared in the embodiments 1-3 has good oil-control fluffy effect. Comparative example 1 has no active ingredient added, comparative example 2 has no white willow bark extract added, comparative example 3 has no lactobacillus bulgaricus added, comparative example 5 has no zinc salt added, comparative example 6 has only sorbitol as humectant, comparative example 7 has no oleamide propyl PG-dimethyl ammonium chloride phosphate added, comparative example 8 has no bis (hydrogenated tallow) phthalic acid amide added, comparative example 9 has excessive sodium hydroxide added, comparative example 10 has no part of water mixed with octanoyl glycine and sodium hydroxide evenly when preparing the shampoo composition, and the prepared shampoo composition has poor oil control fluffiness.
While the foregoing is directed to the preferred embodiments of the present invention, it will be appreciated by those skilled in the art that various modifications and adaptations can be made without departing from the principles of the present invention, and such modifications and adaptations are intended to be comprehended within the scope of the present invention.
Claims (5)
1. The oil-control fluffy shampoo composition is characterized by comprising, by mass, 0.1% -11% of an active ingredient, 0.15% -1.0% of a zinc salt, 0.1% -1.0% of caprylylglycine, 0.1% -0.6% of bis (hydrogenated tallow) phthalic acid amide, 0.1% -1.6% of a polyquaternium, 0.21% -3.2% of a humectant, 0.1% -2.0% of a fat-forming agent, 0.1% -1.0% of a vitamin B, 10% -30% of a surfactant, and the balance of an aqueous carrier to 100%, wherein the aqueous carrier comprises sodium hydroxide, and the polyquaternium comprises, by mass, 0.01% -0.6% of a polyquaternium and 0.05% -1.0% of a polyquaternium;
The active ingredients comprise white willow bark extract, camellia seed extract, aloe vera extract and bamboo leaf extract;
the preparation method of the white willow bark extract comprises the steps of cleaning the white willow bark, drying, crushing, sieving with a 200-400 mesh sieve, adding water to adjust the water content to be 45% -55% to obtain a fermentation substrate, adding a starter, taking out when the fermentation substrate is cultured to pH of 4-4.5 at 40-45 ℃, dehydrating, drying to obtain a fermented product, uniformly mixing the fermented product with 90% -95% ethanol solution, and then performing supercritical carbon dioxide extraction, and recovering ethanol to obtain the active ingredient white willow bark extract;
the starter comprises lactobacillus bulgaricus, streptococcus thermophilus, bacillus subtilis and lactobacillus casei;
The humectant comprises 0.1-2.0% of sorbitol, 0.1-1.0% of trimethylglycine and 0.01-0.2% of arginine according to the mass percentage of the oil-control fluffy shampoo composition;
The fat agent comprises 0.05 to 1.0 percent of C12-13 alcohol lactate and 0.05 to 1.0 percent of oleamide propyl PG-dimethyl ammonium chloride phosphate according to the mass percentage of the oil control fluffy shampoo composition;
the mass ratio of the octanoylglycine to the sodium hydroxide is 3 (1.0-1.2);
The preparation method of the oil-control fluffy shampoo composition comprises the following steps:
S1, adding octanoylglycine and sodium hydroxide into water accounting for 3-7% of the total mass of the water, stirring and neutralizing until the water is completely and uniformly dissolved to obtain a pre-prepared solution;
s2, stirring the rest water and the polyquaternium-10 until the water and the polyquaternium-10 are completely dissolved and transparent;
S3, adding a surfactant into the product obtained in the step S2, heating to 75-85 ℃, and stirring until the surfactant is completely dissolved;
s4, adding di (hydrogenated tallow) phthalic acid amide, zinc salt, humectant and fat-forming agent into the product obtained in the step S3, preserving heat at 75-85 ℃ and stirring for 25-35 min, and then cooling to below 45 ℃;
And S5, adding the pre-prepared solution, the active ingredient, the polyquaternium-7, the B vitamins and the rest components into the product obtained in the step S4, uniformly stirring, and standing to obtain the oil-control fluffy shampoo composition.
2. The oil control and conditioning hair conditioning shampoo composition according to claim 1, wherein the zinc salt comprises zinc chloride 0.05% -0.1%, zinc pyrrolidone carboxylate 0.05% -0.7%, zinc gluconate 0.05% -0.2% by mass of the oil control and conditioning hair conditioning shampoo composition.
3. The oil control and conditioning hair-conditioning and conditioning shampoo composition according to claim 1, wherein the B vitamins comprise vitamin B5.01% -0.8%, vitamin B3.01% -0.5%, the surfactant comprises sodium laureth sulfate 5.0% -20.0%, cocamidopropyl betaine 0.5% -5.0%, disodium cocoyl amphodiacetate 0.5% -3.0%, and cocamide MEA 0.5% -3.0%.
4. The method of preparing an oil control and hair-relaxing shampoo composition according to claim 1, wherein the aqueous carrier comprises, by mass percent of the oil control and hair-relaxing shampoo composition, 0.1% -0.5% of sodium benzoate, 0.1% -1.0% of phenoxyethanol, 0.05% -0.2% of disodium EDTA, 0.1% -2.0% of sodium chloride, 0.05% -1.2% of essence, 0.01% -0.4% of sodium hydroxide, and the balance being water.
5. A method of preparing an oil control and leave-on shampoo composition according to any one of claims 1 to 4 comprising the steps of:
S1, adding octanoylglycine and sodium hydroxide into water accounting for 3-7% of the total mass of the water, stirring and neutralizing until the water is completely and uniformly dissolved to obtain a pre-prepared solution;
s2, stirring the rest water and the polyquaternium-10 until the water and the polyquaternium-10 are completely dissolved and transparent;
S3, adding a surfactant into the product obtained in the step S2, heating to 75-85 ℃, and stirring until the surfactant is completely dissolved;
s4, adding di (hydrogenated tallow) phthalic acid amide, zinc salt, humectant and fat-forming agent into the product obtained in the step S3, preserving heat at 75-85 ℃ and stirring for 25-35 min, and then cooling to below 45 ℃;
And S5, adding the pre-prepared solution, the active ingredient, the polyquaternium-7, the B vitamins and the rest components into the product obtained in the step S4, uniformly stirring, and standing to obtain the oil-control fluffy shampoo composition.
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| CN116807953A (en) * | 2023-08-28 | 2023-09-29 | 广州禾力生物科技有限公司 | Fluffy oil control composition, application thereof and sulfate-free shampoo |
| CN118948694A (en) * | 2024-07-26 | 2024-11-15 | 广州润友新材料有限公司 | Oil-controlling and fluffy composition and application thereof |
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| US20200375872A1 (en) * | 2019-05-31 | 2020-12-03 | L'oreal | Hair care systems and methods for delivery of customized hair care products |
| CN111991261B (en) * | 2020-08-21 | 2021-10-08 | 广州德谷个人护理用品有限公司 | Mild oil control shampoo composition suitable for sensitive scalp and preparation method thereof |
| CN113398036A (en) * | 2021-07-15 | 2021-09-17 | 忧立舒医药科技(广东)有限公司 | No-wash plant scalp hair cleaning agent and preparation method and application thereof |
| CN113712873B (en) * | 2021-09-26 | 2023-04-18 | 湖北省麦诗特生物科技有限公司 | Essence emulsion composition with acne removing and anti-inflammatory effects and preparation method thereof |
| CN114432183A (en) * | 2021-12-27 | 2022-05-06 | 彭氏(惠州)实业发展有限公司 | A kind of shampoo with fluffy effect and preparation method thereof |
| CN115887340A (en) * | 2022-12-09 | 2023-04-04 | 黑龙江隽林科技有限公司 | Pure natural pet plant hair conditioner and preparation method thereof |
| WO2024233405A1 (en) * | 2023-05-05 | 2024-11-14 | Coty Inc. | Compositions and methods comprising a lotus flower extract blend and/or constituents thereof for treating skin |
| CN119112724A (en) * | 2023-06-12 | 2024-12-13 | 泉后(广州)生物科技研究院有限公司 | A scalp oil control composition and its preparation method and application |
| CN118304203A (en) * | 2024-04-15 | 2024-07-09 | 仁和全域(上海)大健康研究院有限公司 | Oil-control fluffy anti-dandruff composition and preparation method thereof |
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| CN116807953A (en) * | 2023-08-28 | 2023-09-29 | 广州禾力生物科技有限公司 | Fluffy oil control composition, application thereof and sulfate-free shampoo |
| CN118948694A (en) * | 2024-07-26 | 2024-11-15 | 广州润友新材料有限公司 | Oil-controlling and fluffy composition and application thereof |
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